The Tyndall effect is light scattering by particles in a colloid such as a very fine suspension (a sol). Also known as Tyndall scattering, it is similar to Rayleigh scattering, in that the intensity of the scattered light is inversely proportional to the fourth power of the wavelength, so blue light is scattered much more strongly than red light. An example in everyday life is the blue colour sometimes seen in the smoke emitted by motorcycles, in particular two-stroke machines where the burnt engine oil provides these particles. [1] The same effect can also be observed with tobacco smoke whose fine particles also preferentially scatter blue light.
Under the Tyndall effect, the longer wavelengths are transmitted more, while the shorter wavelengths are more diffusely reflected via scattering. [1] The Tyndall effect is seen when light-scattering particulate matter is dispersed in an otherwise light-transmitting medium, where the diameter of an individual particle is in the range of roughly 40 to 900 nm, i.e. somewhat below or near the wavelengths of visible light (400–750 nm).
It is particularly applicable to colloidal mixtures; for example, the Tyndall effect is used in nephelometers to determine the size and density of particles in aerosols [1] and other colloidal matter. Investigation of the phenomenon led directly to the invention of the ultramicroscope and turbidimetry.
It is named after the 19th-century physicist John Tyndall, who first studied the phenomenon extensively. [1]
Prior to his discovery of the phenomenon, Tyndall was primarily known for his work on the absorption and emission of radiant heat on a molecular level. In his investigations in that area, it had become necessary to use air from which all traces of floating dust and other particulates had been removed, and the best way to detect these particulates was to bathe the air in intense light. [2] In the 1860s, Tyndall did a number of experiments with light, shining beams through various gases and liquids and recording the results. In doing so, Tyndall discovered that when gradually filling the tube with smoke and then shining a beam of light through it, the beam appeared to be blue from the sides of the tube but red from the far end. [3] This observation enabled Tyndall to first propose the phenomenon which would later bear his name.
In 1902, the ultramicroscope was developed by Richard Adolf Zsigmondy (1865–1929) and Henry Siedentopf (1872–1940), working for Carl Zeiss AG. Curiosity about the Tyndall effect led them to apply bright sunlight for illumination and they were able to determine the size of 4 nm small gold nanoparticles that generate the cranberry glass colour. This work led directly to Zsigmondy's Nobel Prize for chemistry. [4] [5]
Rayleigh scattering is defined by a mathematical formula that requires the light-scattering particles to be far smaller than the wavelength of the light. [6] For a dispersion of particles to qualify for the Rayleigh formula, the particle sizes need to be below roughly 40 nanometres (for visible light),[ citation needed ] and the particles may be individual molecules. [6] Colloidal particles are bigger and are in the rough vicinity of the size of a wavelength of light. Tyndall scattering, i.e. colloidal particle scattering, [7] is much more intense than Rayleigh scattering due to the bigger particle sizes involved.[ citation needed ] The importance of the particle size factor for intensity can be seen in the large exponent it has in the mathematical statement of the intensity of Rayleigh scattering. If the colloid particles are spheroid, Tyndall scattering can be mathematically analyzed in terms of Mie theory, which admits particle sizes in the rough vicinity of the wavelength of light. [6] Light scattering by particles of complex shape are described by the T-matrix method. [8]
The color of blue eyes is due to the Tyndall scattering of light by a translucent layer of turbid media in the iris containing numerous small particles of about 0.6 micrometers in diameter. These particles are finely suspended within the fibrovascular structure of the stroma or front layer of the iris. [9] Some brown irises have the same layer, except with more melanin in it. Moderate amounts of melanin make hazel, dark blue and green eyes.
In eyes that contain both particles and melanin, melanin absorbs light. In the absence of melanin, the layer is translucent (i.e. the light passing through is randomly and diffusely scattered by the particles) and a noticeable portion of the light that enters this translucent layer re-emerges via a radial scattered path. That is, there is backscatter, the redirection of the light waves back out to the open air.
Scattering takes place to a greater extent at shorter wavelengths. The longer wavelengths tend to pass straight through the translucent layer with unaltered paths of yellow light, and then encounter the next layer further back in the iris, which is a light absorber called the epithelium or uvea that is colored brownish-black. The brightness or intensity of scattered blue light that is scattered by the particles is due to this layer along with the turbid medium of particles within the stroma.
Thus, the longer wavelengths are not reflected (by scattering) back to the open air as much as the shorter wavelengths. Because the shorter wavelengths are the blue wavelengths, this gives rise to a blue hue in the light that comes out of the eye. [10] [11] The blue iris is an example of a structural color because it relies only on the interference of light through the turbid medium to generate the color.
Blue eyes and brown eyes, therefore, are anatomically different from each other in a genetically non-variable way because of the difference between turbid media and melanin. Both kinds of eye color can remain functionally separate despite being "mixed" together.
When the day's sky is overcast, sunlight passes through the turbidity layer of the clouds, resulting in scattered, diffuse light on the ground (sunbeam). This exhibits Mie scattering instead of Tyndall scattering because the cloud droplets are larger than the wavelength of the light and scatters all colors approximately equally.[ citation needed ] When the daytime sky is cloudless, the sky's color is blue due to Rayleigh scattering instead of Tyndall scattering because the scattering particles are the air molecules, which are much smaller than the wavelengths of visible light. [12] Similarly, the term Tyndall effect is incorrectly applied to light scattering by large, macroscopic dust particles in the air as due to their large size, they do not exhibit Tyndall scattering. [1]
Scattering process | Particle type | Particle size | Resulting effect |
---|---|---|---|
Rayleigh scattering | Air molecule (N2 and O2) | < 1 nanometer | Sky blue hue |
Tyndall scattering | Colloidal particles in suspension | 50 nm to 1 μm | Blue scattered light |
Mie scattering | Larger air dust, or cloud droplets | > 1 micrometer | All colors equally scattered |
A colloid is a mixture in which one substance consisting of microscopically dispersed insoluble particles is suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others extend the definition to include substances like aerosols and gels. The term colloidal suspension refers unambiguously to the overall mixture. A colloid has a dispersed phase and a continuous phase. The dispersed phase particles have a diameter of approximately 1 nanometre to 1 micrometre.
Rayleigh scattering is the scattering or deflection of light, or other electromagnetic radiation, by particles with a size much smaller than the wavelength of the radiation. For light frequencies well below the resonance frequency of the scattering medium, the amount of scattering is inversely proportional to the fourth power of the wavelength. The phenomenon is named after the 19th-century British physicist Lord Rayleigh.
The iris is a thin, annular structure in the eye in most mammals and birds that is responsible for controlling the diameter and size of the pupil, and thus the amount of light reaching the retina. In optical terms, the pupil is the eye's aperture, while the iris is the diaphragm. Eye color is defined by the iris.
In physics, scattering is a wide range of physical processes where moving particles or radiation of some form, such as light or sound, are forced to deviate from a straight trajectory by localized non-uniformities in the medium through which they pass. In conventional use, this also includes deviation of reflected radiation from the angle predicted by the law of reflection. Reflections of radiation that undergo scattering are often called diffuse reflections and unscattered reflections are called specular (mirror-like) reflections. Originally, the term was confined to light scattering. As more "ray"-like phenomena were discovered, the idea of scattering was extended to them, so that William Herschel could refer to the scattering of "heat rays" in 1800. John Tyndall, a pioneer in light scattering research, noted the connection between light scattering and acoustic scattering in the 1870s. Near the end of the 19th century, the scattering of cathode rays and X-rays was observed and discussed. With the discovery of subatomic particles and the development of quantum theory in the 20th century, the sense of the term became broader as it was recognized that the same mathematical frameworks used in light scattering could be applied to many other phenomena.
Diffuse sky radiation is solar radiation reaching the Earth's surface after having been scattered from the direct solar beam by molecules or particulates in the atmosphere. It is also called sky radiation, the determinative process for changing the colors of the sky. Approximately 23% of direct incident radiation of total sunlight is removed from the direct solar beam by scattering into the atmosphere; of this amount about two-thirds ultimately reaches the earth as photon diffused skylight radiation.
An ultramicroscope is a microscope with a system that lights the object in a way that allows viewing of tiny particles via light scattering, and not light reflection or absorption. When the diameter of a particle is below or near the wavelength of visible light, the particle cannot be seen in a light microscope with the usual methods of illumination. The ultra- in ultramicroscope refers to the ability to see objects whose diameter is shorter than the wavelength of visible light, on the model of the ultra- in ultraviolet.
Turbidity is the cloudiness or haziness of a fluid caused by large numbers of individual particles that are generally invisible to the naked eye, similar to smoke in air. The measurement of turbidity is a key test of both water clarity and water quality.
A nephelometer or aerosol photometer is an instrument for measuring the concentration of suspended particulates in a liquid or gas colloid. A nephelometer measures suspended particulates by employing a light beam and a light detector set to one side of the source beam. Particle density is then a function of the light reflected into the detector from the particles. To some extent, how much light reflects for a given density of particles is dependent upon properties of the particles such as their shape, color, and reflectivity. Nephelometers are calibrated to a known particulate, then use environmental factors (k-factors) to compensate lighter or darker colored dusts accordingly. K-factor is determined by the user by running the nephelometer next to an air sampling pump and comparing results. There are a wide variety of research-grade nephelometers on the market as well as open source varieties.
In the field of optics, transparency is the physical property of allowing light to pass through the material without appreciable scattering of light. On a macroscopic scale, the photons can be said to follow Snell's law. Translucency allows light to pass through but does not necessarily follow Snell's law; the photons can be scattered at either of the two interfaces, or internally, where there is a change in the index of refraction. In other words, a translucent material is made up of components with different indices of refraction. A transparent material is made up of components with a uniform index of refraction. Transparent materials appear clear, with the overall appearance of one color, or any combination leading up to a brilliant spectrum of every color. The opposite property of translucency is opacity. Other categories of visual appearance, related to the perception of regular or diffuse reflection and transmission of light, have been organized under the concept of cesia in an order system with three variables, including transparency, translucency and opacity among the involved aspects.
In chemistry, a suspension is a heterogeneous mixture of a fluid that contains solid particles sufficiently large for sedimentation. The particles may be visible to the naked eye, usually must be larger than one micrometer, and will eventually settle, although the mixture is only classified as a suspension when and while the particles have not settled out.
A sunbeam, in meteorological optics, is a beam of sunlight that appears to radiate from the position of the Sun. Shining through openings in clouds or between other objects such as mountains and buildings, these beams of particle-scattered sunlight are essentially parallel shafts separated by darker shadowed volumes. Their apparent convergence in the sky is a visual illusion from linear perspective. The same illusion causes the apparent convergence of parallel lines on a long straight road or hallway at a distant vanishing point. The scattering particles that make sunlight visible may be air molecules or particulates.
Eye color is a polygenic phenotypic trait determined by two factors: the pigmentation of the eye's iris and the frequency-dependence of the scattering of light by the turbid medium in the stroma of the iris.
In physics, backscatter is the reflection of waves, particles, or signals back to the direction from which they came. It is usually a diffuse reflection due to scattering, as opposed to specular reflection as from a mirror, although specular backscattering can occur at normal incidence with a surface. Backscattering has important applications in astronomy, photography, and medical ultrasonography. The opposite effect is forward scatter, e.g. when a translucent material like a cloud diffuses sunlight, giving soft light.
The color of water varies with the ambient conditions in which that water is present. While relatively small quantities of water appear to be colorless, pure water has a slight blue color that becomes deeper as the thickness of the observed sample increases. The hue of water is an intrinsic property and is caused by selective absorption and scattering of blue light. Dissolved elements or suspended impurities may give water a different color.
Particle agglomeration refers to the formation of assemblages in a suspension and represents a mechanism leading to the functional destabilization of colloidal systems. During this process, particles dispersed in the liquid phase stick to each other, and spontaneously form irregular particle assemblages, flocs, or agglomerates. This phenomenon is also referred to as coagulation or flocculation and such a suspension is also called unstable. Particle agglomeration can be induced by adding salts or other chemicals referred to as coagulant or flocculant.
Dynamic light scattering (DLS) is a technique in physics that can be used to determine the size distribution profile of small particles in suspension or polymers in solution. In the scope of DLS, temporal fluctuations are usually analyzed using the intensity or photon autocorrelation function. In the time domain analysis, the autocorrelation function (ACF) usually decays starting from zero delay time, and faster dynamics due to smaller particles lead to faster decorrelation of scattered intensity trace. It has been shown that the intensity ACF is the Fourier transform of the power spectrum, and therefore the DLS measurements can be equally well performed in the spectral domain. DLS can also be used to probe the behavior of complex fluids such as concentrated polymer solutions.
Light scattering by particles is the process by which small particles scatter light causing optical phenomena such as the blue color of the sky, and halos.
Static light scattering is a technique in physical chemistry that measures the intensity of the scattered light to obtain the average molecular weight Mw of a macromolecule like a polymer or a protein in solution. Measurement of the scattering intensity at many angles allows calculation of the root mean square radius, also called the radius of gyration Rg. By measuring the scattering intensity for many samples of various concentrations, the second virial coefficient, A2, can be calculated.
Atmospheric optics is "the study of the optical characteristics of the atmosphere or products of atmospheric processes .... [including] temporal and spatial resolutions beyond those discernible with the naked eye". Meteorological optics is "that part of atmospheric optics concerned with the study of patterns observable with the naked eye". Nevertheless, the two terms are sometimes used interchangeably.
Earth's shadow is the shadow that Earth itself casts through its atmosphere and into outer space, toward the antisolar point. During the twilight period, the shadow's visible fringe – sometimes called the dark segment or twilight wedge – appears as a dark and diffuse band just above the horizon, most distinct when the sky is clear.