PLX

Last updated

PLX, abbreviation of Picatinny Liquid Explosive, is a liquid binary explosive. It is a mixture of 95% nitromethane (NM) along with 5% ethylene diamine (EDA) as a sensitizer. Other amine compounds can be used instead of ethylene diamine, such as triethylene tetramine, diethylenetriamine or ethanolamine, but EDA has been found to be the most effective amine additive. PLX is a fairly powerful high explosive, marginally exceeding the destructive yield of TNT.

Contents

Properties

PLX, when mixed, is a transparent liquid with a yellow-orange tint. Ethylene diamine is very volatile, requiring the contents to be sealed if any storage is intended. Generally, for safety purposes, the contents are transported separately and mixed on site. PLX is known to have a velocity of detonation (VoD) of anywhere between 6,000 and 7,000 m/s, depending on diameter. Although greatly sensitized by the addition of EDA, PLX still requires a powerful blasting cap or a small booster charge to successfully detonate.

Uses and discovery

PLX was invented during World War II by the Picatinny Arsenal in New Jersey. It was originally designed to clear minefields by being spread via plane over the targeted area or poured from a safe distance and detonated by troops on the ground.

This explosive can also be gelled through the addition of nitrocellulose, ETN, or any number of soluble nitrate esters or gelling agents. This allows for powdered metals, such as aluminum or magnesium, to be suspended in the mixture. The metal powders act as fuel, increasing heat and energy output but lowering the brisance and velocity of detonation. The result is a more sustained blast wave and a "push and heave" effect, desirable for thermobaric purposes. Trzciński[ who? ] reports that 200 grams of a mixture of NM with PMMA as gelling agent and AlMg (45:55, mean particle size = 63 microns) as fuel, in a ratio of 67.2/2.8/30 by mass, has a peak overpressure of 120 kPa 2 m from the(open air) blast site, a 1.65 TNT equivalency in peak pressure, and a 1.62 equivalency in shockwave impulse. [1] As a reference, 104 kPa is widely regarded as a pressure where 50% of eardrums fail. [2] This is still 3 - 5 times less than the pressure needed to achieve a 50% fatality rate via pulmonary injury as per the Bass/Bowen equations (standing adult, facing any direction). [3]

PLX has been implicated as one of the materials capable of being used in catastrophic terrorism, as most steel core columns can not withstand the detonation of 10 – 30 kg PLX in direct contact (explosive on bare steel). Nitromethane and its gelling agents are freely sold to the public in the US, though. Its sale to the public was banned in the EU in September 2014. [4]

It was the supposed explosive used in the film Die Hard with a Vengeance .[ citation needed ] However, the film grossly exaggerated the sensitivity of this explosive mixture.

PLX was one of the explosives used to down Korean Air Flight 858 along with C-4.

Related Research Articles

<span class="mw-page-title-main">Explosive</span> Substance that can explode

An explosive is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances.

<span class="mw-page-title-main">Nitroglycerin</span> Chemical compound

Nitroglycerin (NG), also, known as trinitroglycerin (TNG), nitro, glyceryl trinitrate (GTN), or 1,2,3-trinitroxypropane, is a dense, colorless, oily, explosive liquid most commonly produced by nitrating glycerol with white fuming nitric acid under conditions appropriate to the formation of the nitric acid ester. Chemically, the substance is an organic nitrate compound rather than a nitro compound, but the traditional name is retained. Discovered in 1847 by Ascanio Sobrero, nitroglycerin has been used as an active ingredient in the manufacture of explosives, namely dynamite, and as such it is employed in the construction, demolition, and mining industries. It is combined with nitrocellulose to form double-based smokeless powder, which has been used as a propellant in artillery and firearms since the 1880s.

<span class="mw-page-title-main">TNT</span> Impact-resistant high explosive

Trinitrotoluene, more commonly known as TNT, more specifically 2,4,6-trinitrotoluene, and by its preferred IUPAC name 2-methyl-1,3,5-trinitrobenzene, is a chemical compound with the formula C6H2(NO2)3CH3. TNT is occasionally used as a reagent in chemical synthesis, but it is best known as an explosive material with convenient handling properties. The explosive yield of TNT is considered to be the standard comparative convention of bombs and asteroid impacts. In chemistry, TNT is used to generate charge transfer salts.

<span class="mw-page-title-main">Claymore mine</span> American directional anti-personnel mine

The Claymore mine is a directional anti-personnel mine developed for the United States Armed Forces. Its inventor, Norman MacLeod, named the mine after a large medieval Scottish sword. Unlike a conventional land mine, the Claymore may be command-detonated, and directional, shooting a wide pattern of metal balls into a kill zone. The Claymore can also be activated by a booby-trap tripwire firing system for use in area denial operations.

<span class="mw-page-title-main">Pentaerythritol tetranitrate</span> Explosive chemical compound

Pentaerythritol tetranitrate (PETN), also known as PENT, pentyl, PENTA, TEN, corpent, or penthrite, is an explosive material. It is the nitrate ester of pentaerythritol, and is structurally very similar to nitroglycerin. Penta refers to the five carbon atoms of the neopentane skeleton. PETN is a very powerful explosive material with a relative effectiveness factor of 1.66. When mixed with a plasticizer, PETN forms a plastic explosive. Along with RDX it is the main ingredient of Semtex and C4.

<span class="mw-page-title-main">Bomb</span> Explosive weapon that uses exothermic reaction

A bomb is an explosive weapon that uses the exothermic reaction of an explosive material to provide an extremely sudden and violent release of energy. Detonations inflict damage principally through ground- and atmosphere-transmitted mechanical stress, the impact and penetration of pressure-driven projectiles, pressure damage, and explosion-generated effects. Bombs have been utilized since the 11th century starting in East Asia.

<span class="mw-page-title-main">ANFO</span> Explosive

ANFO ( AN-foh) (or AN/FO, for ammonium nitrate/fuel oil) is a widely used bulk industrial explosive. It consists of 94% porous prilled ammonium nitrate (NH4NO3) (AN), which acts as the oxidizing agent and absorbent for the fuel, and 6% number 2 fuel oil (FO). The use of ANFO originated in the 1950s.

Nitromethane, sometimes shortened to simply "nitro", is an organic compound with the chemical formula CH
3
NO
2
. It is the simplest organic nitro compound. It is a polar liquid commonly used as a solvent in a variety of industrial applications such as in extractions, as a reaction medium, and as a cleaning solvent. As an intermediate in organic synthesis, it is used widely in the manufacture of pesticides, explosives, fibers, and coatings. Nitromethane is used as a fuel additive in various motorsports and hobbies, e.g. Top Fuel drag racing and miniature internal combustion engines in radio control, control line and free flight model aircraft.

<span class="mw-page-title-main">Detonation</span> Explosion at supersonic velocity

Detonation is a type of combustion involving a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations propagate supersonically through shock waves with speeds in the range of 1 km/sec and differ from deflagrations which have subsonic flame speeds in the range of 1 m/sec. Detonation is an explosion of fuel-air mixture. Compared to deflagration, detonation doesn't need to have an external oxidizer. Oxidizers and fuel mix when deflagration occurs. Detonation is more destructive than deflagrations. In detonation, flame front travels through air-fuel faster than sound, while in deflagrations, flame front travels through air-fuel slower than sound

Astrolite is the trade name of a family of explosives, invented by chemist Gerald Hurst in the 1960s during his employment with the Atlas Powder Company. The Astrolite family consists of two compounds, Astrolite G and Astrolite A. Both are two-part liquid-state high explosive mixtures, composed of ammonium nitrate oxidizer and hydrazine rocket fuel. The explosives were extensively studied, manufactured, and used in many countries because of their advantages of high energy, excellent performance, and wide application. They still find some use in commercial and civil blasting applications, but have mostly been superseded by cheaper and safer compounds, largely due to the expense and exceptionally poisonous nature of the hydrazine component.

Ethylenediamine (abbreviated as en when a ligand) is the organic compound with the formula C2H4(NH2)2. This colorless liquid with an ammonia-like odor is a basic amine. It is a widely used building block in chemical synthesis, with approximately 500,000 tonnes produced in 1998. Ethylenediamine is the first member of the so-called polyethylene amines.

<span class="mw-page-title-main">Diethylenetriamine</span> Chemical compound

Diethylenetriamine (abbreviated Dien or DETA) and also known as 2,2’-Iminodi(ethylamine)) is an organic compound with the formula HN(CH2CH2NH2)2. This colourless hygroscopic liquid is soluble in water and polar organic solvents, but not simple hydrocarbons. Diethylenetriamine is structural analogue of diethylene glycol. Its chemical properties resemble those for ethylene diamine, and it has similar uses. It is a weak base and its aqueous solution is alkaline. DETA is a byproduct of the production of ethylenediamine from ethylene dichloride.

There have been many extremely large explosions, accidental and intentional, caused by modern high explosives, boiling liquid expanding vapour explosions (BLEVEs), older explosives such as gunpowder, volatile petroleum-based fuels such as gasoline, and other chemical reactions. This list contains the largest known examples, sorted by date. An unambiguous ranking in order of severity is not possible; a 1994 study by historian Jay White of 130 large explosions suggested that they need to be ranked by an overall effect of power, quantity, radius, loss of life and property destruction, but concluded that such rankings are difficult to assess.

Panclastites are a class of Sprengel explosives similar to oxyliquits. They were first suggested in 1881 by Eugène Turpin, a French chemist. They are a mixture of liquid dinitrogen tetroxide serving as oxidizer with a suitable fuel, e.g. carbon disulfide, in the 3:2 volume ratio. Archived 2008-12-01 at the Wayback Machine Other fuel being used is nitrobenzene. Possible alternative fuels are e.g. nitrotoluene, gasoline, nitromethane, or halocarbons.

<span class="mw-page-title-main">Tovex</span> Water-gel explosive

Tovex is a water-gel explosive composed of ammonium nitrate and methylammonium nitrate that has several advantages over traditional dynamite, including lower toxicity and safer manufacture, transport, and storage. It has thus almost entirely replaced dynamite. There are numerous versions ranging from shearing charges to aluminized common blasting agents. Tovex is used by 80% of international oil companies for seismic exploration.

<span class="mw-page-title-main">Methylammonium nitrate</span> Chemical compound

Methylammonium nitrate is an explosive chemical with the molecular formula CH6N2O3, alternately CH3NH3+NO3. It is the salt formed by the neutralization of methylamine with nitric acid. This substance is also known as methylamine nitrate and monomethylamine nitrate, not to be confused with methyl nitramine or monomethyl nitramine.

<span class="mw-page-title-main">Operation Sailor Hat</span> 1965 explosives test in Kahoolawe, Hawaii

Operation Sailor Hat was a series of explosives effects tests, conducted by the United States Navy Bureau of Ships under the sponsorship of the Defense Atomic Support Agency. The tests consisted of two underwater explosions at San Clemente Island, California in 1964 and three surface explosions at Kahoʻolawe, Hawaii in 1965. They were non-nuclear tests employing large quantities of conventional explosives to determine the effects of a nuclear weapon blast on naval vessels, and the first major test of this kind since Operation Crossroads in July 1946.

Explosive materials are produced in numerous physical forms for their use in mining, engineering, or military applications. The different physical forms and fabrication methods are grouped together in several use forms of explosives.

<span class="mw-page-title-main">Water gel explosive</span> Fuel sensitized explosive mixture

A water-gel explosive is a fuel sensitized explosive mixture consisting of an aqueous ammonium nitrate solution that acts as the oxidizer. Water gels that are cap-insensitive are referred to under United States safety regulations as blasting agents. Water gel explosives have a jelly-like consistency and come in sausage-like packing stapled shut on both sides.

<span class="mw-page-title-main">John Oghalai</span> American otolaryngologist

John Oghalai is an American physician and scientist. He is the Leon J. Tiber and David S. Alpert Chair in Medicine at the University of Southern California Keck School of Medicine and chair of the USC Caruso Department of Otolaryngology. Oghalai is an otolaryngologist. His research focuses on anatomical and molecular mechanisms in hearing and in ear and hearing disorders.

References

  1. Cho, Sung-Il; Gao, Simon S.; Xia, Anping; Wang, Rosalie; Salles, Felipe T.; Raphael, Patrick D.; Abaya, Homer; Wachtel, Jacqueline; Baek, Jongmin; Jacobs, David; Rasband, Matthew N.; Oghalai, John S. (2013). "Mechanisms of Hearing Loss after Blast Injury to the Ear". PLOS ONE. 8 (7): e67618. Bibcode:2013PLoSO...867618C. doi: 10.1371/journal.pone.0067618 . PMC   3698122 . PMID   23840874.
  2. Cho, Sung-Il; Gao, Simon S.; Xia, Anping; Wang, Rosalie; Salles, Felipe T.; Raphael, Patrick D.; Abaya, Homer; Wachtel, Jacqueline; Baek, Jongmin; Jacobs, David; Rasband, Matthew N.; Oghalai, John S. (2013). "Mechanisms of Hearing Loss after Blast Injury to the Ear". PLOS ONE. 8 (7): e67618. Bibcode:2013PLoSO...867618C. doi: 10.1371/journal.pone.0067618 . PMC   3698122 . PMID   23840874.
  3. "Archived copy" (PDF). Archived from the original (PDF) on 2018-05-15. Retrieved 2018-12-05.{{cite web}}: CS1 maint: archived copy as title (link)
  4. "Archived copy" (PDF). Archived from the original (PDF) on 2018-12-06. Retrieved 2018-12-05.{{cite web}}: CS1 maint: archived copy as title (link)