Pesticide standard value

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Pesticide standard values are applied worldwide to control pesticide pollution, [1] since pesticides are largely applied in numerous agricultural, commercial, residential, and industrial applications. Usually, pesticide standard value is regulated in residential surface soil (i.e., pesticide soil regulatory guidance value, or RGV), [1] drinking water (i.e., pesticide drinking water maximum concentration level, or MCL), [2] foods (i.e., pesticide food maximum residue level, or MRL), [3] and other ecological sections (e.g., air, surface water, groundwater, bed sediment, or aquatic organisms). [4]

Drinking water water safe for consumption

Drinking water, also known as potable water, is water that is safe to drink or to use for food preparation. The amount of drinking water required varies. It depends on physical activity, age, health issues, and environmental conditions. Americans, on average, drink one litre of water a day and 95% drink less than three litres per day. For those who work in a hot climate, up to 16 litres a day may be required. Water is essential for life.

Groundwater pollution pollution that occurs when when pollutants are released to the ground and seep down into groundwater

Groundwater pollution occurs when pollutants are released to the ground and make their way down into groundwater. This type of water pollution can also occur naturally due to the presence of a minor and unwanted constituent, contaminant or impurity in the groundwater, in which case it is more likely referred to as contamination rather than pollution.

Stream bed channel bottom of a stream, river, or creek

A stream bed or streambed is the channel bottom of a stream or river, the physical confine of the normal water flow. The lateral confines or channel margins are known as the stream banks or river banks, during all but flood stage. Under certain conditions a river can branch from one stream bed to multiple stream beds. A flood occurs when a stream overflows its banks and flows onto its flood plain. As a general rule, the bed is the part of the channel up to the normal water line, and the banks are that part above the normal water line. However, because water flow varies, this differentiation is subject to local interpretation. Usually, the bed is kept clear of terrestrial vegetation, whereas the banks are subjected to water flow only during unusual or perhaps infrequent high water stages and therefore might support vegetation some or much of the time.

Contents

Definition

Pesticide standard values specify the maximum amount of a pollutant that may be present without prompting some form of regulatory response such as human health and ecological effects. [5] Pesticide standard values are often derived from laboratory toxicology data (i.e., animal tests), human or ecological parameters (i.e., body weight, intake rate, lifetime, etc.), and human health risk models such as USEPA and RIVM models. [6] [7] On the other hand, the European Union took a precautionary approach (in accordance with the principles of its environmental policy) before toxicological data was available and provided very strict and protective standards for all pesticides in drinking water. [8]

Pollutant substance or energy source damaging to the environment

A pollutant is a substance or energy introduced into the environment that has undesired effects, or adversely affects the usefulness of a resource. A pollutant may cause long- or short-term damage by changing the growth rate of plant or animal species, or by interfering with human amenities, comfort, health, or property values. Some pollutants are biodegradable and therefore will not persist in the environment in the long term. However, the degradation products of some pollutants are themselves polluting such as the products DDE and DDD produced from degradation of DDT.

Toxicology branch of biology, chemistry, and medicine

Toxicology is a discipline, overlapping with biology, chemistry, pharmacology, and medicine, that involves the study of the adverse effects of chemical substances on living organisms and the practice of diagnosing and treating exposures to toxins and toxicants. The relationship between dose and its effects on the exposed organism is of high significance in toxicology. Factors that influence chemical toxicity include the dosage, route of exposure, species, age, sex, and environment. Toxicologists are experts on poisons and poisoning.

Acceptable daily intake or ADI is a measure of the amount of a specific substance in food or drinking water that can be ingested (orally) on a daily basis over a lifetime without an appreciable health risk. ADIs are expressed usually in milligrams per kilograms of body weight per day.

Worldwide pesticide standard values

Up till now (November 2017), less than 30% of the worldwide nations have regulated pesticide standard values in surface residential soil, [9] [10] [11] about 50% of the total nations have provided pesticide standard values in drinking water and agricultural foods. [12] Many nations in Africa, Asia, and South America are lacking pesticide standard values for the major human and ecological exposure pathways such as soil, sediment, and water.

Pesticide standard values for many current and historical largely used pesticides such as DDT, aldrin, lindane, glyphosate, MCPA, chlorpyrifos, and 2,4-D often vary over seven, eight, or nine orders of magnitude and are log-normally distributed, which indicates that there is little agreement on the regulation of pesticide standard values among worldwide jurisdictions. [13] Additionally, many worldwide pesticide standard values are not sufficiently low to protect public health based on human health risk uncertainty bounds calculations and maximum legal contribution estimations. [14]

DDT Organochloride known for its insecticidal properties

Dichlorodiphenyltrichloroethane, commonly known as DDT, is a colorless, tasteless, and almost odorless crystalline chemical compound, an organochlorine, originally developed as an insecticide, and ultimately becoming infamous for its environmental impacts. It was first synthesized in 1874 by the Austrian chemist Othmar Zeidler. DDT's insecticidal action was discovered by the Swiss chemist Paul Hermann Müller in 1939. DDT was used in the second half of World War II to control malaria and typhus among civilians and troops. Müller was awarded the Nobel Prize in Physiology or Medicine "for his discovery of the high efficiency of DDT as a contact poison against several arthropods" in 1948.

Aldrin chemical compound

Aldrin is an organochlorine insecticide that was widely used until the 1990s, when it was banned in most countries. Aldrin is a member of the so-called "classic organochlorines" (COC) group of pesticides. COCs enjoyed a very sharp rise in popularity during and after The Second World War. Other noteworthy examples of COCs include DDT. After research showed that organochlorines can be highly toxic to the ecosystem through bioaccumulation, most were banned from use. It is a colourless solid. Before the ban, it was heavily used as a pesticide to treat seed and soil. Aldrin and related "cyclodiene" pesticides became notorious as persistent organic pollutants.

Lindane chemical compound

Lindane, also known as gamma-hexachlorocyclohexane (γ-HCH), gammaxene, Gammallin and sometimes incorrectly called benzene hexachloride (BHC), is an organochlorine chemical and an isomer of hexachlorocyclohexane that has been used both as an agricultural insecticide and as a pharmaceutical treatment for lice and scabies.

See also

Persistent organic pollutants (POPs) are organic compounds that are resistant to environmental degradation through chemical, biological, and photolytic processes. Because of their persistence, POPs bioaccumulate with potential adverse impacts on human health and the environment. The effect of POPs on human and environmental health was discussed, with intention to eliminate or severely restrict their production, by the international community at the Stockholm Convention on Persistent Organic Pollutants in 2001.

Aquatic toxicology

Aquatic toxicology is the study of the effects of manufactured chemicals and other anthropogenic and natural materials and activities on aquatic organisms at various levels of organization, from subcellular through individual organisms to communities and ecosystems. Aquatic toxicology is a multidisciplinary field which integrates toxicology, aquatic ecology and aquatic chemistry.

Regulation of pesticides in the European Union

A pesticide, also called Plant Protection Product (PPP), which is a term used in regulatory documents, consists of several different components. The active ingredient in a pesticide is called “active substance” and these active substances either consist of chemicals or micro-organisms. The aims of these active substances are to specifically take action against organisms that are harmful to plants. In other words, active substances are the active components against pests and plant diseases.

Related Research Articles

Pesticide substance used to destroy pests

Pesticides are substances that are meant to control pests, including weeds. The term pesticide includes all of the following: herbicide, insecticides nematicide, molluscicide, piscicide, avicide, rodenticide, bactericide, insect repellent, animal repellent, antimicrobial, and fungicide. The most common of these are herbicides which account for approximately 80% of all pesticide use. Most pesticides are intended to serve as plant protection products, which in general, protect plants from weeds, fungi, or insects.

Chlordane is a chemical compound and also part of a similarly named pesticide mixture resulting from synthesis. These highly chlorinated cyclodienes were classified as organic pollutants hazardous for human health. They are both resistant to degradation in the environment and in humans/animals and readily accumulate in lipids (fats) of human/animals. Exposure to these compounds has been linked to cancers and many other diseases.

Reclaimed water Converting wastewater into water that can be reused for other purposes

Reclaimed or recycled water is the process of converting wastewater into water that can be reused for other purposes. Reuse may include irrigation of gardens and agricultural fields or replenishing surface water and groundwater. Reused water may also be directed toward fulfilling certain needs in residences, businesses, and industry, and could even be treated to reach drinking water standards. This last option is called either "direct potable reuse" or "indirect potable" reuse, depending on the approach used. Colloquially, the term "toilet to tap" also refers to potable reuse.

Atrazine chemical compound

Atrazine is a herbicide of the triazine class. Atrazine is used to prevent pre- and postemergence broadleaf weeds in crops such as maize (corn) and sugarcane and on turf, such as golf courses and residential lawns. It is one of the most widely used herbicides in US and Australian agriculture. It was banned in the European Union in October 2003, when the EU found groundwater levels exceeding the limits set by regulators, and Syngenta could neither show that this could be prevented nor that these levels were safe.

Bioindicator indicator species that can be used to define the status of an environment

A bioindicator is any species or group of species whose function, population, or status can reveal the qualitative status of the environment. For example, copepods and other small water crustaceans that are present in many water bodies can be monitored for changes that may indicate a problem within their ecosystem. Bioindicators can tell us about the cumulative effects of different pollutants in the ecosystem and about how long a problem may have been present, which physical and chemical testing cannot.

Toxaphene mixture of chemicals used as insecticide

Toxaphene was an insecticide used primarily for cotton in the southern United States during the late 1960s and 1970s. Toxaphene is a mixture of over 670 different chemicals and is produced by reacting chlorine gas with camphene. It can be most commonly found as a yellow to amber waxy solid.

Ecotoxicology is the study of the effects of toxic chemicals on biological organisms, especially at the population, community, ecosystem, and biosphere levels. Ecotoxicology is a multidisciplinary field, which integrates toxicology and ecology.

Pesticide residue refers to the pesticides that may remain on or in food after they are applied to food crops. The maximum allowable levels of these residues in foods are often stipulated by regulatory bodies in many countries. Regulations such as pre-harvest intervals also often prevent harvest of crop or livestock products if recently treated in order to allow residue concentrations to decrease over time to safe levels before harvest. Exposure of the general population to these residues most commonly occurs through consumption of treated food sources, or being in close contact to areas treated with pesticides such as farms or lawns.

Soil contamination pollution of land by human-made chemicals or other alteration

Soil contamination or soil pollution as part of land degradation is caused by the presence of xenobiotic (human-made) chemicals or other alteration in the natural soil environment. It is typically caused by industrial activity, agricultural chemicals, or improper disposal of waste. The most common chemicals involved are petroleum hydrocarbons, polynuclear aromatic hydrocarbons, solvents, pesticides, lead, and other heavy metals. Contamination is correlated with the degree of industrialization and intensity of chemical substance. The concern over soil contamination stems primarily from health risks, from direct contact with the contaminated soil, vapors from the contaminants, and from secondary contamination of water supplies within and underlying the soil. Mapping of contaminated soil sites and the resulting cleanups are time consuming and expensive tasks, requiring extensive amounts of geology, hydrology, chemistry, computer modeling skills, and GIS in Environmental Contamination, as well as an appreciation of the history of industrial chemistry.

Surface runoff The flow of excess stormwater, meltwater, or water from other sources over the Earths surface

Surface runoff is the flow of water that occurs when excess storm water, melt water, or other sources flows over the Earth's surface. This might occur because soil is saturated to full capacity, because rain arrives more quickly than soil can absorb it, or because impervious areas send their runoff to surrounding soil that cannot absorb all of it. Surface runoff is a major component of the water cycle. It is the primary agent in soil erosion by water.

Exposure assessment is a branch of environmental science and occupational hygiene that focuses on the processes that take place at the interface between the environment containing the contaminant(s) of interest and the organism(s) being considered. These are the final steps in the path to release an environmental contaminant, through transport to its effect in a biological system. It tries to measure how much of a contaminant can be absorbed by an exposed target organism, in what form, at what rate and how much of the absorbed amount is actually available to produce a biological effect. Although the same general concepts apply to other organisms, the overwhelming majority of applications of exposure assessment are concerned with human health, making it an important tool in public health.

The Pest Management Regulatory Agency (PMRA) is the Canadian government agency responsible for the regulation of pest control products in Canada under the federal authority of the Pest Control Products Act and Regulations. The agency is a branch that reports to Parliament through Health Canada. The PMRA is responsible for providing access to pest management tools while minimizing the risks to human health and the environment by “using modern evidence-based scientific approaches to pesticide regulation, in an open and transparent manner”. Their main activity areas include: new product evaluation, post market review and compliance and enforcement.

Environmental impact of pesticides

The impact of pesticides consists of the effects of pesticides on non-target species. Pesticides are chemical preparations used to kill fungal or animal pests. Over 98% of sprayed insecticides and 95% of herbicides reach a destination other than their target species, because they are sprayed or spread across entire agricultural fields. Runoff can carry pesticides into aquatic environments while wind can carry them to other fields, grazing areas, human settlements and undeveloped areas, potentially affecting other species. Other problems emerge from poor production, transport and storage practices. Over time, repeated application increases pest resistance, while its effects on other species can facilitate the pest's resurgence.

Clothianidin chemical compound

Clothianidin is an insecticide developed by Takeda Chemical Industries and Bayer AG. Similar to thiamethoxam and imidacloprid, it is a neonicotinoid. Neonicotinoids are a class of insecticides that are chemically similar to nicotine, which has been used as a pesticide since the late 1700s. Clothianidin and other neonicotinoids act on the central nervous system of insects as an agonist of acetylcholine, the neurotransmitter that stimulates nAChR, targeting the same receptor site (AChR) and activating post-synaptic acetylcholine receptors but not inhibiting AChE. Clothianidin and other neonicotinoids were developed to last longer than nicotine, which is more toxic and which breaks down too quickly in the environment. However, studies published in 2012 show that neonicotinoid dust released at planting time may persist in nearby fields for several years and be taken up into non-target plants, which are then foraged by bees and other insects.

California Department of Pesticide Regulation

The California Department of Pesticide Regulation, also known as DPR or CDPR, is one of six boards and departments of the California Environmental Protection Agency (Cal/EPA).

Water quality law

Water quality laws govern the release of pollutants into water resources, including surface water, ground water, and stored drinking water. Some water quality laws, such as drinking water regulations, may be designed solely with reference to human health. Many others, including restrictions on the alteration of the chemical, physical, radiological, and biological characteristics of water resources, may also reflect efforts to protect aquatic ecosystems more broadly. Regulatory efforts may include identifying and categorizing water pollutants, dictating acceptable pollutant concentrations in water resources, and limiting pollutant discharges from effluent sources. Regulatory areas include sewage treatment and disposal, industrial and agricultural waste water management, and control of surface runoff from construction sites and urban environments.

Romen Sova Soviet chemist

Romen Efimovich Sova, was a Soviet and Ukrainian toxicologist. Corresponding Member of the Ukrainian Ecological Academy of Sciences, Doctor of Medical Sciences.

Environmental health ethics is a field of study that combines environmental health policies and ethical consideration towards a mutually acceptable goal. Given the myriad of environmental issues facing society today a sound ethical background can be applied in an attempt to reach a compromise between conflicting interests, like anthropocentrism, global stewardship, religious values, economic development, and public health. A small sample of the scientific disciplines involved in environmental health ethics include: ecology, toxicology, epidemiology, and exposure biology.

Water in Arkansas is an important issue encompassing the conservation, protection, management, distribution and use of the water resource in the state. Arkansas contains a mixture of groundwater and surface water, with a variety of state and federal agencies responsible for the regulation of the water resource. In accordance with agency rules, state, and federal law, the state's water treatment facilities utilize engineering, chemistry, science and technology to treat raw water from the environment to potable water standards and distribute it through water mains to homes, farms, business and industrial customers. Following use, wastewater is collected in collection and conveyance systems, decentralized sewer systems or septic tanks and treated in accordance with regulations at publicly owned treatment works (POTWs) before being discharged to the environment.

References

  1. 1 2 Jennings, A. and Li, Z., 2014. Scope of the worldwide effort to regulate pesticide contamination in surface soils. Journal of environmental management, 146, pp.420-443.
  2. , USEPA-Drinking Water Contaminant Human Health Effects Information.
  3. , USEPA-Regulation of Pesticide Residues on Food
  4. Nowell, L.H. and Resek, E.A., 1994. National standards and guidelines for pesticides in water, sediment, and aquatic organisms: application to water-quality assessments. In Reviews of environmental contamination and toxicology (pp. 1-154). Springer New York
  5. Jennings, A. and Li, Z., 2014. Scope of the worldwide effort to regulate pesticide contamination in surface soils. Journal of environmental management, 146, pp.420-443
  6. , USEPA-Regional Screening Levels (RSLs) - Equations (June 2017 )
  7. , RIVM Committed to health and sustainability
  8. Li, Z. and Jennings, A., 2017. Worldwide regulations of standard values of pesticides for human health risk control: A review. International Journal of Environmental Research and Public Health, 14(7), p.826.
  9. Jennings, A. and Li, Z., 2015. Residential surface soil guidance applied worldwide to the pesticides added to the Stockholm Convention in 2009 and 2011. Journal of environmental management, 160, pp.226-240.
  10. Jennings, A. and Li, Z., 2015. Residential surface soil guidance values applied worldwide to the original 2001 Stockholm Convention POP pesticides. Journal of environmental management, 160, pp.16-29.
  11. Li, Z., 2018. Health risk characterization of maximum legal exposures for persistent organic pollutant (POP) pesticides in residential soil: An analysis. Journal of Environmental Management, 205, pp.163-173.
  12. Li, Z. and Jennings, A., 2017. Worldwide regulations of standard values of pesticides for human health risk control: A review. International Journal of Environmental Research and Public Health, 14(7), p.826.
  13. Li, Z. and Jennings, A., 2017. Worldwide regulations of standard values of pesticides for human health risk control: A review. International Journal of Environmental Research and Public Health, 14(7), p.826.
  14. Li, Z. and Jennings, A., 2017. Implied maximum dose analysis of standard values of 25 pesticides based on major human exposure pathways. AIMS Public Health, 4(4), pp.383-398.