Uranium tile

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The orange-colored tiles in the town hall in Schneeberg, Saxony are made with a Uranium glaze Rathaus Schneeberg Brunnen 110430 (137).JPG
The orange-colored tiles in the town hall in Schneeberg, Saxony are made with a Uranium glaze
Green glazed tile Green Radioactive Tile.jpg
Green glazed tile
Cream colored uranium tile Cream Colored Uranium Tile.jpg
Cream colored uranium tile

Uranium tiles have been used in the ceramics industry for many centuries, as uranium oxide makes an excellent ceramic glaze, and is reasonably abundant. In addition to its medical usage, radium was used in the 1920s and 1930s for making watch, clock and aircraft dials. Because it takes approximately three metric tons of uranium to extract 1 gram of radium, prodigious quantities of uranium were mined to sustain this new industry. The uranium ore itself was considered a waste product and taking advantage of this newly abundant resource, the tile and pottery industry had a relatively inexpensive and abundant source of glazing material. Vibrant colors of orange, yellow, red, green, blue, black, mauve, etc. were produced, and some 25% of all houses and apartments constructed[ where? ] during that period (circa 1920–1940) used bathroom or kitchen tiles that had been glazed with uranium. These can now be detected by a Geiger counter that detects the beta radiation emitted by uranium's decay chain.

Contents

The use of uranium in ceramic glazes ceased during World War II when all uranium was diverted to the Manhattan project and didn't resume until 1959. In 1987, NCRP Report 95 indicated that no manufacturers were using uranium-glaze in dinnerware. [1]

Background

Not long after Henri Becquerel discovered radioactivity in uranium salts, Marie Curie discovered both polonium and radium as two new radioactive elements also present with uranium. The relatively high specific activity and moderate half-life of 1,600 years of 226Ra, the main radioisotope of radium found in uranium ore, made for a material which when mixed with a phosphor allowed for a glow-in-the-dark substance.

Thus, in addition to its medical usage, radium usage also became a major industry in the 1920s and 1930s for making watch, clock and aircraft dials. The radium dial painters brought a certain degree of notoriety to the abuse of radioactive materials, and that precautions needed to be followed with this new substance.

Because it takes approximately three metric tons of uranium to extract 1 gram of 226Ra, prodigious quantities of uranium were mined to sustain this new industry. The uranium ore itself was a "waste product" of this industry. By some estimates, nearly one million tons of uranium were mined to support this industry.

Taking advantage of this newly abundant resource, the tile and pottery glazing industry then had a relatively inexpensive and abundant source of glazing material that produced a wide variety of colors depending upon admixtures, firing, etc.

Vibrant colors of orange, yellow, red, green, blue, black, mauve, etc. were produced on tiles and other ceramic materials, and by some estimates, some 25% of all houses and apartments constructed during that period (circa 1920–1940) used varying amounts of bathroom or kitchen tiles that had been glazed with varying amounts of uranium. These can now be readily found in older homes, apartments, and other buildings still standing from that era by use of a simple Geiger counter that readily detects the beta radiation emitted by uranium's ever-present decay chain radio-daughters. [2]

After Euratom restrictions about uranium uses in ceramic glazes, there are no factories working with uranium glazes, which is why uranium glazed tiles have become rare pieces for collectors. [2]

These glazes are generally made with 238U raw material, known as yellowcake UO2 uranium granules. 21st century contemporary ceramic artist and academic researcher Sencer Sarı is one of the known specialists who is working with these uranium glazes. [3]

Health concerns

Radioactive uranium compounds such as uranium oxide and sodium uranate) are used to impart the colors orange-red, green, yellow and black to ceramic glaze.

Although the uranium in the glaze emits gamma rays, alpha particles, and beta particles, the gamma and alpha emissions are usually too weak to be of concern. [2] The beta particles are the easiest to detect, and they are also responsible for the bulk of the radiation exposure to those handling ceramics that employ a uranium glaze.

NCRP Report 95 reported the following measurements for dinnerware employing uranium glazes: 0.2 to 20 mrad per hour on contact as measured using film badges.

NUREG/CRCP-0001 reported a measurement of approximately 0.7 mR/hr at 25 cm from a Fiesta red dinner plate. It also reported the results of an Oak Ridge National Laboratory analysis that predicted 34.4 mrem/year to a dishwasher at a restaurant using ceramic plates containing 20% uranium in the glaze, 7.9 mrem/year to the waiters, and 0.2 mrem to a patron for a four-hour exposure.

Radioactive decay leads to the presence of radon (222Rn) in the glazing which may be leached through contact with acid. Tableware with uranium glazing should not be in prolonged contact with acid foodstuff such as fruit pulp or vinegar and the glazing should not be damaged or abrased through intensive use of cutlery. [4] An FDA study[ clarification needed ] measured 1.66 x 10−5 uCi/ml in a 4% acetic acid solution in contact with the ceramic dinnerware for 50 hours. This exceeded the ICRP's maximum permissible concentration (MPC).

Ordinary ceramics often contain elevated levels of naturally occurring radionuclides, e.g., 40K and the various members of the uranium and thorium decay series. Because of this, health physicists who are conducting radiation surveys expect to see higher readings when they are making measurements over ceramic tiles and similar materials. Sometimes the higher readings are due to uranium in the glaze; sometimes they are due to the radionuclides in the clay that was used to produce the ceramic.

Reported examples include a vehicle carrying toilets setting off a radiation monitor at a truck weigh station, and health physicists at Oak Ridge National Laboratory reporting excessively high readings while surveying newly purchased urinals for the men's restrooms. [5]

See also

Related Research Articles

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<span class="mw-page-title-main">Radium</span> Chemical element with atomic number 88 (Ra)

Radium is a chemical element; it has symbol Ra and atomic number 88. It is the sixth element in group 2 of the periodic table, also known as the alkaline earth metals. Pure radium is silvery-white, but it readily reacts with nitrogen (rather than oxygen) upon exposure to air, forming a black surface layer of radium nitride (Ra3N2). All isotopes of radium are radioactive, the most stable isotope being radium-226 with a half-life of 1,600 years. When radium decays, it emits ionizing radiation as a by-product, which can excite fluorescent chemicals and cause radioluminescence. For this property, it was widely used in self-luminous paints following its discovery. Of the radioactive elements that occur in quantity, radium is considered particularly toxic, and it is carcinogenic due to the radioactivity of both it and its immediate decay product radon as well as its tendency to accumulate in the bones.

<span class="mw-page-title-main">Uranium</span> Chemical element with atomic number 92 (U)

Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium radioactively decays, usually by emitting an alpha particle. The half-life of this decay varies between 159,200 and 4.5 billion years for different isotopes, making them useful for dating the age of the Earth. The most common isotopes in natural uranium are uranium-238 and uranium-235. Uranium has the highest atomic weight of the primordially occurring elements. Its density is about 70% higher than that of lead and slightly lower than that of gold or tungsten. It occurs naturally in low concentrations of a few parts per million in soil, rock and water, and is commercially extracted from uranium-bearing minerals such as uraninite.

A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferred to one of its electrons to release it as a conversion electron; or used to create and emit a new particle (alpha particle or beta particle) from the nucleus. During those processes, the radionuclide is said to undergo radioactive decay. These emissions are considered ionizing radiation because they are energetic enough to liberate an electron from another atom. The radioactive decay can produce a stable nuclide or will sometimes produce a new unstable radionuclide which may undergo further decay. Radioactive decay is a random process at the level of single atoms: it is impossible to predict when one particular atom will decay. However, for a collection of atoms of a single nuclide the decay rate, and thus the half-life (t1/2) for that collection, can be calculated from their measured decay constants. The range of the half-lives of radioactive atoms has no known limits and spans a time range of over 55 orders of magnitude.

<span class="mw-page-title-main">Radioactive waste</span> Unusable radioactive materials

Radioactive waste is a type of hazardous waste that contains radioactive material. It is a result of many activities, including nuclear medicine, nuclear research, nuclear power generation, nuclear decommissioning, rare-earth mining, and nuclear weapons reprocessing. The storage and disposal of radioactive waste is regulated by government agencies in order to protect human health and the environment.

<span class="mw-page-title-main">Curie (unit)</span> Non-SI unit of radioactivity

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<span class="mw-page-title-main">Uranium-238</span> Isotope of uranium

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<span class="mw-page-title-main">Fiesta (dinnerware)</span> Line of ceramic glazed dinnerware

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Polonium-210 (210Po, Po-210, historically radium F) is an isotope of polonium. It undergoes alpha decay to stable 206Pb with a half-life of 138.376 days (about 4+12 months), the longest half-life of all naturally occurring polonium isotopes (210–218Po). First identified in 1898, and also marking the discovery of the element polonium, 210Po is generated in the decay chain of uranium-238 and radium-226. 210Po is a prominent contaminant in the environment, mostly affecting seafood and tobacco. Its extreme toxicity is attributed to intense radioactivity, mostly due to alpha particles, which easily cause radiation damage, including cancer in surrounding tissue. The specific activity of 210
Po
is 166 TBq/g, i.e., 1.66 × 1014 Bq/g. At the same time, 210Po is not readily detected by common radiation detectors, because its gamma rays have a very low energy. Therefore, 210
Po
can be considered as a quasi-pure alpha emitter.

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<span class="mw-page-title-main">Uranium dioxide</span> Chemical compound

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<span class="mw-page-title-main">Radium dial</span> Instrument dials painted with radium-based paint

Radium dials are watch, clock and other instrument dials painted with luminous paint containing radium-226 to produce radioluminescence. Radium dials were produced throughout most of the 20th century before being replaced by safer tritium-based luminous material in the 1970s and finally by non-toxic, non-radioactive strontium aluminate–based photoluminescent material from the middle 1990s.

<span class="mw-page-title-main">Ceramic glaze</span> Fused coating on ceramic objects

Ceramic glaze, or simply glaze, is a glassy coating on ceramics. It is used for decoration, to ensure the item is impermeable to liquids and to minimise the adherence of pollutants.

<span class="mw-page-title-main">Undark</span> Radioactive luminous radium paint produced in the early 20th century

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<span class="mw-page-title-main">Gamma ray</span> Penetrating form of electromagnetic radiation

A gamma ray, also known as gamma radiation (symbol
γ
), is a penetrating form of electromagnetic radiation arising from the radioactive decay of atomic nuclei. It consists of the shortest wavelength electromagnetic waves, typically shorter than those of X-rays. With frequencies above 30 exahertz (3×1019 Hz) and wavelengths less than 10 picometers (1×10−11 m), gamma ray photons have the highest photon energy of any form of electromagnetic radiation. Paul Villard, a French chemist and physicist, discovered gamma radiation in 1900 while studying radiation emitted by radium. In 1903, Ernest Rutherford named this radiation gamma rays based on their relatively strong penetration of matter; in 1900, he had already named two less penetrating types of decay radiation (discovered by Henri Becquerel) alpha rays and beta rays in ascending order of penetrating power.

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2
He
2+ indicating a helium ion with a +2 charge (missing its two electrons). Once the ion gains electrons from its environment, the alpha particle becomes a normal (electrically neutral) helium atom 4
2
He
.

References

  1. Harry McMaster. Earthenware Dishes and Glaze Therefor. Patent No. 1,890,297,
  2. 1 2 3 msnbc.com, Alan Boyle (2003-12-12). "Uranium hunter follows trail of tiles". msnbc.com. Archived from the original on October 12, 2013. Retrieved 2019-05-28.
  3. "Luminescent fairies (Vilnius 2017) – Sencer Sarı".
  4. Robert Josef Schwankner, Michael Eigenstetter, Rudolf Laubinger, Michael Schmidt (2005), "Strahlende Kostbarkeiten: Uran als Farbkörper in Gläsern und Glasuren", Physik in unserer Zeit, vol. 36, no. 4, Wiley-VCH Verlag, pp. 160–167, doi:10.1002/piuz.200501073, ISSN   0031-9252 {{citation}}: CS1 maint: multiple names: authors list (link)
  5. Frame, Paul (2009-01-20). "General Information About Uranium in Ceramics". demolab.phys.virginia.edu. Retrieved 2022-08-08.