Rheopecty

Last updated

In continuum mechanics, rheopecty or rheopexy is the rare property of some non-Newtonian fluids to show a time-dependent increase in viscosity (time-dependent viscosity); the longer the fluid undergoes shearing force, the higher its viscosity. [1] Rheopectic fluids, such as some lubricants, thicken or solidify when shaken. The opposite and much more common type of behaviour, in which fluids become less viscous the longer they undergo shear, is called thixotropy.

Contents

Examples of rheopectic fluids include gypsum pastes, printer inks, and synovial fluid. [2]

There is ongoing research into new ways to make and use rheopectic materials. There is great interest in possible military uses of this technology. Moreover, the high end of the sports market has also begun to respond to it. Body armor and combat vehicle armor are key areas where efforts are being made to use rheopectic materials. Work is also being done to use these materials in other kinds of protective equipment, which is seen as potentially useful to reduce apparent impact stress in athletics, motor sports, transportation accidents, and all forms of parachuting. In particular, footwear with rheopectic shock absorption is being pursued as a dual-use technology that can provide better support to those who must frequently run, leap, climb, or descend.[ citation needed ]

Confusion between rheopectic and dilatant fluids

An incorrect example often used to demonstrate rheopecty is cornstarch mixed with water (sometimes called oobleck), which is a very viscous, white fluid. It is a cheap and simple demonstration, which can be picked up by hand as a semi-solid, but flows easily when not under pressure. However, oobleck is actually a dilatant fluid, since it does not show the time-dependent, shear-induced change required in order to be labeled rheopectic. These terms are often and easily confused since the terms are rarely used; a true rheopectic fluid would when shaken be liquid at first, becoming thicker as shaking continued.

Just as the opposite behaviour of becoming thinner with time is thixotropism (time dependent pseudoplastic behaviour), rheopectic behaviour may be described as time-dependent dilatant behaviour. [3]

See also

Related Research Articles

<span class="mw-page-title-main">Fluid dynamics</span> Aspects of fluid mechanics involving flow

In physics, physical chemistry and engineering, fluid dynamics is a subdiscipline of fluid mechanics that describes the flow of fluids—liquids and gases. It has several subdisciplines, including aerodynamics and hydrodynamics. Fluid dynamics has a wide range of applications, including calculating forces and moments on aircraft, determining the mass flow rate of petroleum through pipelines, predicting weather patterns, understanding nebulae in interstellar space and modelling fission weapon detonation.

Rheology is the study of the flow of matter, primarily in a fluid state but also as "soft solids" or solids under conditions in which they respond with plastic flow rather than deforming elastically in response to an applied force. Rheology is the branch of physics that deals with the deformation and flow of materials, both solids and liquids.

A viscometer is an instrument used to measure the viscosity of a fluid. For liquids with viscosities which vary with flow conditions, an instrument called a rheometer is used. Thus, a rheometer can be considered as a special type of viscometer. Viscometers can measure only constant viscosity, that is, viscosity that does not change with flow conditions.

A non-Newtonian fluid is a fluid that does not follow Newton's law of viscosity, that is, it has variable viscosity dependent on stress. In particular, the viscosity of non-Newtonian fluids can change when subjected to force. Ketchup, for example, becomes runnier when shaken and is thus a non-Newtonian fluid. Many salt solutions and molten polymers are non-Newtonian fluids, as are many commonly found substances such as custard, toothpaste, starch suspensions, corn starch, paint, blood, melted butter, and shampoo.

A Newtonian fluid is a fluid in which the viscous stresses arising from its flow are at every point linearly correlated to the local strain rate — the rate of change of its deformation over time. Stresses are proportional to the rate of change of the fluid's velocity vector.

In continuum mechanics, a power-law fluid, or the Ostwald–de Waele relationship, is a type of generalized Newtonian fluid for which the shear stress, τ, is given by

<span class="mw-page-title-main">Mixing (process engineering)</span> Process of mechanically stirring a heterogeneous mixture to homogenize it

In industrial process engineering, mixing is a unit operation that involves manipulation of a heterogeneous physical system with the intent to make it more homogeneous. Familiar examples include pumping of the water in a swimming pool to homogenize the water temperature, and the stirring of pancake batter to eliminate lumps (deagglomeration).

In materials science and continuum mechanics, viscoelasticity is the property of materials that exhibit both viscous and elastic characteristics when undergoing deformation. Viscous materials, like water, resist both shear flow and strain linearly with time when a stress is applied. Elastic materials strain when stretched and immediately return to their original state once the stress is removed.

<span class="mw-page-title-main">Thixotropy</span> Change in viscosity of a gel or fluid caused by stress

Thixotropy is a time-dependent shear thinning property. Certain gels or fluids that are thick or viscous under static conditions will flow over time when shaken, agitated, shear-stressed, or otherwise stressed. They then take a fixed time to return to a more viscous state. Some non-Newtonian pseudoplastic fluids show a time-dependent change in viscosity; the longer the fluid undergoes shear stress, the lower its viscosity. A thixotropic fluid is a fluid which takes a finite time to attain equilibrium viscosity when introduced to a steep change in shear rate. Some thixotropic fluids return to a gel state almost instantly, such as ketchup, and are called pseudoplastic fluids. Others such as yogurt take much longer and can become nearly solid. Many gels and colloids are thixotropic materials, exhibiting a stable form at rest but becoming fluid when agitated. Thixotropy arises because particles or structured solutes require time to organize.

<span class="mw-page-title-main">Dilatant</span> Material in which viscosity increases with the rate of shear strain

A dilatant material is one in which viscosity increases with the rate of shear strain. Such a shear thickening fluid, also known by the initialism STF, is an example of a non-Newtonian fluid. This behaviour is usually not observed in pure materials, but can occur in suspensions.

<span class="mw-page-title-main">Synovial fluid</span> Fluid found in the cavities of synovial joints

Synovial fluid, also called synovia,[help 1] is a viscous, non-Newtonian fluid found in the cavities of synovial joints. With its egg white–like consistency, the principal role of synovial fluid is to reduce friction between the articular cartilage of synovial joints during movement. Synovial fluid is a small component of the transcellular fluid component of extracellular fluid.

<span class="mw-page-title-main">Rheometer</span> Scientific instrument used to measure fluid flow (rheology)

A rheometer is a laboratory device used to measure the way in which a viscous fluid flows in response to applied forces. It is used for those fluids which cannot be defined by a single value of viscosity and therefore require more parameters to be set and measured than is the case for a viscometer. It measures the rheology of the fluid.

<span class="mw-page-title-main">Viscous coupling unit</span>

A viscous coupling is a mechanical device which transfers torque and rotation by the medium of a viscous fluid.

Fluid mechanics is the branch of physics concerned with the mechanics of fluids and the forces on them. It has applications in a wide range of disciplines, including mechanical, aerospace, civil, chemical, and biomedical engineering, as well as geophysics, oceanography, meteorology, astrophysics, and biology.

<span class="mw-page-title-main">Shear thinning</span> Non-Newtonian fluid behavior

In rheology, shear thinning is the non-Newtonian behavior of fluids whose viscosity decreases under shear strain. It is sometimes considered synonymous for pseudo-plastic behaviour, and is usually defined as excluding time-dependent effects, such as thixotropy.

<span class="mw-page-title-main">Viscosity</span> Resistance of a fluid to shear deformation

The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity is defined scientifically as a force multiplied by a time divided by an area. Thus its SI units are newton-seconds per square meter, or pascal-seconds.

Liquid armour is a material under research by defense institutions and universities around the world including the United States Army Research Laboratory (ARL). Some of the earliest research in this area was performed at Massachusetts Institute of Technology and University of Delaware in 2003. Liquid armor was initially presented as a way to increase the survivability of soldiers in high risk roles while retaining their mobility, as reported by NPR in an interview with MIT professors and a U.S. admiral.

Constant viscosity elastic liquids, also known as Boger fluids are elastic fluids with constant viscosity. This creates an effect in the fluid where it flows like a liquid, yet behaves like an elastic solid when stretched out. Most elastic fluids exhibit shear thinning, because they are solutions containing polymers. But Boger fluids are exceptions since they are highly dilute solutions, so dilute that shear thinning caused by the polymers can be ignored. Boger fluids are made primarily by adding a small amount of polymer to a Newtonian fluid with a high viscosity, a typical solution being polyacrylamide mixed with corn syrup. It is a simple compound to synthesize but important to the study of rheology because elastic effects and shear effects can be clearly distinguished in experiments using Boger fluids. Without Boger fluids, it was difficult to determine if a non-Newtonian effect was caused by elasticity, shear thinning, or both; non-Newtonian flow caused by elasticity was rarely identifiable. Since Boger fluids can have constant viscosity, an experiment can be done where the results of the flow rates of a Boger liquid and a Newtonian liquid with the same viscosity can be compared, and the difference in the flow rates would show the change caused by the elasticity of the Boger liquid.

<span class="mw-page-title-main">Time-dependent viscosity</span> Property of certain fluids to change viscosity over time

In continuum mechanics, time-dependent viscosity is a property of fluids whose viscosity changes as a function of time. The most common type of this is thixotropy, in which the viscosity of fluids under continuous shear decreases with time; the opposite is rheopecty, in which viscosity increases with time.

Biofluid dynamics may be considered as the discipline of biological engineering or biomedical engineering in which the fundamental principles of fluid dynamics are used to explain the mechanisms of biological flows and their interrelationships with physiological processes, in health and in diseases/disorder. It can be considered as the conjuncture of mechanical engineering and biological engineering. It spans from cells to organs, covering diverse aspects of the functionality of systemic physiology, including cardiovascular, respiratory, reproductive, urinary, musculoskeletal and neurological systems etc. Biofluid dynamics and its simulations in computational fluid dynamics (CFD) apply to both internal as well as external flows. Internal flows such as cardiovascular blood flow and respiratory airflow, and external flows such as flying and aquatic locomotion. Biological fluid Dynamics involves the study of the motion of biological fluids. It can be either circulatory system or respiratory systems. Understanding the circulatory system is one of the major areas of research. The respiratory system is very closely linked to the circulatory system and is very complex to study and understand. The study of Biofluid Dynamics is also directed towards finding solutions to some of the human body related diseases and disorders. The usefulness of the subject can also be understood by seeing the use of Biofluid Dynamics in the areas of physiology in order to explain how living things work and about their motions, in developing an understanding of the origins and development of various diseases related to human body and diagnosing them, in finding the cure for the diseases related to cardiovascular and pulmonary systems.

References

  1. "BBC Science - How to: Make a liquid that's also a solid". Archived from the original on 2016-12-12. Retrieved 2013-10-01.
  2. O'Neill, p.l (1996). "The Inverse Thixotropic Behaviour of Synovial Fluid". Journal of Orthopaedic Rheumatology. 9 (4): 222–228.
  3. Sato, Tatsuo (August 1995). "Rheology of suspensions". The Journal of Coatings Technology: 69. Retrieved March 12, 2016.