Pigeonite | |
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General | |
Category | Silicate mineral (pyroxene) |
Formula (repeating unit) | (Ca,Mg,Fe)(Mg,Fe)Si 2 O 6 |
IMA symbol | Pgt [1] |
Strunz classification | 9.DA.10 |
Dana classification | 65.01.01.04 |
Crystal system | Monoclinic |
Crystal class | Prismatic (2/m) (same H-M symbol) |
Space group | P21/c |
Unit cell | a = 9.7, b = 8.95, c = 5.24 [Å]; β = 108.59°; Z = 4 |
Identification | |
Color | Brown, greenish brown-black |
Crystal habit | Prismatic crystals, to 1 cm; granular, massive. |
Twinning | Commonly twinned simply or multiply on {100} or {001} |
Cleavage | Good on {110}, (110) ^ (110) ~87° |
Fracture | Conchoidal |
Tenacity | Brittle |
Mohs scale hardness | 6 |
Luster | Vitreous to dull |
Streak | Grey white |
Diaphaneity | Semitransparent |
Specific gravity | 3.17 – 3.46 measured |
Optical properties | Biaxial (+) |
Refractive index | nα = 1.683 – 1.722 nβ = 1.684 - 1.722 nγ = 1.704 – 1.752 |
Birefringence | δ = 0.021 – 0.030 |
Pleochroism | Weak to moderate; X = colorless, pale green, brown; Y = pale brown, pale brownish green, brownish pink; Z = colorless, pale green, pale yellow |
2V angle | 0 – 30° measured |
Dispersion | weak to distinct |
References | [2] [3] [4] |
Pigeonite is a mineral in the clinopyroxene subgroup of the pyroxene group. It has a general formula of (Ca,Mg,Fe)(Mg,Fe)Si 2 O 6. The calcium cation fraction can vary from 5% to 25%, with iron and magnesium making up the rest of the cations.
Pigeonite crystallizes in the monoclinic system, as does augite, and a miscibility gap exists between the two minerals. At lower temperatures, pigeonite is unstable relative to augite plus orthopyroxene. The low-temperature limit of pigeonite stability depends upon the Fe/Mg ratio in the mineral and is hotter for more Mg-rich compositions; for a Fe/Mg ratio of about 1, the temperature is about 900 °C. The presence of pigeonite in an igneous rock thus provides evidence for the crystallization temperature of the magma, and hence indirectly for the water content of that magma.
Pigeonite is found as phenocrysts in volcanic rocks on Earth and as crystals in meteorites from Mars and the Moon. In slowly cooled intrusive igneous rocks, pigeonite is rarely preserved. Slow cooling gives the calcium the necessary time to separate itself from the structure to form exsolution lamellae of calcic clinopyroxene, [5] leaving no pigeonite present. [6] Textural evidence of its breakdown to orthopyroxene plus augite may be present, as shown in the accompanying microscopic image.
Pigeonite is named for its type locality on Lake Superior's shores at Pigeon Point, Minnesota, United States. It was first described in 1900. [4] [7]
Gabbro is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is chemically equivalent to rapid-cooling, fine-grained basalt. Much of the Earth's oceanic crust is made of gabbro, formed at mid-ocean ridges. Gabbro is also found as plutons associated with continental volcanism. Due to its variant nature, the term gabbro may be applied loosely to a wide range of intrusive rocks, many of which are merely "gabbroic". By rough analogy, gabbro is to basalt as granite is to rhyolite.
Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks.
Basalt is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron exposed at or very near the surface of a rocky planet or moon. More than 90% of all volcanic rock on Earth is basalt. Rapid-cooling, fine-grained basalt is chemically equivalent to slow-cooling, coarse-grained gabbro. The eruption of basalt lava is observed by geologists at about 20 volcanoes per year. Basalt is also an important rock type on other planetary bodies in the Solar System. For example, the bulk of the plains of Venus, which cover ~80% of the surface, are basaltic; the lunar maria are plains of flood-basaltic lava flows; and basalt is a common rock on the surface of Mars.
Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO
4 tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.
The pyroxenes are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula XY(Si,Al)2O6, where X represents calcium (Ca), sodium (Na), iron or magnesium (Mg) and more rarely zinc, manganese or lithium, and Y represents ions of smaller size, such as chromium (Cr), aluminium (Al), magnesium (Mg), cobalt (Co), manganese (Mn), scandium (Sc), titanium (Ti), vanadium (V) or even iron. Although aluminium substitutes extensively for silicon in silicates such as feldspars and amphiboles, the substitution occurs only to a limited extent in most pyroxenes. They share a common structure consisting of single chains of silica tetrahedra. Pyroxenes that crystallize in the monoclinic system are known as clinopyroxenes and those that crystallize in the orthorhombic system are known as orthopyroxenes.
Augite is a common rock-forming pyroxene mineral with formula (Ca,Na)(Mg,Fe,Al,Ti)(Si,Al)2O6. The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees.
Nephelinite is a fine-grained or aphanitic igneous rock made up almost entirely of nepheline and clinopyroxene. If olivine is present, the rock may be classified as an olivine nephelinite. Nephelinite is dark in color and may resemble basalt in hand specimen. However, basalt consists mostly of clinopyroxene (augite) and calcic plagioclase.
Chromite is a crystalline mineral composed primarily of iron(II) oxide and chromium(III) oxide compounds. It can be represented by the chemical formula of FeCr2O4. It is an oxide mineral belonging to the spinel group. The element magnesium can substitute for iron in variable amounts as it forms a solid solution with magnesiochromite (MgCr2O4). A substitution of the element aluminium can also occur, leading to hercynite (FeAl2O4). Chromite today is mined particularly to make stainless steel through the production of ferrochrome (FeCr), which is an iron-chromium alloy.
Peridotite ( PERR-ih-doh-tyte, pə-RID-ə-) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high proportions of magnesium-rich olivine, with appreciable iron. Peridotite is derived from Earth's mantle, either as solid blocks and fragments, or as crystals accumulated from magmas that formed in the mantle. The compositions of peridotites from these layered igneous complexes vary widely, reflecting the relative proportions of pyroxenes, chromite, plagioclase, and amphibole.
Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthorhombic system (space group Pbnm) with cell parameters a 4.75 Å (0.475 nm), b 10.20 Å (1.020 nm) and c 5.98 Å (0.598 nm).
Diopside is a monoclinic pyroxene mineral with composition MgCaSi
2O
6. It forms complete solid solution series with hedenbergite and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull green crystals in the monoclinic prismatic class. It has two distinct prismatic cleavages at 87 and 93° typical of the pyroxene series. It has a Mohs hardness of six, a Vickers hardness of 7.7 GPa at a load of 0.98 N, and a specific gravity of 3.25 to 3.55. It is transparent to translucent with indices of refraction of nα=1.663–1.699, nβ=1.671–1.705, and nγ=1.693–1.728. The optic angle is 58° to 63°.
Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and metamorphic rocks. The intermediate composition, (Mg,Fe)SiO
3, has historically been known as hypersthene, although this name has been formally abandoned and replaced by orthopyroxene. When determined petrographically or chemically the composition is given as relative proportions of enstatite (En) and ferrosilite (Fs) (e.g., En80Fs20).
Aegirine is a member of the clinopyroxene group of inosilicate minerals. It is the sodium endmember of the aegirine–augite series. It has the chemical formula NaFeSi2O6, in which the iron is present as the ion Fe3+. In the aegirine–augite series, the sodium is variably replaced by calcium with iron(II) and magnesium replacing the iron(III) to balance the charge. Aluminum also substitutes for the iron(III). Acmite is a fibrous green-colored variety.
Komatiite is a type of ultramafic mantle-derived volcanic rock defined as having crystallised from a lava of at least 18 wt% magnesium oxide (MgO). It is classified as a 'picritic rock'. Komatiites have low silicon, potassium and aluminium, and high to extremely high magnesium content. Komatiite was named for its type locality along the Komati River in South Africa, and frequently displays spinifex texture composed of large dendritic plates of olivine and pyroxene.
Melilite refers to a mineral of the melilite group. Minerals of the group are solid solutions of several endmembers, the most important of which are gehlenite and åkermanite. A generalized formula for common melilite is (Ca,Na)2(Al,Mg,Fe2+)[(Al,Si)SiO7]. Discovered in 1793 near Rome, it has a yellowish, greenish-brown color. The name derives from the Greek words meli (μέλι) "honey" and lithos (λίθους) "stone".The name refers to a group of minerals (melilite group) with chemically similar composition, nearly always minerals in åkermanite-gehlenite series.
The tholeiitic magma series is one of two main magma series in subalkaline igneous rocks, the other being the calc-alkaline series. A magma series is a chemically distinct range of magma compositions that describes the evolution of a mafic magma into a more evolved, silica rich end member. Rock types of the tholeiitic magma series include tholeiitic basalt, ferro-basalt, tholeiitic basaltic andesite, tholeiitic andesite, dacite and rhyolite. The variety of basalt in the series was originally called tholeiite but the International Union of Geological Sciences recommends that tholeiitic basalt be used in preference to that term.
Normative mineralogy is a calculation of the composition of a rock sample that estimates the idealised mineralogy of a rock based on a quantitative chemical analysis according to the principles of geochemistry.
The endmember hornblende tschermakite (☐Ca2(Mg3Al2)(Si6Al2)O22(OH)2) is a calcium rich monoclinic amphibole mineral. It is frequently synthesized along with its ternary solid solution series members tremolite and cummingtonite so that the thermodynamic properties of its assemblage can be applied to solving other solid solution series from a variety of amphibole minerals.
Clinopyroxene thermobarometry is a scientific method that uses the mineral clinopyroxene to determine the temperature and pressure of the magma when the mineral crystalized. Clinopyroxene is found in many igneous rocks, so the method can be used to determine information about the entire rock. Many different minerals can be used for geothermobarometry, but clinopyroxene is especially useful because it's a common phenocryst in igneous rocks and easy to identify, and the crystallization of jadeite, a type of clinopyroxene, implies a growth in molar volume, making it a good indicator of pressure.
Kanoite is a light pinkish brown silicate mineral that is found in metamorphic rocks. It is an inosilicate and has a chemical formula of (Mg,Mn2+)2Si2O6. It is a member of pyroxene group and clinopyroxene subgroup.