KREEP

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Thorium concentrations on the Moon, as mapped by Lunar Prospector. Thorium correlates with the location of KREEP. Lunar Thorium concentrations.jpg
Thorium concentrations on the Moon, as mapped by Lunar Prospector . Thorium correlates with the location of KREEP.

KREEP, an acronym built from the letters K (the atomic symbol for potassium), REE (rare-earth elements) and P (for phosphorus), is a geochemical component of some lunar impact breccia and basaltic rocks. Its most significant feature is somewhat enhanced concentration of a majority of so-called "incompatible" elements [1] (those that are concentrated in the liquid phase during magma crystallization) and the heat-producing elements, namely radioactive uranium, thorium, and potassium (due to presence of the radioactive 40K). [2]

Contents

Typical composition

The typical composition of KREEP includes about one percent, by mass, of potassium and phosphorus oxides, 20 to 25 parts per million of rubidium, and a concentration of the element lanthanum that is 300 to 350 times the concentrations found in carbonaceous chondrites. [3] Most of potassium, phosphorus and rare-earth elements in KREEP basalts are incorporated in the grains of the phosphate minerals apatite and merrillite. [4]

Possible origin

Indirectly, it has been deduced that the origin of KREEP is contained in the origin of the Moon. This is now commonly thought to be the result of a rocky object the size of Mars that struck the Earth about 4.5 billion (4.5×109) years ago. [5] This collision threw a large amount of broken rock into orbit around the Earth. This ultimately gathered together to form the Moon. [6]

Given the high energy such a collision would involve, it has been deduced that a large portion of the Moon would have been liquified, and this formed a lunar magma ocean. As the crystallization of this liquid rock proceeded, minerals such as olivine and pyroxene precipitated and sank to the bottom to form the lunar mantle.

After the solidification was about 75% complete, the material anorthositic plagioclase began to crystallize, and because of its low density, it floated, forming a solid crust. Hence, elements that are usually incompatible (i.e., those that usually partition in the liquid phase) would have been progressively concentrated into the magma. Thus a KREEP-rich magma was formed that was sandwiched at first between the crust and mantle. The evidence for these processes comes from the highly anorthositic composition of the crust of the lunar highlands, as well as the presence of the rocks rich in KREEP. [7]

Lunar Prospector measurements

Before the mission of Lunar Prospector lunar satellite, it was commonly thought that these KREEP materials had been formed in a widespread layer beneath the crust. However, the measurements from the gamma-ray spectrometer on-board this satellite showed that the KREEP-containing rocks are primarily concentrated underneath the Oceanus Procellarum and the Mare Imbrium. This is a unique lunar geological province that is now known as the Procellarum KREEP Terrane.

Basins far from this province that dug deeply into the crust (and possibly the mantle), such as the Mare Crisium, the Mare Orientale, and the South Pole–Aitken basin, show only little or no enhancements of KREEP within their rims or ejecta. The enhancement of heat-producing radioactive elements within the crust (and/or the mantle) of the Procellarum KREEP Terrane is almost certainly responsible for the longevity and intensity of mare volcanism on the nearside of the Moon. [8]

See also

Related Research Articles

<span class="mw-page-title-main">Oceanus Procellarum</span> Vast lunar mare on the western edge of the near side of Earths Moon

Oceanus Procellarum is a vast lunar mare on the western edge of the near side of the Moon. It is the only one of the lunar maria to be called an "Oceanus" (ocean), due to its size: Oceanus Procellarum is the largest of the maria ("seas"), stretching more than 2,500 km (1,600 mi) across its north–south axis and covering roughly 4,000,000 km2 (1,500,000 sq mi), accounting for 10.5% of the total lunar surface area.

<span class="mw-page-title-main">Crust (geology)</span> Outermost solid shell of astronomical bodies

In geology, the crust is the outermost solid shell of a rocky planet, dwarf planet, or natural satellite. It is usually distinguished from the underlying mantle by its chemical makeup; however, in the case of icy satellites, it may be distinguished based on its phase.

<span class="mw-page-title-main">South Pole–Aitken basin</span> Large impact crater on the Moon

The South Pole–Aitken basin is an immense impact crater on the far side of the Moon. At roughly 2,500 km (1,600 mi) in diameter and between 6.2 and 8.2 km (3.9–5.1 mi) deep, it is one of the largest known impact craters in the Solar System. It is the largest, oldest, and deepest basin recognized on the Moon. It is estimated that it was formed 4.2 to 4.3 billion years ago, during the Pre-Nectarian epoch. It was named for two features on opposite sides of the basin: the lunar South Pole at one end and the crater Aitken on the northern end. The outer rim of this basin can be seen from Earth as a huge mountain chain located on the Moon's southern limb, sometimes informally called "Leibnitz mountains".

<span class="mw-page-title-main">Lunar geologic timescale</span> Geological dating system of the Moon

The lunar geological timescale divides the history of Earth's Moon into five generally recognized periods: the Copernican, Eratosthenian, Imbrian, Nectarian, and Pre-Nectarian. The boundaries of this time scale are related to large impact events that have modified the lunar surface, changes in crater formation through time, and the size-frequency distribution of craters superposed on geological units. The absolute ages for these periods have been constrained by radiometric dating of samples obtained from the lunar surface. However, there is still much debate concerning the ages of certain key events, because correlating lunar regolith samples with geological units on the Moon is difficult, and most lunar radiometric ages have been highly affected by an intense history of bombardment.

<span class="mw-page-title-main">Planetary differentiation</span> Astrogeological concept

In planetary science, planetary differentiation is the process by which the chemical elements of a planetary body accumulate in different areas of that body, due to their physical or chemical behavior. The process of planetary differentiation is mediated by partial melting with heat from radioactive isotope decay and planetary accretion. Planetary differentiation has occurred on planets, dwarf planets, the asteroid 4 Vesta, and natural satellites.

<span class="mw-page-title-main">Anorthosite</span> Mafic intrusive igneous rock composed predominantly of plagioclase

Anorthosite is a phaneritic, intrusive igneous rock characterized by its composition: mostly plagioclase feldspar (90–100%), with a minimal mafic component (0–10%). Pyroxene, ilmenite, magnetite, and olivine are the mafic minerals most commonly present.

<span class="mw-page-title-main">Lunar mare</span> Large, dark, basaltic plains on Earths Moon

The lunar maria are large, dark, basaltic plains on Earth's Moon, formed by ancient asteroid impacts on the far side on the Moon that triggered volcanic activity on the opposite (near) side. They were dubbed maria, Latin for 'seas', by early astronomers who mistook them for actual seas. They are less reflective than the "highlands" as a result of their iron-rich composition, and hence appear dark to the naked eye. The maria cover about 16% of the lunar surface, mostly on the side visible from Earth. The few maria on the far side are much smaller, residing mostly in very large craters. The traditional nomenclature for the Moon also includes one oceanus (ocean), as well as features with the names lacus ('lake'), palus ('marsh'), and sinus ('bay'). The last three are smaller than maria, but have the same nature and characteristics.

<span class="mw-page-title-main">Planetary core</span> Innermost layer(s) of a planet

A planetary core consists of the innermost layers of a planet. Cores may be entirely solid or entirely liquid, or a mixture of solid and liquid layers as is the case in the Earth. In the Solar System, core sizes range from about 20% to 85% of a planet's radius (Mercury).

A mantle is a layer inside a planetary body bounded below by a core and above by a crust. Mantles are made of rock or ices, and are generally the largest and most massive layer of the planetary body. Mantles are characteristic of planetary bodies that have undergone differentiation by density. All terrestrial planets, a number of asteroids, and some planetary moons have mantles.

<span class="mw-page-title-main">Geology of the Moon</span> Structure and composition of the Moon

The geology of the Moon is quite different from that of Earth. The Moon lacks a true atmosphere, and the absence of free oxygen and water eliminates erosion due to weather. Instead, the surface is eroded much more slowly through bombardment of the lunar surface by micrometeorites. It does not have any known form of plate tectonics, it has a lower gravity, and because of its small size, it cooled faster. In addition to impacts, the geomorphology of the lunar surface has been shaped by volcanism, which is now thought to have ended less than 50 million years ago. The Moon is a differentiated body, with a crust, mantle, and core.

<span class="mw-page-title-main">Moon rock</span> Rock from the Moon

Moon rock or lunar rock is rock originating from Earth's Moon. This includes lunar material collected during the course of human exploration of the Moon, and rock that has been ejected naturally from the Moon's surface and landed on Earth as meteorites.

<span class="mw-page-title-main">Oldest dated rocks</span> Includes rocks over 4 billion years old from the Hadean Eon

The oldest dated rocks formed on Earth, as an aggregate of minerals that have not been subsequently broken down by erosion or melted, are more than 4 billion years old, formed during the Hadean Eon of Earth's geological history. Meteorites that were formed in other planetary systems can pre-date Earth. Particles from the Murchison meteorite were dated in January 2020 to be 7 billion years old.

<span class="mw-page-title-main">Lunar magma ocean</span> Theorized historical geological layer on the Moon

The Lunar Magma Ocean (LMO) is the layer of molten rock that is theorized to have been present on the surface of the Moon. The Lunar Magma Ocean was likely present on the Moon from the time of the Moon's formation to tens or hundreds of millions years after that time. It is a thermodynamic consequence of the Moon's relatively rapid formation in the aftermath of a giant impact between the proto-Earth and another planetary body. As the Moon accreted from the debris from the giant impact, gravitational potential energy was converted to thermal energy. Due to the rapid accretion of the Moon, thermal energy was trapped since it did not have sufficient time to thermally radiate away energy through the lunar surface. The subsequent thermochemical evolution of the Lunar Magma Ocean explains the Moon's largely anorthositic crust, europium anomaly, and KREEP material.

<span class="mw-page-title-main">Lunar terrane</span> Geologic province on the Moon

A lunar terrane is a major geological province on the Moon. Three terranes have been identified on the Moon: the Procellarum KREEP Terrane, the Feldspathic Highlands Terrane, and the South Pole–Aitken Terrane. Each terrane has a unique origin, composition, and thermal evolution.

<span class="mw-page-title-main">Internal structure of the Moon</span>

Having a mean density of 3,346.4 kg/m3, the Moon is a differentiated body, being composed of a geochemically distinct crust, mantle, and planetary core. This structure is believed to have resulted from the fractional crystallization of a magma ocean shortly after its formation about 4.5 billion years ago. The energy required to melt the outer portion of the Moon is commonly attributed to a giant impact event that is postulated to have formed the Earth-Moon system, and the subsequent reaccretion of material in Earth orbit. Crystallization of this magma ocean would have given rise to a mafic mantle and a plagioclase-rich crust.

<span class="mw-page-title-main">Atmosphere of the Moon</span> Very scant presence of gases around the Moon

The atmosphere of the Moon is a very scant presence of gases surrounding the Moon. For most practical purposes, the Moon is considered to be surrounded by vacuum. The elevated presence of atomic and molecular particles in its vicinity compared to interplanetary medium, referred to as "lunar atmosphere" for scientific objectives, is negligible in comparison with the gaseous envelopes surrounding Earth and most planets of the Solar System. The pressure of this small mass is around 3×10−15 atm (0.3 nPa), varying throughout the day, and in total mass less than 10 metric tonnes. Otherwise, the Moon is considered not to have an atmosphere because it cannot absorb measurable quantities of radiation, does not appear layered or self-circulating, and requires constant replenishment due to the high rate at which its gases get lost into space.

<span class="mw-page-title-main">Hadley–Apennine</span> Moon landing site of American Apollo 15

Hadley–Apennine is a region on the near side of Earth's Moon that served as the landing site for the American Apollo 15 mission, the fourth manned landing on the Moon and the first of the "J-missions", in July 1971. The site is located on the eastern edge of Mare Imbrium on a lava plain known as Palus Putredinis. Hadley–Apennine is bordered by the Montes Apenninus, a mountain range, and Hadley Rille, a meandering channel, on the east and west, respectively.

<span class="mw-page-title-main">Compton–Belkovich Thorium Anomaly</span> Lunar hotspot

The Compton–Belkovich Thorium Anomaly is a hotspot on the Moon. It is on the far side of the Moon and was found by a gamma-ray spectrometer in 1998. It is an area of concentrated thorium, a 'fertile' element. Lunar rock samples from the Apollo missions reveal that most lunar volcanism occurred around 3 to 4 billion years ago, but this feature could have formed as recently as 1 billion years ago due to the unknown history of the moon's far side.

Magma oceans exist during periods of Earth's or any planet's accretion when the planet is completely or partly molten.

<span class="mw-page-title-main">Volcanism on the Moon</span> Volcanic processes and landforms on the Moon

Volcanism on the Moon is represented by the presence of volcanoes, pyroclastic deposits and vast lava plains on the lunar surface. The volcanoes are typically in the form of small domes and cones that form large volcanic complexes and isolated edifices. Calderas, large-scale collapse features generally formed late in a volcanic eruptive episode, are exceptionally rare on the Moon. Lunar pyroclastic deposits are the result of lava fountain eruptions from volatile-laden basaltic magmas rapidly ascending from deep mantle sources and erupting as a spray of magma, forming tiny glass beads. However, pyroclastic deposits formed by less common non-basaltic explosive eruptions are also thought to exist on the Moon. Lunar lava plains cover large swaths of the Moon's surface and consist mainly of voluminous basaltic flows. They contain a number of volcanic features related to the cooling of lava, including lava tubes, rilles and wrinkle ridges.

References

  1. Taylor, G. Jeffrey (August 31, 2000). "A New Moon for the Twenty-First Century". Planetary Science Research Discoveries. University of Hawaii . Retrieved August 11, 2009.
  2. Shearer, Charles K.; Hess, Paul C.; Wieczorek, Mark A.; et al. (2006). "Thermal and Magmatic Evolution of the Moon". Reviews in Mineralogy and Geochemistry . Mineralogical Society of America and Geochemical Society. 60 (1): 365–518. Bibcode:2006RvMG...60..365S. doi:10.2138/rmg.2006.60.4 . Retrieved August 11, 2009.
  3. Neal, C. R.; Taylor, L. A. (March 1988). "'K-Frac + REEP-Frac': A New Understanding of KREEP in Terms of Granite and Phosphate Petrogenesis". Abstracts of the Lunar and Planetary Science Conference. 19: 831. Bibcode:1988LPI....19..831N . Retrieved November 24, 2013.
  4. Lucey, Paul; Korotev, Randy; Taylor, Larry; et al. (2006). understanding the lunar surface and Space-Moon Interactions. Mineralogical society of America. p. 100.
  5. Belbruno, E.; Gott III, J. Richard (2005). "Where Did The Moon Come From?". The Astronomical Journal . 129 (3): 1724–1745. arXiv: astro-ph/0405372 . Bibcode:2005AJ....129.1724B. doi:10.1086/427539. S2CID   12983980.
  6. Taylor, G. Jeffrey (November 22, 2005). "Gamma Rays, Meteorites, Lunar Samples, and the Composition of the Moon". Planetary Science Research Discoveries. University of Hawaii. Retrieved August 11, 2009.
  7. Wieczorek, Mark A.; Jolliff, Bradley L.; Khan, Amir; et al. (2006). "The Constitution and Structure of the Lunar Interior". Reviews in Mineralogy and Geochemistry. Mineralogical Society of America and Geochemical Society. 60 (1): 221–364. Bibcode:2006RvMG...60..221W. doi:10.2138/rmg.2006.60.3 . Retrieved August 11, 2009.
  8. Jolliff, Bradley L.; Gillis, Jeffrey J.; Haskin, Larry A.; Korotev, Randy L.; Wieczorek, Mark A. (February 25, 2000). "Major lunar crustal terranes: Surface expressions and crust-mantle origins". Journal of Geophysical Research . Washington, D.C.: American Geophysical Union. 105 (E2): 4197–4216. Bibcode:2000JGR...105.4197J. doi: 10.1029/1999JE001103 .