A photon is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they always move at the speed of light in vacuum, 299792458 m/s. The photon belongs to the class of boson particles.
Spectroscopy is the field of study that measures and interprets the electromagnetic spectra that result from the interaction between electromagnetic radiation and matter as a function of the wavelength or frequency of the radiation. Matter waves and acoustic waves can also be considered forms of radiative energy, and recently gravitational waves have been associated with a spectral signature in the context of the Laser Interferometer Gravitational-Wave Observatory (LIGO).
Atomic, molecular, and optical physics (AMO) is the study of matter–matter and light–matter interactions, at the scale of one or a few atoms and energy scales around several electron volts. The three areas are closely interrelated. AMO theory includes classical, semi-classical and quantum treatments. Typically, the theory and applications of emission, absorption, scattering of electromagnetic radiation (light) from excited atoms and molecules, analysis of spectroscopy, generation of lasers and masers, and the optical properties of matter in general, fall into these categories.
Photoluminescence is light emission from any form of matter after the absorption of photons. It is one of many forms of luminescence and is initiated by photoexcitation, hence the prefix photo-. Following excitation, various relaxation processes typically occur in which other photons are re-radiated. Time periods between absorption and emission may vary: ranging from short femtosecond-regime for emission involving free-carrier plasma in inorganic semiconductors up to milliseconds for phosphoresence processes in molecular systems; and under special circumstances delay of emission may even span to minutes or hours.
Raman scattering or the Raman effect is the inelastic scattering of photons by matter, meaning that there is both an exchange of energy and a change in the light's direction. Typically this effect involves vibrational energy being gained by a molecule as incident photons from a visible laser are shifted to lower energy. This is called normal Stokes Raman scattering. The effect is exploited by chemists and physicists to gain information about materials for a variety of purposes by performing various forms of Raman spectroscopy. Many other variants of Raman spectroscopy allow rotational energy to be examined and electronic energy levels may be examined if an X-ray source is used in addition to other possibilities. More complex techniques involving pulsed lasers, multiple laser beams and so on are known.
In physics, absorption of electromagnetic radiation is how matter takes up a photon's energy — and so transforms electromagnetic energy into internal energy of the absorber. A notable effect is attenuation, or the gradual reduction of the intensity of light waves as they propagate through a medium. Although the absorption of waves does not usually depend on their intensity, in certain conditions (optics) the medium's transparency changes by a factor that varies as a function of wave intensity, and saturable absorption occurs.
Coherent anti-Stokes Raman spectroscopy, also called Coherent anti-Stokes Raman scattering spectroscopy (CARS), is a form of spectroscopy used primarily in chemistry, physics and related fields. It is sensitive to the same vibrational signatures of molecules as seen in Raman spectroscopy, typically the nuclear vibrations of chemical bonds. Unlike Raman spectroscopy, CARS employs multiple photons to address the molecular vibrations, and produces a coherent signal. As a result, CARS is orders of magnitude stronger than spontaneous Raman emission. CARS is a third-order nonlinear optical process involving three laser beams: a pump beam of frequency ωp, a Stokes beam of frequency ωS and a probe beam at frequency ωpr. These beams interact with the sample and generate a coherent optical signal at the anti-Stokes frequency (ωpr+ωp-ωS). The latter is resonantly enhanced when the frequency difference between the pump and the Stokes beams (ωp-ωS) coincides with the frequency of a Raman resonance, which is the basis of the technique's intrinsic vibrational contrast mechanism.
Raman amplification is based on the stimulated Raman scattering (SRS) phenomenon, when a lower frequency 'signal' photon induces the inelastic scattering of a higher-frequency 'pump' photon in an optical medium in the nonlinear regime. As a result of this, another 'signal' photon is produced, with the surplus energy resonantly passed to the vibrational states of the medium. This process, as with other stimulated emission processes, allows all-optical amplification. Optical fiber is today mostly used as the nonlinear medium for SRS, for telecom purposes; in this case it is characterized by a resonance frequency downshift of ~11 THz. The SRS amplification process can be readily cascaded, thus accessing essentially any wavelength in the fiber low-loss guiding windows. In addition to applications in nonlinear and ultrafast optics, Raman amplification is used in optical telecommunications, allowing all-band wavelength coverage and in-line distributed signal amplification.
In atomic physics, two-photon absorption, also called two-photon excitation or non-linear absorption, is the simultaneous absorption of two photons of identical or different frequencies in order to excite a molecule from one state to a higher energy, most commonly an excited electronic state. Absorption of two photons with different frequencies is called non-degenerate two-photon absorption. Since TPA depends on the simultaneous absorption of two photons, the probability of TPA is proportional to the square of the light intensity; thus it is a nonlinear optical process. The energy difference between the involved lower and upper states of the molecule is equal or smaller than the sum of the photon energies of the two photons absorbed. Two-photon absorption is a third-order process, with absorption cross section typically several orders of magnitude smaller than one-photon absorption cross section.
PVLAS aims to carry out a test of quantum electrodynamics and possibly detect dark matter at the Department of Physics and National Institute of Nuclear Physics in Ferrara, Italy. It searches for vacuum polarization causing nonlinear optical behavior in magnetic fields. Experiments began in 2001 at the INFN Laboratory in Legnaro and continue today with new equipment.
Robert William Boyd is an American physicist noted for his work in optical physics and especially in nonlinear optics. He is currently the Canada Excellence Research Chair Laureate in Quantum Nonlinear Optics based at the University of Ottawa, professor of physics cross-appointed to the school of electrical engineering and computer science at the University of Ottawa, and professor of optics and professor of physics at the University of Rochester.
A parametric process is an optical process in which light interacts with matter in such a way as to leave the quantum state of the material unchanged. As a direct consequence of this there can be no net transfer of energy, momentum, or angular momentum between the optical field and the physical system. In contrast a non-parametric process is a process in which any part of the quantum state of the system changes.
Quantum-optical spectroscopy is a quantum-optical generalization of laser spectroscopy where matter is excited and probed with a sequence of laser pulses.
Linear optical quantum computing or linear optics quantum computation (LOQC) is a paradigm of quantum computation, allowing universal quantum computation. LOQC uses photons as information carriers, mainly uses linear optical elements, or optical instruments to process quantum information, and uses photon detectors and quantum memories to detect and store quantum information.
Integrated quantum photonics, uses photonic integrated circuits to control photonic quantum states for applications in quantum technologies. As such, integrated quantum photonics provides a promising approach to the miniaturisation and scaling up of optical quantum circuits. The major application of integrated quantum photonics is Quantum technology:, for example quantum computing, quantum communication, quantum simulation, quantum walks and quantum metrology.
Stimulated Raman spectroscopy, also referred to as stimulated Raman scattering (SRS) is a form of spectroscopy employed in physics, chemistry, biology, and other fields. The basic mechanism resembles that of spontaneous Raman spectroscopy: a pump photon, of the angular frequency , which is scattered by a molecule has some small probability of inducing some vibrational transition, as opposed to inducing a simple Rayleigh transition. This makes the molecule emit a photon at a shifted frequency. However, SRS, as opposed to spontaneous Raman spectroscopy, is a third-order non-linear phenomenon involving a second photon—the Stokes photon of angular frequency —which stimulates a specific transition. When the difference in frequency between both photons resembles that of a specific vibrational transition the occurrence of this transition is resonantly enhanced. In SRS, the signal is equivalent to changes in the intensity of the pump and Stokes beams. The signals are typically rather low, of the order of a part in 10^5, thus calling for modulation-transfer techniques: one beam is modulated in amplitude and the signal is detected on the other beam via a lock-in amplifier. Employing a pump laser beam of a constant frequency and a Stokes laser beam of a scanned frequency allows for the unraveling of the spectral fingerprint of the molecule. This spectral fingerprint differs from those obtained by other spectroscopy methods such as Rayleigh scattering as the Raman transitions confer to different exclusion rules than those that apply for Rayleigh transitions.
Coherent Raman scattering (CRS) microscopy is a multi-photon microscopy technique based on Raman-active vibrational modes of molecules. The two major techniques in CRS microscopy are stimulated Raman scattering (SRS) and coherent anti-Stokes Raman scattering (CARS). SRS and CARS were theoretically predicted and experimentally realized in the 1960s. In 1982 the first CARS microscope was demonstrated. In 1999, CARS microscopy using a collinear geometry and high numerical aperture objective were developed in Xiaoliang Sunney Xie's lab at Harvard University. This advancement made the technique more compatible with modern laser scanning microscopes. Since then, CRS's popularity in biomedical research started to grow. CRS is mainly used to image lipid, protein, and other bio-molecules in live or fixed cells or tissues without labeling or staining. CRS can also be used to image samples labeled with Raman tags, which can avoid interference from other molecules and normally allows for stronger CRS signals than would normally be obtained for common biomolecules. CRS also finds application in other fields, such as material science and environmental science.
Hyper–Rayleigh scattering Optical Activity, is a nonlinear optical physical effect whereby chiral scatterers convert light to higher frequencies via harmonic generation processes, in a way that the intensity of generated light depends on the chirality of the scatterers. "Hyper–Rayleigh scattering" is a nonlinear optical counterpart to Rayleigh scattering. "Optical activity" refers to any changes in light properties that are due to chirality.
Debabrata Goswami FInstP FRSC, is an Indian chemist and the Prof. S. Sampath Chair Professor of Chemistry, at the Indian Institute of Technology Kanpur. He is also a professor of The Department of Chemistry and The Center for Lasers & Photonics at the same Institute. Goswami is an associate editor of the open-access journal Science Advances. He is also an Academic Editor for PLOS One and PeerJ Chemistry. He has contributed to the theory of Quantum Computing as well as nonlinear optical spectroscopy. His work is documented in more than 200 research publications. He is an elected Fellow of the Royal Society of Chemistry, Fellow of the Institute of Physics, the SPIE, and The Optical Society. He is also a Senior Member of the IEEE, has been awarded a Swarnajayanti Fellowship for Chemical Sciences, and has held a Wellcome Trust Senior Research Fellowship. He is the third Indian to be awarded the International Commission for Optics Galileo Galilei Medal for excellence in optics.
Malvin Carl Teich is an American physicist and computational neuroscientist and Professor Emeritus at Columbia University and Boston University. He is also a consultant to government, academia, and private industry, where he serves as an advisor in intellectual-property conflicts. He is the coauthor of Fundamentals of Photonics, and of Fractal-Based Point Processes.
