Red rot is a degradation process found in vegetable-tanned leather. [1]
Red rot is caused by prolonged storage or exposure to high relative humidity, environmental pollution, and high temperature. In particular, red rot occurs at pH values of 4.2 to 4.5. Sulfur dioxide converts to sulfurous acid which forms hydrogen peroxide. The peroxide combines with residual tannins in the leather to oxidize proteins, creating ammonium sulfate and ammonium bisulfate. [2]
Red rot is also caused by problems in the tanning or in the bookbinding. In the tanning examples are: sulfuric acid residue, use of contaminated water and incomplete tanning. The bookbinding process can cause red rot when acids and bases are used when coloring the leather. [3]
The decay manifests as a characteristic powdering of the leather's surface, along with structural weakness through loss, delamination, and a felt-like consistency.
The damage caused by red rot is irreversible. However, its spread, if caused by environmental factors, may be retarded by an application of a consolidant (such as Klucel G) coated with a sealer (such as Renaissance Wax). [4]
The progress of red rot can be stopped or slowed with a treatment of aluminium alkoxide solution, which increases the pH value and becomes (in the presence of water) a buffering inorganic aluminium salt in the leather. [5]
Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal.
In organic chemistry, ethers are a class of compounds that contain an ether group—an oxygen atom connected to two alkyl or aryl groups. They have the general formula R−O−R′, where R and R′ represent the alkyl or aryl groups. Ethers can again be classified into two varieties: if the alkyl or aryl groups are the same on both sides of the oxygen atom, then it is a simple or symmetrical ether, whereas if they are different, the ethers are called mixed or unsymmetrical ethers. A typical example of the first group is the solvent and anaesthetic diethyl ether, commonly referred to simply as "ether". Ethers are common in organic chemistry and even more prevalent in biochemistry, as they are common linkages in carbohydrates and lignin.
Leather is a strong, flexible and durable material obtained from the tanning, or chemical treatment, of animal skins and hides to prevent decay. The most common leathers come from cattle, sheep, goats, equine animals, buffalo, pigs and hogs, and aquatic animals such as seals and alligators.
Sulfuric acid or sulphuric acid, known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formula H2SO4. It is a colorless, odorless and viscous liquid that is miscible with water.
Perchloric acid is a mineral acid with the formula HClO4. Usually found as an aqueous solution, this colorless compound is a stronger acid than sulfuric acid, nitric acid and hydrochloric acid. It is a powerful oxidizer when hot, but aqueous solutions up to approximately 70% by weight at room temperature are generally safe, only showing strong acid features and no oxidizing properties. Perchloric acid is useful for preparing perchlorate salts, especially ammonium perchlorate, an important rocket fuel component. Perchloric acid is dangerously corrosive and readily forms potentially explosive mixtures.
An alum is a type of chemical compound, usually a hydrated double sulfate salt of aluminium with the general formula XAl(SO
4)
2·12 H
2O, where X is a monovalent cation such as potassium or ammonium. By itself, "alum" often refers to potassium alum, with the formula KAl(SO
4)
2·12 H
2O. Other alums are named after the monovalent ion, such as sodium alum and ammonium alum.
Soil pH is a measure of the acidity or basicity (alkalinity) of a soil. Soil pH is a key characteristic that can be used to make informative analysis both qualitative and quantitatively regarding soil characteristics. pH is defined as the negative logarithm (base 10) of the activity of hydronium ions in a solution. In soils, it is measured in a slurry of soil mixed with water, and normally falls between 3 and 10, with 7 being neutral. Acid soils have a pH below 7 and alkaline soils have a pH above 7. Ultra-acidic soils and very strongly alkaline soils are rare.
Tanning is the process of treating skins and hides of animals to produce leather. A tannery is the place where the skins are processed.
Potassium alum, potash alum, or potassium aluminium sulfate is a chemical compound: the double sulfate of potassium and aluminium, with chemical formula KAl(SO4)2. It is commonly encountered as the dodecahydrate, KAl(SO4)2·12H2O. It crystallizes in an octahedral structure in neutral solution and cubic structure in an alkali solution with space group P a −3 and lattice parameter of 12.18 Å. The compound is the most important member of the generic class of compounds called alums, and is often called simply alum.
Aluminium sulfate is a salt with the formula Al2(SO4)3. It is soluble in water and is mainly used as a coagulating agent (promoting particle collision by neutralizing charge) in the purification of drinking water and wastewater treatment plants, and also in paper manufacturing.
A persulfate is a compound containing the anions SO2−
5 or S
2O2−
8. The anion SO2−
5 contains one peroxide group per sulfur center, whereas in S
2O2−
8, the peroxide group bridges the sulfur atoms. In both cases, sulfur adopts the normal tetrahedral geometry typical for the S(VI) oxidation state. These salts are strong oxidizers.
Sodium sulfide is a chemical compound with the formula Na2S, or more commonly its hydrate Na2S·9H2O. Both the anhydrous and the hydrated salts in pure crystalline form are colorless solids, although technical grades of sodium sulfide are generally yellow to brick red owing to the presence of polysulfides and commonly supplied as a crystalline mass, in flake form, or as a fused solid. They are water-soluble, giving strongly alkaline solutions. When exposed to moist air, Na2S and its hydrates emit hydrogen sulfide, an extremely toxic, flammable and corrosive gas which smells like rotten eggs.
Ammonium aluminium sulfate, also known as ammonium alum or just alum (though there are many different substances also called "alum"), is a white crystalline double sulfate usually encountered as the dodecahydrate, formula (NH4)Al(SO4)2·12H2O. It is used in small amounts in a variety of niche applications. The dodecahydrate occurs naturally as the rare mineral tschermigite.
Bleach is the generic name for any chemical product that is used industrially or domestically to remove color (whitening) from a fabric or fiber or to clean or to remove stains in a process called bleaching. It often refers specifically to a dilute solution of sodium hypochlorite, also called "liquid bleach".
Chromium(III) sulfate usually refers to the inorganic compounds with the formula Cr2(SO4)3.x(H2O), where x can range from 0 to 18. Additionally, ill-defined but commercially important "basic chromium sulfates" are known. These salts are usually either violet or green solids that are soluble in water. It is commonly used in tanning leather.
The leather manufacturing process is divided into three sub-processes: preparatory stages, tanning and crusting. All true leathers will undergo these sub-processes. A further sub-process, surface coating may be added into the sequence. The list of operations that leathers undergo vary with the type of leather.
Ammonium iron(III) sulfate, NH4Fe(SO4)2·12 H2O, or NH4[Fe(H2O)6](SO4)2·6 H2O, also known as ferric ammonium sulfate (FAS) or iron alum, is a double salt in the class of alums, which consists of compounds with the general formula AB(SO4)2 · 12 H2O. It has the appearance of weakly violet, octahedrical crystals. There has been some discussion regarding the origin of the crystals' colour, with some ascribing it to impurities in the compound, and others claiming it to be a property of the crystal itself.
Isopropyl alcohol is a colorless, flammable organic compound with a pungent alcoholic odor. As an isopropyl group linked to a hydroxyl group it is the simplest example of a secondary alcohol, where the alcohol carbon atom is attached to two other carbon atoms. It is a structural isomer of propan-1-ol and ethyl methyl ether.
The conservation and restoration of books, manuscripts, documents and ephemera is an activity dedicated to extending the life of items of historical and personal value made primarily from paper, parchment, and leather. When applied to cultural heritage, conservation activities are generally undertaken by a conservator. The primary goal of conservation is to extend the lifespan of the object as well as maintaining its integrity by keeping all additions reversible. Conservation of books and paper involves techniques of bookbinding, restoration, paper chemistry, and other material technologies including preservation and archival techniques.
The conservation and restoration of leather objects is the process of determining the causes of deterioration, followed by deciding the best course of action for preserving the leather objects for the future.