Alternatives assessment or alternatives analysis is a problem-solving approach used in environmental design, technology, and policy. It aims to minimize environmental harm by comparing multiple potential solutions in the context of a specific problem, design goal, or policy objective. It is intended to inform decision-making in situations with many possible courses of action, a wide range of variables to consider, and significant degrees of uncertainty. Alternatives assessment was originally developed as a robust way to guide precautionary action and avoid paralysis by analysis; authors such as O'Brien have presented alternatives assessment as an approach that is complementary to risk assessment, the dominant decision-making approach in environmental policy. [1] Likewise, Ashford has described the similar concept of technology options analysis as a way to generate innovative solutions to the problems of industrial pollution more effectively than through risk-based regulation. [2] [3]
Alternatives assessment is practiced in a variety of settings, including but not limited to green chemistry, sustainable design, supply-chain chemicals management, and chemicals policy. [4] One prominent application area for alternatives assessment is the substitution of hazardous chemicals with safer alternatives, also known as chemical alternatives assessment. [5]
Generally, alternatives assessment involves considering a number of possible options to achieve a specific objective, and applying a principled comparative analysis. The objective is usually to improve the environmental performance or safety of a specific product, material, process, or other activity. Potential alternatives considered in the analysis may include different chemical substances, materials, technologies, methods of use, or even extensive redesign to enable new ways of achieving the objective while avoiding the problem. Understanding the consequences of each available option is central to the process and goals of alternatives assessment, because this helps avoid decisions that substitute one problem with another (unknown) problem. The comparative analysis can involve any number of criteria for evaluating options, and these are typically focused on environmental health and sustainability. [6]
There is no single protocol that dictates how options should be identified, evaluated, and compared in an alternatives assessment. Rather, a number of different alternatives assessment frameworks exist, which serve to structure decision-making and to enable systematic consideration of the key factors. Jacobs and colleagues identify six major components of alternatives assessment: evaluation of hazard, exposure, life cycle impacts, technical feasibility, and economic feasibility; and an overall decision-making strategy. [7]
One major framework, the Lowell Center for Sustainable Production Alternatives Assessment Framework, [6] conceives of alternatives assessment very broadly, as a reflexive problem-solving process that recognizes the social and technical complexity of environmental problems. It emphasizes aspects such as stakeholder participation, transparency of the process, and open discussion of values in decision-making. Most other frameworks are more narrow and primarily focused on technical aspects. [7]
Chemical alternatives assessment (or substitution of hazardous chemicals) is the use of alternatives assessment for finding safer and environmentally preferable design options to reduce or eliminate the use of hazardous chemical substances. Safer alternatives to hazardous chemicals may simply be other chemical substances, or may involve deeper changes in material or product design. [8] [9] Chemical alternatives assessment aims to provide the basis for well-informed decision-making by thoroughly characterizing chemicals and materials (and other design options) across a wide range of environmental and health impact categories. The rationale for this is to avoid shifting environmental health burdens from one category of impacts to another (e.g., substituting a carcinogenic chemical with a neurotoxic one), and to minimize the unintended consequences of decisions made under conditions of uncertainty and ignorance—in other words, to prevent "regrettable substitutions", where an alternative appeared better based on limited knowledge, but turned out to be worse or equally bad. [10]
An array of methodologies and tools for chemical alternatives assessment have been developed worldwide and have been deployed in a variety of industry sectors. [5] [11] Chemical alternatives assessment frameworks include chemical hazard assessment methods that consider a wide range of hazard endpoints, such as those defined in the Globally Harmonized System or the GreenScreen for Safer Chemicals.
Scientists from a variety of government agencies, academic institutions, non-profit organizations, and firms have contributed to developing the practice of alternatives assessment.
Scientific research in the US federal government has contributed to alternatives assessment frameworks and practices. In 2014 the US National Research Council released a chemical alternatives assessment framework developed by an expert working group. [15] Prior to this, the US Environmental Protection Agency ran a program called Design for the Environment (now called Safer Choice), which developed chemical alternatives assessment methodology [8] and created partnerships to undertake numerous alternatives assessments for chemicals of concern in products. [16]
Alternatives assessment has featured in some state-level chemicals policies and regulatory activities. The Massachusetts Toxics Use Reduction Institute has provided public technical assistance for "toxics use reduction planning", which includes alternatives assessment. [17] More recently, the California Department of Toxic Substances Control is implementing new regulations that require firms to undertake alternatives assessments for selected priority chemicals in products. [18] The Interstate Chemicals Clearinghouse, an association of state governments, has also produced its own guide to alternatives assessment. [19]
Some US-based companies have begun to use chemical alternatives assessment to address chemical safety issues in supply chains. For example, firms that participate in the Business-NGO Working Group for Safer Chemicals and Sustainable Materials have produced their own guidance for chemical alternatives assessment. [20]
The Sweden-based non-governmental organization ChemSec has been active in developing resources and tools for the substitution of hazardous chemicals. The Substitution support portal (SUBSPORT) is an EU-based collaboratively-developed resource for chemical substitution. [21] It includes alternatives assessment case studies. In Sweden, the Swedish Centre for Chemical Substitution works to promote the use of Alternatives Assessment by providing education and support to companies.
One notable initiative spearheaded by ChemSec is the Substitution Support Portal (SUBSPORT). This EU-based platform serves as a collaborative resource for chemical substitution, bringing together expertise and knowledge from various stakeholders, including industry, academia, and NGOs. SUBSPORT provides valuable information and guidance on alternatives assessment, enabling users to navigate the complex landscape of chemical substitution effectively.
One significant aspect of SUBSPORT is its collection of alternatives assessment case studies. These case studies offer practical examples of how alternative assessments have been conducted in different contexts and industries. By showcasing successful substitution efforts, SUBSPORT not only inspires companies and organizations to adopt safer alternatives but also provides them with valuable insights into the methodologies and processes involved in conducting alternatives assessments.
In Sweden, the Swedish Centre for Chemical Substitution (SCCS) plays a crucial role in promoting the use of alternatives assessment among companies. The SCCS actively works to raise awareness about the benefits of alternatives assessment and provides education and support to help companies implement this approach effectively. By offering training programs, workshops, and technical expertise, the SCCS equips companies with the necessary knowledge and tools to identify and implement safer alternatives to hazardous chemicals.
Furthermore, the SCCS serves as a platform for collaboration and knowledge exchange among stakeholders involved in chemical substitution. It facilitates the sharing of best practices, experiences, and resources, fostering a community-driven approach towards sustainable chemical management. Through its initiatives, the SCCS strives to create a supportive environment where companies can make informed decisions about chemical substitution and drive positive change in their operations.
Toxicology is a scientific discipline, overlapping with biology, chemistry, pharmacology, and medicine, that involves the study of the adverse effects of chemical substances on living organisms and the practice of diagnosing and treating exposures to toxins and toxicants. The relationship between dose and its effects on the exposed organism is of high significance in toxicology. Factors that influence chemical toxicity include the dosage, duration of exposure, route of exposure, species, age, sex, and environment. Toxicologists are experts on poisons and poisoning. There is a movement for evidence-based toxicology as part of the larger movement towards evidence-based practices. Toxicology is currently contributing to the field of cancer research, since some toxins can be used as drugs for killing tumor cells. One prime example of this is ribosome-inactivating proteins, tested in the treatment of leukemia.
Risk assessment determines possible mishaps, their likelihood and consequences, and the tolerances for such events. The results of this process may be expressed in a quantitative or qualitative fashion. Risk assessment is an inherent part of a broader risk management strategy to help reduce any potential risk-related consequences.
The Agency for Toxic Substances and Disease Registry (ATSDR) is a federal public health agency within the United States Department of Health and Human Services' Centers for Disease Control and Prevention. The agency focuses on minimizing human health risks associated with exposure to hazardous substances. It works closely with other federal, state, and local agencies; tribal governments; local communities; and healthcare providers. Its mission is to "Serve the public through responsive public health actions to promote healthy and safe environments and prevent harmful exposures." ATSDR was created as an advisory, nonregulatory agency by the Superfund legislation and was formally organized in 1985.
Superfund is a United States federal environmental remediation program established by the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA). The program is administered by the Environmental Protection Agency (EPA). The program is designed to investigate and clean up sites contaminated with hazardous substances. Sites managed under this program are referred to as Superfund sites. Of all the sites selected for possible action under this program, 1178 remain on the National Priorities List (NPL) that makes them eligible for cleanup under the Superfund program. Sites on the NPL are considered the most highly contaminated and undergo longer-term remedial investigation and remedial action (cleanups). The state of New Jersey, the fifth smallest state in the U.S., is the location of about ten percent of the priority Superfund sites, a disproportionate amount.
Green chemistry, similar to sustainable chemistry or circular chemistry, is an area of chemistry and chemical engineering focused on the design of products and processes that minimize or eliminate the use and generation of hazardous substances. While environmental chemistry focuses on the effects of polluting chemicals on nature, green chemistry focuses on the environmental impact of chemistry, including lowering consumption of nonrenewable resources and technological approaches for preventing pollution.
Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) is a European Union regulation dating from 18 December 2006. REACH addresses the production and use of chemical substances, and their potential impacts on both human health and the environment. Its 849 pages took seven years to pass, and it has been described as the most complex legislation in the Union's history and the most important in 20 years. It is the strictest law to date regulating chemical substances and will affect industries throughout the world. REACH entered into force on 1 June 2007, with a phased implementation over the next decade. The regulation also established the European Chemicals Agency, which manages the technical, scientific and administrative aspects of REACH.
The Toxic Substances Control Act (TSCA) is a United States law, passed by the 94th United States Congress in 1976 and administered by the United States Environmental Protection Agency (EPA), that regulates chemicals not regulated by other U.S. federal statutes, including chemicals already in commerce and the introduction of new chemicals. When the TSCA was put into place, all existing chemicals were considered to be safe for use and subsequently grandfathered in. Its three main objectives are to assess and regulate new commercial chemicals before they enter the market, to regulate chemicals already existing in 1976 that posed an "unreasonable risk of injury to health or the environment", as for example PCBs, lead, mercury and radon, and to regulate these chemicals' distribution and use.
Waste (management) hierarchy is a tool used in the evaluation of processes that protect the environment alongside resource and energy consumption from most favourable to least favourable actions. The hierarchy establishes preferred program priorities based on sustainability. To be sustainable, waste management cannot be solved only with technical end-of-pipe solutions and an integrated approach is necessary.
The European Chemicals Agency is an agency of the European Union working for the safe use of chemicals. It manages the technical and administrative aspects of the implementation of the European Union regulation called Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH). ECHA is the driving force among regulatory authorities in implementing the EU's chemicals legislation. ECHA has to ascertain that companies comply with the legislation, advances the safe use of chemicals, provides information on chemicals and addresses chemicals of concern. It is located in Helsinki, Finland. ECHA is an independent and mature regulatory agency established by REACH. It is not a subsidiary entity of the European Commission.
Electronic waste describes discarded electrical or electronic devices. It is also commonly known as waste electrical and electronic equipment (WEEE) or end-of-life (EOL) electronics. Used electronics which are destined for refurbishment, reuse, resale, salvage recycling through material recovery, or disposal are also considered e-waste. Informal processing of e-waste in developing countries can lead to adverse human health effects and environmental pollution. The growing consumption of electronic goods due to the Digital Revolution and innovations in science and technology, such as bitcoin, has led to a global e-waste problem and hazard. The rapid exponential increase of e-waste is due to frequent new model releases and unnecessary purchases of electrical and electronic equipment (EEE), short innovation cycles and low recycling rates, and a drop in the average life span of computers.
Hexabromocyclododecane is a brominated flame retardant. It consists of twelve carbon, eighteen hydrogen, and six bromine atoms tied to the ring. Its primary application is in extruded (XPS) and expanded (EPS) polystyrene foam used as thermal insulation in construction. Other uses are upholstered furniture, automobile interior textiles, car cushions and insulation blocks in trucks, packaging material, video cassette recorder housing, and electric and electronic equipment. According to UNEP, "HBCD is produced in China, Europe, Japan, and the USA. The known current annual production is approximately 28,000 tonnes per year. The main share of the market volume is used in Europe and China". Due to its persistence, toxicity, and ecotoxicity, the Stockholm Convention on Persistent Organic Pollutants decided in May 2013 to list hexabromocyclododecane in Annex A to the convention with specific exemptions for production and use in expanded polystyrene and extruded polystyrene in buildings. Because HBCD has 16 possible stereo-isomers with different biological activities, the substance poses a difficult problem for manufacture and regulation.
Design for the environment (DfE) is a design approach to reduce the overall human health and environmental impact of a product, process or service, where impacts are considered across its life cycle. Different software tools have been developed to assist designers in finding optimized products or processes/services. DfE is also the original name of a United States Environmental Protection Agency (EPA) program, created in 1992, that works to prevent pollution, and the risk pollution presents to humans and the environment. The program provides information regarding safer chemical formulations for cleaning and other products. EPA renamed its program "Safer Choice" in 2015.
Decabromodiphenyl ether is a brominated flame retardant which belongs to the group of polybrominated diphenyl ethers (PBDEs). It was commercialised in the 1970s and was initially thought to be safe, but is now recognised as a hazardous and persistent pollutant. It was added to Annex A of the Stockholm Convention on Persistent Organic Pollutants in 2017, which means that treaty members must take measures to eliminate its production and use. The plastics industry started switching to decabromodiphenyl ethane as an alternative in the 1990s, but this is now also coming under regulatory pressure due to concerns over human health.
Because of the ongoing controversy on the implications of nanotechnology, there is significant debate concerning whether nanotechnology or nanotechnology-based products merit special government regulation. This mainly relates to when to assess new substances prior to their release into the market, community and environment.
The California Green Chemistry Initiative (CGCI) is a six-part initiative to reduce public and environmental exposure to toxins through improved knowledge and regulation of chemicals; two parts became statute in 2008. The other four parts were not passed, but are still on the agenda of the California Department of Toxic Substances Control green ribbon science panel discussions. The two parts of the California Green Chemistry Initiative that were passed are known as AB 1879 : Hazardous Materials and Toxic Substances Evaluation and Regulation and SB 509 : Toxic Information Clearinghouse. Implementation of CGCI has been delayed indefinitely beyond the January 1, 2011.
The International Chemical Secretariat (ChemSec) is a non-profit environmental organisation founded in Sweden in 2002 to advocate in favour of stricter regulatory controls on potentially hazardous chemicals and to work with businesses on reducing the production and use of hazardous substances in their products and supply chains. ChemSec receives about 25 percent of its funding from the Swedish Government, the rest comes from foundations, mainly in the EU and the US, as well as from individuals. ChemSec maintains the SIN List, identifying hazardous substances likely to be restricted under EU REACH regulation.
The substitution of dangerous chemicals in the workplace is the process of replacing or eliminating the use chemicals that have significant chemical hazards. The goal of the substitution process is to improve occupational health and safety and minimize harmful environmental impacts. The process can be time-consuming; assessments of dangers, costs, and practicality may be necessary. Substituting hazardous chemicals follows the principles of green chemistry and can result in clean technology.
Spent Potlining (SPL) is a waste material generated in the primary aluminium smelting industry. Spent Potlining is also known as Spent Potliner and Spent Cell Liner.
Hazard substitution is a hazard control strategy in which a material or process is replaced with another that is less hazardous. Substitution is the second most effective of the five members of the hierarchy of hazard controls in protecting workers, after elimination. Substitution and elimination are most effective early in the design process, when they may be inexpensive and simple to implement, while for an existing process they may require major changes in equipment and procedures. The concept of prevention through design emphasizes integrating the more effective control methods such as elimination and substitution early in the design phase.
The GreenScreen for Safer Chemicals is a transparent, open standard for assessing chemical hazard that supports alternatives assessment for toxics use reduction through identifying chemicals of concern and safer alternatives. It is used by researchers, product formulators and certifiers in a variety of industries, including building products, textiles, apparel, and consumer products.
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