Suessite

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Suessite
Suessite.jpg
General
CategoryIron silicide
Formula
(repeating unit)
Fe3Si
IMA symbol Sss [1]
Strunz classification 1.BB.05
Crystal system Cubic
Crystal class Hexoctahedral (m3m)
H-M symbol: (4/m 3 2/m)
Space group Im3m
Unit cell a = 2.841 Å; Z = 0.5
Identification
ColorCream white in reflected light, Terrestrial is light gray with a yellow tint
Crystal habit forms oval accumulations, polycrystalline aggregates
Cleavage None
Specific gravity 6.34
Optical propertiesX-ray Wavelength = 1.541838
Other characteristicsFerromagnetic,

degree of disorder = 11%, Curie point = 550°C, magnetic moment = 4.6 μB,

microhardness = 531–532 kg/mm

Contents

2
References [2] [3] [4] [5]

Suessite is a rare iron silicide mineral with chemical formula: Fe3Si. [6] The mineral was named after Professor Hans E. Suess. It was discovered in 1982 during the chemical analysis of The North Haig olivine pigeonite achondrite (ureilite). It is a cream white color in reflected light, and ranges in size from 1 μm "blebs" to elongated grains that can reach up to 0.45 cm in length. [7] This mineral belongs in the isometric crystal class. The isometric class has crystallographic axes that are all the same length and each of the three axes perpendicular to the other two. It is isotropic, has a structural type of DO3 and a crystal lattice of BiF3. [8]

Optical properties

Suessite is an isotropic mineral, Isotropism is defined as an optical property of a mineral that stays the same from whatever direction it is observed. In thin-section microscopy, an isotropic mineral has only one refractive index. This means that light that passes through the mineral is not split into two different directions, but it passes through unchanged. [9] Suessite, as determined from the previous definition, only has one index of refraction. When Keil, Fuchs, and Berkley first discovered the mineral they described it as having a relatively low optical relief, but there was no determination of the index of refraction. [10] In plane polarized light, suessite is a reddish-brown color that shows no pleochroism. [11]

Importance

"Suessite can form under highly reducing conditions" say the scientists who discovered this mineral. Only one out of eight ureilites studied (the North Haig ureilite) by this group contained suessite. Most contained trace amounts of kamacite which is the mineral from which Suessite is formed. In this particular study, the meteorite that contained suessite contained the highest amounts of shock metamorphism, which can be determined from the size of a shatter cone created from the impact. This could mean that suessite is formed due to the extreme increase in temperature combined with reduction of silicate rims, shortly followed by a rapid decrease in temperature. This means that, in meteorites, the abundance of suessite can be used to identify deformation associated with shock metamorphism, which could be used to determine various characteristics of the studied meteorites. [12]

Other iron silicide minerals

The other natural iron silicides include gupeiite (Fe3Si), hapkeite (Fe2Si), linzhiite (FeSi2), luobusaite (Fe0.84Si2), naquite (FeSi), xifengite (Fe5Si3), and zangboite (TiFeSi2). [13]

Related Research Articles

<span class="mw-page-title-main">Kamacite</span> Alloy of iron and nickel found in meteorites

Kamacite is an alloy of iron and nickel, which is found on Earth only in meteorites. According to the International Mineralogical Association (IMA) it is considered a proper nickel-rich variety of the mineral native iron. The proportion iron:nickel is between 90%:10% and 95%:5%; small quantities of other elements, such as cobalt or carbon may also be present. The mineral has a metallic luster, is gray and has no clear cleavage although its crystal structure is isometric-hexoctahedral. Its density is about 8 g/cm3 and its hardness is 4 on the Mohs scale. It is also sometimes called balkeneisen.

<span class="mw-page-title-main">Peridot</span> Green gem-quality mineral

Peridot, sometimes called chrysolite, is a yellowish-green transparent variety of olivine. Peridot is one of the few gemstones that occur in only one color.

<span class="mw-page-title-main">Pentlandite</span> Iron–nickel sulfide

Pentlandite is an iron–nickel sulfide with the chemical formula (Fe,Ni)9S8. Pentlandite has a narrow variation range in nickel to iron ratios (Ni:Fe), but it is usually described as 1:1. In some cases, this ratio is skewed by the presence of pyrrhotite inclusions. It also contains minor cobalt, usually at low levels as a fraction of weight.

<span class="mw-page-title-main">Metamorphism</span> Change of minerals in pre-existing rocks without melting into liquid magma

Metamorphism is the transformation of existing rock to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of 150 °C (300 °F), and often also at elevated pressure or in the presence of chemically active fluids, but the rock remains mostly solid during the transformation. Metamorphism is distinct from weathering or diagenesis, which are changes that take place at or just beneath Earth's surface.

<span class="mw-page-title-main">Chondrite</span> Class of stony meteorites made of round grains

A chondrite is a stony (non-metallic) meteorite that has not been modified, by either melting or differentiation of the parent body. They are formed when various types of dust and small grains in the early Solar System accreted to form primitive asteroids. Some such bodies that are captured in the planet's gravity well become the most common type of meteorite by arriving on a trajectory toward the planet's surface. Estimates for their contribution to the total meteorite population vary between 85.7% and 86.2%.

<span class="mw-page-title-main">Coffinite</span> Uranium-bearing silicate mineral

Coffinite is a uranium-bearing silicate mineral with formula: U(SiO4)1−x(OH)4x.

<span class="mw-page-title-main">Forsterite</span> Magnesium end-member of olivine, a nesosilicate mineral

Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthorhombic system (space group Pbnm) with cell parameters a 4.75 Å (0.475 nm), b 10.20 Å (1.020 nm) and c 5.98 Å (0.598 nm).

<span class="mw-page-title-main">Sperrylite</span>

Sperrylite is a platinum arsenide mineral with the chemical formula PtAs2 and is an opaque metallic tin white mineral which crystallizes in the isometric system with the pyrite group structure. It forms cubic, octahedral or pyritohedral crystals in addition to massive and reniform habits. It has a Mohs hardness of 6–7 and a very high specific gravity of 10.6.

<span class="mw-page-title-main">Lawsonite</span>

Lawsonite is a hydrous calcium aluminium sorosilicate mineral with formula CaAl2Si2O7(OH)2·H2O. Lawsonite crystallizes in the orthorhombic system in prismatic, often tabular crystals. Crystal twinning is common. It forms transparent to translucent colorless, white, pink, and bluish to pinkish grey glassy to greasy crystals. Refractive indices are nα = 1.665, nβ = 1.672 – 1.676, and nγ = 1.684 – 1.686. It is typically almost colorless in thin section, but some lawsonite is pleochroic from colorless to pale yellow to pale blue, depending on orientation. The mineral has a Mohs hardness of 7.5 and a specific gravity of 3.09. It has perfect cleavage in two directions and a brittle fracture.

<span class="mw-page-title-main">Ferrihydrite</span> Iron oxyhydroxide mineral

Ferrihydrite (Fh) is a widespread hydrous ferric oxyhydroxide mineral at the Earth's surface, and a likely constituent in extraterrestrial materials. It forms in several types of environments, from freshwater to marine systems, aquifers to hydrothermal hot springs and scales, soils, and areas affected by mining. It can be precipitated directly from oxygenated iron-rich aqueous solutions, or by bacteria either as a result of a metabolic activity or passive sorption of dissolved iron followed by nucleation reactions. Ferrihydrite also occurs in the core of the ferritin protein from many living organisms, for the purpose of intra-cellular iron storage.

<span class="mw-page-title-main">Ringwoodite</span> High-pressure phase of magnesium silicate

Ringwoodite is a high-pressure phase of Mg2SiO4 (magnesium silicate) formed at high temperatures and pressures of the Earth's mantle between 525 and 660 km (326 and 410 mi) depth. It may also contain iron and hydrogen. It is polymorphous with the olivine phase forsterite (a magnesium iron silicate).

Jarosewichite is a rare manganese arsenate mineral with formula: Mn2+3Mn3+(AsO4)(OH)6. It was first described in Franklin, New Jersey which is its only reported occurrence. Its chemical composition and structure are similar to chlorophoenicite. This mineral is orthorhombic with 2/m2/m2/m point group. Its crystals are prismatic or barrel-shaped. The color of jarosewichite is dark red to black. It has subvitreous luster of fracture surfaces and reddish-orange streak. This mineral occurs with flinkite, franklinite, andradite and cahnite.

<span class="mw-page-title-main">Iddingsite</span>

Iddingsite is a microcrystalline rock that is derived from alteration of olivine. It is usually studied as a mineral, and consists of a mixture of remnant olivine, clay minerals, iron oxides, and ferrihydrites. Debates over iddingsite's non-definite crystal structure caused it to be de-listed as an official mineral by the IMA; thus, it is properly referred to as a rock.

Paulingite or paulingite-K is a rare zeolite mineral that is found in vesicles in the basaltic rocks from the Columbia River near Rock Island Dam, Washington.

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<span class="mw-page-title-main">Enstatite chondrite</span> Rare type of meteorite

Enstatite chondrites are a rare form of meteorite, rich in the mineral enstatite. Only about 200 E-Type chondrites are currently known, comprising about 2% of the chondrites that fall on Earth. There are two main subtypes: EH and EL, classified based on their iron content.

<span class="mw-page-title-main">Khatyrkite</span>

Khatyrkite is a rare mineral which is mostly composed of copper and aluminium, but may contain up to about 15% of zinc or iron. Its chemical structure is described by an approximate formula (Cu,Zn)Al2 or (Cu,Fe)Al2. It was discovered in 1985 in a placer in association with another rare mineral cupalite. These two minerals have only been found at 62°39′11″N174°30′02″E in the area of the Iomrautvaam, a tributary of the Khatyrka river, in the Koryak Mountains, in Anadyrsky District, Chukotka, Russia. Analysis of one of the samples containing khatyrkite showed that the small rock was from a meteorite. A geological expedition has identified the exact place of the original discovery and found more specimens of the Khatyrka meteorite. The mineral's name derives from the Khatyrka zone where it was discovered. Its type specimen is preserved in the Mining Museum in Saint Petersburg, and parts of it can be found in other museums, such as Museo di Storia Naturale di Firenze.

<span class="mw-page-title-main">Coloradoite</span> Rare telluride ore

Coloradoite, also known as mercury telluride (HgTe), is a rare telluride ore associated with metallic deposit. Gold usually occurs within tellurides, such as coloradoite, as a high-finess native metal.

<span class="mw-page-title-main">Maricite</span> Phosphate mineral

Maricite or marićite is a sodium iron phosphate mineral (NaFe2+PO4), that has two metal cations connected to a phosphate tetrahedron. It is structurally similar to the much more common mineral olivine. Maricite is brittle, usually colorless to gray, and has been found in nodules within shale beds often containing other minerals.

Caswell Silver was an American geologist and entrepreneur who was President of Sundance Oil Company from 1960 to 1984. In addition to the business of oil and gas exploration, he was active in the American Association of Petroleum Geologists and published original research on petroleum geology. He endowed the Caswell Silver Foundation at the University of New Mexico.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Keil, K.,Berkley, J.L., and Fuchs, L.H. (1982) Suessite, Fe3Si: a New Mineral in the North Haig Ureilite. American Mineralogist, 67, 126.
  3. - (2010) "AMCSD Suessite." National Science Foundation <http://rruff.geo.arizona.edu/AMS/result.php>. Accessed 29 September 2010.
  4. Cabris, L.J., Fleischer, M., and Pabst, A. (1981) New Mineral Names. American Mineralogist, 66, 1099.
  5. Norvgorodova, M.I., Yosopov, R.G., Dmitrieva, M.T., Tsepin, A.I., Sivtsov, A.V., Gorshkov, A.I., Korovoshkin, V.V., and Yakubovskaya, N.Y. (1984) First Occurrence of Suessite on the Earth. International Geology Review, 26, 98.
  6. (2010) Suessite Glossary of Geology, American Geological Institute, <http://glossary.agiweb.org>. Accessed 13 September 2010.
  7. Keil, K., Berkley, J. L., and Fuchs, L.H. (1982) Suessite, Fe3Si: a New Mineral in the North Haig Ureilite. American Mineralogist, 67, 126.
  8. Norvgorodova, M.I., Yosopov, R.G., Dmitrieva, M.T., Tsepin, A.I., Sivtsov, A.V., Gorshkov, A.I., Korovoshkin, V.V., and Yakubovskaya, N.Y. (1984) First Occurrence of Suessite on the Earth. International Geology Review, 26, 98.
  9. Klein, C. and Dutrow, B. (2008) The Manual of Mineral Science, 23rd Edition
  10. Keil, K., Berkley, J. L., and Fuchs, L.H. (1982) Suessite, Fe3Si: a New Mineral in the North Haig Ureilite. American Mineralogist, 67, 126.
  11. Klein, C. and Dutrow, B. (2008) The Manual of Mineral Science, 23rd Edition
  12. Keil, K., Berkley, J. L., and Fuchs, L.H. (1982) Suessite, Fe3Si: a New Mineral in the North Haig Ureilite. American Mineralogist, 67, 126.
  13. Mindat, http://www.mindat.org