Subpsoromic acid

Last updated
Subpsoromic acid
Subpsoromic acid.svg
Names
IUPAC name
10-formyl-9-hydroxy-3-methoxy-7-methyl-6-oxobenzo[b][1,4]benzodioxepine-1-carboxylic acid [1]
Other names
  • SCHEMBL2111989 [1]
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/C17H12O8/c1-7-3-11(19)10(6-18)15-13(7)17(22)24-12-5-8(23-2)4-9(16(20)21)14(12)25-15/h3-6,19H,1-2H3,(H,20,21)
    Key: SYHVWKKTKCTSSQ-UHFFFAOYSA-N
  • CC1=CC(=C(C2=C1C(=O)OC3=CC(=CC(=C3O2)C(=O)O)OC)C=O)O
Properties
C17H12O8
Molar mass 344.275 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Subpsoromic acid is a depsidone with the molecular formula C17H12O8 which has been isolated from the lichen Ocellularia praestans . [2] [1]

Related Research Articles

Depside

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<i>Niebla</i> (lichen) Genus of lichen

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A spot test in lichenology is a spot analysis used to help identify lichens. It is performed by placing a drop of a chemical on different parts of the lichen and noting the colour change associated with application of the chemical. The tests are routinely encountered in dichotomous keys for lichen species, and they take advantage of the wide array of lichen products produced by lichens and their uniqueness among taxa. As such, spot tests reveal the presence or absence of chemicals in various parts of a lichen. They were first proposed by the botanist William Nylander in 1866.

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Norstictic acid Chemical compound

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John Alan (Jack) Elix emeritus professor in chemistry at the Australian National University, is an organic chemist who has contributed in many fields: lichenology, lichen chemotaxonomy, plant physiology and biodiversity and natural product chemistry. He has authored 2282 species names, and 67 genera in the field of mycology.

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Ocellularia aptrootiana is a species of corticolous lichen in the family Graphidaceae. Found in Sri Lanka, it was formally described as a new species in 2014 by lichenologists Gothamie Weerakoon, Robert Lücking, and Helge Thorsten Lumbsch. The type specimen was collected from Mahailluppallama at an altitude of 170 m (560 ft). Here, in a low-altitude, dry, semi-evergreen forest, it was found growing around a water tank. The specific epithet aptrootiana honours Dutch lichenologist André Aptroot, "for his important contributions to tropical lichenology and his help with the research by the first author". Ocellularia aptrootiana has a grey, smooth to uneven or cracked thallus up to convert 5 cm (2 in) in diameter. The ascospores are hyaline, ellipsoid in shape, contain seven septa, and measure 20–25 by 6–7 μm. Secondary chemicals present in the lichen include psoromic acid, subpsoromic acid, and 2’-O-demethylpsoromic acids.

Ocellularia balangoda is a species of corticolous lichen in the family Graphidaceae. Found in Sri Lanka, it was formally described as a new species in 2014 by lichenologists Gothamie Weerakoon, Robert Lücking, and Helge Thorsten Lumbsch. The type specimen was collected from a high-altitude tea estate in Hunnasgiriya at an altitude of 1,240 m (4,070 ft); here it was found growing on tree trunks. The specific epithet refers to the prehistoric hominids known as Balangoda Man, who lived in Sri Lanka about 38,000 to 28,500 years ago. Ocellularia balangoda has a grey thallus up to 5 cm (2 in) in diameter, with a papillose (pimply) to verrucose (warty) textured surface. The ascospores are hyaline, ellipsoid in shape, contain seven septa, and measure 25–30 by 5–7 μm. Secondary chemicals present in the lichen include protocetraric acid and virensic acid.

Ocellularia cloonanii is a species of corticolous lichen in the family Graphidaceae. Found in Sri Lanka, it was formally described as a new species in 2014 by lichenologists Gothamie Weerakoon, Robert Lücking, and Helge Thorsten Lumbsch. The type specimen was collected from a high-elevation montane forest in the Fishing Hut Tea Estate at an altitude of 1,870 m (6,140 ft). The lichen is only known to occur at the type locality in the Horton Plains. The specific epithet cloonanii honours Colman Patrick Cloonan, "for his immense help in carrying out the research studies". Ocellularia cloonanii has a olive-grey thallus up to 5 cm (2 in) in diameter, with continuous but uneven surface. Its ascospores are hyaline, ellipsoid in shape, contain seven to nine septa, and measure 35–40 by 7–10 μm. Secondary chemicals present in the lichen include psoromic acid, subpsoromic acid, and 2’-O-demethylpsoromic acid.

Ocellularia raveniana is a species of corticolous lichen in the family Graphidaceae. Found in Sri Lanka, it was formally described as a new species in 2014 by lichenologists Gothamie Weerakoon, Robert Lücking, and Helge Thorsten Lumbsch. The type specimen was collected from a high-elevation tea estate in Matale at an altitude of 1,360 m (4,460 ft). The lichen is only known to occur at the type locality and in the Sabaragamuwa Mountain Range. The specific epithet raveniana honours botanist and environmentalist Peter H. Raven, longtime director and now President Emeritus of the Missouri Botanical Garden. Ocellularia raveniana has a cream-colored to white thallus up to 10 cm (4 in) in diameter, with an uneven to somewhat verrucose (warty) surface. Its ascospores are hyaline, oblong to ellipsoid in shape, contain seven to nine septa, and measure 25–35 by 8–10 μm. Secondary chemicals present in the lichen include protocetraric acid, and virensic acid.

Rhabdodiscus isidiatus is a species of corticolous lichen in the family Graphidaceae. Found in Sri Lanka, it was formally described as a new species in 2014 by lichenologists Gothamie Weerakoon, Robert Lücking, and Helge Thorsten Lumbsch. The type specimen was collected from the Elkaduwa Plantation in Matale at an altitude of 915 m (3,002 ft). The lichen is only known to occur at the type locality, which is a patch of mid-elevation, disturbed montane forest. The specific epithet isidiatus refers to the presence of isidia on the thallus. Rhabdodiscus isidiatus has a cream-colored to white, smooth to uneven thallus up to 5 cm (2 in) in diameter. The ascomata are rounded and prominent, measuring 0.7–1.0 mm in diameter with a 0.3–0.5 mm wide pore and a light brown rim. Its ascospores are hyaline, ellipsoid in shape, contain three thick septa, and measure 12–15 by 5–6 μm. Secondary chemicals present in the lichen include psoromic acid, subpsoromic acid, and 2'-O-demethylpsoromic acid.

Ocellularia upretii is a species of corticolous (bark-dwelling) lichen in the family Graphidaceae. It is found in India.

Ocellularia diospyri is a rare species of corticolous (bark-dwelling) lichen in the family Graphidaceae. It is found in northern Thailand.

Ocellularia neoperforata is a rare species of corticolous (bark-dwelling) lichen in the family Graphidaceae. Found in Malaysia, it was formally described as a new species in 2002 by lichenologists Natsurang Homchantara and Brian J. Coppins. The type specimen was collected by the second author from Gunung Mulu National Park (Sarawak) at an elevation of about 100 m (330 ft); here, it was found in a heath forest growing on a young tree. It is only known from the type collection at the type locality. The lichen has a shiny and smooth, greenish-grey thallus with a dense cortex and a white medulla. Its ascospores are trans-septate, narrowly ellipsoid, and measure 11–15 μm long. It contains fumarprotocetraric acid, a secondary compound. Ocellularia perforata is a lookalike species after which O. neoperforata is named. In contrast to the latter lichen, it has larger ascospores, less emergent apothecia, and contains protocetraric acid.

Ocellularia pluriporoides is a species of corticolous (bark-dwelling) lichen in the family Graphidaceae. Found in Northern Thailand, it was formally described as a new species in 2002 by lichenologists Natsurang Homchantara and Brian J. Coppins. The type specimen was collected in Doi Suthep National Park at an elevation of 1,600 m (5,200 ft); here, in an oak/chestnut forest, it was found growing on the trunk of Vaccinium sprengelii.

Ocellularia subleucina is a species of corticolous (bark-dwelling) lichen in the family Graphidaceae. Found in south-eastern Thailand, it was formally described as a new species in 2002 by lichenologists Natsurang Homchantara and Brian J. Coppins. The type specimen was collected in Khao Khitchakut National Park ; here it was found growing on trees in a lowland forest at an elevation of 400 m (1,300 ft). The lichen has a smooth to finely wrinkled, grey olivaceous thallus with a dense cortex and a white medulla. It does not contain any lichen substances. The specific epithet subleucina refers to its similarity with Ocellularia leucina, a lookalike species with smaller ascospores that contains psoromic acid.

Ocellularia wolseleyana is a species of lichen in the family Graphidaceae. Found in Eastern Thailand, it was formally described as a new species in 2002 by lichenologists Natsurang Homchantara and Brian J. Coppins. The type specimen was collected by the first author in Khao Yai National Park at an elevation of 830 m (2,720 ft). Here, in a mixed deciduous forest, the lichen was found growing on rock and on bark. It has a smooth and shiny, irregularly cracked thallus that ranges in colour from whitish mineral grey to olivaceous grey. It has a dense cortex and a white to creamy buff medulla. It contains psoromic acid, a secondary compound. Ocellularia neomasonhalei is similar in appearance to O. wolseleyana.

References

  1. 1 2 3 "Subpsoromic acid". Pubchem.ncbi.NLM.nih.gov.
  2. Elix, John A.; Wardlaw, Judith H.; Kalb, Klaus (2000). "Subpsoromic Acid, a New Depsidone from the Lichen Ocellularia praestans". Australian Journal of Chemistry. 53 (9): 813. doi:10.1071/CH00113.