Yttrium(III) bromide

Last updated
Yttrium(III) bromide [1]
YBr3structure.jpg
Names
IUPAC name
Yttrium(III) bromide
Other names
Yttrium tribromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.375 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 236-728-2
PubChem CID
UNII
  • InChI=1S/3BrH.Y/h3*1H;/q;;;+3/p-3 Yes check.svgY
    Key: FSDCGXUNLWDJNL-UHFFFAOYSA-K Yes check.svgY
  • InChI=1/3BrH.Y/h3*1H;/q;;;+3/p-3
    Key: FSDCGXUNLWDJNL-DFZHHIFOAK
  • Br[Y](Br)Br
Properties
YBr3
Molar mass 328.618 g/mol
Appearancecolorless hygroscopic crystals
Melting point 904 °C (1,659 °F; 1,177 K)
83.3 g/100 mL at 30°C
Structure
Trigonal, hR24
R-3, No. 148
Hazards
GHS labelling:
GHS-pictogram-exclam.svg
Warning
H315, H319, H335
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
NFPA 704 (fire diamond)
1
0
0
Related compounds
Other anions
Yttrium(III) fluoride
Yttrium(III) chloride
Yttrium(III) iodide
Other cations
Scandium bromide
Lutetium(III) bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
X mark.svgN  verify  (what is  Yes check.svgYX mark.svgN ?)

Yttrium(III) bromide is an inorganic compound with the chemical formula YBr3. It is a white solid. Anhydrous yttrium(III) bromide can be produced by reacting yttrium oxide or yttrium(III) bromide hydrate and ammonium bromide. The reaction proceeds via the intermediate (NH4)3YBr6. [3] Another method is to react yttrium carbide (YC2) and elemental bromine. [4] Yttrium(III) bromide can be reduced by yttrium metal to YBr or Y2Br3. [5] It can react with osmium to produce Y4Br4Os. [6]

Related Research Articles

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Terbium is a chemical element with the symbol Tb and atomic number 65. It is a silvery-white, rare earth metal that is malleable, and ductile. The ninth member of the lanthanide series, terbium is a fairly electropositive metal that reacts with water, evolving hydrogen gas. Terbium is never found in nature as a free element, but it is contained in many minerals, including cerite, gadolinite, monazite, xenotime and euxenite.

<span class="mw-page-title-main">Cerium(III) chloride</span> Chemical compound

Cerium(III) chloride (CeCl3), also known as cerous chloride or cerium trichloride, is a compound of cerium and chlorine. It is a white hygroscopic salt; it rapidly absorbs water on exposure to moist air to form a hydrate, which appears to be of variable composition, though the heptahydrate CeCl3·7H2O is known. It is highly soluble in water, and (when anhydrous) it is soluble in ethanol and acetone.

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Neodymium(III) chloride or neodymium trichloride is a chemical compound of neodymium and chlorine with the formula NdCl3. This anhydrous compound is a mauve-colored solid that rapidly absorbs water on exposure to air to form a purple-colored hexahydrate, NdCl3·6H2O. Neodymium(III) chloride is produced from minerals monazite and bastnäsite using a complex multistage extraction process. The chloride has several important applications as an intermediate chemical for production of neodymium metal and neodymium-based lasers and optical fibers. Other applications include a catalyst in organic synthesis and in decomposition of waste water contamination, corrosion protection of aluminium and its alloys, and fluorescent labeling of organic molecules (DNA).

<span class="mw-page-title-main">Samarium(III) chloride</span> Chemical compound

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Erbium(III) chloride is a violet solid with the formula ErCl3. It is used in the preparation of erbium metal.

<span class="mw-page-title-main">Yttrium(III) chloride</span> Chemical compound

Yttrium(III) chloride is an inorganic compound of yttrium and chloride. It exists in two forms, the hydrate (YCl3(H2O)6) and an anhydrous form (YCl3). Both are colourless solids that are highly soluble in water and deliquescent.

<span class="mw-page-title-main">Ytterbium(III) bromide</span> Chemical compound

Ytterbium(III) bromide (YbBr3) is an inorganic chemical compound.

<span class="mw-page-title-main">Terbium(III) bromide</span> Chemical compound

Terbium(III) bromide (TbBr3) is a crystalline chemical compound.

<span class="mw-page-title-main">Indium(III) bromide</span> Chemical compound

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<span class="mw-page-title-main">Magnesium bromide</span> Chemical compound

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An yttrium compound is a chemical compound containing yttrium. Among these compounds, yttrium generally has a +3 valence. The solubility properties of yttrium compounds are similar to those of the lanthanides. For example oxalates and carbonates are hardly soluble in water, but soluble in excess oxalate or carbonate solutions as complexes are formed. Sulfates and double sulfates are generally soluble. They resemble the "yttrium group" of heavy lanthanide elements.

Dysprosium(II) chloride (DyCl2), also known as dysprosium dichloride, is an ionic chemical compound of dysprosium and chlorine. This salt is a reduced compound, as the normal oxidation state of dysprosium in dysprosium compounds is +3.

Lanthanide trichlorides are a family of inorganic compound with the formula LnCl3, where Ln stands for a lanthanide metal. The trichlorides are standard reagents in applied and academic chemistry of the lanthanides. They exist as anhydrous solids and as hydrates.

<span class="mw-page-title-main">Neodymium compounds</span> Chemical compounds with at least one neodymium atom

Neodymium compounds are compounds formed by the lanthanide metal neodymium (Nd). In these compounds, neodymium generally exhibits the +3 oxidation state, such as NdCl3, Nd2(SO4)3 and Nd(CH3COO)3. Compounds with neodymium in the +2 oxidation state are also known, such as NdCl2 and NdI2. Some neodymium compounds have colors that vary based upon the type of lighting.

<span class="mw-page-title-main">Europium compounds</span> Chemical compounds with at least one europium atom

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

<span class="mw-page-title-main">Lanthanum(III) iodide</span> Chemical compound

Lanthanum(III) iodide is an inorganic compound containing lanthanum and iodine with the chemical formula LaI
3
.

<span class="mw-page-title-main">Dysprosium(III) bromide</span> Chemical compound

Dysprosium(III) bromide is an inorganic compound of bromine and dysprosium, with the chemical formula of DyBr3.

Erbium compounds are compounds containing the element erbium (Er). These compounds are usually dominated by erbium in the +3 oxidation state, although the +2, +1 and 0 oxidation states have also been reported.

Protactinium compounds are compounds containing the element protactinium. These compounds usually have protactinium in the +5 oxidation state, although these compounds can also exist in the +2, +3 and +4 oxidation states.

References

  1. Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, Florida: CRC Press, pp. 4–94, ISBN   0-8493-0594-2
  2. "Yttrium(III) bromide anhydrous, powder, 99.9% | Sigma-Aldrich".
  3. Gerd Meyer, Siegfried Dötsch, Thomas Staffel (1987). "The ammonium-bromide route to anhydrous rare earth bromides MBr3". Journal of the Less Common Metals. 127: 155–160. doi:10.1016/0022-5088(87)90372-9.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  4. Mussler, R. E.; Campbell, T. T.; Block, F. E.; Robidart, G. B. Metallothermic reduction of yttrium halides. Bureau of Mines Report of Investigations, 1963. 6259. pp 21.
  5. H. Mattausch, J. B. Hendricks, R. Eger, J. D. Corbett, A. Simon (1980). "Reduced halides of yttrium with strong metal-metal bonding: yttrium monochloride, monobromide, sesquichloride, and sesquibromide". Inorganic Chemistry. 19 (7): 2128–2132. doi:10.1021/ic50209a057. ISSN   0020-1669.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  6. Peter K. Dorhout, John D. Corbett (1992). "A novel structure type in reduced rare-earth metal halides. One-dimensional confacial chains based on centered square antiprismatic metal units: Y4Br4Os and Er4Br4Os". Journal of the American Chemical Society. 114 (5): 1697–1701. doi:10.1021/ja00031a024. ISSN   0002-7863.