Fluidisation is a phenomenon whereby solid particulate is placed under certain conditions to cause it to behave like a fluid. A fluidized bed is a system conceived to facilitate the fluidisation. Fluidized beds have a wide range of applications including but not limited to: assisting with chemical reactions, heat transfer, mixing and drying. According to Collin et al. (2009), an annular fluidized bed consists of "a large central nozzle surrounded by a stationary fluidized bed". [1]
A general Annular Fluidized Bed (AFB) introduces gas at high speeds that enter the reactor from the bottom of the large central nozzle and additional fluidized gas is introduced through an annular nozzle ring. As a result, gas and solids are extensively mixed in the dense bottom part of the mixing chamber and flow upward in the riser. The gas and solids both leave the riser and are separated in a cyclone depending on the set velocities. The separated gas flows through a bag filter and the solids move downwards in the downer which is fed into the bottom of the plant which repeats the process again.
The bottom section of the riser is narrowed to avoid solids from accumulating in the bottom section. Instead of the riser walls being smooth it is generally composed of membrane waterwall surfaces, this added feature influences the solid flow patterns in the vicinity, hence influences mixing and gas-solid mixing. The riser exits are divided into two types; “once through exits” which involves the exits being smoothly curve or tapered. [3] This exit allows a large net circulation and is optimal for short uniform residence time as well as quickly decaying catalysts. The other exit is “internal reflux exits” which is an abrupt exit causing a substantial amount of entrained solids being internally separated from the gas reaching the top of the reactor. [3] The cyclone is an integral part of an annular fluidized bed, particular sized particles are separated by varying the velocity of feed gas. [1] Consequently, at high velocity gas provides enough kinetic energy to separate particles from the fluidized bed. The feed gas and small particles fly into a cyclone separator and there the feed- gas and particles are separated. In turn, particles can be returned or removed to the bed depending on the size of the particle. The entrained solids are captured and sent back to the base of the riser through a vertical standpipe. [4] The large central nozzle is the main component of the Annular Fluidized bed and this differentiate itself from other fluidized beds. The central nozzle is surrounded by a stationary fluidized bed and “due to moderate primary gas fluidisation of the annulus, the solids overflow at the upper edge of the central nozzle” [1] which is then transported and mixed in the mixing chamber by a high upward velocity central secondary gas stream.
The annular fluidized bed is a new type of fluidized bed that has a specific type of motion where it moves in radial. There is relatively little axial mixing of gases and there is radial motion. The axial flow profile of the annular fluidized bed can be determined by pressure drops along the plant height, which can be divided into three major parts: the annulus, the bottom and the top part of the mixing chamber. Based on the height of the bed, while the annulus has a porosity close to the solids minimal fluidization porosity, each region of bed is characterized by different pressure gradients. The closer to the central nozzle, the lower the pressure gradient and the higher the pressure drop in the mixing chamber. With known pressure gradient (ΔP/ΔH), the solid concentration can be calculated using Wirth equation shown below:
〖(1-ε)〗_∆P=∆P/∆H(ρ_s-ρ_f )g
According to an experiment characterization of the flow pattern in an annular fluidized bed carried out by Anne Collin, Karl-Ernst Wirth and Michael Stroder, [1] at a height of 150mm above the central nozzle, the pressure gradient is approximately zero for small velocities and increases with increasing velocity.
Two distinct types of flow are shown in two different regions: “the flow pattern directly above the central nozzle shows a typical jet profile characterized by low solids concentrations around 8% and high upwards solids velocities (3 m/s) thus resulting in high local solids mass fluxes.” The surrounding of annular region at the bottom of the mixing chamber is on the other hand, the flow pattern is characterized by high solids concentration “with increasing values towards the wall e.g. 46% for the 100 mm probe height above the central nozzle” The solids velocities and mass fluxes are positive around the wall region where a descending is expected. However, the measured velocities may not be an accurate portrayal of the actual solids velocities in the region where high transversal and radial mixing are present. This is due to only vertical velocities being recorded by the capacitance probes. Hence, the calculated solids mass fluxes always have to be considered in the same direction. To summarize, the fully developed flow pattern in the annular fluidized bed shows a core-annulus structure, which is “characterized by the typical formation of a central jet surrounded by a region of high solids concentration at the bottom of the mixing chamber.” Varying the fluidization velocity in the annulus promotes more solids to be removed from bubbles and enables the convective mass flux to penetrate into the jet increase. The amount of solids that can be integrated into the jet at the end is determined by the gas velocity. Moreover, the ratio of the internal to the external solids circulation in the plant can be regulated due to the interaction of both mechanisms. [1]
As gas velocity in the annulus depends on a calculated velocity of the solids ejected from bubbles, it is more difficult for the solids coming from the annulus with increasing velocity in the nozzle to penetrate into the central gas jet under a constant fluidization velocity. Increasing the central velocity at a height of 25 mm above the nozzle decreases the time-averaged solids concentration. However, an increase in this velocity has no effect on the solids concentration above the annulus. On the other hand, for a low central gas velocity, the solids velocities over the annulus and above the nozzle show nearly the same value with sharp velocity gradient.
The flow pattern of a circulating fluidized bed is fully developed at the probe height of 200mm above the central nozzle. At this height, the typical concentration increases towards the wall and after combining with the falling solids velocity, this results in a negative solid mass flux. The shape of the solids concentration profile is independent on the gas velocity, however the absolute concentration is lower over the cross-section with integral solid concentrations. As a result, the solids mass flux has a slight decrease with increasing gas velocity in the central nozzle with integral values over the plant cross-section.
Bubbling occurs in the annular fluidized bed caused by the introduction of gas by the central nozzle at a certain velocity moves in the general upwards direction. The sudden eruption of gas at the central nozzle causes particles to be transport in the bubbles wake [1] By increasing the velocity of the annulus results in an increase in the bubble size and the bubbling velocity. The new increase in bubble dynamics enables “the ejected solids to penetrate deeper into the central gas jet”. [1] As a result of this, the concentration and velocity of solids increases and consequently the solid optimum mass flux increases.
Due to the particular characteristics of AFB whereby gasses are introduced through the central nozzle at a high velocity, an intense mixing zone is achieved on the bed comparable to the conditions by an external loop of a Circulating fluidized bed. [2] The AFB combines the advantages of long solid residence time and good heat and mass transfer, [1] making it ideal for use heat exchanging processes such as cooling, heating or heat recovery and facilitating reactions. AFB can be combined with other fluidized bed types to assist with the process and further enhance its existing properties to increase productivity of a process.
The AFB characteristics are highly desirable in some applications however it can have an undesirable effect on other applications, which would require shorter residence times and a less intense mixing such as an ore roasters where particles would not be required to leave the fluidized bed. The cost of an AFB would also be higher compared to that of other fluidized beds as the introduction of the central nozzle complicates production of the components and introduces extra cost. An AFB would require more frequent maintenance and higher maintenance costs due to the extra and more complicated components. The central nozzle may easily clog due to unwanted particles entering the nozzle.
Though the AFB has potential to improve the efficiency of current processes, it is not without limitations. Due to the AFB being a recent advancement in fluidization technology, little systematic study has been done on this, and characterising global and local flow patterns may prove difficult for chemical engineers as the “bed hydrodynamics are not the same in small and large scale fluidized beds”. [1] The implementation of this new technology into existing plants may prove difficult and costly; therefore there have been only a few advancement of the AFB since its conception. Few plants exists where AFB technology has been implemented however there may still be a few years before its full industrial applications will be realized and widely used.
An annular fluidized bed (AFB) can have a wide range of applications due to its ability to be used in conjunction with other fluidized bed type. [2] The AFB is ideal for applications that require a fast and efficient heat and mass transfer with intense mixing. These applications can range from dryers, heat exchangers, heaters, coolers and reactors.
Though a relatively new technology, the use of AFB in the industry has slowly increased over the years. One such example is the company Outotec, who specialises in the field of fluidization technology. Outotec has integrated the use of AFB in its recent plants designs to further improve the process. Current existing plants by Outotec utilising AFB include: [2]
Note: Facts and figures obtained for Outetec The Circored, Circoheat and Circotherm processes devised by the company are some examples of applications for this fluidized bed technology.
As seen from the Outotec examples, an annular fluidized bed can have a wide range of applications as any other fluidization technology. However, as it is a recent development in this field its full potential has yet to be realized and implemented for industrial applications
One application of an AFB is the purification of air. It begins by focusing the sun's ultraviolet light on particles of silica gel, which are coated with a fine layer of titanium dioxide catalyst. The uvlight then able to charge these particles. These positive and negative charged particles are then available to initiate various chemical reactions. [6] When polluted air is passed through the central nozzle and into the fluidised bed, contaminants that contact the photo-catalytic particles are adsorbed onto the particle surface. The contaminants react with the positive and negative charges and are chemically broken down. The result is purified air.
Off-gas is the gaseous product exiting a cyclone separator that is connected to a fluidized bed. If the gas is clean and contaminate free it can be cooled via a condenser and then filtered to remove fine particles. Once filtered it may be directed back into the system or tapered off. In various cases volatile and/or poisonous gases may be used as feed gas for fluidised beds. The off gas produced from the operation may have a considerable amount of such gases and therefore need to be neutralised. Allowing the gases to escape into the environment may cause green house gases and are toxic to local flora and fauna. Cleaning off-gas increases sustainability and negates adverse effects to the environment.
During the operation of a fluidised bed particles are transported by the kinetic energy provided by a feed gas. At certain velocities fine particles may fly into a cyclone and separated from the flue gas. These fine particles can either be returned to the system or removed. Once removed these particles depending on their nature may have adverse effects on the environment and must be treated carefully.
For example, in mining process currently in Mozambique, annular fluidised beds are used to preheat and reduce ilmenite ore, ilmenite is hazardous compound as crystalline silica is known to cause lung fibrosis and is a known carcinogen. [7] Companies operating such equipment and detrimental substances must dispose of their waste properly.
Spray drying is a method of forming a dry powder from a liquid or slurry by rapidly drying with a hot gas. This is the preferred method of drying of many thermally-sensitive materials such as foods and pharmaceuticals, or materials which may require extremely consistent, fine particle size. Air is most commonly used as the heated drying medium; however, nitrogen may be used if the liquid is flammable or if the product is oxygen-sensitive.
In viscous fluid dynamics, the Archimedes number (Ar), is a dimensionless number used to determine the motion of fluids due to density differences, named after the ancient Greek scientist and mathematician Archimedes.
Fluidized bed combustion (FBC) is a combustion technology used to burn solid fuels.
Fluidization is a process similar to liquefaction whereby a granular material is converted from a static solid-like state to a dynamic fluid-like state. This process occurs when a fluid is passed up through the granular material.
A chemical reactor is an enclosed volume in which a chemical reaction takes place. In chemical engineering, it is generally understood to be a process vessel used to carry out a chemical reaction, which is one of the classic unit operations in chemical process analysis. The design of a chemical reactor deals with multiple aspects of chemical engineering. Chemical engineers design reactors to maximize net present value for the given reaction. Designers ensure that the reaction proceeds with the highest efficiency towards the desired output product, producing the highest yield of product while requiring the least amount of money to purchase and operate. Normal operating expenses include energy input, energy removal, raw material costs, labor, etc. Energy changes can come in the form of heating or cooling, pumping to increase pressure, frictional pressure loss or agitation.
A coolant is a substance, typically liquid, that is used to reduce or regulate the temperature of a system. An ideal coolant has high thermal capacity, low viscosity, is low-cost, non-toxic, chemically inert and neither causes nor promotes corrosion of the cooling system. Some applications also require the coolant to be an electrical insulator.
A fluidized bed is a physical phenomenon that occurs when a solid particulate substance is under the right conditions so that it behaves like a fluid. The usual way to achieve a fluidized bed is to pump pressurized fluid into the particles. The resulting medium then has many properties and characteristics of normal fluids, such as the ability to free-flow under gravity, or to be pumped using fluid technologies.
A batch reactor is a chemical reactor in which a non-continuous reaction is conducted, i.e., one where the reactants, products and solvent do not flow in or out of the vessel during the reaction until the target reaction conversion is achieved. By extension, the expression is somehow inappropriately used for other batch fluid processing operations that do not involve a chemical reaction, such as solids dissolution, product mixing, batch distillation, crystallization, and liquid/liquid extraction. In such cases, however, they may not be referred to as reactors but rather with a term specific to the function they perform.
In fluid mechanics, multiphase flow is the simultaneous flow of materials with two or more thermodynamic phases. Virtually all processing technologies from cavitating pumps and turbines to paper-making and the construction of plastics involve some form of multiphase flow. It is also prevalent in many natural phenomena.
A fluidized bed reactor (FBR) is a type of reactor device that can be used to carry out a variety of multiphase chemical reactions. In this type of reactor, a fluid is passed through a solid granular material at high enough speeds to suspend the solid and cause it to behave as though it were a fluid. This process, known as fluidization, imparts many important advantages to an FBR. As a result, FBRs are used for many industrial applications.
Membrane bioreactors are combinations of membrane processes like microfiltration or ultrafiltration with a biological wastewater treatment process, the activated sludge process. These technologies are now widely used for municipal and industrial wastewater treatment. The two basic membrane bioreactor configurations are the submerged membrane bioreactor and the side stream membrane bioreactor. In the submerged configuration, the membrane is located inside the biological reactor and submerged in the wastewater, while in a side stream membrane bioreactor, the membrane is located outside the reactor as an additional step after biological treatment.
A bubble column reactor is a chemical reactor that belongs to the general class of multiphase reactors, which consists of three main categories: trickle bed reactor, fluidized bed reactor, and bubble column reactor. A bubble column reactor is a very simple device consisting of a vertical vessel filled with water with a gas distributor at the inlet. Due to the ease of design and operation, which does not involve moving parts, they are widely used in the chemical, biochemical, petrochemical, and pharmaceutical industries to generate and control gas-liquid chemical reactions.
Gas core reactor rockets are a conceptual type of rocket that is propelled by the exhausted coolant of a gaseous fission reactor. The nuclear fission reactor core may be either a gas or plasma. They may be capable of creating specific impulses of 3,000–5,000 s and thrust which is enough for relatively fast interplanetary travel. Heat transfer to the working fluid (propellant) is by thermal radiation, mostly in the ultraviolet, given off by the fission gas at a working temperature of around 25,000 °C.
A spray is a dynamic collection of drops dispersed in a gas. The process of forming a spray is known as atomization. A spray nozzle is the device used to generate a spray. The two main uses of sprays are to distribute material over a cross-section and to generate liquid surface area. There are thousands of applications in which sprays allow material to be used most efficiently. The spray characteristics required must be understood in order to select the most appropriate technology, optimal device and size.
The extended discrete element method (XDEM) is a numerical technique that extends the dynamics of granular material or particles as described through the classical discrete element method (DEM) by additional properties such as the thermodynamic state, stress/strain or electro-magnetic field for each particle. Contrary to a continuum mechanics concept, the XDEM aims at resolving the particulate phase with its various processes attached to the particles. While the discrete element method predicts position and orientation in space and time for each particle, the extended discrete element method additionally estimates properties such as internal temperature and/or species distribution or mechanical impact with structures.
The circulating fluidized bed (CFB) is a type of fluidized bed combustion that utilizes a recirculating loop for even greater efficiency of combustion. while achieving lower emission of pollutants. Reports suggest that up to 95% of pollutants can be absorbed before being emitted into the atmosphere. The technology is limited in scale however, due to its extensive use of limestone, and the fact that it produces waste byproducts.
As an extension of the fluidized bed family of separation processes, the flash reactor (FR) employs turbulent fluid introduced at high velocities to encourage chemical reactions with feeds and subsequently achieve separation through the chemical conversion of desired substances to different phases and streams. A flash reactor consists of a main reaction chamber and an outlet for separated products to enter downstream processes.
Vibratory Fluidized Bed (VFB) is a type of fluidized bed where the mechanical vibration enhances the performance of fluidization process. Since the first discovery of vibratory fluidized bed, its vibration properties proves to be more efficient in dealing with fine particles which appears to be very difficult to achieve with normal fluidized bed. Even though numerous publications and its popularity in industrial applications, the knowledge about vibratory dynamics and properties are very limited. Future research and development are needed to further improve this technology to bring it to another level.
Three-dimensional electrical capacitance tomography also known as electrical capacitance volume tomography (ECVT) is a non-invasive 3D imaging technology applied primarily to multiphase flows. It was introduced in the early 2000s as an extension of the conventional two-dimensional ECT. In conventional electrical capacitance tomography, sensor plates are distributed around a surface of interest. Measured capacitance between plate combinations is used to reconstruct 2D images (tomograms) of material distribution. Because the ECT sensor plates are required to have lengths on the order of the domain cross-section, 2D ECT does not provide the required resolution in the axial dimension. In ECT, the fringing field from the edges of the plates is viewed as a source of distortion to the final reconstructed image and is thus mitigated by guard electrodes. 3D ECT exploits this fringing field and expands it through 3D sensor designs that deliberately establish an electric field variation in all three dimensions. In 3D tomography, the data are acquired in 3D geometry, and the reconstruction algorithm produces the three-dimensional image directly, in contrast to 2D tomography, where 3D information might be obtained by stacking 2D slices reconstructed individually.
Peter Noël Rowe FREng FIChemE, ) was a Ramsay professor of chemical engineering at University College London and former president of the Institution of Chemical Engineers.
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