List of glues

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See adhesive for general discussion of glue.

This is a list of various types of glue . Historically, the term "glue" only referred to protein colloids prepared from animal flesh. The meaning has been extended to refer to any fluid adhesive.

Contents

There are many adhesive substances that are considered or commonly referred to as "glue".

Plant- and animal-based adhesives

TypeSubtypesSource(s)ManufactureChemistryVolatilesSafetyPropertiesShelf lifeWorking timeSettingStrengthSolventsUsesDate
Roasted hydrocarbons Tar, pitch, and asphalt/ bitumen Made from plants (especially wood) or fossil hydrocarbonsnatural or artificial destructive distillation Hydrocarbon goo of no specific chemical formulaEmits Volatile organic compounds, especially when heatedhealth effects understudied (see Asphalt#Health and safety)dark, viscous, more flexible when heatedIndefinite, may stiffenIndefiniteReversibly becomes more flexible and fluid when heatedwater-repellant, Sealant, hafting prehistoric
Mixed-protein glues [1] Casein glue Milk, limestone and brine Milk curd is mixed with alkalisnon-toxic (preservatives excepted)Once wet, 6–7 hours.~4 hours for softwood, 8 for hardwood; must be under pressure for >0.5-2 hrstensile strength exceeds most woods, 2,200-3,00 pounds per square inchwater-resistant, depending on alkalis used Woodworking, paper glue, fireproof laminatesMedieval or earlier
Soybean glue As for casein glue, but using soy protein Soy protein is mixed with alkalis
Albumin glues (blood glues and egg albumin adhesive, EAA)blood (serum albumin) or eggs prehistoric
Gelatin glues hide glue, including rabbit-skin glue;

bone glue, and fish glue including isinglass

Animal connective tissue

and bones

hides are acid-treated, neutralized, and repeatedly soaked; the soaking-water is dried into chipshydrolyzed collagen Until it cools Thermoplastic. Somewhat brittle when setWater-solubleCabinetmaking, bookbinding, lutherie, glue-size
Keratin glues Hoof glue and horn glue hooves of ungulates, animal horns Hooves or horns are fragmented, boiled into goo, and acidifiedpartially- hydrolyzed keratin Until it cools Thermoplastic. Hardens as it cools, but does not become brittleGluing and stiffening textiles, cabinetmaking, glass sealant
Fibrin glue human fibrinogen and human thrombin when two parts are mixed, they form fibrin 10–60 secondsconverts to fibrin Medicine
Waxes Beeswax made by insects
Starch glues potato starch, rice glue, wheatpaste starches (plant energy-storage chemicals)Starch may be purified before being mixed with water; leaving gluten in makes a more permanent bond
Dextrin glues British gum, Coccoina usually derived from potato starchmid-19th century
Polysaccharide glues mucilage, agar, algin
Tree gums/resins Balsam (fir) resins, such as Canada balsam, Dammar gum, Gum Arabic (also called acacia gum), Mastic
Latex rubber cement

(cow gum)

latex, a coagulating plant fluid, also made syntheticallylatex is dissolved in an organic solventorganic solvent evaporates as it setssolvent may be hazardous; latex is an allergen
Methyl cellulose cellulose, a plant structural material, and methyl chlorideheating cellulose with an alkali and reacting it with methyl chloride

Solvent-type glues

Solvent adhesives temporarily dissolve the substance they are gluing, and bond by solvent-welding material together with the re-solidified material.

TypeSubtypesSource(s)ManufactureChemistryVolatilesSafetyPropertiesShelf lifeWorking timeSettingStrengthSolventsUsesDate
Ketones Acetone dissolves ABS plastic it is volatile
Polystyrene cement/Butanone/methyl ethyl ketone (MEK) dissolves polystyreneit is volatileVapour is heavier-than-air and explosive. Toxic, neuropsychological effects. Rapidly absorbed through undamaged skin and lungs. Produces toxic ozone. [2]
Dichloromethane Dissolves: it is volatile, boiling at 39.6°C (103.3°F; 312.8K)Will also glue acrylic to wood. [3] Clear, waterproof, exterior grades exist. [4] 24 hours to set fully. [5]

Synthetic glues

Synthetic monomer glues

A tube of Super Glue cyanoacrylate Super glue.jpg
A tube of Super Glue cyanoacrylate
TypeSubtypesSource(s)ManufactureChemistryVolatilesSafetyPropertiesShelf lifeWorking timeSettingStrengthSolventsUsesDate
Acrylonitrile synthetic monomer
Cyanoacrylate ("Superglue", "Krazy Glue")synthetic monomer
Methyl acrylate ("acrylic")synthetic monomer

Synthetic polymer glues

Thermoplastic polymers

Thermoplastic glues including hot-melt adhesives cure reversibly as they cool, like the gelatin and keratin glues listed above. They frequently don't emit volatiles unless overheated.

TypeSubtypesSource(s)ManufactureChemistryVolatilesSafetyPropertiesShelf lifeSettingStrengthSolventsUsesDate
Ethylene-vinyl acetate synthetic polyethylene mixed with about 11% vinyl acetate
Polyolefins (polyethylene, polypropylene, etc.)synthetic thermosetting
Polyamides synthetic
Polyesters synthetic
Polyurethanes synthetic
Polycaprolactone syntheticbiodegradablevery low melting temperature, 40–60 °C (104–140 °F) and heat conductivity means it can be moulded by hand. Can be used to mould itself.
  • Styrene acrylic copolymer – e.g. "No More Nails"

Thermosetting polymers

Thermosetting glues or thermosets cure irreversibly by polymerization. The polymerization can be triggered by heat or other radiation, or high pressure or a catalyst/hardener may be added.

TypeSubtypesSource(s)ManufactureChemistryVolatilesSafetyPropertiesShelf lifeWorking timeSettingStrengthSolventsUsesDate
Phenol formaldehyde resins (PF), also called phenolic resins Resorcinol glue, Para tertiary butylphenol formaldehyde resin synthetic resorcinol or similar is mixed with phenol to make a resin; cured by adding formaldehyde offgasses phenol and formeldehydephenol and formeldehyde are toxic, PTBPF causes contact allergiesTemperature-, UV-, and microbe-resistant. No gap-filling; joint must fit tightly. Brown in colour, sands off. [6] A few years, unmixed.Temperature-dependent. Will not cure at temperatures below 10 °C (50 °F). [6] Needs to be clampedStructuralWater-soluble until set, waterproof after. [6] laminating plywood, especially for exterior use; woodworking
Urea-formaldehyde gluesynthetic urea and formaldehyde offgasses urea and formeldehydeformeldehyde is toxic, urea is an irritant thermosetting
Polysulfides syntheticWill melt acrylic, polycarbonate, ABS and PVC plastic. Can be used to glue nylon, epoxy, and polyoxymethylene. [7]

By use

Related Research Articles

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Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation.

<span class="mw-page-title-main">Cyanoacrylate</span> Type of fast-acting adhesive

Cyanoacrylates are a family of strong fast-acting adhesives with industrial, medical, and household uses. They are derived from ethyl cyanoacrylate and related esters. The cyanoacrylate group in the monomer rapidly polymerizes in the presence of water to form long, strong chains.

<span class="mw-page-title-main">Petrochemical</span> Chemical product derived from petroleum

Petrochemicals are the chemical products obtained from petroleum by refining. Some chemical compounds made from petroleum are also obtained from other fossil fuels, such as coal or natural gas, or renewable sources such as maize, palm fruit or sugar cane.

<span class="mw-page-title-main">Epoxy</span> Type of material

Epoxy is the family of basic components or cured end products of epoxy resins. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups. The epoxide functional group is also collectively called epoxy. The IUPAC name for an epoxide group is an oxirane.

<span class="mw-page-title-main">Varnish</span> Transparent hard protective finish or film

Varnish is a clear transparent hard protective coating or film. It is not to be confused with wood stain. It usually has a yellowish shade due to the manufacturing process and materials used, but it may also be pigmented as desired. It is sold commercially in various shades.

<span class="mw-page-title-main">Lamination</span> Technique of fusing layers of material

Lamination is the technique/process of manufacturing a material in multiple layers, so that the composite material achieves improved strength, stability, sound insulation, appearance, or other properties from the use of the differing materials, such as plastic. A laminate is a permanently assembled object created using heat, pressure, welding, or adhesives. Various coating machines, machine presses and calendering equipment are used.

Araldite is a registered trademark of Huntsman Advanced Materials referring to their range of engineering and structural epoxy, acrylic, and polyurethane adhesives. Swiss manufacturers originally launched Araldite DIY adhesive products in 1946. The first batches of Araldite epoxy resins, for which the brand is best known, were made in Duxford, England in 1950.

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<span class="mw-page-title-main">Polyvinyl fluoride</span> Chemical compound

Polyvinyl fluoride (PVF) or –(CH2CHF)n– is a polymer material mainly used in the flammability-lowering coatings of airplane interiors and photovoltaic module backsheets. It is also used in raincoats and metal sheeting. Polyvinyl fluoride is a thermoplastic fluoropolymer with a repeating vinyl fluoride unit, and it is structurally very similar to polyvinyl chloride.

A binder or binding agent is any material or substance that holds or draws other materials together to form a cohesive whole mechanically, chemically, by adhesion or cohesion.

<span class="mw-page-title-main">Hot-melt adhesive</span> Glue applied by heating

Hot-melt adhesive (HMA), also known as hot glue, is a form of thermoplastic adhesive that is commonly sold as solid cylindrical sticks of various diameters designed to be applied using a hot glue gun. The gun uses a continuous-duty heating element to melt the plastic glue, which the user pushes through the gun either with a mechanical trigger mechanism on the gun, or with direct finger pressure. The glue squeezed out of the heated nozzle is initially hot enough to burn and even blister skin. The glue is sticky when hot, and solidifies in a few seconds to one minute. Hot-melt adhesives can also be applied by dipping or spraying, and are popular with hobbyists and crafters both for affixing and as an inexpensive alternative to resin casting.

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<span class="mw-page-title-main">Pressure-sensitive adhesive</span> Type of non reactive adhesive

Pressure-sensitive adhesive is a type of nonreactive adhesive which forms a bond when pressure is applied to bond the adhesive with a surface. No solvent, water, or heat is needed to activate the adhesive. It is used in pressure-sensitive tapes, labels, glue dots, stickers, sticky note pads, automobile trim, and a wide variety of other products.

Synthetic resins are industrially produced resins, typically viscous substances that convert into rigid polymers by the process of curing. In order to undergo curing, resins typically contain reactive end groups, such as acrylates or epoxides. Some synthetic resins have properties similar to natural plant resins, but many do not.

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<span class="mw-page-title-main">Acrylonitrile styrene acrylate</span> Chemical compound

Acrylonitrile styrene acrylate (ASA), also called acrylic styrene acrylonitrile, is an amorphous thermoplastic developed as an alternative to acrylonitrile butadiene styrene (ABS), that has improved weather resistance. It is an acrylate rubber-modified styrene acrylonitrile copolymer. It is used for general prototyping in 3D printing, where its UV resistance and mechanical properties make it an excellent material for use in fused filament fabrication printers, particularly for outdoor applications. ASA is also widely used in the automotive industry.

The conservation-restoration of panel paintings involves preventive and treatment measures taken by paintings conservators to slow deterioration, preserve, and repair damage. Panel paintings consist of a wood support, a ground, and an image layer. They are typically constructed of two or more panels joined together by crossbeam braces which can separate due to age and material instability caused by fluctuations in relative humidity and temperature. These factors compromise structural integrity and can lead to warping and paint flaking. Because wood is particularly susceptible to pest damage, an IPM plan and regulation of the conditions in storage and display are essential. Past treatments that have fallen out of favor because they can cause permanent damage include transfer of the painting onto a new support, planing, and heavy cradling. Today's conservators often have to remediate damage from previous restoration efforts. Modern conservation-restoration techniques favor minimal intervention that accommodates wood's natural tendency to react to environmental changes. Treatments may include applying flexible battens to minimize deformation or simply leaving distortions alone, instead focusing on preventive care to preserve the artwork in its original state.

Adhesive bonding is a joining technique used in the manufacture and repair of a wide range of products. Along with welding and soldering, adhesive bonding is one of the basic joining processes. In this technique, components are bonded together using adhesives. The broad range of types of adhesives available allows numerous materials to be bonded together in products as diverse as vehicles, mobile phones, personal care products, buildings, computers and medical devices.

Waterborne resins are sometimes called water-based resins. They are resins or polymeric resins that use water as the carrying medium as opposed to solvent or solvent-less. Resins are used in the production of coatings, adhesives, sealants, elastomers and composite materials. When the phrase waterborne resin is used, it usually describes all resins which have water as the main carrying solvent. The resin could be water-soluble, water reducible or water dispersed.

References

  1. Bye, Carolyn N. (1990). "Casein and Mixed Protein Adhesives". Handbook of Adhesives. pp. 135–152. doi:10.1007/978-1-4613-0671-9_7. ISBN   978-1-4612-8019-4.
  2. Simon B.N. Thompson (Winter 2010). "Implications for cognitive rehabilitation and brain injury from exposure to Methyl Ethyl Ketone (MEK): a review" (PDF). Journal of Cognitive Rehabilitation. 28(Winter): 4–14. Archived from the original (PDF) on 2022-01-21.
  3. "Tensol 70 Glue | EVO-STIK Two Part Adhesive | Silmid". www.silmid.com.
  4. "Chemical Bonding | Perspex Fabrication | UV & Solvent bonding, Tensol 70". IPFL.
  5. "Gluing Acrylic | Acrylic". www.ultimatehandyman.co.uk. Retrieved 6 March 2023.
  6. 1 2 3 Boat, Classic (2011-03-11). "Adhesives for Wooden Boats: Structural Glues". Classic Boat Magazine. Retrieved 2022-11-11.
  7. "Marine Caulking & Adhesives". West Marine. Retrieved 2022-11-11.