Glauconite | |
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General | |
Category | Phyllosilicate |
Formula (repeating unit) | (K,Na)(Fe,Al,Mg)2(Si,Al)4O10(OH)2 |
IMA symbol | Glt [1] |
Crystal system | Monoclinic |
Crystal class | Prismatic (2/m) (same H-M symbol) |
Space group | C2/m |
Unit cell | a = 5.234 Å, b = 9.066 Å, c = 10.16 Å; β = 100.5°; Z = 2 |
Identification | |
Color | Blue green, green, yellow green |
Crystal habit | Elastic platy/micaceous, or as rounded pellets/aggregates |
Cleavage | Perfect [001] |
Mohs scale hardness | 2 |
Luster | Dull, earthy |
Streak | Light green |
Diaphaneity | Translucent to nearly opaque |
Specific gravity | 2.4–2.95 |
Optical properties | Biaxial (-); moderate relief |
Refractive index | nα = 1.590 – 1.612 nβ = 1.609 – 1.643 nγ = 1.610 – 1.644 |
Birefringence | δ = 0.020 – 0.032 |
Pleochroism | X = yellow-green, green; Y = Z = deeper yellow, bluish green |
Other characteristics | loosely bound aggregates, crumbles radioactivity: barely detectable |
References | [2] [3] [4] |
Glauconite is an iron potassium phyllosilicate (mica group) mineral of characteristic green color which is very friable [5] and has very low weathering resistance.
It crystallizes with a monoclinic geometry. Its name is derived from the Greek glaucos ( γλαυκός ) meaning 'bluish green', referring to the common blue-green color of the mineral; its sheen (mica glimmer) and blue-green color. Its color ranges from olive green, black green to bluish green, and yellowish on exposed surfaces due to oxidation. In the Mohs scale it has a hardness of 2, roughly the same as gypsum. [6] The relative specific gravity range is 2.4–2.95. It is normally found as dark green rounded concretions with the dimensions of a sand grain. It can be confused with chlorite (also of green color) or with a clay mineral. Glauconite has the chemical formula (K,Na)(Fe,Al,Mg)2(Si,Al)4O10(OH)2.
Glauconite particles are one of the main components of greensand, glauconitic siltstone and glauconitic sandstone. Glauconite has been called a marl in an old and broad sense of that word. Thus references to "greensand marl" sometimes refer specifically to glauconite. The Glauconitic Marl formation is named after it, and there is a glauconitic sandstone formation in the Mannville Group of Western Canada.
At the broadest level, glauconite is an authigenic mineral and forms exclusively in marine settings. [7] It is commonly associated with low-oxygen conditions. [8]
Normally, glauconite is considered a diagnostic mineral indicative of continental shelf marine depositional environments with slow rates of accumulation and gradational boundaries. For instance, it appears in Jurassic/lower Cretaceous deposits of greensand, so-called after the coloration caused by glauconite, its presence gradually lessening further landward. It can also be found in sand or clay formations, or in impure limestones and in chalk. It develops as a consequence of diagenetic alteration of sedimentary deposits at the surface, bio-chemical reduction and subsequent mineralogical changes affecting iron-bearing micas such as biotite, and is also influenced by the decaying process of organic matter degraded by bacteria in marine animal shells. In these cases, the organic matter creates the reducing environment needed to form glauconite within otherwise oxygenated sediment. Glauconite deposits are commonly found in nearshore sands, open oceans and shallow seas, such as the Mediterranean Sea. Glauconite remains absent in fresh-water lakes, but is noted in shelf sediments of the western Black Sea. [9] The wide distribution of these sandy deposits was first made known by naturalists on board the fifth HMS Challenger, in the expedition of 1872–1876.
Glauconite has long been used in Europe as a green pigment for artistic oil paint under the name green earth. [10] [11] One example is its use in Russian "icon paintings", another widespread use was for underpainting of human flesh in medieval painting. [12] It is also found as mineral pigment in wall paintings from the ancient Roman Gaul. [13]
Glauconite, a major component of greensand, is a common source of potassium (K+) in plant fertilizers and is also used to adjust soil pH. It is used for soil conditioning in both organic and non-organic farming, whether as an unprocessed material (mixed in adequate proportions) or as a feedstock in the synthesis of commercial fertilizer powders. In Brazil, greensand refers to a fertilizer produced from a glauconitic siltstone unit belonging to the Serra da Saudade Formation, Bambuí Group, of Neoproterozoic/Ediacaran age. The outcrops occur [14] in the Serra da Saudade ridge, in the Alto Paranaíba region, Minas Gerais state. It is a silty-clayed sedimentary rock, laminated, bluish-green, composed of glauconite (40-80%), potassium feldspar (10-15%), quartz (10-60%), muscovite (5%) and minor quantities of biotite (2%), goethite (<1%), titanium and manganese oxides (<1%), barium phosphate and rare-earth element phosphates (<1%).
Enriched levels of potash have K2O grades between 8 and 12%, thickness up to 50 metres (160 ft) and are associated to the glauconitic levels, dark-green in color. Glauconite is authigenic and highly mature. The high concentration of this mineral is related to a depositional environment with a low sedimentation rate. The glauconitic siltstone has resulted from a high-level flooding event in the Bambuí Basin. The sedimentary provenance is from supracrustal felsic elements in a continental margin environment with acid magmatic arc (foreland basin).
Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2Si2O5(OH)4) and tiny fragments (silt-sized particles) of other minerals, especially quartz and calcite. Shale is characterized by its tendency to split into thin layers (laminae) less than one centimeter in thickness. This property is called fissility. Shale is the most common sedimentary rock.
Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles to settle in place. The particles that form a sedimentary rock are called sediment, and may be composed of geological detritus (minerals) or biological detritus. The geological detritus originated from weathering and erosion of existing rocks, or from the solidification of molten lava blobs erupted by volcanoes. The geological detritus is transported to the place of deposition by water, wind, ice or mass movement, which are called agents of denudation. Biological detritus was formed by bodies and parts of dead aquatic organisms, as well as their fecal mass, suspended in water and slowly piling up on the floor of water bodies. Sedimentation may also occur as dissolved minerals precipitate from water solution.
Marl is an earthy material rich in carbonate minerals, clays, and silt. When hardened into rock, this becomes marlstone. It is formed in marine or freshwater environments, often through the activities of algae.
Greensand or green sand is a sand or sandstone which has a greenish color. This term is specifically applied to shallow marine sediment that contains noticeable quantities of rounded greenish grains. These grains are called glauconies and consist of a mixture of mixed-layer clay minerals, such as smectite and glauconite. Greensand is also loosely applied to any glauconitic sediment.
The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.
Celadonite is a mica group mineral, a phyllosilicate of potassium, iron in both oxidation states, aluminium and hydroxide with formula K(Mg,Fe2+
)(Fe3+
,Al)[Si
4O
10](OH)
2.
Red beds are sedimentary rocks, typically consisting of sandstone, siltstone, and shale, that are predominantly red in color due to the presence of ferric oxides. Frequently, these red-colored sedimentary strata locally contain thin beds of conglomerate, marl, limestone, or some combination of these sedimentary rocks. The ferric oxides, which are responsible for the red color of red beds, typically occur as a coating on the grains of sediments comprising red beds. Classic examples of red beds are the Permian and Triassic strata of the western United States and the Devonian Old Red Sandstone facies of Europe.
The Perth Basin is a thick, elongated sedimentary basin in Western Australia. It lies beneath the Swan Coastal Plain west of the Darling Scarp, representing the western limit of the much older Yilgarn Craton, and extends further west offshore. Cities and towns including Perth, Busselton, Bunbury, Mandurah and Geraldton are built over the Perth Basin.
Clastic rocks are composed of fragments, or clasts, of pre-existing minerals and rock. A clast is a fragment of geological detritus, chunks, and smaller grains of rock broken off other rocks by physical weathering. Geologists use the term clastic to refer to sedimentary rocks and particles in sediment transport, whether in suspension or as bed load, and in sediment deposits.
The Chugwater Formation is a mapped bedrock unit consisting primarily of red sandstone, in the states of Wyoming, Montana, and Colorado in the United States. It is recognized as a geologic formation in Colorado and Montana, but as a Group, the Chugwater Group, in Wyoming. Despite its presence below the highly studied Morrison Formation, the Chugwater receives little attention.
Soil color is often the most visually apparent property of soil. While color itself does not influence the behavior or practical use of soils, it does indicate important information about the soil organic matter content, mineralogy, moisture, and drainage.
The Kaolin deposits of the Charentes Basin in France are clay deposits formed sedimentarily and then confined by other geological structures.
This glossary of geology is a list of definitions of terms and concepts relevant to geology, its sub-disciplines, and related fields. For other terms related to the Earth sciences, see Glossary of geography terms.
The Lower Greensand Group is a geological unit present across large areas of Southern England. It was deposited during the Aptian and Albian stages of the Early Cretaceous. It predominantly consists of sandstone and unconsolidated sand that were deposited in shallow marine conditions.
The Matawan Formation is a geologic formation in Maryland and New Jersey. It preserves fossils dating back to the Cretaceous period.
The geology of West Sussex in southeast England comprises a succession of sedimentary rocks of Cretaceous age overlain in the south by sediments of Palaeogene age. The sequence of strata from both periods consists of a variety of sandstones, mudstones, siltstones and limestones. These sediments were deposited within the Hampshire and Weald basins. Erosion subsequent to large scale but gentle folding associated with the Alpine Orogeny has resulted in the present outcrop pattern across the county, dominated by the north facing chalk scarp of the South Downs. The bedrock is overlain by a suite of Quaternary deposits of varied origin. Parts of both the bedrock and these superficial deposits have been worked for a variety of minerals for use in construction, industry and agriculture.
The geology of North Macedonia includes the study of rocks dating to the Precambrian and a wide array of volcanic, sedimentary and metamorphic rocks formed in the last 539 million years.
The geology of Lithuania consists of ancient Proterozoic basement rock overlain by thick sequences of Paleozoic, Mesozoic and Cenozoic marine sedimentary rocks, with some oil reserves, abundant limestone, dolomite, phosphorite and glauconite. Lithuania is a country in the Baltic region of northern-eastern Europe.
The Earlie Formation is a stratigraphic unit of Middle Cambrian age in the Western Canada Sedimentary Basin that is present beneath the plains of Alberta and eastern Saskatchewan. It was named for Earlie Lake in the County of Vermilion River, Alberta, by D.C. Pugh in 1971, who described the type section based on data from an oil well drilled in that area.