Chemical hazard

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A video on how exposure sampling works during a health hazard evaluation
A chemical burn Chemical Burn.jpg
A chemical burn

Chemical hazards are typical of hazardous chemicals and hazardous materials in general. Exposure to certain chemicals can cause acute or long-term adverse health effects. Chemical hazards are usually classified separately from biological hazards (biohazards). Main classifications of chemical hazards include asphyxiants, corrosives, irritants, sensitizers, carcinogens, mutagens, teratogens, reactants, and flammables. [1] In the workplace, exposure to chemical hazards is a type of occupational hazard. The use of protective personal equipment (PPE) may substantially reduce the risk of damage from contact with hazardous materials. [2]

Contents

Long-term exposure to chemical hazards such as silica dust, engine exhausts, tobacco smoke, and lead (among others) have been shown to increase risk of heart disease, stroke, and high blood pressure. [3]

Types of chemical hazard

HazardExample
Flammable and combustible liquids Diesel
Compressed gases Propane
Explosives TNT
Organic peroxides Methyl ethyl ketone peroxide (used in the manufacturing of polyester)
Reactives Benzoyl peroxide (used as a bleaching agent)
Oxidizers Potassium permanganate (used as an industrial disinfectant and sterilizer)
Pyrophorics White phosphorus
Carcinogens Benzene (feed-stock for many petrochemical processes)
Reproductive toxins Lead, dioxins
Teratogens Thalidomide (immunomodulatory drug)
Irritants Hydrochloric acid (used in food manufacturing and ore processing)
Corrosives Sulfuric acid (used to manufacture chemicals)
Sensitizers Latex
Hepatotoxins Trichlorethylene (used in metal degreasing and dry-cleaning, historically in anaesthesia)
Nephrotoxins Naproxen (an NSAID)
Radioactive materials Uranium salts, plutonium

Routes of exposure

The most common exposure route to chemicals in the work environment is through inhalation. [4] Gas, vapour, mist, dust, fumes, and smoke can all be inhaled. Those with occupations involving physical work may inhale higher levels of chemicals if working in an area with contaminated air. This is because workers who do physical work will exchange over 10,000 litres of air over an 8-hour day, while workers who do not do physical work will exchange only 2,800 litres. [5] If the air is contaminated in the workplace, more air exchange will lead to the inhalation of higher amounts of chemicals. [6]

Chemicals may be ingested when food or drink is contaminated by unwashed hands or from clothing or poor handling practices. [7] When ingestion of a chemical hazard occurs it comes from when those said chemicals are absorbed while in the digestive tract of the body. Ingestion only occurs when food or drink has contact with the toxic chemical. This can happen through direct or indirect ingestion. When food or drink is brought into an environment where harmful chemicals are unsealed there is the possibility of those chemical vapors or particles contaminating the food or the drink. A more direct form of chemical ingestion is the possibility of consuming the chemical directly. This rarely happens but, it is possible, that if there is little to no labeling on the chemical containers and if they aren’t secured properly an accident can occur which could lead to someone mistakenly assuming the chemical was something it wasn't. [8]

Chemical exposure to the skin is a common workplace injury and may also occur in domestic situations with chemicals such as bleach or drain-cleaners. The exposure of chemicals to the skin most often results in local irritation to the exposed area. [9] In some exposures, the chemical will be absorbed through the skin and will result in poisoning. [9] The eyes have a strong sensitivity to chemicals, and are consequently an area of high concern for chemical exposure. Chemical exposure to the eyes results in irritation and may result in burns and vision loss. [10]

Injection is an uncommon method of chemical exposure in the workplace. Chemicals can be injected into the skin when a worker is punctured by a sharp object, such as a needle. Chemical exposure through injection may result in the chemical entering directly into the bloodstream. [11]

Symbols of chemical hazards

Chemical Hazard Symbols GHS HAZCOM Safety Labels.jpg
Chemical Hazard Symbols

Hazard pictographs are a type of labeling system that alerts people at a glance that there are hazardous chemicals present. The symbols help identify whether the chemicals that are going to be in use may potentially cause physical harm, or harm to the environment. The symbols are distinctive, as they are shaped like diamonds with red borders. These signs can be divided into:

These pictographs are also subdivided into class and categories for each classification. The assignments for each chemical depends on their type and their severity.

Controlling chemical exposure

Elimination and substitution

Chemical exposure is estimated to have caused approximately 190,000 illnesses and 50,000 deaths of workers annually. [13] There exists an unknown link between chemical exposure and subsequent illness and/or death. Therefore, the majority of these illnesses and deaths are thought to be caused by a lack of knowledge and/or awareness concerning the dangers of chemicals. The best method of controlling chemical exposure within the workplace is through the elimination or the substitution of all chemicals that are thought or known to cause illness and/or death. [14]

Engineering controls

Although the elimination and the substitution of the harmful chemicals is the best known method for controlling chemical exposure, there are other methods that can be implemented to diminish exposure. The implementation of engineering controls is an example of another method for controlling chemical exposures. When engineer controls are implemented, there is a physical change made to the work environment that will eliminate or reduce the risk to chemical exposure. An example of engineer controls is the enclosure or isolation of the process that creates the chemical hazard. [14]

Administrative controls and safe work practices

If the process that creates the chemical hazard cannot be enclosed or isolated, the next best method is the implementation of administrative and work practices controls. This is the establishment of administrative and work practices that will reduce the amount of time and how often the workers will be exposed to the chemical hazard. An example of administrative and work practices controls is the establishment of work schedules in which workers have rotating job assignments. This will ensure that all workers have limited exposure to chemical hazards. [14]

Personal Protective Equipment (PPE)

Employers should provide personal protective equipment (PPE) to protect their workers from chemicals used within the workplace. The use of PPE prevents workers from being exposed to chemicals through the routes of exposure—inhalation, absorption through skin and/or eyes, ingestion, and injection. One example of how PPE usage can prevent chemical exposure concerns respirators. If workers wear respirators, they will prevent the exposure of chemicals through inhalation. [14]

First aid

In case of an emergency, it is recommended to understand first aid procedures in order to minimize any damage. Different types of chemicals can cause a variety of damage. Most sources agree that it is best to rinse any contacted skin or eye with water immediately. Currently, there is insufficient evidence of how long the rinsing should be done, as the degree of impacts will vary for substances such as corrosive chemicals. However, the recommended flush time is as follows:

Transporting the affected person to a health care facility may be important, depending on condition. In the case that the victim needs to be transported before the recommended flush time, then flushing should be done during the transportation process. Some chemical manufacturers may state the specific type of cleansing agent that is recommended. [15]

Long-term risks

Cancers

Many factors contribute to cancer, but some things can advance its progression in the body. One of these major factors is something known as carcinogenesis. Carcinogenesis have the capability of changing your DNA. They change your DNA by actually destroying your genetic makeup within your cells and if left alone this damage can be cancerous which could lead to tumors or blood cancer. Cancer doesn’t develop instantly; it takes a while to build up and could even possibly take years before a cancerous strand comes up. OSHA subpart 1926 subpart D states “Employers must limit an employee's exposure to any substance listed in Table 1 or 2 of this section in accordance with the following”. Limits are in place to try and prevent the build-up of Carcinogens in your DNA to hopefully prevent any long-term exposure and stop any form of cancer from forming. Some chemicals don’t individually cause cancer but, can work together to enhance the effects of carcinogens. For instance, exposure to multiple chemicals in an unsafe industrial setting or through environmental contamination can potentially raise cancer risk beyond the sum of individual exposures. [16]

Cardiovascular disease

A 2017 SBU report found evidence that workplace exposure to silica dust, engine exhaust or welding fumes is associated with heart disease. [3] Associations also exist for exposure to arsenic, benzopyrenes, lead, dynamite, carbon disulfide, carbon monoxide, metalworking fluids and occupational exposure to tobacco smoke. [3] Working with the electrolytic production of aluminium, or the production of paper when the sulphate pulping process is used, is associated with heart disease. [3] An association was also found between heart disease and exposure to compounds which are no longer permitted in certain work environments, such as phenoxy acids containing TCDD (dioxin) or asbestos. [3]

Workplace exposure to silica dust or asbestos is also associated with pulmonary heart disease. There is evidence that workplace exposure to lead, carbon disulphide, or phenoxyacids containing TCDD, as well as working in an environment where aluminium is being electrolytically produced, are associated with stroke. [3]

Reproductive and Developmental Disorder

Many things about the mixture of chemical exposures what it does to the human body and its functions are unknown. However, after many unfortunate occurrences, they have begun to link chemical hazards to health problems. The CDC has confirmed that pesticides and carbon disulfide plus other abrasive chemicals have led to high levels of emotional stress among women and could be linked to disruptions in the brain and ovaries. [17] Any contact with harmful chemicals during the first few months of pregnancy or even after has been connected to some miscarriages and has affected the menstrual cycle to the point that it has been able to block ovulation. When you look into the health issues caused during pregnancy due to harmful chemicals you must also think about how these chemicals can affect infants or fetuses. Some toxic chemical exposures have been associated with autism, attention deficit hyperactivity disorder and adult or childhood cancer. Clinicals offer the opportunity to counsel pregnant patients on reducing their contact with harmful environmental health exposures. [18]

See also

Related Research Articles

<span class="mw-page-title-main">Personal protective equipment</span> Equipment designed to help protect an individual from hazards

Personal protective equipment (PPE) is protective clothing, helmets, goggles, or other garments or equipment designed to protect the wearer's body from injury or infection. The hazards addressed by protective equipment include physical, electrical, heat, chemical, biohazards, and airborne particulate matter. Protective equipment may be worn for job-related occupational safety and health purposes, as well as for sports and other recreational activities. Protective clothing is applied to traditional categories of clothing, and protective gear applies to items such as pads, guards, shields, or masks, and others. PPE suits can be similar in appearance to a cleanroom suit.

<span class="mw-page-title-main">Occupational hygiene</span> Management of workplace health hazards

Occupational hygiene is the anticipation, recognition, evaluation, control, and confirmation (ARECC) of protection from risks associated with exposures to hazards in, or arising from, the workplace that may result in injury, illness, impairment, or affect the well-being of workers and members of the community. These hazards or stressors are typically divided into the categories biological, chemical, physical, ergonomic and psychosocial. The risk of a health effect from a given stressor is a function of the hazard multiplied by the exposure to the individual or group. For chemicals, the hazard can be understood by the dose response profile most often based on toxicological studies or models. Occupational hygienists work closely with toxicologists for understanding chemical hazards, physicists for physical hazards, and physicians and microbiologists for biological hazards. Environmental and occupational hygienists are considered experts in exposure science and exposure risk management. Depending on an individual's type of job, a hygienist will apply their exposure science expertise for the protection of workers, consumers and/or communities.

<span class="mw-page-title-main">Pentachlorophenol</span> Chemical compound

Pentachlorophenol (PCP) is an organochlorine compound used as a pesticide and a disinfectant. First produced in the 1930s, it is marketed under many trade names. It can be found as pure PCP, or as the sodium salt of PCP, the latter of which dissolves easily in water. It can be biodegraded by some bacteria, including Sphingobium chlorophenolicum.

<span class="mw-page-title-main">Sawdust</span> Byproduct or waste product of woodworking operations (sawing, sanding, milling, etc.)

Sawdust is a by-product or waste product of woodworking operations such as sawing, sanding, milling and routing. It is composed of very small chips of wood. These operations can be performed by woodworking machinery, portable power tools or by use of hand tools. In some manufacturing industries it can be a significant fire hazard and source of occupational dust exposure.

<span class="mw-page-title-main">Environmental hazard</span> Harmful substance, a condition or an event

Environmental hazards are those hazards that affect biomes or ecosystems. Well known examples include oil spills, water pollution, slash and burn deforestation, air pollution, ground fissures, and build-up of atmospheric carbon dioxide. Physical exposure to environmental hazards is usually involuntary

Occupational lung diseases comprise a broad group of diseases, including occupational asthma, industrial bronchitis, chronic obstructive pulmonary disease (COPD), bronchiolitis obliterans, inhalation injury, interstitial lung diseases, infections, lung cancer and mesothelioma. These can be caused directly or due to immunological response to an exposure to a variety of dusts, chemicals, proteins or organisms. Occupational cases of interstitial lung disease may be misdiagnosed as COPD, idiopathic pulmonary fibrosis, or a myriad of other diseases; leading to a delay in identification of the causative agent.

Environment, health and safety is an interdisciplinary field focused on the study and implementation of practical aspects environmental protection and safeguard of people's health and safety, especially at company level and in an occupational context. It is what organizations must do to make sure that their activities do not cause harm. Commonly, quality - quality assurance and quality control - is adjoined to form a company division referred to as HSQE or equivalent initialisms.

<span class="mw-page-title-main">Occupational hazard</span> Hazard experienced in the workplace

An occupational hazard is a hazard experienced in the workplace. This encompasses many types of hazards, including chemical hazards, biological hazards (biohazards), psychosocial hazards, and physical hazards. In the United States, the National Institute for Occupational Safety and Health (NIOSH) conduct workplace investigations and research addressing workplace health and safety hazards resulting in guidelines. The Occupational Safety and Health Administration (OSHA) establishes enforceable standards to prevent workplace injuries and illnesses. In the EU, a similar role is taken by EU-OSHA.

Workplace health surveillance or occupational health surveillance (U.S.) is the ongoing systematic collection, analysis, and dissemination of exposure and health data on groups of workers. The Joint ILO/WHO Committee on Occupational Health at its 12th Session in 1995 defined an occupational health surveillance system as "a system which includes a functional capacity for data collection, analysis and dissemination linked to occupational health programmes".

<span class="mw-page-title-main">Reproductive toxicity</span> A hazard associated with chemical substances

Reproductive toxicity refers to the potential risk from a given chemical, physical or biologic agent to adversely affect both male and female fertility as well as offspring development. Reproductive toxicants may adversely affect sexual function, ovarian failure, fertility as well as causing developmental toxicity in the offspring. Lowered effective fertility related to reproductive toxicity relates to both male and female effects alike and is reflected in decreased sperm counts, semen quality and ovarian failure. Infertility is medically defined as a failure of a couple to conceive over the course of one year of unprotected intercourse. As many as 20% of couples experience infertility. Among men, oligospermia is defined as a paucity of viable spermatozoa in the semen, whereas azoospermia refers to the complete absence of viable spermatozoa in the semen.

<span class="mw-page-title-main">Physical hazard</span> Hazard due to a physical agent

A physical hazard is an agent, factor or circumstance that can cause harm with contact. They can be classified as type of occupational hazard or environmental hazard. Physical hazards include ergonomic hazards, radiation, heat and cold stress, vibration hazards, and noise hazards. Engineering controls are often used to mitigate physical hazards.

Inhalation is a major route of exposure that occurs when an individual breathes in polluted air which enters the respiratory tract. Identification of the pollutant uptake by the respiratory system can determine how the resulting exposure contributes to the dose. In this way, the mechanism of pollutant uptake by the respiratory system can be used to predict potential health impacts within the human population.

Occupational cancer is cancer caused by occupational hazards. Several cancers have been directly tied to occupational hazards, including chimney sweeps' carcinoma, mesothelioma, and others.

Many laboratories contain significant risks, and the prevention of laboratory accidents requires great care and constant vigilance. Examples of risk factors include high voltages, high and low pressures and temperatures, corrosive and toxic chemicals and chemical vapours, radiation, fire, explosions, and biohazards including infective organisms and their toxins.

<span class="mw-page-title-main">Occupational hearing loss</span> Form of hearing loss

Occupational hearing loss (OHL) is hearing loss that occurs as a result of occupational hazards, such as excessive noise and ototoxic chemicals. Noise is a common workplace hazard, and recognized as the risk factor for noise-induced hearing loss and tinnitus but it is not the only risk factor that can result in a work-related hearing loss. Also, noise-induced hearing loss can result from exposures that are not restricted to the occupational setting.

Occupational toxicology is the application of toxicology to chemical hazards in the workplace. It focuses on substances and conditions that people may be exposed to in workplaces, including inhalation and dermal exposures, which are most prevalent when discussing occupational toxicology. These environmental and individual exposures can impact health, and there is a focus on identifying early adverse affects that are more subtle than those presented in clinical medicine.

Engineering controls are strategies designed to protect workers from hazardous conditions by placing a barrier between the worker and the hazard or by removing a hazardous substance through air ventilation. Engineering controls involve a physical change to the workplace itself, rather than relying on workers' behavior or requiring workers to wear protective clothing.

Chemical safety includes all those policies, procedures and practices designed to minimize the risk of exposure to potentially hazardous chemicals. This includes the risks of exposure to persons handling the chemicals, to the surrounding environment, and to the communities and ecosystems within that environment. Manufactured chemicals, either pure or in mixtures, solutions and emulsions, are ubiquitous in modern society, at industrial, occupational and private scale. However, there are chemicals that should not mix or get in contact with others, as they can produce byproducts that may be toxic, carcinogenic, explosive etc., or can be dangerous in themselves. To avoid disasters and mishaps, maintaining safety is paramount.

<span class="mw-page-title-main">Occupational dust exposure</span> Occupational hazard in agriculture, construction, forestry, and mining

Occupational dust exposure can occur in various settings, including agriculture, construction, forestry, and mining. Dust hazards include those that arise from handling grain and cotton, as well as from mining coal. Wood dust, commonly referred to as "sawdust", is another occupational dust hazard that can pose a risk to workers' health.

The health and safety hazards of nanomaterials include the potential toxicity of various types of nanomaterials, as well as fire and dust explosion hazards. Because nanotechnology is a recent development, the health and safety effects of exposures to nanomaterials, and what levels of exposure may be acceptable, are subjects of ongoing research. Of the possible hazards, inhalation exposure appears to present the most concern, with animal studies showing pulmonary effects such as inflammation, fibrosis, and carcinogenicity for some nanomaterials. Skin contact and ingestion exposure, and dust explosion hazards, are also a concern.

References

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  14. 1 2 3 4 "Hierarchy of Controls | Environmental Health & Safety (EHS)". ehs.utexas.edu. Retrieved 2024-04-07.
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