Manganese lactate

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Manganese lactate
Manganese lactate.svg
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 240-182-0
PubChem CID
  • InChI=1S/2C3H6O3.Mn/c2*1-2(4)3(5)6;/h2*2,4H,1H3,(H,5,6);/q;;+2/p-2
    Key: KSNGEYQWLMRSIR-UHFFFAOYSA-L
  • CC(C(=O)[O-])O.CC(C(=O)[O-])O.[Mn+2]
Properties
C
6
H
10
MnO
6
Molar mass 233.08 g/mol
AppearancePink crystals
Very soluble
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Manganese lactate is an organic chemical compound, a salt of manganese and lactic acid with the formula Mn(C3H5O3)2. The compound forms light pink crystals, soluble in water, forming crystalline hydrates. [1] [2]

Contents

Synthesis

Dissolution of manganese carbonate in lactic acid solution:

MnCO3 + 2C3H6O3 → Mn(C3H5O3)2 + CO2 + H2O

Physical properties

Manganese lactate forms light pink crystals.

Manganese lactate is soluble in water and ethanol.

Manganese lactate forms crystalline hydrates of composition Mn(C3H5O3)2•n H2O, where n = 2 and 3. [3] Each lactate is a bidentate ligand. Two water molecules coordinate directly to the metal as well, cis to each other, to complete the octahedral cluster. In the trihydrate, the third water molecule is involved in hydrogen-bonding further away in the crystal structure. [4]

Its dihydrate forms an orthorhombic crystal, the space group is P212121. [5]

The trihydrate is a monoclinic crystal, and the space group is P21. [6] [7]

Related Research Articles

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Oxalic acid is an organic acid with the IUPAC name ethanedioic acid and formula HO2C−CO2H. It is the simplest dicarboxylic acid. It is a white crystalline solid that forms a colorless solution in water. Its name comes from the fact that early investigators isolated oxalic acid from flowering plants of the genus Oxalis, commonly known as wood-sorrels. It occurs naturally in many foods, but excessive ingestion of oxalic acid or prolonged skin contact can be dangerous.

Calcium sulfate Laboratory and industrial chemical

Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO4 and related hydrates. In the form of γ-anhydrite (the anhydrous form), it is used as a desiccant. One particular hydrate is better known as plaster of Paris, and another occurs naturally as the mineral gypsum. It has many uses in industry. All forms are white solids that are poorly soluble in water. Calcium sulfate causes permanent hardness in water.

Water of crystallization

In chemistry, water(s) of crystallization or water(s) of hydration are water molecules that are present inside crystals. Water is often incorporated in the formation of crystals from aqueous solutions. In some contexts, water of crystallization is the total mass of water in a substance at a given temperature and is mostly present in a definite (stoichiometric) ratio. Classically, "water of crystallization" refers to water that is found in the crystalline framework of a metal complex or a salt, which is not directly bonded to the metal cation.

Manganese(II) chloride Chemical compound

Manganese(II) chloride is the dichloride salt of manganese, MnCl2. This inorganic chemical exists in the anhydrous form, as well as the dihydrate (MnCl2·2H2O) and tetrahydrate (MnCl2·4H2O), with the tetrahydrate being the most common form. Like many Mn(II) species, these salts are pink, with the paleness of the color being characteristic of transition metal complexes with high spin d5 configurations. It is a paramagnetic salt.

Iron(II) chloride Chemical compound

Iron(II) chloride, also known as ferrous chloride, is the chemical compound of formula FeCl2. It is a paramagnetic solid with a high melting point. The compound is white, but typical samples are often off-white. FeCl2 crystallizes from water as the greenish tetrahydrate, which is the form that is most commonly encountered in commerce and the laboratory. There is also a dihydrate. The compound is highly soluble in water, giving pale green solutions.

Calcium lactate Chemical compound

Calcium lactate is a white crystalline salt with formula C
6
H
10
CaO
6
, consisting of two lactate anions H
3
C
(CHOH)CO
2
for each calcium cation Ca2+
. It forms several hydrates, the most common being the pentahydrate C
6
H
10
CaO
6
·5H
2
O
.

Permanganic acid (or manganic(VII) acid) is the inorganic compound with the formula HMnO4. This strong oxoacid has been isolated as its dihydrate. It is the conjugate acid of permanganate salts. It is the subject of few publications and its characterization as well as its uses are very limited.

Chromium(III) fluoride Chemical compound

Chromium(III) fluoride is the name for the inorganic compounds with the chemical formula CrF3 as well as several related hydrates. The compound CrF3 is a green crystalline solid that is insoluble in common solvents, but the coloured hydrates [Cr(H2O)6]F3 and [Cr(H2O)6]F3•3H2O are soluble in water. The trihydrate is green, and the hexahydrate is violet. The anhydrous form sublimes at 1100–1200 °C.

Manganese heptoxide Chemical compound

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Cobalt(II) nitrate Chemical compound

Cobalt nitrate is the inorganic compound with the formula Co(NO3)2.xH2O. It is cobalt(II)'s salt. The most common form is the hexahydrate Co(NO3)2·6H2O, which is a red-brown deliquescent salt that is soluble in water and other polar solvents.

Chromium(III) nitrate Chemical compound

Chromium(III) nitrate describes several inorganic compounds consisting of chromium, nitrate and varying amounts of water. Most common is the dark violet hygrosscopic solid. An anhydrous green form is also known. Chromium(III) nitrate compounds are of a limited commercial importance, finding some applications in the dyeing industry. It is common in academic laboratories for the synthesis of chromium coordination complexes.

Iron(II) lactate Chemical compound

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Croconic acid Chemical compound

Croconic acid or 4,5-dihydroxycyclopentenetrione is a chemical compound with formula C5H2O5 or (C=O)3(COH)2. It has a cyclopentene backbone with two hydroxyl groups adjacent to the double bond and three ketone groups on the remaining carbon atoms. It is sensitive to light, soluble in water and ethanol and forms yellow crystals that decompose at 212 °C.

Chromium(II) sulfate Chemical compound

Chromium(II) sulfate refers to inorganic compounds with the chemical formula CrSO4·n H2O. Several closely related hydrated salts are known. The pentahydrate is a blue solid that dissolves readily in water. Solutions of chromium(II) are easily oxidized by air to Cr(III) species. Solutions of Cr(II) are used as specialized reducing agents of value in organic synthesis.

The nickel organic acid salts are organic acid salts of nickel. In many of these the ionised organic acid acts as a ligand.

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Yttrium oxalate is an inorganic compound, a salt of yttrium and oxalic acid with the chemical formula Y2(C2O4)3. The compound does not dissolve in water and forms crystalline hydrates—colorless crystals.

Manganese oxalate is a chemical compound, a salt of manganese and oxalic acid with the chemical formula MnC
2
O
4
. The compound creates light pink crystals, does not dissolve in water, and forms crystalline hydrates. It occurs naturally as the mineral Lindbergite.

Lutetium(III) nitrate is an inorganic compound, a salt of lutetium and nitric acid with the chemical formula Lu(NO3)3. The compound forms colorless crystals, dissolves in water, and also forms crystalline hydrates. The compound is poisonous.

Silver lactate Chemical compound

Silver lactate is an organic chemical compound, a salt of silver and lactic acid with the formula CH3CH(OH)COOAg.

Zinc lactate is a chemical compound, a salt of zinc and lactic acid with the formula Zn(C3H5O3)2.

References

  1. "Manganese(II) Lactate Trihydrate". American Elements . Retrieved 17 January 2022.
  2. "Jost Chemical - Manganese Lactate, CAS Number 51877-53-3 (anh.)". Jost Chemical. Retrieved 17 January 2022.
  3. "Manganese(II) lactate trihydrate". Sigma Aldrich . Retrieved 17 January 2022.
  4. Ke, Zeng-Bo; Fan, Xin-Hui; Di, You-Ying; Chen, Feng-Ying; Zhang, Li-Jun; Yang, Ke; Li, Bing (March 2022). "Crystal Structures and Solution Chemical Properties of Two Lactate Complexes Mn[(C3H5O3)2(H2O)2]⋅H2O(s) and Cu(C3H5O3)2(s)". Journal of Molecular Structure . 1252: 132145. Bibcode:2022JMoSt125232145K. doi:10.1016/j.molstruc.2021.132145. S2CID   245214598.
  5. Lis, T. (15 March 1982). "Structure of manganese(II) L-lactate dihydrate". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 38 (3): 937–939. doi:10.1107/S056774088200449X.
  6. Singh, K. D.; Jain, S. C.; Sakore, T. D.; Biswas, A. B. (October 1975). "Crystal structure of some metal complexes of lactic acid". Zeitschrift für Kristallographie . 141 (5–6): 473–475. Bibcode:1975ZK....141..473S. doi:10.1524/zkri.1975.141.5-6.473.
  7. Kemmitt, Tim; Mills, Ann M.; Gainsford, Graeme J. (2001). "The Formation of Manganese Carboxylates from MnO and MnO2 and their Application in Lithium Manganate Precursors: X-Ray Crystal Structure of Manganese Lactate Trihydrate". Australian Journal of Chemistry . 54 (1): 37–42. doi:10.1071/CH01012 . Retrieved 17 January 2022.