Tenual

Last updated
Tenual
Tenual.png
Names
IUPAC name
4-(hydroxymethyl)-6-methoxy-2-methyl-3-benzoxepine-5-carbaldehyde
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/C14H14O4/c1-9-6-10-4-3-5-12(17-2)14(10)11(7-15)13(8-16)18-9/h3-7,16H,8H2,1-2H3
    Key: CREMPVZYABCSKM-UHFFFAOYSA-N
  • COc1cccc2c1C(C=O)=C(CO)OC(C)=C2
Properties
C14H14O4
Molar mass 246.262 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Tenual is a natural product derived from Asphodeline tenuior . It is a 3-benzoxepin derivative with methoxy, methyl, hydroxymethyl, and carbaldehyde side chains. [1] [2]

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Asphodeline tenuior, the thin asphodeline, is a species of plant in the family Asphodelaceae, subfamily Asphodeloideae. It is native to the Caucasus, as well as from eastern Turkey and northwestern Iran. Within Russia, it is known from eastern Krasnodar Krai, Karachay-Cherkessia, Stavropol Krai and western Kabardino-Balkaria. It can be found on stony slopes and scree on limestone and sandstone, from elevations of 500–1,000 m. It is threatened by habitat loss and degradation, due to lime pits, slope terracing and cattle pasturing.

  1. Asphodeline tenuior var. puberulentaTuzlaci - eastern Turkey
  2. Asphodeline tenuior subsp. tenuiflora(K.Koch) Tuzlaci - Turkey, Iran, south Caucasus
  3. Asphodeline tenuior subsp. tenuior - north and south Caucasus
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References

  1. Ulubelen, Ayhan; Tuzlaci, Ertan; Atilan, Nur (January 1989). "Oxepine derivatives and anthraquinones from Asphodeline tenuior and A. Taurica". Phytochemistry. 28 (2): 649–650. doi:10.1016/0031-9422(89)80076-7.
  2. von Angerer, S. (2004). "Category 2, Hetarenes and Related Ring Systems: Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles". Science of Synthesis. 4: 653. doi:10.1055/sos-SD-017-00991.