Related Research Articles
In electromagnetism, a dielectric is an electrical insulator that can be polarised by an applied electric field. When a dielectric material is placed in an electric field, electric charges do not flow through the material as they do in an electrical conductor, because they have no loosely bound, or free, electrons that may drift through the material, but instead they shift, only slightly, from their average equilibrium positions, causing dielectric polarisation. Because of dielectric polarisation, positive charges are displaced in the direction of the field and negative charges shift in the direction opposite to the field. This creates an internal electric field that reduces the overall field within the dielectric itself. If a dielectric is composed of weakly bonded molecules, those molecules not only become polarised, but also reorient so that their symmetry axes align to the field.
An electro-optic modulator (EOM) is an optical device in which a signal-controlled element exhibiting an electro-optic effect is used to modulate a beam of light. The modulation may be imposed on the phase, frequency, amplitude, or polarization of the beam. Modulation bandwidths extending into the gigahertz range are possible with the use of laser-controlled modulators.
In solid-state physics and solid-state chemistry, a band gap, also called a bandgap or energy gap, is an energy range in a solid where no electronic states exist. In graphs of the electronic band structure of solids, the band gap refers to the energy difference between the top of the valence band and the bottom of the conduction band in insulators and semiconductors. It is the energy required to promote an electron from the valence band to the conduction band. The resulting conduction-band electron are free to move within the crystal lattice and serve as charge carriers to conduct electric current. It is closely related to the HOMO/LUMO gap in chemistry. If the valence band is completely full and the conduction band is completely empty, then electrons cannot move within the solid because there are no available states. If the electrons are not free to move within the crystal lattice, then there is no generated current due to no net charge carrier mobility. However, if some electrons transfer from the valence band to the conduction band, then current can flow. Therefore, the band gap is a major factor determining the electrical conductivity of a solid. Substances having large band gaps are generally insulators, those with small band gaps are semiconductors, and conductors either have very small band gaps or none, because the valence and conduction bands overlap to form a continuous band.
Fused quartz, fused silica or quartz glass is a glass consisting of almost pure silica (silicon dioxide, SiO2) in amorphous (non-crystalline) form. This differs from all other commercial glasses, such as soda-lime glass, lead glass, or borosilicate glass, in which other ingredients are added which change the glasses' optical and physical properties, such as lowering the melt temperature, the spectral transmission range, or the mechanical strength. Fused quartz, therefore, has high working and melting temperatures, making it difficult to form and less desirable for most common applications, but is much stronger, more chemically resistant, and exhibits lower thermal expansion, making it more suitable for many specialized uses such as lighting and scientific applications.
The photorefractive effect is a nonlinear optical effect seen in certain crystals and other materials that respond to light by altering their refractive index. The effect can be used to store temporary, erasable holograms and is useful for holographic data storage. It can also be used to create a phase-conjugate mirror or an optical spatial soliton.
In optics, the Pockels effect, or Pockels electro-optic effect, is a directionally-dependent linear variation in the refractive index of an optical medium that occurs in response to the application of an electric field. It is named after the German physicist Friedrich Carl Alwin Pockels, who studied the effect in 1893. The non-linear counterpart, the Kerr effect, causes changes in the refractive index at a rate proportional to the square of the applied electric field. In optical media, the Pockels effect causes changes in birefringence that vary in proportion to the strength of the applied electric field.
The Kerr effect, also called the quadratic electro-optic (QEO) effect, is a change in the refractive index of a material in response to an applied electric field. The Kerr effect is distinct from the Pockels effect in that the induced index change for the Kerr effect is directly proportional to the square of the electric field instead of varying linearly with it. All materials show a Kerr effect, but certain liquids display it more strongly than others. The Kerr effect was discovered in 1875 by Scottish physicist John Kerr.
A metamaterial is a type of material engineered to have a property, typically rarely observed in naturally occurring materials, that is derived not from the properties of the base materials but from their newly designed structures. Metamaterials are usually fashioned from multiple materials, such as metals and plastics, and are usually arranged in repeating patterns, at scales that are smaller than the wavelengths of the phenomena they influence. Their precise shape, geometry, size, orientation, and arrangement give them their "smart" properties of manipulating electromagnetic, acoustic, or even seismic waves: by blocking, absorbing, enhancing, or bending waves, to achieve benefits that go beyond what is possible with conventional materials.
Multiferroics are defined as materials that exhibit more than one of the primary ferroic properties in the same phase:
Barium titanate (BTO) is an inorganic compound with chemical formula BaTiO3. It is the barium salt of metatitanic acid. Barium titanate appears white as a powder and is transparent when prepared as large crystals. It is a ferroelectric, pyroelectric, and piezoelectric ceramic material that exhibits the photorefractive effect. It is used in capacitors, electromechanical transducers and nonlinear optics.
Lithium niobate is a synthetic salt consisting of niobium, lithium, and oxygen. Its single crystals are an important material for optical waveguides, mobile phones, piezoelectric sensors, optical modulators and various other linear and non-linear optical applications. Lithium niobate is sometimes referred to by the brand name linobate.
Bismuth ferrite (BiFeO3, also commonly referred to as BFO in materials science) is an inorganic chemical compound with perovskite structure and one of the most promising multiferroic materials. The room-temperature phase of BiFeO3 is classed as rhombohedral belonging to the space group R3c. It is synthesized in bulk and thin film form and both its antiferromagnetic (G type ordering) Néel temperature (approximately 653 K) and ferroelectric Curie temperature are well above room temperature (approximately 1100K). Ferroelectric polarization occurs along the pseudocubic direction () with a magnitude of 90–95 μC/cm2.
Nonlinear photonic crystals are usually used as quasi-phase-matching materials. They can be one-dimensional, two-dimensional or three-dimensional.
A tunable metamaterial is a metamaterial with a variable response to an incident electromagnetic wave. This includes remotely controlling how an incident electromagnetic wave interacts with a metamaterial. This translates into the capability to determine whether the EM wave is transmitted, reflected, or absorbed. In general, the lattice structure of the tunable metamaterial is adjustable in real time, making it possible to reconfigure a metamaterial device during operation. It encompasses developments beyond the bandwidth limitations in left-handed materials by constructing various types of metamaterials. The ongoing research in this domain includes electromagnetic band gap metamaterials (EBG), also known as photonic band gap (PBG), and negative refractive index material (NIM).
In its most general form, the magnetoelectric effect (ME) denotes any coupling between the magnetic and the electric properties of a material. The first example of such an effect was described by Wilhelm Röntgen in 1888, who found that a dielectric material moving through an electric field would become magnetized. A material where such a coupling is intrinsically present is called a magnetoelectric.
Organic photorefractive materials are materials that exhibit a temporary change in refractive index when exposed to light. The changing refractive index causes light to change speed throughout the material and produce light and dark regions in the crystal. The buildup can be controlled to produce holographic images for use in biomedical scans and optical computing. The ease with which the chemical composition can be changed in organic materials makes the photorefractive effect more controllable.
Glass poling is the physical process through which the distribution of the electrical charges is changed. In principle, the charges are randomly distributed and no permanent electric field exists inside the glass.
A polar metal, metallic ferroelectric, or ferroelectric metal is a metal that contains an electric dipole moment. Its components have an ordered electric dipole. Such metals should be unexpected, because the charge should conduct by way of the free electrons in the metal and neutralize the polarized charge. However they do exist. Probably the first report of a polar metal was in single crystals of the cuprate superconductors YBa2Cu3O7−δ. A polarization was observed along one (001) axis by pyroelectric effect measurements, and the sign of the polarization was shown to be reversible, while its magnitude could be increased by poling with an electric field. The polarization was found to disappear in the superconducting state. The lattice distortions responsible were considered to be a result of oxygen ion displacements induced by doped charges that break inversion symmetry. The effect was utilized for fabrication of pyroelectric detectors for space applications, having the advantage of large pyroelectric coefficient and low intrinsic resistance. Another substance family that can produce a polar metal is the nickelate perovskites. One example interpreted to show polar metallic behavior is lanthanum nickelate, LaNiO3. A thin film of LaNiO3 grown on the (111) crystal face of lanthanum aluminate, (LaAlO3) was interpreted to be both conductor and a polar material at room temperature. The resistivity of this system, however, shows an upturn with decreasing temperature, hence does not strictly adhere to the definition of a metal. Also, when grown 3 or 4 unit cells thick (1-2 nm) on the (100) crystal face of LaAlO3, the LaNiO3 can be a polar insulator or polar metal depending on the atomic termination of the surface. Lithium osmate, LiOsO3 also undergoes a ferrorelectric transition when it is cooled below 140K. The point group changes from R3c to R3c losing its centrosymmetry. At room temperature and below, lithium osmate is an electric conductor, in single crystal, polycrystalline or powder forms, and the ferroelectric form only appears below 140K. Above 140K the material behaves like a normal metal. Artificial two-dimensional polar metal by charge transfer to a ferroelectric insulator has been realized in LaAlO3/Ba0.8Sr0.2TiO3/SrTiO3 complex oxide heterostructures.
Charge modulation spectroscopy is an electro-optical spectroscopy technique tool. It is used to study the charge carrier behavior of organic field-effect transistors. It measures the charge introduced optical transmission variation by directly probing the accumulation charge at the burning interface of semiconductor and dielectric layer where the conduction channel forms.
Electroreflectance is the change of reflectivity of a solid due to the influence of an electric field close to, or at the interface of the solid with a liquid. The change in reflectivity is most noticeable at very specific ranges of photon energy, corresponding to the band gaps at critical points of the Brillouin zone.
References
References discussing techniques described in this article
- Müller, Manfred; Soergel, Elisabeth; Buse, Karsten (2003). "Influence of ultraviolet illumination on the poling characteristics of lithium niobate crystals" (PDF). Applied Physics Letters. 83 (9). AIP Publishing: 1824–1826. Bibcode:2003ApPhL..83.1824M. doi:10.1063/1.1606504. ISSN 0003-6951. S2CID 118643463. Archived from the original on 2011-07-16.
- Kapphan, S. E.; Kislova, I.; Wierschem, M.; Lindemann, T.; Gao, M.; Pankrath, R.; Vikhnin, V. S.; Kutsenko, A. B. (2003). "Light-Induced Polaronic Absorption at Low Temperature in Pure and (Fe, Ce, Cr) Doped SrxBa1−xNb2O6 or Ba1−xCaxTiO3 Crystals and Photodissociation of Vis Centers Into Small Polarons" (PDF). Radiation Effects and Defects in Solids. 158 (1–6). Informa UK Limited: 357–362. Bibcode:2003REDS..158..357K. doi:10.1080/1042015021000052656. ISSN 1042-0150. S2CID 95403481. Archived from the original (PDF) on 2012-02-04.
References describing related techniques
- Grachev, Alexander I.; Kamshilin, Alexei A. (2005). "Electric polarization induced by optical orientation of dipolar centers in non-polar piezoelectrics". Optics Express. 13 (21). The Optical Society: 8565–8570. Bibcode:2005OExpr..13.8565G. doi: 10.1364/opex.13.008565 . ISSN 1094-4087. PMID 19498886.
- Anna Fragemann (2005). Optical Parametric Amplification with Periodically Poled KTiOPO4 (doctoral). Stockholm, Sweden: Department of Physics, Royal Institute of Technology.
- Sangalli, P.; Giulotto, E.; Rollandi, L.; Calvi, P.; Camagni, P.; Samoggia, G. (1998-03-15). "Photoinduced electronic transport in K1−xLixTaO3". Physical Review B. 57 (11). American Physical Society (APS): 6231–6234. Bibcode:1998PhRvB..57.6231S. doi:10.1103/physrevb.57.6231. ISSN 0163-1829.
Other articles about ferroelectric data storage
- "Tiny Bubbles in Nanofilms",
- Bo-Kuai Lai, Inna Ponomareva, Ivan Naumov, Igor Kornev, Huaxiang Fu, Laurent Bellaiche, and Greg Salamo, press release, University of Arkansas, 16 Mar. 2006