Potassium iodate

Last updated
Potassium iodate
Potassium-iodate-unit-cell-3D-balls.png
Jodicnan draselny.JPG
Names
IUPAC name
Potassium iodate
Other names
Iodic acid, potassium salt
Identifiers
3D model (JSmol)
ChemSpider
DrugBank
ECHA InfoCard 100.028.938 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 231-831-9
E number E917 (glazing agents, ...)
PubChem CID
RTECS number
  • NN1350000
UNII
  • InChI=1S/HIO3.K/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1 Yes check.svgY
    Key: JLKDVMWYMMLWTI-UHFFFAOYSA-M Yes check.svgY
  • InChI=1/HIO3.K/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1
    Key: JLKDVMWYMMLWTI-REWHXWOFAL
  • [K+].[O-]I(=O)=O
Properties
KIO3
Molar mass 214.001 g/mol
Appearancewhite crystalline powder
Odor odorless
Density 3.89 g/cm3
Melting point 560 °C (1,040 °F; 833 K) (decomposes)
4.74 g/100 mL (0 °C)
9.16 g/100 mL (25 °C)
32.3 g/100 mL (100 °C)
Solubility soluble in KI solution
insoluble in alcohol, liquid ammonia, nitric acid
63.1·10−6 cm3/mol
Hazards
GHS labelling:
GHS-pictogram-rondflam.svg GHS-pictogram-acid.svg GHS-pictogram-exclam.svg
H272, H302, H318
P210, P280, P301+P312+P330, P305+P351+P338+P310
NFPA 704 (fire diamond)
NFPA 704.svgHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 2: Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water. E.g. white phosphorusSpecial hazard OX: Oxidizer. E.g. potassium perchlorate
2
0
2
OX
Flash point Non-flammable
Related compounds
Other anions
Potassium chlorate
Potassium bromate
Other cations
Sodium iodate
Related compounds
Potassium iodide
Potassium periodate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
X mark.svgN  verify  (what is  Yes check.svgYX mark.svgN ?)

Potassium iodate (K I O3) is an ionic inorganic compound with the formula KIO3. It is a white salt that is soluble in water. [1]

Contents

Preparation and properties

It can be prepared by reacting a potassium-containing base such as potassium hydroxide with iodic acid, for example: [1]

HIO3 + KOH → KIO3 + H2O

It can also be prepared by adding iodine to a hot, concentrated solution of potassium hydroxide: [1]

3 I2 + 6 KOH → KIO3 + 5 KI + 3 H2O

Or by fusing potassium iodide with potassium chlorate, bromate or perchlorate, the melt is extracted with water and potassium iodate is isolated from the solution by crystallization: [2]

KI + KClO3 → KIO3 + KCl

The analogous reaction with potassium hypochlorite is also possible: [3]

KI + 3KOCl → 3KCl + KIO3

Conditions/substances to avoid include: heat, shock, friction, [4] combustible materials, [1] reducing materials, aluminium, [4] organic compounds, [1] carbon, hydrogen peroxide and sulfides. [4]

Applications

Potassium iodate is sometimes used for iodination of table salt to prevent iodine deficiency. In the US, iodized salt contains antioxidants, because atmospheric oxygen can oxidize wet iodide to iodine; other countries simply use potassium iodate instead. [5] Salt mixed with ferrous fumarate and potassium iodate, "double fortified salt", are used to address both iron and iodine deficiencies. [6] Potassium iodate is also used to provide iodine in some baby formula. [7]

Like potassium bromate, potassium iodate is occasionally used as a maturing agent in baking. [8]

Radiation protection

An unopened box of potassium iodate tablets distributed in the early 2000s to Irish households in case of a terror attack on British nuclear facilities. Potassium iodate tablets.jpg
An unopened box of potassium iodate tablets distributed in the early 2000s to Irish households in case of a terror attack on British nuclear facilities.

Potassium iodate may be used to protect against accumulation of radioactive iodine in the thyroid by saturating the body with a stable source of iodine prior to exposure. [9] Approved by the World Health Organization for radiation protection, potassium iodate (KIO3) is an alternative to potassium iodide (KI), which has poor shelf life in hot and humid climates. [10] The UK, Singapore, United Arab Emirates, and the U.S. states Idaho and Utah all maintain potassium iodate tablets towards this end.[ citation needed ] Following the September 11 attacks, the government of Ireland issued potassium iodate tablets to all households for a similar purpose. [11]

Recommended Dosage for Radiological Emergencies involving radioactive iodine [12]
AgeKI in mgKIO3 in mg
Over 12 years old130170
3 – 12 years old6585
1 – 36 months old3242
< 1 month old1621

Potassium iodate is not approved by the U.S. Food and Drug Administration (FDA) for use as a thyroid blocker, and the FDA has taken action against US websites that promote this use. [13] [14]

Safety

Potassium iodate is an oxidizing agent and as such it can form explosive mixtures when combined with organic compounds. [1]

Related Research Articles

<span class="mw-page-title-main">Iodine</span> Chemical element, symbol I and atomic number 53

Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at 114 °C (237 °F), and boils to a violet gas at 184 °C (363 °F). The element was discovered by the French chemist Bernard Courtois in 1811 and was named two years later by Joseph Louis Gay-Lussac, after the Ancient Greek Ιώδης, meaning 'violet'.

<span class="mw-page-title-main">Potassium hydroxide</span> Inorganic compound (KOH)

Potassium hydroxide is an inorganic compound with the formula KOH, and is commonly called caustic potash.

<span class="mw-page-title-main">Potassium permanganate</span> Chemical compound

Potassium permanganate is an inorganic compound with the chemical formula KMnO4. It is a purplish-black crystalline salt, that dissolves in water as K+ and MnO
4
, an intensely pink to purple solution.

<span class="mw-page-title-main">Potassium iodide</span> Ionic compound (KI)

Potassium iodide is a chemical compound, medication, and dietary supplement. It is a medication used for treating hyperthyroidism, in radiation emergencies, and for protecting the thyroid gland when certain types of radiopharmaceuticals are used. In the third world it is also used for treating skin sporotrichosis and phycomycosis. It is a supplement used by people with low dietary intake of iodine. It is administered orally.

<span class="mw-page-title-main">Potassium perchlorate</span> Chemical compound

Potassium perchlorate is the inorganic salt with the chemical formula KClO4. Like other perchlorates, this salt is a strong oxidizer although it usually reacts very slowly with organic substances. This, usually obtained as a colorless, crystalline solid, is a common oxidizer used in fireworks, ammunition percussion caps, explosive primers, and is used variously in propellants, flash compositions, stars, and sparklers. It has been used as a solid rocket propellant, although in that application it has mostly been replaced by the higher performance ammonium perchlorate.

<span class="mw-page-title-main">Iodised salt</span> Table salt preparation with iodide salts added

Iodised salt is table salt mixed with a minute amount of various salts of the element iodine. The ingestion of iodine prevents iodine deficiency. Worldwide, iodine deficiency affects about two billion people and is the leading preventable cause of intellectual and developmental disabilities. Deficiency also causes thyroid gland problems, including endemic goitre. In many countries, iodine deficiency is a major public health problem that can be cheaply addressed by purposely adding small amounts of iodine to the sodium chloride salt.

<span class="mw-page-title-main">Iodate</span> Polyatomic anion (IO3) with charge -1

An iodate is the polyatomic anion with the formula IO−3. It is the most common form of iodine in nature, as it comprises the major iodine-containing ores. Iodate salts are often colorless. They are the salts of iodic acid.

<span class="mw-page-title-main">Potassium periodate</span> Chemical compound

Potassium periodate is an inorganic salt with the molecular formula KIO4. It is composed of a potassium cation and a periodate anion and may also be regarded as the potassium salt of periodic acid. Note that the pronunciation is per-iodate, not period-ate.

<span class="mw-page-title-main">Potassium manganate</span> Chemical compound

Potassium manganate is the inorganic compound with the formula K2MnO4. This green-colored salt is an intermediate in the industrial synthesis of potassium permanganate, a common chemical. Occasionally, potassium manganate and potassium permanganate are confused, but each compound's properties are distinct.

<span class="mw-page-title-main">Iodine clock reaction</span> Experiment to show chemical kinetics in action

The iodine clock reaction is a classical chemical clock demonstration experiment to display chemical kinetics in action; it was discovered by Hans Heinrich Landolt in 1886. The iodine clock reaction exists in several variations, which each involve iodine species and redox reagents in the presence of starch. Two colourless solutions are mixed and at first there is no visible reaction. After a short time delay, the liquid suddenly turns to a shade of dark blue due to the formation of a triiodide–starch complex. In some variations, the solution will repeatedly cycle from colorless to blue and back to colorless, until the reagents are depleted.

<span class="mw-page-title-main">Sodium iodate</span> Chemical compound

Sodium iodate (NaIO3) is the sodium salt of iodic acid. Sodium iodate is an oxidizing agent. It has several uses.

<span class="mw-page-title-main">Dough conditioner</span>

A dough conditioner, flour treatment agent, improving agent or bread improver is any ingredient or chemical added to bread dough to strengthen its texture or otherwise improve it in some way. Dough conditioners may include enzymes, yeast nutrients, mineral salts, oxidants and reductants, bleaching agents and emulsifiers. They are food additives combined with flour to improve baking functionality. Flour treatment agents are used to increase the speed of dough rising and to improve the strength and workability of the dough.

Calcium iodate is any of two inorganic compounds with the formula Ca(IO3)2(H2O)x, where x = 0 or 1. Both are colourless salts that occur as the minerals lautarite and bruggenite, respectively. A third mineral form of calcium iodate is dietzeite, a salt containing chromate with the formula Ca2(IO3)2CrO4. These minerals are the most common compounds containing iodate.

Potassium iodide (KI) and potassium iodate (KIO3) are called thyroid blockers when used in radiation protection.

<span class="mw-page-title-main">Iodine in biology</span> Use of Iodine by organisms

Iodine is an essential trace element in biological systems. It has the distinction of being the heaviest element commonly needed by living organisms as well as the second-heaviest known to be used by any form of life. It is a component of biochemical pathways in organisms from all biological kingdoms, suggesting its fundamental significance throughout the evolutionary history of life.

<span class="mw-page-title-main">Ammonium iodate</span> Chemical compound

Ammonium iodate is an inorganic salt which is sparingly soluble in cold, and moderately soluble in hot water, like all iodate salts, it is a strong oxidizer.

Iodine is a chemical element with many uses in medicine, depending on the form. Elemental iodine and iodophors are topical antiseptics. Iodine, in non-elemental form, functions as an essential nutrient in human biology. Organic compounds containing iodine are also useful iodinated contrast agents in X-ray imaging.

<span class="mw-page-title-main">Phosphonium iodide</span> Chemical compound

Phosphonium iodide is a chemical compound with the formula PH
4
I
. It is an example of a salt containing an unsubstituted phosphonium cation. Phosphonium iodide is commonly used as storage for phosphine and as a reagent for substituting phosphorus into organic molecules.

<span class="mw-page-title-main">Potassium thiosulfate</span> Chemical compound

Potassium thiosulfate, commonly abbreviated KTS, is an inorganic compound with the formula K2S2O3. This salt can form multiple hydrates, such as the monohydrate, dihydrate, and the pentahydrate, all of which are white or colorless solids. It is used as a fertilizer.

<span class="mw-page-title-main">Disulfur diiodide</span> Chemical compound

Disulfur diiodide is an unstable inorganic chemical compound with the chemical formula S2I2. It is a red-brown solid that decomposes above −30 °C to elemental sulfur and iodine.

References

  1. 1 2 3 4 5 6 Lyday, Phyllis A.; Kaiho Tatsuo (26 November 2015). "Iodine and Iodine Compounds". In Ley, Claudia (ed.). Ullmann's Encyclopedia of Industrial Chemistry (7th ed.). Weinheim: Wiley-VCH. p. 9. doi:10.1002/14356007.a14_381.pub2. ISBN   9783527306732.
  2. Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN   0-07-049439-8
  3. Andrews, Launcelot W. (July 1903). "Titrations with potassium iodide". Journal of the American Chemical Society . Easton, Pennsylvania: US Postal Service. 25 (7): 756. doi:10.1021/ja02009a012 via HathiTrust.
  4. 1 2 3 Regulatory Affairs (23 March 2023). "Safety Data Sheet" (Potassium iodate MSDS) (5 ed.). Fair Lawn, NJ: Thermo Fisher Scientific. Archived from the original on 22 September 2023. Retrieved 22 September 2023.
  5. Arroyave, Guillermo; Pineda, Oscar; Scrimshaw, Nevin S. (1956) [May 1955]. "The stability of potassium iodate in crude table salt". Bulletin of the World Health Organization . 14 (1): 183–185. PMC   2538103 . PMID   13329845.
  6. Diosady, Levente L.; Mannar, M.G. Venkatesh; Krishnaswamy, Kiruba (2019). "Improving the lives of millions through new double fortification of salt technology". Maternal & Child Nutrition. 15 (Suppl 3): e12773. doi:10.1111/mcn.12773. PMC   6594086 . PMID   31148400.
  7. James, Maia (2023-04-04). "Best Baby Formula Guide". Gimme the Good Stuff. Retrieved 2023-09-22.
  8. Carson, Lin (ed.). "Potassium iodate". BAKERpedia. Portland, OR . Retrieved 22 September 2023.
  9. Astbury, John; Horsley, Stephen; Gent, Nick (1999), "Evaluation of a scheme for the pre-distribution of stable iodine (potassium iodate) to the civilian population residing within the immediate countermeasures zone of a nuclear submarine construction facility", Journal of Public Health, 21 (4): 2008–10, doi: 10.1093/pubmed/21.4.412 , PMID   11469363, archived from the original on 2008-09-05
  10. Pahuja, D.N.; Rajan, M.G.; Borkar, A.V.; Samuel, A.M. (Nov 2008), "Potassium iodate and its comparison to potassium iodide as a blocker of 131I uptake by the thyroid in rats", Health Physics, 65 (5): 545–9, doi:10.1097/00004032-199311000-00014, PMID   8225995
  11. "Decision to Discontinue the Future Distribution of Iodine Tablets". Archived from the original on 2013-10-18. Retrieved 2013-05-22.
  12. Guidelines for Iodine Prophylaxis following Nuclear Accidents (PDF), Geneva: World Health Organization, 1999
  13. "Potassium iodide vs potassium iodate. Which one works?".
  14. W. Charles Becoat (29 May 2003). "Potassium Iodate Warning Letter" (PDF). Food and Drug Administration.