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Mono-N-protected amino acid (MPAA) is a bifunctional ligand that plays a key role in C–H functionalizations by accelerating the reaction rate and imparting specified chirality into the product. Amino acids are ideal building blocks for chiral ligand synthesis due to the cost, accessibility, large variety, solubility, and inherent chirality. Naturally occurring amino acids are transformed into chiral MPAA ligands that, upon coordination to metal complexes, allow reactions to occur that are otherwise energetically unfavorable. Great strides in the development of MPAA ligands over the past two decades have led to the integral role that enantioselective catalysis now plays in complex organic synthesis.
References
- 1 2 3 4 5 The University of Queensland. "Chemist discovers formula for research success". UQ News. Retrieved 12 August 2022.
- ↑ Smith, Sean (1989). Experimental and theoretical studies of ion-molecule reactions (Doctoral thesis). UC Research Repository, University of Canterbury. doi:10.26021/7869. hdl:10092/7814.
- 1 2 "Sean Smith". Integrated Materials Design Lab. Retrieved 12 August 2022.
- ↑ "NCI supercomputing facility names new director". Computerworld. Retrieved 12 August 2022.
- 1 2 3 4 "Professor Sean Smith to become Director of NCI". ANU. 17 July 2017. Retrieved 12 August 2022.
- ↑ The University of Queensland. "Research excellence rewarded". UQ News. Retrieved 12 August 2022.
