Uranium tile

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The orange-colored tiles in the town hall in Schneeberg, Saxony are made with a Uranium glaze Rathaus Schneeberg Brunnen 110430 (137).JPG
The orange-colored tiles in the town hall in Schneeberg, Saxony are made with a Uranium glaze
Green radioactive tile Green Radioactive Tile.jpg
Green radioactive tile
Cream colored uranium tile Cream Colored Uranium Tile.jpg
Cream colored uranium tile

Uranium tiles have been used in the ceramics industry for many centuries, as uranium oxide makes an excellent ceramic glaze, and is reasonably abundant. In addition to its medical usage, radium was used in the 1920s and 1930s for making watch, clock and aircraft dials. Because it takes approximately three metric tons of uranium to extract 1 gram of radium, prodigious quantities of uranium were mined to sustain this new industry. The uranium ore itself was considered a waste product and taking advantage of this newly abundant resource, the tile and pottery industry had a relatively inexpensive and abundant source of glazing material. Vibrant colors of orange, yellow, red, green, blue, black, mauve, etc. were produced, and some 25% of all houses and apartments constructed[ where? ] during that period (circa 1920–1940) used bathroom or kitchen tiles that had been glazed with uranium. These can now be detected by a Geiger counter that detects the beta radiation emitted by uranium's decay chain.

Contents

The use of uranium in ceramic glazes ceased during World War II when all uranium was diverted to the Manhattan project and didn't resume until 1959. In 1987, NCRP Report 95 indicated that no manufacturers were using uranium-glaze in dinnerware. [1]

Potential doses

Although the uranium in the glaze emits gamma rays, alpha particles, and beta particles, the gamma and alpha emissions are weak. The beta particles are the easiest to detect, and they are also responsible for the bulk of the radiation exposure to those handling ceramics that employ a uranium glaze.

NCRP Report 95 reported the following measurements for dinnerware employing uranium glazes: 0.2 to 20 mrad per hour on contact as measured using film badges;

NUREG/CRCP-0001 reported a measurement of approximately 0.7 mR/hr at 25 cm from a Fiesta red dinner plate. It also reported the results of an Oak Ridge National Laboratory analysis that predicted 34.4 mrem/year to a dishwasher at a restaurant using ceramic plates containing 20% uranium in the glaze, 7.9 mrem/year to the waiters, and 0.2 mrem to a patron for a four-hour exposure.

It is likely that the major health issue associated with this dinnerware is not the radiation exposures but the ingestion of uranium or other heavy metals that have leached into food or drink in contact with the dinnerware. One FDA study[ clarification needed ] measured 1.66 x 10−5 uCi/ml in a 4% acetic acid solution in contact with the ceramic dinnerware for 50 hours. This exceeded the ICRP's maximum permissible concentration (MPC).

Ordinary ceramics often contain elevated levels of naturally occurring radionuclides, e.g., 40K and the various members of the uranium and thorium decay series. Because of this, health physicists who are conducting radiation surveys expect to see higher readings when they are making measurements over ceramic tiles and similar materials. Sometimes the higher readings are due to uranium in the glaze; sometimes they are due to the radionuclides in the clay that was used to produce the ceramic.

Reported examples include a vehicle carrying toilets setting off a radiation monitor at a truck weigh station, and health physicists at Oak Ridge National Laboratory reporting excessively high readings while surveying newly purchased urinals for the men's restrooms. [2]

Ceramics can be particularly radioactive if some compound of uranium (e.g., uranium oxide, sodium uranate) has been used to impart color (e.g., orange-red, green, yellow, black) to the glaze.

Background

Not long after Henri Becquerel discovered radioactivity in uranium salts, Marie Curie discovered both polonium and radium as two new radioactive elements also present with uranium. The relatively high specific activity and moderate half-life of 1,600 years of 226Ra, the main radioisotope of radium found in uranium ore, made for a material which when mixed with a phosphor allowed for a glow-in-the-dark substance.

Thus, in addition to its medical usage, radium usage also became a major industry in the 1920s and 1930s for making watch, clock and aircraft dials. The radium dial painters brought a certain degree of notoriety to the abuse of radioactive materials, and that precautions needed to be followed with this new substance.

Because it takes approximately three metric tons of uranium to extract 1 gram of 226Ra, prodigious quantities of uranium were mined to sustain this new industry. The uranium ore itself was a "waste product" of this industry. By some estimates, nearly one million tons of uranium were mined to support this industry.

Taking advantage of this newly abundant resource, the tile and pottery glazing industry then had a relatively inexpensive and abundant source of glazing material that produced a wide variety of colors depending upon admixtures, firing, etc.

Vibrant colors of orange, yellow, red, green, blue, black, mauve, etc. were produced on tiles and other ceramic materials, and by some estimates, some 25% of all houses and apartments constructed during that period (circa 1920–1940) used varying amounts of bathroom or kitchen tiles that had been glazed with varying amounts of uranium. These can now be readily found in older homes, apartments, and other buildings still standing from that era by use of a simple Geiger counter that readily detects the beta radiation emitted by uranium's ever-present decay chain radio-daughters. [3]

After Euratom restrictions about uranium uses in ceramic glazes, there are no factories left working with uranium glazes, which is why uranium glazed tiles have become rare pieces for collectors. [4]

These glazes are generally made with 238U raw material, known as yellowcake UO2 uranium granules. 21st century contemporary ceramic artist and academic researcher Sencer Sari is one of the known specialists who is working with these uranium glazes. [5]

In most situations, the radiation exposure is not excessive, but there are some exceptions in which pure uranium oxide (which produces red-orange coloration as a glaze) on bathroom floors can pose a hazard for infants crawling around for hours on end, day after day.[ citation needed ]

See also

Related Research Articles

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<span class="mw-page-title-main">Radium</span> Chemical element, symbol Ra and atomic number 88

Radium is a chemical element with the symbol Ra and atomic number 88. It is the sixth element in group 2 of the periodic table, also known as the alkaline earth metals. Pure radium is silvery-white, but it readily reacts with nitrogen (rather than oxygen) upon exposure to air, forming a black surface layer of radium nitride (Ra3N2). All isotopes of radium are radioactive, the most stable isotope being radium-226 with a half-life of 1,600 years. When radium decays, it emits ionizing radiation as a by-product, which can excite fluorescent chemicals and cause radioluminescence.

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<span class="mw-page-title-main">Uranium-238</span> Isotope of uranium

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<span class="mw-page-title-main">Fiesta (dinnerware)</span> Line of ceramic glazed dinnerware

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<span class="mw-page-title-main">Luminous paint</span> Paint that glows in the dark

Luminous paint or luminescent paint is paint that exhibits luminescence. In other words, it gives off visible light through fluorescence, phosphorescence, or radioluminescence. There are three types of luminous paints: fluorescent paint, phosphorescent paint and radioluminescent paint.

<span class="mw-page-title-main">Uranium dioxide</span> Chemical compound

Uranium dioxide or uranium(IV) oxide , also known as urania or uranous oxide, is an oxide of uranium, and is a black, radioactive, crystalline powder that naturally occurs in the mineral uraninite. It is used in nuclear fuel rods in nuclear reactors. A mixture of uranium and plutonium dioxides is used as MOX fuel. Prior to 1960, it was used as yellow and black color in ceramic glazes and glass.

<span class="mw-page-title-main">Radium dial</span> Instrument dials painted with radium-based paint

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<span class="mw-page-title-main">Ceramic glaze</span> Fused coating on ceramic objects

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<span class="mw-page-title-main">Undark</span> Radioactive luminous radium paint produced in the early 20th century

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Radiobiology is a field of clinical and basic medical sciences that involves the study of the action of ionizing radiation on living things, especially health effects of radiation. Ionizing radiation is generally harmful and potentially lethal to living things but can have health benefits in radiation therapy for the treatment of cancer and thyrotoxicosis. Its most common impact is the induction of cancer with a latent period of years or decades after exposure. High doses can cause visually dramatic radiation burns, and/or rapid fatality through acute radiation syndrome. Controlled doses are used for medical imaging and radiotherapy.

<span class="mw-page-title-main">Gamma ray</span> Energetic electromagnetic radiation arising from radioactive decay of atomic nuclei

A gamma ray, also known as gamma radiation (symbol γ or ), is a penetrating form of electromagnetic radiation arising from the radioactive decay of atomic nuclei. It consists of the shortest wavelength electromagnetic waves, typically shorter than those of X-rays. With frequencies above 30 exahertz (3×1019 Hz), it imparts the highest photon energy. Paul Villard, a French chemist and physicist, discovered gamma radiation in 1900 while studying radiation emitted by radium. In 1903, Ernest Rutherford named this radiation gamma rays based on their relatively strong penetration of matter; in 1900 he had already named two less penetrating types of decay radiation (discovered by Henri Becquerel) alpha rays and beta rays in ascending order of penetrating power.

<span class="mw-page-title-main">Alpha particle</span> Helium-4 nucleus; particle of two protons and two neutrons

Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay, but may also be produced in other ways. Alpha particles are named after the first letter in the Greek alphabet, α. The symbol for the alpha particle is α or α2+. Because they are identical to helium nuclei, they are also sometimes written as He2+
or 4
2
He2+
indicating a helium ion with a +2 charge. Once the ion gains electrons from its environment, the alpha particle becomes a normal helium atom 4
2
He
.

References

  1. Harry McMaster. Earthenware Dishes and Glaze Therefor. Patent No. 1,890,297,
  2. Frame, Paul (2009-01-20). "General Information About Uranium in Ceramics". demolab.phys.virginia.edu. Retrieved 2022-08-08.
  3. http://www.nbcnews.com/id/3077213/ns/technology_and_science-science/t/uranium-hunter-follows-trail-tiles/ Uranium hunter follows trail of tiles
  4. msnbc.com, Alan Boyle (2003-12-12). "Uranium hunter follows trail of tiles". msnbc.com. Retrieved 2019-05-28.
  5. "Luminescent fairies (Vilnius 2017) – Sencer Sarı".