In physics, cryogenics is the production and behaviour of materials at very low temperatures.
Distillation, or classical distillation, is the process of separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distillation is the heating of solid materials to produce gaseous products ; this may involve chemical changes such as destructive distillation or cracking. Distillation may result in essentially complete separation, or it may be a partial separation that increases the concentration of selected components; in either case, the process exploits differences in the relative volatility of the mixture's components. In industrial applications, distillation is a unit operation of practically universal importance, but is a physical separation process, not a chemical reaction. An installation used for distillation, especially of distilled beverages, is a distillery. Distillation includes the following applications:
Superfluid helium-4 is the superfluid form of helium-4, an isotope of the element helium. A superfluid is a state of matter in which matter behaves like a fluid with zero viscosity. The substance, which looks like a normal liquid, flows without friction past any surface, which allows it to continue to circulate over obstructions and through pores in containers which hold it, subject only to its own inertia.
The following is a timeline of low-temperature technology and cryogenic technology. It also lists important milestones in thermometry, thermodynamics, statistical physics and calorimetry, that were crucial in development of low temperature systems.
A cryopump or a "cryogenic pump" is a vacuum pump that traps gases and vapours by condensing them on a cold surface, but are only effective on some gases. The effectiveness depends on the freezing and boiling points of the gas relative to the cryopump's temperature. They are sometimes used to block particular contaminants, for example in front of a diffusion pump to trap backstreaming oil, or in front of a McLeod gauge to keep out water. In this function, they are called a cryotrap, waterpump or cold trap, even though the physical mechanism is the same as for a cryopump.
Liquid nitrogen—LN2—is nitrogen in a liquid state at low temperature. Liquid nitrogen has a boiling point of about −195.8 °C (−320 °F; 77 K). It is produced industrially by fractional distillation of liquid air. It is a colorless, low viscosity liquid that is widely used as a coolant.
Liquid helium is a physical state of helium at very low temperatures at standard atmospheric pressures. Liquid helium may show superfluidity.
A 3He/4He dilution refrigerator is a cryogenic device that provides continuous cooling to temperatures as low as 2 mK, with no moving parts in the low-temperature region. The cooling power is provided by the heat of mixing of the helium-3 and helium-4 isotopes.
A heat pipe is a heat-transfer device that employs phase transition to transfer heat between two solid interfaces.
An evaporative cooler is a device that cools air through the evaporation of water. Evaporative cooling differs from other air conditioning systems, which use vapor-compression or absorption refrigeration cycles. Evaporative cooling exploits the fact that water will absorb a relatively large amount of heat in order to evaporate. The temperature of dry air can be dropped significantly through the phase transition of liquid water to water vapor (evaporation). This can cool air using much less energy than refrigeration. In extremely dry climates, evaporative cooling of air has the added benefit of conditioning the air with more moisture for the comfort of building occupants.
A refrigerator designed to reach cryogenic temperatures is often called a cryocooler. The term is most often used for smaller systems, typically table-top size, with input powers less than about 20 kW. Some can have input powers as low as 2–3 W. Large systems, such as those used for cooling the superconducting magnets in particle accelerators are more often called cryogenic refrigerators. Their input powers can be as high as 1 MW. In most cases cryocoolers use a cryogenic fluid as the working substance and employ moving parts to cycle the fluid around a thermodynamic cycle. The fluid is typically compressed at room temperature, precooled in a heat exchanger, then expanded at some low temperature. The returning low-pressure fluid passes through the heat exchanger to precool the high-pressure fluid before entering the compressor intake. The cycle is then repeated.
A cryostat is a device used to maintain low cryogenic temperatures of samples or devices mounted within the cryostat. Low temperatures may be maintained within a cryostat by using various refrigeration methods, most commonly using cryogenic fluid bath such as liquid helium. Hence it is usually assembled into a vessel, similar in construction to a vacuum flask or Dewar. Cryostats have numerous applications within science, engineering, and medicine.
An absorption refrigerator is a refrigerator that uses a heat source to provide the energy needed to drive the cooling process. The system uses two coolants, the first of which performs evaporative cooling and is then absorbed into the second coolant; heat is needed to reset the two coolants to their initial states. The principle can also be used to air-condition buildings using the waste heat from a gas turbine or water heater. Using waste heat from a gas turbine makes the turbine very efficient because it first produces electricity, then hot water, and finally, air-conditioning—trigeneration. Absorption refrigerators are commonly used in recreational vehicles (RVs), campers, and caravans because the heat required to power them can be provided by a propane fuel burner, by a low-voltage DC electric heater or by a mains-powered electric heater. Unlike more common vapor-compression refrigeration systems, an absorption refrigerator has no moving parts.
Vapour-compression refrigeration or vapor-compression refrigeration system (VCRS), in which the refrigerant undergoes phase changes, is one of the many refrigeration cycles and is the most widely used method for air conditioning of buildings and automobiles. It is also used in domestic and commercial refrigerators, large-scale warehouses for chilled or frozen storage of foods and meats, refrigerated trucks and railroad cars, and a host of other commercial and industrial services. Oil refineries, petrochemical and chemical processing plants, and natural gas processing plants are among the many types of industrial plants that often utilize large vapor-compression refrigeration systems. Cascade refrigeration systems may also be implemented using two compressors.
An evaporator is a device used to turn a liquid into a gas.
A lambda point refrigerator is a device used to cool liquid helium, typically around a superconducting magnet or for low temperature measurements, from approximately 4.2 K to temperatures near the lambda point of helium, the temperature at which normal fluid helium transitions to the superfluid helium II. Cooling is achieved by pumping the liquid helium in the bath through a cooling coil via a needle valve and vacuum pump. The reduced pressure in the coil causes some of the helium to evaporate, creating a two-phase system within the cooling coil. The heat removed via evaporation lowers the temperature of the cooling coil closer to the lambda point. Since the cooling coil is immersed in the liquid helium bath, liquid surrounding the coil is also cooled. The colder, higher density liquid sinks away from the coil toward the bottom of the bath while the warmer, lower density liquid helium rises to the top. Liquid helium typically has poor thermal conductivity, so convective currents associated with a temperature gradient in the bath provide a constant flow of this colder liquid helium toward the bottom of the bath, allowing temperatures below 4.2 K to be realized in the helium bath, typically close to 2.2 K.
The pulse tube refrigerator (PTR) or pulse tube cryocooler is a developing technology that emerged largely in the early 1980s with a series of other innovations in the broader field of thermoacoustics. In contrast with other cryocoolers, this cryocooler can be made without moving parts in the low temperature part of the device, making the cooler suitable for a wide variety of applications.
A helium-3 refrigerator is a simple device used in experimental physics for obtaining temperatures down to about 0.2 kelvins. By evaporative cooling of helium-4, a 1-K pot liquefies a small amount of helium-3 in a small vessel called a helium-3 pot. Evaporative cooling at low pressure of the liquid helium-3, usually driven by adsorption since due to its high price the helium-3 is usually contained in a closed system to avoid losses, cools the helium-3 pot to a fraction of a kelvin.
A cryogenic gas plant is an industrial facility that creates molecular oxygen, molecular nitrogen, argon, krypton, helium, and xenon at relatively high purity. As air is made up of nitrogen, the most common gas in the atmosphere, at 78%, with oxygen at 19%, and argon at 1%, with trace gasses making up the rest, cryogenic gas plants separate air inside a distillation column at cryogenic temperatures to produce high purity gasses such as argon, nitrogen, oxygen, and many more with 1 ppm or less impurities. The process is based on the general theory of the Hampson-Linde cycle of air separation, which was invented by Carl von Linde in 1895.
In the field of cryogenics, helium [He] is utilized for a variety of reasons. The combination of helium’s extremely low molecular weight and weak interatomic reactions yield interesting properties when helium is cooled below its critical temperature of 5.2 K to form a liquid. Even at absolute zero (0K), helium does not condense to form a solid under ambient pressure. In this state, the zero point vibrational energies of helium are comparable to very weak interatomic binding interactions, thus preventing lattice formation and giving helium its fluid characteristics. Within this liquid state, helium has two phases referred to as helium I and helium II. Helium I displays thermodynamic and hydrodynamic properties of classical fluids, along with quantum characteristics. However, below its lambda point of 2.17 K, helium transitions to He II and becomes a quantum superfluid with zero viscosity.
