Stolzite

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Stolzite
Stolzite-t07-25b.jpg
Stolzite, Broken Hill, Australia (size: 3.6 x 3.0 x 2.6 cm)
General
CategoryTungstate minerals
Formula
(repeating unit)
PbWO4
IMA symbol Sz [1]
Strunz classification 7.GA.05
Crystal system Tetragonal
Crystal class Dipyramidal (4/m)
H-M symbol: (4/m)
Space group I41/a
Unit cell a = 5.461, c = 12.049 [Å]; Z = 4
Identification
ColorReddish brown, brown, yellowish gray, smoky gray, straw-yellow, lemon-yellow; may be green, orange, red
Crystal habit Crystals dipyramidal to tabular
Cleavage Imperfect on {001}, indistinct on {011}
Fracture Conchoidal to uneven
Tenacity Brittle
Mohs scale hardness2.5–3
Luster Resinous, subadamantine
Streak White
Diaphaneity Translucent to transparent
Specific gravity 8.34
Optical propertiesUniaxial (−)
Refractive index nω = 2.270 nε = 2.180 – 2.190
Birefringence δ = 0.090
References [2] [3] [4] [5]

Stolzite is a mineral, a lead tungstate; with the formula PbW O 4. It is similar to, and often associated with, wulfenite which is the same chemical formula except that the tungsten is replaced by molybdenum. Stolzite crystallizes in the tetragonal crystal system and is dimorphous with the monoclinic form raspite. [4]

Stolzite crystal from the Darwin District, Inyo County, California (size: 2.0 x 1.7 x 1.6 cm) Stolzite-174595.jpg
Stolzite crystal from the Darwin District, Inyo County, California (size: 2.0 × 1.7 × 1.6 cm)

Lead tungstate crystals have the optical transparency of glass combined with much higher density (8.28 g/cm3 vs ~2.2 g/cm3 for fused silica). They are used as scintillators in particle physics because of their short radiation length (0.89 cm), low Molière radius (2.2 cm), quick scintillation response, and radiation hardness. [6] Lead tungstate crystals are used in the Compact Muon Solenoid's electromagnetic calorimeter. [6]

It was first described in 1820 by August Breithaupt, who called it Scheelbleispath and then by François Sulpice Beudant in 1832, who called it scheelitine. In 1845, Wilhelm Karl Ritter von Haidinger coined the name stolzite for an occurrence in the Ore Mountains, Bohemia (today the Czech Republic), naming it after Joseph Alexi Stolz of Teplice in Bohemia. [4] [5] It occurs in oxidized hydrothermal tungsten-lead ore deposits typically in association with raspite, cerussite, anglesite, pyromorphite and mimetite. [3]

See also

Related Research Articles

<span class="mw-page-title-main">Wolframite</span> Iron manganese tungstate mineral

Wolframite is an iron, manganese, and tungstate mineral with a chemical formula of (Fe,Mn)WO4 that is the intermediate mineral between ferberite (Fe2+ rich) and hübnerite (Mn2+ rich). Along with scheelite, the wolframite series are the most important tungsten ore minerals. Wolframite is found in quartz veins and pegmatites associated with granitic intrusives. Associated minerals include cassiterite, scheelite, bismuth, quartz, pyrite, galena, sphalerite, and arsenopyrite.

<span class="mw-page-title-main">Scintillator</span> Material which glows when excited by ionizing radiation

A scintillator is a material that exhibits scintillation, the property of luminescence, when excited by ionizing radiation. Luminescent materials, when struck by an incoming particle, absorb its energy and scintillate. Sometimes, the excited state is metastable, so the relaxation back down from the excited state to lower states is delayed. The process then corresponds to one of two phenomena: delayed fluorescence or phosphorescence. The correspondence depends on the type of transition and hence the wavelength of the emitted optical photon.

<span class="mw-page-title-main">Wulfenite</span> Molybdate mineral

Wulfenite is a lead molybdate mineral with the formula PbMoO4. It can be most often found as thin tabular crystals with a bright orange-red to yellow-orange color, sometimes brown, although the color can be highly variable. In its yellow form it is sometimes called "yellow lead ore".

<span class="mw-page-title-main">Acanthite</span> Mineral, silver sulfide

Acanthite is a form of silver sulfide with the chemical formula Ag2S. It crystallizes in the monoclinic system and is the stable form of silver sulfide below 173 °C (343 °F). Argentite is the stable form above that temperature. As argentite cools below that temperature its cubic form is distorted to the monoclinic form of acanthite. Below 173 °C acanthite forms directly. Acanthite is the only stable form in normal air temperature.

<span class="mw-page-title-main">Anglesite</span> Lead sulfate mineral

Anglesite is a lead sulfate mineral with the chemical formula PbSO4. It occurs as an oxidation product of primary lead sulfide ore, galena. Anglesite occurs as prismatic orthorhombic crystals and earthy masses, and is isomorphous with barite and celestine. It contains 74% of lead by mass and therefore has a high specific gravity of 6.3. Anglesite's color is white or gray with pale yellow streaks. It may be dark gray if impure.

<span class="mw-page-title-main">Scheelite</span> Calcium tungstate mineral

Scheelite is a calcium tungstate mineral with the chemical formula CaWO4. It is an important ore of tungsten (wolfram). Scheelite is originally named after Swedish chemist Carl Wilhelm Scheele (1742–1786). Well-formed crystals are sought by collectors and are occasionally fashioned into gemstones when suitably free of flaws. Scheelite has been synthesized using the Czochralski process; the material produced may be used to imitate diamond, as a scintillator, or as a solid-state lasing medium. It was also used in radium paint in the same fashion as was zinc sulphide, and Thomas Edison invented a fluoroscope with a calcium tungstate-coated screen, making the images six times brighter than those with barium platinocyanide; the latter chemical allowed Röntgen to discover X-rays in early November 1895.

<span class="mw-page-title-main">Hübnerite</span>

Hübnerite or hubnerite is a mineral consisting of manganese tungsten oxide (chemical formula MnWO4). It is the manganese endmember of the manganese–iron wolframite solid solution series. It forms reddish brown to black monoclinic prismatic submetallic crystals. The crystals are typically flattened and occur with fine striations. It has a high specific gravity of 7.15 and a Mohs hardness of 4.5. It is transparent to translucent with perfect cleavage. Refractive index values are nα = 2.170 – 2.200, nβ = 2.220, and nγ = 2.300 – 2.320.

<span class="mw-page-title-main">Ferberite</span>

Ferberite is the iron endmember of the manganese–iron wolframite solid solution series. The manganese endmember is hübnerite. Ferberite is a black monoclinic mineral composed of iron(II) tungstate, FeWO4.

Cadmium tungstate (CdWO4 or CWO), the cadmium salt of tungstic acid, is a dense, chemically inert solid which is used as a scintillation crystal to detect gamma rays. It has density of 7.9 g/cm3 and melting point of 1325 °C. It is toxic if inhaled or swallowed. Its crystals are transparent, colorless, with slight yellow tint. It is odorless. Its CAS number is 7790-85-4. It is not hygroscopic.

The Molière radius is a characteristic constant of a material giving the scale of the transverse dimension of the fully contained electromagnetic showers initiated by an incident high energy electron or photon. By definition, it is the radius of a cylinder containing on average 90% of the shower's energy deposition. Two Molière radii contain 95% of the shower's energy deposition. It is related to the radiation length X0 by the approximate relation RM = 0.0265 X0 (Z + 1.2), where Z is the atomic number. The Molière radius is useful in experimental particle physics in the design of calorimeters: a smaller Molière radius means better shower position resolution, and better shower separation due to a smaller degree of shower overlaps.

Mosesite is a very rare mineral found in few locations. It is a mercury mineral found as an accessory in deposits of mercury, often in conjunction with limestone. It is known to be found in the U.S. states of Texas and Nevada, and the Mexican states of Guerrero and Querétaro. It was named after Professor Alfred J. Moses (1859–1920) for his contributions to the field of mineralogy in discovering several minerals found alongside mosesite. The mineral itself is various shades of yellow and a high occurrence of spinel twinning. It becomes isotropic when heated to 186 °C (367 °F).

<span class="mw-page-title-main">Russellite (mineral)</span> Bismuth tungstate mineral

Russellite is a bismuth tungstate mineral with the chemical formula Bi2WO6. It crystallizes in the orthorhombic crystal system. Russellite is yellow or yellow-green in color, with a Mohs hardness of 3+12.

<span class="mw-page-title-main">Raspite</span>

Raspite is a mineral, a lead tungstate; with the formula PbWO4. It forms yellow to yellowish brown monoclinic crystals. It is the low temperature monoclinic dimorph of the tetragonal stolzite.

Pinalite is a rare lead tungstate–chloride mineral with formula: Pb3WO5Cl2.

<span class="mw-page-title-main">Tarbuttite</span> Phosphate mineral

Tarbuttite is a rare phosphate mineral with formula Zn2(PO4)(OH). It was discovered in 1907 in what is now Zambia and named for Percy Coventry Tarbutt.

<span class="mw-page-title-main">Research Institute for Nuclear Problems of Belarusian State University</span> Research institute in Minsk, Belarus

The Research Institute for Nuclear Problems of Belarusian State University is a research institute in Minsk, Belarus. Its main fields of research are nuclear physics, particle physics, materials science and nanotechnology.

Metarauchite is a member of the autunite group, found at the Jáchymov ore district, Czech Republic and in Schneeberg, Germany. The autunite group is a group of structured uranyl phosphates and arsenates; the other members of the group are autunite, bassetite, heinrichite, kahlerite, nováčekite-I, nováčekite-II, rauchite, sabugalite, saléeite, torbernite, uranocircite, uranospinite, and zeunerite. The mineral is named after Czech mineral collector Luděk Rauch, who died in the Jáchymov mines during mineral prospecting.

Lahnsteinite is a basic sulfate mineral first discovered in the Friedrichssegen Mine, Germany in a goethite cavity. Though found in goethite, the crystals of Lahnsteinite are few millimeters in size, and are tabular shaped. Lahnsteinite was the first mineral discovered in the Lahn Valley deposits. The empirical formula for lahnsteinite is (Zn3.3,Fe0.27,Cu0.11)3.91(S0.98O4)(OH)5*3H2.10O.

Parascorodite is a rare, secondary iron-arsenate mineral. It has a chemical formula of (FeAsO4·2H2O) and was discovered in 1967 using X-ray powder diffraction methods, when an unknown substance was found along with scorodite on medieval ore dumps in the Czech Republic. The holotype of parascorodite can be found in the mineralogical collection of the National Museum, Prague, Czech Republic under acquisition number P1p25/98.

Ophirite is a tungstate mineral first discovered in the Ophir Hill Consolidated mine at Ophir district, Oquirrh Mountains, Tooele County, Utah, United States of America. It was found underground near a calcite cave in one veinlet, six centimeters wide by one meter long, surrounded by different sulfides. Before the closing of the mine in 1972, it was dominated by sulfide minerals, and the Ophir district was known for being a source of zinc, copper, silver, and lead ores. The crystals are formed as tablets. It is the first known mineral to contain a heteropolyanion, a lacunary defect derivative of the Keggin anion. The chemical formula of ophirite is Ca2Mg4[Zn2Mn3+2(H2O)2(Fe3+W9O34)2] · 46•H2O. The mineral has been approved by the Commission on New Minerals and Mineral Names, IMA, to be named ophirite for its type locality, the Ophir Consolidated mine.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Mineralienatlas
  3. 1 2 Handbook of Mineralogy
  4. 1 2 3 Mindat.org
  5. 1 2 Wevmineral data
  6. 1 2 The CMS Collaboration (2006). "Chapter 1. Introduction". CMS Physics : Technical Design Report Volume 1: Detector Performance and Software. CERN. p. 14. ISBN   9789290832683. CMS has chosen lead tungstate scintillating crystals for its ECAL. These crystals have short radiation (X0 = 0.89 cm) and Moliere (2.2 cm) lengths, are fast (80% of the light is emitted within 25 ns) and radiation hard (up to 10 Mrad).