Seth Darling

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Seth Darling in 2021 SethDarling.jpg
Seth Darling in 2021
Seth Darling
Education University of Chicago (PhD), Haverford College (BA)
Occupation(s)Chief Science & Technology Officer and Senior Scientist
Organization(s) Argonne National Laboratory, University of Chicago
Known forWater/Energy Materials
AwardsR&D 100 Award Winner (2017, 2014)
Website https://www.anl.gov/profile/seth-b-darling

Seth B. Darling is the Chief Science & Technology Officer of the Advanced Energy Technologies Directorate at Argonne National Laboratory. He previously served as director of the Center for Molecular Engineering, a research and development organization partnered with the University of Chicago focusing on advanced materials for cleaning water, quantum information science, and polymer science. Darling is also a senior scientist at both the U.S. Department of Energy’s (DOE) Argonne National Laboratory and the University of Chicago’s Pritzker School of Molecular Engineering. He also directs the Advanced Materials for Energy-Water Systems (AMEWS) Center, a DOE Energy Frontier Research Center formed in 2018. [1]

Contents

Darling has made contributions to the development of new materials for energy and water, including hybrid materials for polymer and perovskite solar cells and membrane materials for water filtration. He has co-created material synthesis techniques that are used commercially, including sequential infiltration synthesis (SIS), which is used to create coatings for semiconductor fabrication, optical surfaces, and reusable oil sorbents. [2] [3] [4] [5]

Career and education

Darling holds a PhD in physical chemistry from the University of Chicago and a bachelor’s degree in chemistry and astronomy from Haverford College. [1] He completed his postdoctoral studies at Argonne as a Glenn Seaborg Fellow before joining its Center for Nanoscale Materials as a staff scientist. [1] Darling was later promoted to director of the Institute for Molecular Engineering at Argonne, later renamed the Center for Molecular Engineering. [6] In 2018, he became a senior scientist and was named director of the AMEWS Center. [1]

Darling previously was the chief technical officer of Visual Molecules LLC, a position he held from 2008 until 2017. [1]

Major research contributions

Darling's research focuses on developing and studying advanced materials for applications in water treatment and other technological separations. Specifically, his group has developed coatings that offer both passive (adsorption prevention) and active (catalytic degradation) properties to mitigate membrane fouling, photothermal materials for wastewater treatment (a form of solar thermal energy), and sorbents for selective removal of contaminants.

Darling has analyzed the behavior, commercial viability, scalability, and ecological impacts of photovoltaic technologies. [7] [8] This work reveals fundamental mechanisms of their operation and provides guidance on which solar energy technologies are sustainable and economical. Much of this work focused on the structure and properties of organic and hybrid materials. [9] [10] [11] This includes polymer solar cells and perovskite solar cells.

Darling co-invented sequential infiltration synthesis (SIS) with Jeffrey Elam. SIS is a material synthesis technique derived from atomic layer deposition (ALD). [12] While ALD alternates chemical vapors to grow materials one atomic layer at a time, in SIS the vapor is diffused into the polymer rather than on top of it. SIS has been used to create coatings for semiconductor fabrication and has applications in nanolithography (recognized with an R&D100 award in 2014), [13] optical coatings, advanced sorbents, and membranes. SIS was also used to in the development of the Oleo Sponge to engineer a reusable oleophilic material that grabs oil molecules from water to mitigate oil spills. [14] [15]

Darling studied the directed self-assembly of polymers and polymer/nanoparticle hybrid systems. [16] He’s investigated ways to tune the nanostructures that form when block copolymers self-assemble, in order to create useful materials for nanotechnologies and other applications. [17] His most cited paper reviews methods to control the self-assembly of block copolymers and their application in microelectronics and other technologies. [16]

Book authorship

Darling has co-authored two books:

Awards and honors

Related Research Articles

<span class="mw-page-title-main">Organic electronics</span> Field of materials science

Organic electronics is a field of materials science concerning the design, synthesis, characterization, and application of organic molecules or polymers that show desirable electronic properties such as conductivity. Unlike conventional inorganic conductors and semiconductors, organic electronic materials are constructed from organic (carbon-based) molecules or polymers using synthetic strategies developed in the context of organic chemistry and polymer chemistry.

<span class="mw-page-title-main">Argonne National Laboratory</span> American science and engineering research laboratory in Illinois

Argonne National Laboratory is a federally funded research and development center in Lemont, Illinois, United States. Founded in 1946, the laboratory is owned by the United States Department of Energy and administered by UChicago Argonne LLC of the University of Chicago. The facility is the largest national laboratory in the Midwest.

<span class="mw-page-title-main">Molecular engineering</span> Field of study in molecular properties

Molecular engineering is an emerging field of study concerned with the design and testing of molecular properties, behavior and interactions in order to assemble better materials, systems, and processes for specific functions. This approach, in which observable properties of a macroscopic system are influenced by direct alteration of a molecular structure, falls into the broader category of “bottom-up” design.

<span class="mw-page-title-main">Advanced Photon Source</span> Particle accelerator

The Advanced Photon Source (APS) at Argonne National Laboratory is a storage-ring-based high-energy X-ray light source facility. It is one of five X-ray light sources owned and funded by the U.S. Department of Energy Office of Science. The APS began operation on March 26, 1995. It is operated as a user facility, meaning that it is open to the world’s scientific community, and more than 5,500 researchers make use of its resources each year.

Dieter Martin Gruen is a German-born American scientist, who was a senior member of the Materials Science Division at Argonne National Laboratory. He received B.S. and M.S. (1947) degrees in chemistry from Northwestern University and the Ph.D. (1951) in chemical physics from the University of Chicago.

<span class="mw-page-title-main">Organic solar cell</span> Type of photovoltaic

An organic solar cell (OSC) or plastic solar cell is a type of photovoltaic that uses organic electronics, a branch of electronics that deals with conductive organic polymers or small organic molecules, for light absorption and charge transport to produce electricity from sunlight by the photovoltaic effect. Most organic photovoltaic cells are polymer solar cells.

The Argonne–Northwestern Solar Energy Research Center is a joint research program between the Argonne National Laboratory and Northwestern University. Michael R. Wasielewski, Professor of Chemistry at Northwestern founded the ANSER center in 2007 and is its current director. The center's goal is to develop the fundamental understanding, materials, and methods necessary to create efficient and economically viable technologies for solar fuels and electricity production. The union of synthesis, measurement, theory, and engineering allows ANSER to create exceptional new energy conversion systems. As part of its $777 million effort to establish Energy Frontier Research Centers, Grants provided by the US Department of Energy will enable the ANSER "to analyse photosynthesis for ways to create more efficient photovoltaic cells and create hybrid solar cells that have both organic and inorganic components."

<span class="mw-page-title-main">Solar cell research</span> Research in the field of photovoltaics

There are currently many research groups active in the field of photovoltaics in universities and research institutions around the world. This research can be categorized into three areas: making current technology solar cells cheaper and/or more efficient to effectively compete with other energy sources; developing new technologies based on new solar cell architectural designs; and developing new materials to serve as more efficient energy converters from light energy into electric current or light absorbers and charge carriers.

<span class="mw-page-title-main">Nanocrystal solar cell</span>

Nanocrystal solar cells are solar cells based on a substrate with a coating of nanocrystals. The nanocrystals are typically based on silicon, CdTe or CIGS and the substrates are generally silicon or various organic conductors. Quantum dot solar cells are a variant of this approach which take advantage of quantum mechanical effects to extract further performance. Dye-sensitized solar cells are another related approach, but in this case the nano-structuring is a part of the substrate.

<span class="mw-page-title-main">Polyfluorene</span> Chemical compound

Polyfluorene is a polymer with formula (C13H8)n, consisting of fluorene units linked in a linear chain — specifically, at carbon atoms 2 and 7 in the standard fluorene numbering. It can also be described as a chain of benzene rings linked in para positions with an extra methylene bridge connecting every pair of rings.

Marek W. Urban is an American professor and polymer and materials scientist who works in polymers, polymer spectroscopy, stimuli-responsive materials, and self-healing polymers.

<span class="mw-page-title-main">Nepal Academy of Science and Technology</span> Autonomous body

Nepal Academy of Science and Technology (NAST), previously RONAST, is an autonomous apex body established in 1982 to promote science and technology in Nepal. With the implementation of federal structure by the government of Nepal, it has opened its first provincial office at Mahendranagar.

Diketopyrrolopyrroles (DPPs) are organic dyes and pigments based on the heterocyclic dilactam 2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione, widely used in optoelectronics. DPPs were initially used as pigments in the painting industry due to their high resistance to photodegradation. More recently, DPP derivatives have been also investigated as promising fluorescent dyes for bioimaging applications, as well as components of materials for use in organic electronics.

Luis M. Campos is a Professor in the Department of Chemistry at Columbia University. Campos leads a research team focused on nanostructured materials, macromolecular systems, and single-molecule electronics.

Eilaf Egap is an adjunct assistant professor of Materials Science at Rice University. She works on imaging techniques and biomaterials for early diagnostics and drug delivery. She was a Massachusetts Institute of Technology MLK Visiting Scholar in 2011.

Jeffrey Elam is a Distinguished Fellow, Senior Chemist and Group Leader in the Applied Materials Division at the U.S. Department of Energy's Argonne National Laboratory. He leads Argonne's atomic layer deposition (ALD) research program, where he directs research and development and commercialization of thin film coating technologies for energy applications.

Khalil Amine is a materials scientist at Argonne National Laboratory, an Argonne distinguished fellow, and group leader of the Battery Technology group. His research team is focused on the development of advanced battery systems for transportation applications. In addition to his Argonne appointment, he is an adjunct professor at Stanford University, Imam Abdulrahman Bin Faisal University, Hong Kong University of Science & Technology, King Abdulaziz University, Hanyang University, and Peking University.

Ellen Moons is a Belgian materials scientist who is a professor at Karlstad University. Her research considers the organisation of molecules and materials in thin films. She is mainly interested in organic and hybrid materials for solution processed photovoltaics.

Tijana Rajh is American materials scientist who is a professor and director of the Arizona State University School of Molecular Sciences. Her research considers the development of nanomaterials and materials for quantum technologies. She was awarded the Association for Women in Science Innovator Award in 2009, and named a Fellow of the American Association for the Advancement of Science in 2014.

Sequential infiltration synthesis (SIS) is a technique derived from atomic layer deposition (ALD) in which a polymer is infused with inorganic material using sequential, self-limiting exposures to gaseous precursors, allowing precise control over the composition, structure, and properties of product materials. This synthesis involves metal-organic vapour-phase precursors and co-reactants dissolving and diffusing into polymers, interacting with the polymer's functional groups via reversible complex formation and/or irreversible chemical reactions, and yielding desired composite materials, which may be nanostructured. The metal-organic precursor (A) and co-react vapour (B) are supplied in an alternating ABAB sequence. Following SIS, the organic phase can be removed thermally or chemically to leave only the inorganic components behind. The precise control over the infiltration and synthesis via SIS allows the creation of materials with tailored properties such as composition, mechanics, stoichiometry, porosity, conductivity, refractive index, and chemical functionality on the nanoscale. This versatility makes SIS useful in applications widely ranging from electronics to energy storage to catalysis. SIS is sometimes referred to as "multiple pulsed vapour-phase infiltration" (MPI), "vapour phase infiltration" (VPI) or "sequential vapour infiltration" (SVI).

References

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  2. "YouTube". www.youtube.com. Retrieved 2020-06-19.
  3. Its the End of Water as we Know It | Seth Darling | TEDxSavannah , retrieved 2020-06-19
  4. "New Sponge Can Soak Up 90 Times its Own Weight in Oil". WTTW News. Retrieved 2020-06-19.
  5. McMahon, Jeff. "Argonne Scientist Urges Next Generation Solar: 'We Have No Choice'". Forbes. Retrieved 2020-06-19.
  6. "Seth Darling named Director of the Institute for Molecular Engineering at Argonne | Argonne National Laboratory". www.anl.gov. Retrieved 2020-06-19.
  7. "Energy& Environmental Science".
  8. Darling, Seth B.; You, Fengqi; Veselka, Thomas; Velosa, Alfonso (2011-08-26). "Assumptions and the levelized cost of energy for photovoltaics". Energy & Environmental Science. 4 (9): 3133–3139. doi:10.1039/C0EE00698J. ISSN   1754-5706.
  9. Chen, Wei; Nikiforov, Maxim P.; Darling, Seth B. (2012-07-18). "Morphology characterization in organic and hybrid solar cells". Energy & Environmental Science. 5 (8): 8045–8074. doi:10.1039/C2EE22056C. ISSN   1754-5706.
  10. Liao, Hsueh-Chung; Ho, Chun-Chih; Chang, Chun-Yu; Jao, Meng-Huan; Darling, Seth B.; Su, Wei-Fang (2013-09-01). "Additives for morphology control in high-efficiency organic solar cells". Materials Today. 16 (9): 326–336. doi: 10.1016/j.mattod.2013.08.013 . ISSN   1369-7021.
  11. "The Case for Organic Photovoltaics" (PDF).
  12. "Sequential Infiltration Synthesis For Advanced Lithography" (PDF).
  13. 1 2 "Argonne wins three R&D 100 awards | Argonne National Laboratory". www.anl.gov. Retrieved 2020-06-19.
  14. staff, C. N. N. "Our oceans are amazing, but they need our help". CNN. Retrieved 2020-06-19.
  15. Ritter, Malcolm. "Scientist tweak seat cushion material to clean up oil spills". Business Insider. Retrieved 2020-06-19.
  16. 1 2 Darling, S. B. (2007-10-01). "Directing the self-assembly of block copolymers". Progress in Polymer Science. 32 (10): 1152–1204. doi:10.1016/j.progpolymsci.2007.05.004. ISSN   0079-6700.
  17. Darling, Seth B. (2009). "Block copolymers for photovoltaics". Energy & Environmental Science. 2 (12): 1266. doi:10.1039/b912086f. ISSN   1754-5692.
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