Togo competed at the 2004 Summer Olympics in Athens, Greece, from 13 to 29 August 2004. The country's participation at Athens marked its seventh appearance in the Summer Olympics since its debut at the 1972 Summer Games in Munich, West Germany. The delegation included two track and field athletes and a single canoeist; Jan Sekpona in the men's 800 metres, Sandrine Thiébaud-Kangni in the women's 400 metres, and Benjamin Boukpeti in the men's K-1. Both Sekpona and Thiébaud-Kangni were eliminated in the first round of their competitions, while Boukpeti progressed to the semi-finals.
Gambia took part in the 2008 Summer Olympics, held in Beijing, China from 8 to 24 August 2008. It was Gambia's seventh appearance in the summer Olympics since its debut in 1984. The Gambia team included three athletes; runners Suwaibou Sanneh and Fatou Tiyana as well as boxer Badou Jack. Jack, a middleweight at his first Olympics, was selected as flag bearer for both the opening and closing ceremonies. None of the Gambia athletes progressed further than the qualifying heats.
Benin took part in the 2008 Summer Olympics which were held in Beijing, China from 8 to 24 August 2008. The country's participation at Beijing marked its eighth consecutive appearance in the summer Olympics since its debut in 1972, and its ninth Olympic appearance ever. The Benin delegation included five athletes in 2008, participating in three sports: athletics, swimming and taekwondo. Fabienne Feraez, a sprinter, was selected as the flag bearer for the opening ceremony. None of the Benin athletes progressed further than the heat round.
São Tomé and Príncipe competed at the 2008 Summer Olympics in Beijing, China from 8–24 August 2008. This marked the country's fourth entry in the Olympics, since its debut in the 1996 Summer Olympics in Atlanta, Georgia, United States. The country's delegation consisted of three competitors, competing in two disciplines: they were athletics competitors Naiel Santiago D'Almeida and Celma Bonfim da Graça, and canoeist Alcino Silva. None of the competitors made it to their event final, though Silva did advance to the semi-finals.
Jessica Esther "Jess" Fox is a French-born Australian Program and Policy Officer and world and Olympic champion slalom canoeist who has competed at the international level since 2008.
Chad competed at the 2012 Summer Olympics in London, which was held from 27 July to 12 August 2012. This marked the nation's eleventh appearance at the Summer Olympics since its debut in the 1964 Summer Olympics. The Chadian delegation included track and field athlete Hinikissia Ndikert and judoka Carine Ngarlemdana. Ngarlemdana was the flag bearer for the opening ceremony and Ndikert was the flag bearer for the closing ceremony. Neither of Chad's athletes progressed beyond the first round of their events. Chad was one of only two countries to have a female-only team at the 2012 games.
Equatorial Guinea competed at the 2012 Summer Olympics in London, which was held from 27 July to 12 August 2012. The country's participation at London marked its eighth appearance in the Summer Olympics since its début at the 1984 Summer Olympics. The delegation included two track and field athletes, Benjamín Enzema and Bibiana Olama who both qualified for the Games via wildcard places because their fastest times did not meet the required qualification standards. Olama was selected as the flag bearer for both the opening and closing ceremonies. Both athletes did not advance beyond the first round of their respective events.
Malawi competed at the 2012 Summer Olympics in London, which was held from 27 July to 12 August 2012. The country's participation at London marked its ninth appearance in the Summer Olympics since its début at the 1972 Summer Olympics. The delegation included two track and field athletes; Mike Tebulo and Ambwene Simukonda, and one swimmer; Joyce Tafatatha. Tebulo and Simukonda qualified through wildcard places for their respective events. Tebulo was selected as the flag bearer for the opening and closing ceremonies. Tebulo finished 44th in the men's marathon, while Simukonda did not advance beyond the first round of the women's 400 metres. Tafatatha won her heat in the women's 50 metre freestyle but her time was not fast enough to allow her to progress into the semi-finals of the event.
Mauritania competed at the 2012 Summer Olympics in London, which was held from 27 July to 12 August 2012. The country's participation at London marked its eighth appearance in the Summer Olympics since its debut in the 1984 Summer Olympics. The delegation included two track and field athletes, Jidou El Moctar and Aicha Fall, who were selected to the team by wildcard places, as the nation had no athletes that met either the "A" or "B" qualifying standards. Moctar was selected as flag bearer for the opening ceremony while a LOCOG Games Maker carried it for the closing ceremony. Neither of the two athletes progressed beyond the heats.
Eswatini (Swaziland) competed at the 2012 Summer Olympics in London, which was held from 27 July to 12 August 2012. The country's participation at London marked its ninth appearance in the Summer Olympics since its debut at the 1972 Summer Olympics. The delegation included two track and field athletes: Sibusiso Matsenjwa and Phumlile Ndzinisa, and one swimmer, Luke Hall; the first two competitors qualified for the Games through wildcard places while Hall was awarded a universality place by FINA. Hall was selected as the flag bearer for the opening ceremony and Matensjwa held it for the closing ceremony. All three competitors did not advance further than the heat stages of their respective events.
The women's canoe sprint K-1 500 metres at the 2012 Olympic Games in London took place between 7 and 9 August at Eton Dorney.
Ana Sátila Vieira Vargas is a Brazilian slalom canoeist who has competed at the international level since 2011.
Adzo Rebecca Kpossi is a Togolese swimmer who specialises in butterfly and freestyle. Kpossi competed in both the 2012 and 2016 Summer Olympics. At both of her Olympics, she competed in the 50 metre freestyle. She has also competed in two World Championships, a World Short Course Championship and an African Games.
Tsholofelo Thipe is a South African sprinter, who specialized in the 400 metres. She set a personal best time of 51.15 seconds by winning the 400 metres event at the 2009 South African Championships in Stellenbosch. She was born in Rustenburg, North West Province.
Norma Murabito is an Italian sprint canoeist. Murabito is a member of Aniene Canoeing Club in Rome, and is coached and trained by Stefano Grillo.
Marharyta Ryhorauna Makhneva, née Tsishkevich, Belarusian: Маргарыта Рыгораўна Махнева (Цішкевіч); Łacinka: Marharyta Ryhoraŭna Machnieva (Ciškievič); born 13 February 1992) is a Belarusian sprint canoeist. She won two gold medals at the 2015 World Championships and the bronze medal in Women's K-4 500 metres at the 2016 Summer Olympics. She won a silver medal at the 2020 Summer Olympics, in Women's K-4 500 metres.
Darisleydis Amador Rodríguez is a Cuban sprint canoeist. She won a silver medal in the women's K-1 200 metres at the 2011 Pan American Games in Guadalajara, Mexico by thirty-seven thousandths of a second (0.037) behind winner Carrie Johnson of the United States, with a time of 41.840 seconds.
Dayexi Gandarela Sosa is a Cuban sprint canoeist. She edged out the Argentine pair by two thirds of a second (0.67) for the gold medal in the women's K-2 500 metres at the 2011 Pan American Games in Guadalajara, Mexico.
Zhou Yu is a Chinese sprint canoeist. She won gold and silver medal in the women's kayak singles at the 2010 Asian Games in Guangzhou, China. Zhou is also a member of Hunan Sports Club, there she is coached and trained by Wu Yubiao.
Asumi Ōmura is a Japanese sprint canoeist, born in Shizuoka Prefecture. She won silver and bronze medal in the women's kayak doubles and four at the 2010 Asian Games in Guangzhou, China, respectively. Ōmura is also a member of the canoe and kayak team at Waseda University in Shinjuku, and is coached and trained by Octavian Ispas of Romania.
South Africa 
