Paratooite-(La)

Last updated
Paratooite-(La)
Paratooite-(La)-132875.jpg
Paratooite-(La): Locality: Paratoo copper mine, Yunta, Olary Province, South Australia, Australia. Field of view 6 mm.
General
Category Carbonate mineral
Formula
(repeating unit)
(La,Sr,Ca)4CuCa(Na,Ca)2(CO3)8
IMA symbol Pto-La [1]
Strunz classification 5/B.0; 5.AD.20 (Nickel-Strunz)
Crystal system Orthorhombic
Crystal class Dipyramidal: mmm
Space group Pbam
Unit cell a = 7.2250, b = 12.7626 c = 10.0559 [Å]
Identification
Colorpale turquoise-blue to pale blue
Crystal habit blades (sheaves) intergrown to form spray-like aggregates
Cleavage {100} (possible)
Mohs scale hardness4 (probably)
Luster vitreous or pearly
Streak pale blue
Specific gravity 1.97-2.02 (measured)
Optical propertiesbiaxial negative, α = 1.605(3), β = 1.696(3), γ = 1.752(2)
Pleochroism moderate, very pale blue (X) to greenish blue (Y = Z)
2V angle 72.6 °
References [2] [3] [4]

Paratooite-(La) is a complex lanthanum copper(II) calcium sodium carbonate mineral, representing a unique elemental combination among the known minerals. It is a secondary, weathering mineral. [5] [6] [7] There is a heterovalent diadochy substitution of lanthanum by strontium and calcium; also sodium is substituted by calcium in the mineral. Its structure proved to be more difficult to describe within the initial approach. It was later shown to be a superstructure of another rare earth carbonate mineral, carbocernaite. [8] The "-(La)" suffix in the mineral's name is known as Levinson suffix. It refers to the particular element, of a group of elements (notably lanthanides), that dominates in the particular structural site. As such, the element would show major, dominant occupancy at this particular site. [9]

Related Research Articles

<span class="mw-page-title-main">Cerite</span> Silicate mineral group containing cerium

Cerite is a complex silicate mineral group containing cerium, formula (Ce,La,Ca)
9
(Mg,Fe3+
)(SiO
4
)
6
(SiO
3
OH)(OH)
3
. The cerium and lanthanum content varies with the Ce rich species and the La rich species. Analysis of a sample from the Mountain Pass carbonatite gave 35.05% Ce
2
O
3
and 30.04% La
2
O
3
.

<span class="mw-page-title-main">Mckelveyite-(Y)</span>

Mckelveyite-(Y) is a hydrated sodium, barium, yttrium, and uranium–containing carbonate mineral, with the chemical formula Ba3Na(Ca,U)Y(CO3)6·3H2O.

<span class="mw-page-title-main">Clinohedrite</span>

Clinohedrite is a rare silicate mineral. Its chemical composition is a hydrous calcium-zinc silicate; CaZn(SiO4)·H2O. It crystallizes in the monoclinic system and typically occurs as veinlets and fracture coatings. It is commonly colorless, white to pale amethyst in color. It has perfect cleavage and the crystalline habit has a brilliant luster. It has a Mohs hardness of 5.5 and a specific gravity of 3.28 - 3.33.

<span class="mw-page-title-main">Gaspéite</span> Nickel carbonate mineral

Gaspéite, a very rare nickel carbonate mineral, with the formula (Ni,Fe,Mg)CO3, is named for the place it was first described, in the Gaspé Peninsula, Québec, Canada.

<span class="mw-page-title-main">Agrellite</span>

Agrellite (NaCa2Si4O10F) is a rare triclinic inosilicate mineral with four-periodic single chains of silica tetrahedra.

<span class="mw-page-title-main">Gedrite</span>

Gedrite is a crystal belonging to the orthorhombic ferromagnesian subgroup of the amphibole supergroup of the double chain inosilicate minerals with the ideal chemical formula Mg2(Mg3Al2)(Si6Al2)O22(OH)2.

<span class="mw-page-title-main">Schröckingerite</span> Radioactive yellow uranium-containing carbonate mineral

Schröckingerite is a radioactive yellow uranium-containing carbonate mineral, hydrated sodium calcium uranyl sulfate carbonate fluoride. Schröckingerite crystallizes in the orthorhombic system, occurring as globular clusters, and fluoresces yellow-green under ultraviolet light.

<span class="mw-page-title-main">Ancylite</span> Group of hydrous strontium carbonate minerals

Ancylite is a group of hydrous strontium carbonate minerals containing cerium, lanthanum and minor amounts of other rare-earth elements. The chemical formula is Sr(Ce,La)(CO3)2(OH)·H2O with ancylite-Ce enriched in cerium and ancylite-La in lanthanum.

<span class="mw-page-title-main">Aktashite</span>

Aktashite is a rare arsenic sulfosalt mineral with formula Cu6Hg3As4S12. It is a copper mercury-bearing sulfosalt and is the only sulfosalt mineral with essential Cu and Hg yet known. It is of hydrothermal origin. It was published without approval of the IMA-CNMNC, but recognized as valid species by the IMA-CNMNC Sulfosalts Subcommittee (2008).

Znucalite or CaZn11(UO2)(CO3)3(OH)20·4(H2O) is a rare, radioactive, white to pale cream colored uranium-containing carbonate mineral, hydrated calcium zinc uranyl carbonate hydroxide. Znucalite crystallizes in the orthorhombic system, often forming aggregates or crusts, and is found as a rare secondary species in carbonate-hosted (meaning it is mined from carbonate containing formations such as limestone) polymetallic veins, and nearby oxidizing uranium veins; on dump material and coating mine walls, apparently of post-mine origin. It fluoresces yellow-green under UV light.

<span class="mw-page-title-main">Decrespignyite-(Y)</span>

Decrespignyite-(Y) is a copper yttrium rare earth carbonate chloride hydrate;

<span class="mw-page-title-main">Cornetite</span> Phosphate of copper

Cornetite is a phosphate of copper with hydroxyl, named after the geologist Jules Cornet. It was discovered in 1917.

<span class="mw-page-title-main">Zirsilite-(Ce)</span>

Zirsilite-(Ce) is a very rare mineral of the eudialyte group, with formula (Na,□)12(Ce,Na)3Ca6Mn3Zr3NbSi(Si9O27)2(Si3O9)2O(OH)3(CO3)·H2O. The original formula was extended to show the presence of cyclic silicate groups and the presence of silicon at the M4 site, according to the nomenclature of the eudialyte group.according to the nomenclature of eudialyte group. Zirsilite-(Ce) differs from carbokentbrooksite in cerium-dominance over sodium only. Both minerals are intimately associated. The only other currently known representative of the eudialyte group having rare earth elements (in particular cerium, as suggested by the "-Ce)" Levinson suffix in the name) in dominance is johnsenite-(Ce).

<span class="mw-page-title-main">Ferrokentbrooksite</span> Mineral of the eudialyte group

Ferrokentbrooksite is a moderately rare mineral of the eudialyte group, with formula Na15Ca6(Fe,Mn)3Zr3NbSi25O73(O,OH,H2O)3(Cl,F,OH)2. The original formula was extended form to show the presence of cyclic silicate groups and presence of silicon at the M4 site, according to the nomenclature of eudialyte group. As suggested by its name, it is the (ferrous) iron analogue of kentbrooksite. When compared to the latter, it is also chlorine-dominant instead of being fluorine-dominant. The original (holotype) material is also relatively enriched in rare earth elements, including cerium and yttrium.

Mogovidite is a very rare mineral of the eudialyte group, with formula Na9(Ca,Na)6Ca6(Fe3+,Fe2+)2Zr3[]Si(Si9O27)2(Si3O9)2(CO3)(OH,H2O)4. The formula given is based on the original one but extended to show the presence of cyclic silicate groups. It is similar to feklichevite, differing from it in the presence of essential vacancies and carbonate group. Another specific feature is the dominance of ferric iron - a feature shared with other eudialyte-group members, including feklichevite, fengchengite, golyshevite and ikranite. Similarly to golyshevite, it is calcium-dominant, however on three sites: M(1), N(3) and N(4). It has a molecular mass of 3,066.24 gm.

Reederite-(Y) is a rare mineral with the formula (Na,Mn,Fe)15(Y,REE)2(CO3)9(SO3F)Cl. It is the only known mineral with fluorosulfate (fluorosulfonate). "REE" in the formula stands for rare earth elements other than yttrium, that is mostly cerium, with traces of neodymium, dysprosium, lanthanum and erbium. The formula also includes a Levinson suffix "-(Y)" pointing to the dominance of yttrium at the corresponding site. Reederite-(Y) crystallizes in the hexagonal crystal system with the space group P6, rarely seen among minerals.

<span class="mw-page-title-main">Cerianite-(Ce)</span> Oxide mineral

Cerianite-(Ce) is a relatively rare oxide mineral, belonging to uraninite group with the formula (Ce,Th)O
2
. It is one of a few currently known minerals containing essential tetravalent cerium, the other examples being stetindite and dyrnaesite-(La).

Filipstadite is a very rare mineral of the spinel group, with the formula (Mn,Mg)(Sb5+0.5Fe3+0.5)O4. It is isometric, although it was previously though to be orthorhombic. When compared to a typical spinel, both the octahedral and tetrahedral sites are split due to cation ordering. Filipstadite is chemically close to melanostibite. The mineral comes from Långban, Sweden, a manganese skarn deposit famous for many rare minerals.

Monazite-(La) is a relatively rare representative of the monazite group, with lanthanum being the dominant rare earth element in its structure. As such, it is the lanthanum analogue of monazite-(Ce), monazite-(Nd), and monazite-(Sm). It is also the phosphorus analogue of gasparite-(La). The group contains simple rare earth phosphate minerals with the general formula of ATO4, where A = Ce, La, Nd, or Sm (or, rarely, Bi), and B = P or, rarely, As. The A site may also bear Ca and Th.

Monazite-(Nd) is a relatively rare representative of the monazite group, with neodymium being the dominant rare earth element in its structure. This variety of monazite is typically colored bright rose-red. It is the neodymium analogue of monazite-(Ce), monazite-(La), and monazite-(Sm). The group contains simple rare earth phosphate minerals with the general formula of ATO4, where A = Ce, La, Nd, or Sm (or, rarely, Bi), and B = P or, rarely, As. The A site may also bear Ca and Th.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Pring, A., Wallwork, K., Brugger, J., Kolitsch, U. (2006) Paratooite-(La), a new lanthanum-dominant rare-earth copper carbonate from Paratoo, South Australia. Mineralogical Magazine, 70, 131-138
  3. Mindat, Paratooite-(La), https://www.mindat.org/min-27579.html
  4. Handbook of Mineralogy, Paratooite-(La), http://www.handbookofmineralogy.org/pdfs/paratooite-(La).pdf
  5. Pring, A., Wallwork, K., Brugger, J., Kolitsch, U. (2006) Paratooite-(La), a new lanthanum-dominant rare-earth copper carbonate from Paratoo, South Australia. Mineralogical Magazine, 70, 131-138
  6. Mindat, Paratooite-(La), https://www.mindat.org/min-27579.html
  7. Handbook of Mineralogy, Paratooite-(La), http://www.handbookofmineralogy.org/pdfs/paratooite-(La).pdf
  8. Krivovichev, S.V., Panikorovskii, T.L., Zolotarev, A.A., Bocharov, V.N., Kasatkin, A.V., Škoda, R. (2019) Jahn-Teller distortion and cation ordering: The crystal structure of paratooite-(La), a superstructure of carbocernaite. Minerals, 9, 370
  9. Burke, E.A.J., Kampf, A. (2008) The use of suffixes is mineral names. Mineral Matters, in: Elements, 96; http://elementsmagazine.org/archives/e4_2/e4_2_dep_mineralmatters.pdf, visited 21.12.2019