Pesticide standard value

Last updated

Pesticide standard values are applied worldwide to control pesticide pollution, [1] since pesticides are largely applied in numerous agricultural, commercial, residential, and industrial applications. Usually, pesticide standard value is regulated in residential surface soil (i.e., pesticide soil regulatory guidance value, or RGV), [1] drinking water (i.e., pesticide drinking water maximum concentration level, or MCL), [2] foods (i.e., pesticide food maximum residue level, or MRL), [3] and other ecological sections (e.g., air, surface water, groundwater, bed sediment, or aquatic organisms). [4]

Contents

Definition

Pesticide standard values specify the maximum amount of a pollutant that may be present without prompting some form of regulatory response such as human health and ecological effects. [1] Pesticide standard values are often derived from laboratory toxicology data (i.e., animal tests), human or ecological parameters (i.e., body weight, intake rate, lifetime, etc.), and human health risk models such as USEPA and RIVM models. [5] [6] On the other hand, the European Union took a precautionary approach (in accordance with the principles of its environmental policy) before toxicological data was available and provided very strict and protective standards for all pesticides in drinking water. [7]

Worldwide pesticide standard values

Up till now (November 2017), less than 30% of the worldwide nations have regulated pesticide standard values in surface residential soil, [8] [9] [10] about 50% of the total nations have provided pesticide standard values in drinking water and agricultural foods. [7] Many nations in Africa, Asia, and South America are lacking pesticide standard values for the major human and ecological exposure pathways such as soil, sediment, and water.

Pesticide standard values for many current and historical largely used pesticides such as DDT, aldrin, lindane, glyphosate, MCPA, chlorpyrifos, and 2,4-D often vary over seven, eight, or nine orders of magnitude and are log-normally distributed, which indicates that there is little agreement on the regulation of pesticide standard values among worldwide jurisdictions. [7] Additionally, many worldwide pesticide standard values are not sufficiently low to protect public health based on human health risk uncertainty bounds calculations and maximum legal contribution estimations. [11]

See also

Related Research Articles

Chlordane, or chlordan, is an organochlorine compound that was used as a pesticide. It is a white solid. In the United States, chlordane was used for termite-treatment of approximately 30 million homes until it was banned in 1988. Chlordane was banned 10 years earlier for food crops like corn and citrus, and on lawns and domestic gardens.

<span class="mw-page-title-main">Water pollution</span> Contamination of water bodies

Water pollution is the contamination of water bodies, with a negative impact on their uses. It is usually a result of human activities. Water bodies include lakes, rivers, oceans, aquifers, reservoirs and groundwater. Water pollution results when contaminants mix with these water bodies. Contaminants can come from one of four main sources. These are sewage discharges, industrial activities, agricultural activities, and urban runoff including stormwater. Water pollution may affect either surface water or groundwater. This form of pollution can lead to many problems. One is the degradation of aquatic ecosystems. Another is spreading water-borne diseases when people use polluted water for drinking or irrigation. Water pollution also reduces the ecosystem services such as drinking water provided by the water resource.

<span class="mw-page-title-main">Lindane</span> Organochlorine chemical and an isomer of hexachlorocyclohexane

Lindane, also known as gamma-hexachlorocyclohexane (γ-HCH), gammaxene, Gammallin and benzene hexachloride (BHC), is an organochlorine chemical and an isomer of hexachlorocyclohexane that has been used both as an agricultural insecticide and as a pharmaceutical treatment for lice and scabies.

Polybrominated diphenyl ethers or PBDEs, are a class of organobromine compounds that are used as flame retardants. Like other brominated flame retardants, PBDEs have been used in a wide array of products, including building materials, electronics, furnishings, motor vehicles, airplanes, plastics, polyurethane foams, and textiles. They are structurally akin to polychlorinated diphenyl ethers (PCDEs), polychlorinated biphenyls (PCBs) and other polyhalogenated compounds, consisting of two halogenated aromatic rings. PBDEs are classified according to the average number of bromine atoms in the molecule. The life-saving benefits of fire retardants led to their popularization. Standards for mass transit vehicles continues to increase as of 2021.

<span class="mw-page-title-main">Aquatic toxicology</span> Study of manufactured products on aquatic organisms

Aquatic toxicology is the study of the effects of manufactured chemicals and other anthropogenic and natural materials and activities on aquatic organisms at various levels of organization, from subcellular through individual organisms to communities and ecosystems. Aquatic toxicology is a multidisciplinary field which integrates toxicology, aquatic ecology and aquatic chemistry.

<span class="mw-page-title-main">Atrazine</span> Herbicide

Atrazine is a chlorinated herbicide of the triazine class. It is used to prevent pre-emergence broadleaf weeds in crops such as maize (corn), soybean and sugarcane and on turf, such as golf courses and residential lawns. Atrazine's primary manufacturer is Syngenta and it is one of the most widely used herbicides in the United States, Canadian, and Australian agriculture. Its use was banned in the European Union in 2004, when the EU found groundwater levels exceeding the limits set by regulators, and Syngenta could not show that this could be prevented nor that these levels were safe.

<span class="mw-page-title-main">Toxaphene</span> Chemical compound

Toxaphene was an insecticide used primarily for cotton in the southern United States during the late 1960s and the 1970s. Toxaphene is a mixture of over 670 different chemicals and is produced by reacting chlorine gas with camphene. It can be most commonly found as a yellow to amber waxy solid.

<span class="mw-page-title-main">Soil contamination</span> Pollution of land by human-made chemicals or other alteration

Soil contamination, soil pollution, or land pollution as a part of land degradation is caused by the presence of xenobiotic (human-made) chemicals or other alteration in the natural soil environment. It is typically caused by industrial activity, agricultural chemicals or improper disposal of waste. The most common chemicals involved are petroleum hydrocarbons, polynuclear aromatic hydrocarbons, solvents, pesticides, lead, and other heavy metals. Contamination is correlated with the degree of industrialization and intensity of chemical substance. The concern over soil contamination stems primarily from health risks, from direct contact with the contaminated soil, vapour from the contaminants, or from secondary contamination of water supplies within and underlying the soil. Mapping of contaminated soil sites and the resulting clean ups are time-consuming and expensive tasks, and require expertise in geology, hydrology, chemistry, computer modelling, and GIS in Environmental Contamination, as well as an appreciation of the history of industrial chemistry.

<span class="mw-page-title-main">Surface runoff</span> Flow of excess rainwater not infiltrating in the ground over its surface

Surface runoff is the unconfined flow of water over the ground surface, in contrast to channel runoff. It occurs when excess rainwater, stormwater, meltwater, or other sources, can no longer sufficiently rapidly infiltrate in the soil. This can occur when the soil is saturated by water to its full capacity, and the rain arrives more quickly than the soil can absorb it. Surface runoff often occurs because impervious areas do not allow water to soak into the ground. Furthermore, runoff can occur either through natural or human-made processes.

Exposure assessment is a branch of environmental science and occupational hygiene that focuses on the processes that take place at the interface between the environment containing the contaminant of interest and the organism being considered. These are the final steps in the path to release an environmental contaminant, through transport to its effect in a biological system. It tries to measure how much of a contaminant can be absorbed by an exposed target organism, in what form, at what rate and how much of the absorbed amount is actually available to produce a biological effect. Although the same general concepts apply to other organisms, the overwhelming majority of applications of exposure assessment are concerned with human health, making it an important tool in public health.

<span class="mw-page-title-main">Ecotoxicity</span>

Ecotoxicity, the subject of study in the field of ecotoxicology, refers to the biological, chemical or physical stressors that affect ecosystems. Such stressors can occur in the natural environment at densities, concentrations, or levels high enough to disrupt natural biochemical and physiological behavior and interactions. This ultimately affects all living organisms that comprise an ecosystem.

<span class="mw-page-title-main">Environmental toxicology</span> Multidisciplinary field of science

Environmental toxicology is a multidisciplinary field of science concerned with the study of the harmful effects of various chemical, biological and physical agents on living organisms. Ecotoxicology is a subdiscipline of environmental toxicology concerned with studying the harmful effects of toxicants at the population and ecosystem levels.

<span class="mw-page-title-main">Clothianidin</span> Chemical compound

Clothianidin is an insecticide developed by Takeda Chemical Industries and Bayer AG. Similar to thiamethoxam and imidacloprid, it is a neonicotinoid. Neonicotinoids are a class of insecticides that are chemically similar to nicotine, which has been used as a pesticide since the late 1700s. Clothianidin and other neonicotinoids act on the central nervous system of insects as an agonist of nAChR, the same receptor as acetylcholine, the neurotransmitter that stimulates and activating post-synaptic acetylcholine receptors but not inhibiting AChE. Clothianidin and other neonicotinoids were developed to last longer than nicotine, which is more toxic and which breaks down too quickly in the environment.

<span class="mw-page-title-main">Agricultural pollution</span> Type of pollution caused by agriculture

Agricultural pollution refers to biotic and abiotic byproducts of farming practices that result in contamination or degradation of the environment and surrounding ecosystems, and/or cause injury to humans and their economic interests. The pollution may come from a variety of sources, ranging from point source water pollution to more diffuse, landscape-level causes, also known as non-point source pollution and air pollution. Once in the environment these pollutants can have both direct effects in surrounding ecosystems, i.e. killing local wildlife or contaminating drinking water, and downstream effects such as dead zones caused by agricultural runoff is concentrated in large water bodies.

<span class="mw-page-title-main">Water quality law</span>

Water quality laws govern the protection of water resources for human health and the environment. Water quality laws are legal standards or requirements governing water quality, that is, the concentrations of water pollutants in some regulated volume of water. Such standards are generally expressed as levels of a specific water pollutants that are deemed acceptable in the water volume, and are generally designed relative to the water's intended use - whether for human consumption, industrial or domestic use, recreation, or as aquatic habitat. Additionally, these laws provide regulations on the alteration of the chemical, physical, radiological, and biological characteristics of water resources. Regulatory efforts may include identifying and categorizing water pollutants, dictating acceptable pollutant concentrations in water resources, and limiting pollutant discharges from effluent sources. Regulatory areas include sewage treatment and disposal, industrial and agricultural waste water management, and control of surface runoff from construction sites and urban environments. Water quality laws provides the foundation for regulations in water standards, monitoring, required inspections and permits, and enforcement. These laws may be modified to meet current needs and priorities.

<span class="mw-page-title-main">Romen Sova</span> Soviet chemist (1938–2001)

Romen Efimovich Sova, was a Soviet and Ukrainian toxicologist. Corresponding Member of the Ukrainian Ecological Academy of Sciences, Doctor of Medical Sciences.

Persistent, bioaccumulative and toxic substances (PBTs) are a class of compounds that have high resistance to degradation from abiotic and biotic factors, high mobility in the environment and high toxicity. Because of these factors PBTs have been observed to have a high order of bioaccumulation and biomagnification, very long retention times in various media, and widespread distribution across the globe. Most PBTs in the environment are either created through industry or are unintentional byproducts.

Environmental health ethics is a field of study that combines environmental health policies and ethical consideration towards a mutually acceptable goal. Given the myriad of environmental issues facing society today a sound ethical background can be applied in an attempt to reach a compromise between conflicting interests, like anthropocentrism, global stewardship, religious values, economic development, and public health. A small sample of the scientific disciplines involved in environmental health ethics include: ecology, toxicology, epidemiology, and exposure biology.

Contaminants of emerging concern (CECs) is a term used by water quality professionals to describe pollutants that have been detected in environmental monitoring samples, that may cause ecological or human health impacts, and typically are not regulated under current environmental laws. Sources of these pollutants include agriculture, urban runoff and ordinary household products and pharmaceuticals that are disposed to sewage treatment plants and subsequently discharged to surface waters.

<span class="mw-page-title-main">Ohio River Park</span> Contaminated site in Pennsylvania, U.S.

Ohio River Park is a Superfund Site located in Neville Island, Pennsylvania. Between the 1920s-1970s, the Site was used for municipal waste, pesticide manufacturing, coke sludge disposal, cement manufacturing disposal, and pesticide waste. In 1977, Neville Land Company donated the Site to Allegheny County who started developing the Site as a community park. In 1979, Allegheny County found various hazardous contaminants on the Site. On August 30, 1990, the Site was determined to be a Superfund Site due to VOCs, SVOCs, inorganics, and pesticides being present in the surface soil, subsurface soil, surface water, river sediment, and groundwater. Soil remediation began in February 1998 and ended in September 1999. Today, Ohio River Park has the Robert Morris University Island Sports Center and Coraopolis Bridge on top of it. Additionally, benzene continues to be monitored because it is still present in the Site's groundwater.

References

  1. 1 2 3 Jennings, A. and Li, Z., 2014. Scope of the worldwide effort to regulate pesticide contamination in surface soils. Journal of environmental management, 146, pp.420-443.
  2. , USEPA-Drinking Water Contaminant Human Health Effects Information.
  3. , USEPA-Regulation of Pesticide Residues on Food
  4. Nowell, L.H. and Resek, E.A., 1994. National standards and guidelines for pesticides in water, sediment, and aquatic organisms: application to water-quality assessments. In Reviews of environmental contamination and toxicology (pp. 1-154). Springer New York
  5. , USEPA-Regional Screening Levels (RSLs) - Equations (June 2017 )
  6. , RIVM Committed to health and sustainability
  7. 1 2 3 Li, Z. and Jennings, A., 2017. Worldwide regulations of standard values of pesticides for human health risk control: A review. International Journal of Environmental Research and Public Health, 14(7), p.826.
  8. Jennings, A. and Li, Z., 2015. Residential surface soil guidance applied worldwide to the pesticides added to the Stockholm Convention in 2009 and 2011. Journal of environmental management, 160, pp.226-240.
  9. Jennings, A. and Li, Z., 2015. Residential surface soil guidance values applied worldwide to the original 2001 Stockholm Convention POP pesticides. Journal of environmental management, 160, pp.16-29.
  10. Li, Z., 2018. Health risk characterization of maximum legal exposures for persistent organic pollutant (POP) pesticides in residential soil: An analysis. Journal of Environmental Management, 205, pp.163-173.
  11. Li, Z. and Jennings, A., 2017. Implied maximum dose analysis of standard values of 25 pesticides based on major human exposure pathways. AIMS Public Health, 4(4), pp.383-398.