Shock sensitivity is a comparative measure of the sensitivity to sudden compression (by impact or blast) of an explosivechemical compound. Determination of the shock sensitivity of a material intended for practical use is one important aspect of safety testing of explosives. A variety of tests and indices are in use, of which one of the more common is the Rotter Impact Test with results expressed as FoI (Figure of Insensitivity.) At least four other impact tests are in common use, while various "gap tests" are used to measure sensitivity to blast shock.
Sensitivities vary widely
A few materials such as nitrogen triiodide cannot be touched at all without detonating, and so are of purely academic interest. Some other compounds with a high sensitivity to shock, such as nitroglycerin and acetone peroxide, may detonate from a firm jolt and so cannot be legally transported in pure form. Acetone peroxide is often used by amateurs and terrorists as a means to detonate other explosives as well as acting as the main blasting agent, often resulting in injuries or death to those who underestimate its sensitivity. A number of methods are known to desensitize nitroglycerine so that it can be transported for medical uses, and it is also incorporated into other less sensitive explosives, such as dynamites and gelignites.
Many practical commercial materials of intermediate sensitivity, such as gelignites and water gel explosives, can be safely handled as they will not explode from casual shocks such as being dropped or lightly knocked by a tool. However, they may explode if struck forcefully by a metal tool, and would certainly explode in the barrel if they were used in an artillery shell. Reliable initiation of such materials requires the small explosion of a detonator. Apart from this another explosive material such as Armstrong's mixture is also used in commercial markets and even sold to the public in the form of fireworks, cap guns and party poppers.
Still less sensitive materials such as blasting agents like ANFO, are so insensitive that the impulse from the detonator must be amplified by an explosive booster charge to secure reliable detonation. Some polymer bonded explosives— especially those based on TATB— are designed for use in insensitive munitions, which are unlikely to detonate even if struck by another explosive weapon.
An explosive is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances.
Lead(II) azide Pb(N3)2 is an inorganic compound. More so than other azides, it is explosive. It is used in detonators to initiate secondary explosives. In a commercially usable form, it is a white to buff powder.
2,4,6-Trinitrophenylmethylnitramine or tetryl (C7H5N5O8) is an explosive compound used to make detonators and explosive booster charges.
A detonator is a device used to make an explosive or explosive device explode. Detonators come in a variety of types, depending on how they are initiated and details of their inner working, which often involve several stages. Types of detonators include non-electric and electric. Non-electric detonators are typically stab or pyrotechnic while electric are typically "hot wire", exploding bridge wire or explosive foil.
C-4 or Composition C-4 is a common variety of the plastic explosive family known as Composition C, which uses RDX as its explosive agent. C-4 is composed of explosives, plastic binder, plasticizer to make it malleable, and usually a marker or odorizing taggant chemical. C-4 has a texture similar to modelling clay and can be molded into any desired shape. C-4 is relatively insensitive and can be detonated only by the shock wave from a detonator or blasting cap.
ANFO ( AN-foh) (or AN/FO, for ammonium nitrate/fuel oil) is a widely used bulk industrial high explosive. It consists of 94% porous prilled ammonium nitrate (NH4NO3) (AN), which acts as the oxidizing agent and absorbent for the fuel, and 6% number 2 fuel oil (FO). The use of ANFO originated in the 1950s.
An explosive booster is a sensitive explosive charge that acts as a bridge between a conventional detonator and a low-sensitivity explosive such as TNT. By itself, the initiating detonator would not deliver sufficient energy to set off the low-sensitivity charge. However, it detonates the primary charge, which then delivers an explosive shockwave that is sufficient to detonate the secondary, main, high-energy charge.
The exploding-bridgewire detonator is a type of detonator used to initiate the detonation reaction in explosive materials, similar to a blasting cap because it is fired using an electric current. EBWs use a different physical mechanism than blasting caps, using more electricity delivered much more rapidly. They explode with more precise timing after the electric current is applied by the process of exploding wire. The precise timing of exploding wire detonators compared with other types of detonators has led to their common use in nuclear weapons.
A triggering sequence, also called an explosive train or a firing train, is a sequence of events that culminates in the detonation of explosives. For safety reasons, most widely used high explosives are difficult to detonate. A primary explosive of higher sensitivity is used to trigger a uniform and predictable detonation of the main body of the explosive. Although the primary explosive itself is generally a more sensitive and expensive compound, it is only used in small quantities and in relatively safely packaged forms. By design there are low explosives and high explosives made such that the low explosives are highly sensitive and high explosives are comparatively insensitive. This not only affords inherent safety to the usage of explosives during handling and transport, but also necessitates an explosive triggering sequence or explosive train. The explosive triggering sequence or the explosive train essentially consists of an 'initiator', an 'intermediary' and the 'high explosive'.
Detonating cord is a thin, flexible plastic tube usually filled with pentaerythritol tetranitrate. With the PETN exploding at a rate of approximately 6,400 m/s (21,000 ft/s), any common length of detonation cord appears to explode instantaneously. It is a high-speed fuse which explodes, rather than burns, and is suitable for detonating high explosives. The detonation velocity is sufficient to use it for synchronizing multiple charges to detonate almost simultaneously even if the charges are placed at different distances from the point of initiation. It is used to reliably and inexpensively chain together multiple explosive charges. Typical uses include mining, drilling, demolitions, and warfare.
Figure of Insensitivity is an inverse scale of measure of the impact sensitivity of an explosive substance. In this particular context the term 'Insensitivity' refers to the likelihood of initiation/detonation by impact, friction, electrostatic discharge, application of flame, etc. It is a quantitative measure of the level of stimulus required to cause explosive decomposition.
The safety testing of explosives involves the determination of various properties of the different energetic materials that are used in commercial, mining, and military applications. It is highly desirable to measure the conditions under which explosives can be set off for several reasons, including: safety in handling, safety in storage, and safety in use.
A slapper detonator, also called exploding foil initiator (EFI), is a detonator developed by Lawrence Livermore National Laboratory, US Patent No. 4,788,913. It is an improvement over the earlier exploding-bridgewire detonator. Instead of directly coupling the shock wave from the exploding wire, the expanding plasma from an explosion of a metal foil drives another thin plastic or metal foil called a "flyer" or a "slapper" across a gap, and its high-velocity impact on an explosive then delivers the energy and shock needed to initiate a detonation. Normally all the slapper's kinetic energy is supplied by the heating of the plasma by the current passing through it, though constructions with a "back strap" to further drive the plasma forward by magnetic field also exist. This assembly is quite efficient; up to 30% of the electrical energy can be converted to the slapper's kinetic energy. The device's name is derived from the English word "slap".
Hexamethylene triperoxide diamine (HMTD) is a high explosive organic compound. HMTD is an organic peroxide, a heterocyclic compound with a cage-like structure. It is a primary explosive. It has been considered as an initiating explosive for blasting caps in the early part of 20th century, mostly because of its high initiating power and its inexpensive production. As such, it was quickly taken up as a primary explosive in mining applications. However, it has since been superseded by more (chemically) stable compounds such as dextrinated lead azide and DDNP. HMTD is widely used in amateur-made blasting caps.
A contact explosive is a chemical substance that explodes violently when it is exposed to a relatively small amount of energy. Though different contact explosives have varying amounts of energy sensitivity, they are all much more sensitive relative to other kinds of explosives. Contact explosives are a part of a group of explosives called primary explosives, which are also very sensitive to stimuli but not to the degree of contact explosives. The extreme sensitivity of contact explosives is due to either chemical composition, bond type, or structure.
Diazodinitrophenol (DDNP) was the first diazo compound produced; it was subsequently used to make dyes and explosives. It forms yellow crystals in pure form; however, the color of impure forms may vary from dark yellow to green to dark brown. It is soluble in acetic acid, acetone, concentrated hydrochloric acid, like most non-polar solvents and is slightly soluble in water.
A pyrotechnic fastener is a fastener, usually a nut or bolt, that incorporates a pyrotechnic charge that can be initiated remotely. One or more explosive charges embedded within the bolt are typically activated by an electric current, and the charge breaks the bolt into two or more pieces. The bolt is typically scored around its circumference at the point(s) where the severance should occur. Such bolts are often used in space applications to ensure separation between rocket stages, because they are lighter and much more reliable than mechanical latches.
In explosives engineering, sensitivity refers to the degree to which an explosive can be initiated by impact, heat, or friction. Current in-use standard methods of mechanical sensitivity determination differ by the sample preparation, sample arrangement, instrument type, go/not go criteria, and the statistical analysis of results.
A sympathetic detonation, also called flash over or secondary/secondaries (explosion), is a detonation, usually unintended, of an explosive charge by a nearby explosion.
Staged detonation is an overall principle used for many explosive devices. A general description of the principle is that one explosive compound with one set of properties is detonated, and the detonation wave from this is transfers into another explosive compound with different set of properties.
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