The TAS classification can be used to assign names to many common types of volcanic rocks based upon the relationships between the combined alkali content and the silica content. These chemical parameters are useful, because the relative proportions of alkalis and silica play an important role in determining actual mineralogy and normative mineralogy. The classification appears to be and can be simple to use for rocks that have been chemically analyzed. Except for the following quotation from Johannsen (1937), this entry is based upon Le Maitre and others (2002).
TAS stands for Total Alkali Silica.
Before using the TAS or any other classification, however, the following words of Johannsen (1937) should be kept in mind.
The subtitle of the classification chapter by Johannsen (1937) is "Chacun a son goût" (to each his own taste).
Furthermore, as discussed in considerable detail by Le Maitre and others (2002), the classification cannot be applied to all volcanic rocks. Certain rocks cannot be named using the diagram. For others, additional chemical, mineralogic, or textural criteria must be used, as for lamprophyres.
The TAS classification should be applied only to rocks for which the mineral mode cannot be determined (otherwise, use a scheme based on mineralogy, such as the QAPF diagram or one of the other diagrams presented in the entry for igneous rocks). Before classifying rocks using the TAS diagram, the chemical analyses must be recalculated to 100% excluding water and carbon dioxide.
The names provided by Le Maitre et al. (2002) for fields in the TAS diagram are listed below.
B (Basalt) (Use normative mineralogy to subdivide)
O1 (Basaltic andesite)
O2 (Andesite)
O3 (Dacite)
R (Rhyolite)
T (Trachyte or Trachydacite) (Use normative mineralogy to decide)
Ph (Phonolite)
S1 (Trachybasalt) *Sodic and potassic variants are Hawaiite and Potassic Trachybasalt
S2 (Basaltic trachyandesite) *Sodic and potassic variants are Mugearite and Shoshonite
S3 (Trachyandesite *Sodic and potassic variants are Benmoreite and Latite
Pc (Picrobasalt)
U1 (Basanite or Tephrite) (Use normative mineralogy to decide)
U2 (Phonotephrite)
U3 (Tephriphonolite)
F (Foidite) (Name according to dominant feldspathoid when possible. Melilitites also plot in this area and can be distinguished by additional chemical criteria.)
A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks include basalt, diabase and gabbro. Mafic rocks often also contain calcium-rich varieties of plagioclase feldspar. Mafic materials can also be described as ferromagnesian.
Andesite is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predominantly of sodium-rich plagioclase plus pyroxene or hornblende.
Basanite is an igneous, volcanic (extrusive) rock with aphanitic to porphyritic texture. It is composed mostly of feldspathoids, pyroxenes, olivine, and plagioclase and forms from magma low in silica and enriched in alkali metal oxides that solidifies rapidly close to the Earth's surface.
Volcanic rock is a rock formed from lava erupted from a volcano. Like all rock types, the concept of volcanic rock is artificial, and in nature volcanic rocks grade into hypabyssal and metamorphic rocks and constitute an important element of some sediments and sedimentary rocks. For these reasons, in geology, volcanics and shallow hypabyssal rocks are not always treated as distinct. In the context of Precambrian shield geology, the term "volcanic" is often applied to what are strictly metavolcanic rocks. Volcanic rocks and sediment that form from magma erupted into the air are called "pyroclastics," and these are also technically sedimentary rocks.
Nephelinite is a fine-grained or aphanitic igneous rock made up almost entirely of nepheline and clinopyroxene. If olivine is present, the rock may be classified as an olivine nephelinite. Nephelinite is dark in color and may resemble basalt in hand specimen. However, basalt consists mostly of clinopyroxene (augite) and calcic plagioclase.
Nepheline syenite is a holocrystalline plutonic rock that consists largely of nepheline and alkali feldspar. The rocks are mostly pale colored, grey or pink, and in general appearance they are not unlike granites, but dark green varieties are also known. Phonolite is the fine-grained extrusive equivalent.
Lamprophyres are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica-undersaturated mafic or ultramafic rocks with high magnesium oxide, >3% potassium oxide, high sodium oxide, and high nickel and chromium.
Essexite, also called nepheline monzogabbro, is a dark gray or black holocrystalline plutonic igneous rock. Its name is derived from the type locality in Essex County, Massachusetts, in the United States.
Picrite basalt or picrobasalt is a variety of high-magnesium olivine basalt that is very rich in the mineral olivine. It is dark with yellow-green olivine phenocrysts (20-50%) and black to dark brown pyroxene, mostly augite.
A QAPF diagram is a double quasi-ternary diagram which is used to classify igneous rocks based on mineralogic composition. The acronym QAPF stands for "Quartz, Alkali feldspar, Plagioclase, Feldspathoid (Foid)". These are the mineral groups used for classification in QAPF diagram. Q, A, P and F percentages are normalized.
Trachyandesite is an extrusive igneous rock with a composition between trachyte and andesite. It has little or no free quartz, but is dominated by sodic plagioclase and alkali feldspar. It is formed from the cooling of lava enriched in alkali metals and with an intermediate content of silica.
The tholeiitic magma series is one of two main magma series in subalkaline igneous rocks, the other being the calc-alkaline series. A magma series is a chemically distinct range of magma compositions that describes the evolution of a mafic magma into a more evolved, silica rich end member. Rock types of the tholeiitic magma series include tholeiitic basalt, ferro-basalt, tholeiitic basaltic andesite, tholeiitic andesite, dacite and rhyolite. The variety of basalt in the series was originally called tholeiite but the International Union of Geological Sciences recommends that tholeiitic basalt be used in preference to that term.
The calc-alkaline magma series is one of two main subdivisions of the subalkaline magma series, the other subalkaline magma series being the tholeiitic series. A magma series is a series of compositions that describes the evolution of a mafic magma, which is high in magnesium and iron and produces basalt or gabbro, as it fractionally crystallizes to become a felsic magma, which is low in magnesium and iron and produces rhyolite or granite. Calc-alkaline rocks are rich in alkaline earths and alkali metals and make up a major part of the crust of the continents.
Hawaiite is an olivine basalt with a composition between alkali basalt and mugearite. It was first used as a name for some lavas found on the island of Hawaii.
Alkali basalt or alkali olivine basalt is a dark-colored, porphyritic volcanic rock usually found in oceanic and continental areas associated with volcanic activity, such as oceanic islands, continental rifts and volcanic fields. Alkali basalt is characterized by relatively high alkali (Na2O and K2O) content relative to other basalts and by the presence of olivine and titanium-rich augite in its groundmass and phenocrysts, and nepheline in its CIPW norm.
Igneous rock, or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava.
Trachybasalt is a volcanic rock with a composition between trachyte and basalt. It resembles basalt but has a high content of alkali metal oxides. Minerals in trachybasalt include alkali feldspar, calcic plagioclase, olivine, clinopyroxene and likely very small amounts of leucite or analcime.
Basaltic andesite is a volcanic rock that is intermediate in composition between basalt and andesite. It is composed predominantly of augite and plagioclase. Basaltic andesite can be found in volcanoes around the world, including in Central America and the Andes of South America.
The alkaline magma series is a chemically distinct range of magma compositions that describes the evolution of an alkaline mafic magma into a more evolved, silica-rich end member.