Rheopecty

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In continuum mechanics, rheopecty or rheopexy is the rare property of some non-Newtonian fluids to show a time-dependent increase in viscosity (time-dependent viscosity); the longer the fluid undergoes shearing force, the higher its viscosity. [1] Rheopectic fluids, such as some lubricants, thicken or solidify when shaken. The opposite and much more common type of behaviour, in which fluids become less viscous the longer they undergo shear, is called thixotropy.

Examples of rheopectic fluids include gypsum pastes and printer inks. In the body synovial fluid exhibits the extraordinary property of inverse thixotropy or rheopexy. [2]

There is ongoing research into new ways to make and use rheopectic materials. There is great interest in possible military uses of this technology. Moreover, the high end of the sports market has also begun to respond to it. Body armor and combat vehicle armor are key areas where efforts are being made to use rheopectic materials. Work is also being done to use these materials in other kinds of protective equipment, which is seen as potentially useful to reduce apparent impact stress in athletics, motor sports, transportation accidents, and all forms of parachuting. In particular, footwear with rheopectic shock absorption is being pursued as a dual-use technology that can provide better support to those who must frequently run, leap, climb, or descend.[ citation needed ]

Confusion between rheopectic and dilatant fluids

An incorrect example often used to demonstrate rheopecty is cornstarch mixed with water (sometimes called oobleck), which is a very viscous, white fluid. It is a cheap and simple demonstration, which can be picked up by hand as a semi-solid, but flows easily when not under pressure. However, oobleck is actually a dilatant fluid, since it does not show the time-dependent, shear-induced change required in order to be labeled rheopectic. These terms are often and easily confused since the terms are rarely used; a true rheopectic fluid would when shaken be liquid at first, becoming thicker as shaking continued.

Just as the opposite behaviour of becoming thinner with time is thixotropism (time dependent pseudoplastic behaviour), rheopectic behaviour may be described as time-dependent dilatant behaviour. [3]

Related Research Articles

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<span class="mw-page-title-main">Fluid dynamics</span> Aspects of fluid mechanics involving flow

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Rheology is the study of the flow of matter, primarily in a fluid state, but also as "soft solids" or solids under conditions in which they respond with plastic flow rather than deforming elastically in response to an applied force. Rheology is a branch of physics, and it is the science that deals with the deformation and flow of materials, both solids and liquids.

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<span class="mw-page-title-main">Thixotropy</span> Change in viscosity of a gel or fluid caused by stress

Thixotropy is a time-dependent shear thinning property. Certain gels or fluids that are thick or viscous under static conditions will flow over time when shaken, agitated, shear-stressed, or otherwise stressed. They then take a fixed time to return to a more viscous state. Some non-Newtonian pseudoplastic fluids show a time-dependent change in viscosity; the longer the fluid undergoes shear stress, the lower its viscosity. A thixotropic fluid is a fluid which takes a finite time to attain equilibrium viscosity when introduced to a steep change in shear rate. Some thixotropic fluids return to a gel state almost instantly, such as ketchup, and are called pseudoplastic fluids. Others such as yogurt take much longer and can become nearly solid. Many gels and colloids are thixotropic materials, exhibiting a stable form at rest but becoming fluid when agitated. Thixotropy arises because particles or structured solutes require time to organize. An overview of thixotropy has been provided by Mewis and Wagner.

<span class="mw-page-title-main">Dilatant</span> Material in which viscosity increases with the rate of shear strain

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<span class="mw-page-title-main">Rheometer</span> Scientific instrument used to measure fluid flow (rheology)

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<span class="mw-page-title-main">Viscous coupling unit</span>

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<span class="mw-page-title-main">Shear thinning</span> Non-Newtonian fluid behavior

In rheology, shear thinning is the non-Newtonian behavior of fluids whose viscosity decreases under shear strain. It is sometimes considered synonymous for pseudo-plastic behaviour, and is usually defined as excluding time-dependent effects, such as thixotropy.

<span class="mw-page-title-main">Viscosity</span> Resistance of a fluid to shear deformation

The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity is defined scientifically as a force multiplied by a time divided by an area. Thus its SI units are newton-seconds per square meter, or pascal-seconds.

Liquid armour is a material under research by defense institutions and universities around the world including the United States Army Research Laboratory (ARL). Some of the earliest research in this area was performed at Massachusetts Institute of Technology and University of Delaware in 2003. Liquid armor was initially presented as a way to increase the survivability of soldiers in high risk roles while retaining their mobility, as reported by NPR in an interview with MIT professors and a U.S. admiral.

<span class="mw-page-title-main">Time-dependent viscosity</span> Property of certain fluids to change viscosity over time

In continuum mechanics, time-dependent viscosity is a property of fluids whose viscosity changes as a function of time. The most common type of this is thixotropy, in which the viscosity of fluids under continuous shear decreases with time; the opposite is rheopecty, in which viscosity increases with time.

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References

  1. "BBC Science - How to: Make a liquid that's also a solid". Archived from the original on 2016-12-12. Retrieved 2013-10-01.
  2. O'Neill, p.l (1996). "The Inverse Thixotropic Behaviour of Synovial Fluid". Journal of Orthopaedic Rheumatology. 9 (4): 222–228.
  3. Sato, Tatsuo (August 1995). "Rheology of suspensions". The Journal of Coatings Technology: 69. Retrieved March 12, 2016.