Drying

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Laundry hung on a clothes line in a drying room (dehumidifier in the background and duct for ventilation in the ceiling) Raumluft waeschetrockner.jpg
Laundry hung on a clothes line in a drying room (dehumidifier in the background and duct for ventilation in the ceiling)

Drying is a mass transfer process consisting of the removal of water or another solvent [1] by evaporation from a solid, semi-solid or liquid. This process is often used as a final production step before selling or packaging products. To be considered "dried", the final product must be solid, in the form of a continuous sheet (e.g., paper), long pieces (e.g., wood), particles (e.g., cereal grains or corn flakes) or powder (e.g., sand, salt, washing powder, milk powder). A source of heat and an agent to remove the vapor produced by the process are often involved. In bioproducts like food, grains, and pharmaceuticals like vaccines, the solvent to be removed is almost invariably water. Desiccation may be synonymous with drying or considered an extreme form of drying.

Contents

In the most common case, a gas stream, e.g., air, applies the heat by convection and carries away the vapor as humidity. Other possibilities are vacuum drying, where heat is supplied by conduction or radiation (or microwaves), while the vapor thus produced is removed by the vacuum system. Another indirect technique is drum drying (used, for instance, for manufacturing potato flakes), where a heated surface is used to provide the energy, and aspirators draw the vapor outside the room. In contrast, the mechanical extraction of the solvent, e.g., water, by filtration or centrifugation, is not considered "drying" but rather "draining".

Drying mechanism

In some products having a relatively high initial moisture content, an initial linear reduction of the average product moisture content as a function of time may be observed for a limited time, often known as a "constant drying rate period". Usually, in this period, it is surface moisture outside individual particles that is being removed. The drying rate during this period is mostly dependent on the rate of heat transfer to the material being dried. Therefore, the maximum achievable drying rate is considered to be heat-transfer limited. If drying is continued, the slope of the curve, the drying rate, becomes less steep (falling rate period) and eventually tends to become nearly horizontal at very long times. The product moisture content is then constant at the "equilibrium moisture content", where it is, in practice, in equilibrium with the dehydrating medium. In the falling-rate period, water migration from the product interior to the surface is mostly by molecular diffusion, i.e. the water flux is proportional to the moisture content gradient. This means that water moves from zones with higher moisture content to zones with lower values, a phenomenon explained by the second law of thermodynamics. If water removal is considerable, the products usually undergo shrinkage and deformation, except in a well-designed freeze-drying process. The drying rate in the falling-rate period is controlled by the rate of removal of moisture or solvent from the interior of the solid being dried and is referred to as being "mass-transfer limited". This is widely noticed in hygroscopic products such as fruits and vegetables, where drying occurs in the falling rate period with the constant drying rate period said to be negligible. [2]

Methods of drying

In a typical phase diagram, the boundary between gas and liquid runs from the triple point to the critical point. Regular drying is the green arrow, while supercritical drying is the red arrow and freeze drying is the blue. Drying.svg
In a typical phase diagram, the boundary between gas and liquid runs from the triple point to the critical point. Regular drying is the green arrow, while supercritical drying is the red arrow and freeze drying is the blue.

The following are some general methods of drying:

Applications of drying

Film formation

In the coatings and adhesives industry, drying is used to cure solvent-based films. In some cases, highly structured films can result. For example, evaporation of solvent from a solution containing helical polymer results in a highly ordered array of squashed toroidal structures. [4]

Food

Drying of fish in Lofoten in the production of stockfish Stockfish in Lofoten.jpg
Drying of fish in Lofoten in the production of stockfish

Foods are dried to inhibit microbial development and quality decay. However, the extent of drying depends on product end-use. Cereals and oilseeds are dried after harvest to the moisture content that allows microbial stability during storage. Vegetables are blanched before drying to avoid rapid darkening, and drying is not only carried out to inhibit microbial growth, but also to avoid browning during storage. Concerning dried fruits, the reduction of moisture acts in combination with its acid and sugar contents to provide protection against microbial growth. Products such as milk powder must be dried to very low moisture contents in order to ensure flowability and avoid caking. This moisture is lower than that required to ensure inhibition to microbial development. Other products as crackers are dried beyond the microbial growth threshold to confer a crispy texture, which is liked by consumers.

Non-food products

Among non-food products, some of those that require considerable drying are wood (as part of timber processing), paper, flax, and washing powder. The first two, owing to their organic origins, may develop mold if insufficiently dried. Another benefit of drying is a reduction in volume and weight.

Sludges and fecal materials from sanitation processes

In the area of sanitation, drying of sewage sludge from sewage treatment plants, fecal sludge or feces collected in urine-diverting dry toilets (UDDT) is a common method to achieve pathogen kill, as pathogens can only tolerate a certain dryness level. In addition, drying is required as a process step if the excreta based materials are meant to be incinerated. [5]

See also

Bibliography

  1. Greensmith, M. (1998). Practical Dehydration. Woodhead Publishing, Ltd.
  2. Genskow, L.R.; Beimesch, W.E.; Hecht, J.P.; Kemp, I.C.; Langrish, T.; Schwartzbach, C.; Smith, (F).L. (2007). Chemical Engineers' Handbook. Mc Graw Hill Professional. pp. Chapter 12 (Evaporative Cooling and Solids Drying).
  3. A.S., Mujumdar (1998). Handbook of Industrial Drying. Boca Ratón: CRC Press.

Related Research Articles

<span class="mw-page-title-main">Spray drying</span> Method of converting liquid or slurry to powder

Spray drying is a method of forming a dry powder from a liquid or slurry by rapidly drying with a hot gas. This is the preferred method of drying of many thermally-sensitive materials such as foods and pharmaceuticals, or materials which may require extremely consistent, fine particle size. Air is the heated drying medium; however, if the liquid is a flammable solvent such as ethanol or the product is oxygen-sensitive then nitrogen is used.

<span class="mw-page-title-main">Instant coffee</span> Drink made by rehydrating powdered coffee

Instant coffee is a beverage derived from brewed coffee beans that enables people to quickly prepare hot coffee by adding hot water or milk to coffee solids in powdered or crystallized form and stirring. The product was first invented in Invercargill, the largest city in Southland, New Zealand, in 1890. Instant coffee solids refers to the dehydrated and packaged solids available at retail used to make instant coffee. Instant coffee solids are commercially prepared by either freeze-drying or spray drying, after which it can be rehydrated. Instant coffee in a concentrated liquid form, as a beverage, is also manufactured.

<span class="mw-page-title-main">Dehumidifier</span> Device which reduces humidity

A dehumidifier is an air conditioning device which reduces and maintains the level of humidity in the air. This is done usually for health or thermal comfort reasons, or to eliminate musty odor and to prevent the growth of mildew by extracting water from the air. It can be used for household, commercial, or industrial applications. Large dehumidifiers are used in commercial buildings such as indoor ice rinks and swimming pools, as well as manufacturing plants or storage warehouses. Typical air conditioning systems combine dehumidification with cooling, by operating cooling coils below the dewpoint and draining away the water that condenses.

<span class="mw-page-title-main">Blanching (cooking)</span> Brief scalding of food in boiling water

Blanching is a cooking process in which a food, usually a vegetable or fruit, is scalded in boiling water, removed after a brief timed interval, and finally plunged into iced water or placed under cold running water to halt the cooking process. Blanching foods helps reduce quality loss over time. Blanching is often used as a treatment prior to freezing, dehydrating, or canning vegetables or fruits to deactivate enzymes, modify texture, remove the peel and wilt tissue. The inactivation of enzymes preserves color, flavor, and nutritional value. The process has three stages: preheating, blanching, and cooling. The most common blanching methods for vegetables/fruits are hot water and steam, while cooling is either done using cold water or cool air. Other benefits of blanching include removing pesticide residues and decreasing microbial load. Drawbacks to the blanching process can include leaching of water-soluble and heat-sensitive nutrients and the production of effluent.

<span class="mw-page-title-main">Dried fruit</span> Fruit from which the majority of the original water content has been removed

Dried fruit is fruit from which the majority of the original water content has been removed either naturally, through sun drying, or through the use of specialized dryers or dehydrators. Dried fruit has a long tradition of use dating back to the fourth millennium BC in Mesopotamia, and is prized because of its sweet taste, nutritive value, and long shelf life.

<span class="mw-page-title-main">Rotary evaporator</span> Device used in chemical laboratories

A rotary evaporator (rotavap) is a device used in chemical laboratories for the efficient and gentle removal of solvents from samples by evaporation. When referenced in the chemistry research literature, description of the use of this technique and equipment may include the phrase "rotary evaporator", though use is often rather signaled by other language.

<span class="mw-page-title-main">Freeze drying</span> Low temperature dehydration process

Freeze drying, also known as lyophilization or cryodesiccation, is a low temperature dehydration process that involves freezing the product and lowering pressure, thereby removing the ice by sublimation. This is in contrast to dehydration by most conventional methods that evaporate water using heat.

<span class="mw-page-title-main">Dielectric heating</span> Heating using radio waves

Dielectric heating, also known as electronic heating, radio frequency heating, and high-frequency heating, is the process in which a radio frequency (RF) alternating electric field, or radio wave or microwave electromagnetic radiation heats a dielectric material. At higher frequencies, this heating is caused by molecular dipole rotation within the dielectric.

<span class="mw-page-title-main">Onion powder</span> Dried ground onion commonly used as a seasoning

Onion powder is dehydrated, ground onion that is commonly used as a seasoning. It is a common ingredient in seasoned salt and spice mixes, such as beau monde seasoning. Some varieties are prepared using toasted onion. White, yellow and red onions may be used. Onion powder is a commercially prepared food product that has several culinary uses. Onion powder can also be homemade.

<span class="mw-page-title-main">Vacuum evaporation</span>

Vacuum evaporation is the process of causing the pressure in a liquid-filled container to be reduced below the vapor pressure of the liquid, causing the liquid to evaporate at a lower temperature than normal. Although the process can be applied to any type of liquid at any vapor pressure, it is generally used to describe the boiling of water by lowering the container's internal pressure below standard atmospheric pressure and causing the water to boil at room temperature.

Level sensors detect the level of liquids and other fluids and fluidized solids, including slurries, granular materials, and powders that exhibit an upper free surface. Substances that flow become essentially horizontal in their containers because of gravity whereas most bulk solids pile at an angle of repose to a peak. The substance to be measured can be inside a container or can be in its natural form. The level measurement can be either continuous or point values. Continuous level sensors measure level within a specified range and determine the exact amount of substance in a certain place, while point-level sensors only indicate whether the substance is above or below the sensing point. Generally the latter detect levels that are excessively high or low.

<span class="mw-page-title-main">Wood drying</span> Also known as seasoning, which is the reduction of the moisture content of wood prior to its use

Wood drying reduces the moisture content of wood before its use. When the drying is done in a kiln, the product is known as kiln-dried timber or lumber, whereas air drying is the more traditional method.

<span class="mw-page-title-main">Evaporator</span> Machine transforming a liquid into a gas

An evaporator is a type of heat exchanger device that facilitates evaporation by utilizing conductive and convective heat transfer to provide the necessary thermal energy for phase transition from liquid to vapor. Within evaporators, a circulating liquid is exposed to an atmospheric or reduced pressure environment, causing it to boil at a lower temperature compared to normal atmospheric boiling.

Dynamic vapor sorption (DVS) is a gravimetric technique that measures how quickly and how much of a solvent is absorbed by a sample such as a dry powder absorbing water. It does this by varying the vapor concentration surrounding the sample and measuring the change in mass which this produces. The technique is mostly used for water vapor, but is suitable for a wide range of organic solvents. Daryl Williams, founder of Surface Measurement Systems Ltd, developed Dynamic Vapor Sorption in 1991; the first instrument was delivered to Pfizer UK in 1992. DVS was originally developed to replace the time and labor-intensive desiccators and saturated salt solutions used to measure water vapor sorption isotherms.

<span class="mw-page-title-main">Flower preservation</span> Preservation techniques

Flower preservation has existed since early history, although deliberate flower preservation is a more recent phenomenon. In the Middle East, the bones of pre-historic man were discovered with delicate wild flowers probably as a tribute to a passing loved one. Evidence of deliberate use of specific flowers is indicated by the pollen grains that were present. Brightly colored and vivid flowers were also found in Egyptian tombs. These flowers were approximated to be 4,000 years old. In the sixteenth century medicinal nosegays began to give way to ornamental ones. Flowers essentially started to be used for decorative purposes such as jewels, fans and gloves. During the Elizabethan Age the once familiar ruff was replaced by soft lacy collars, and bosom flowers also became popular.

Vacuum drying is the mass transfer operation in which the moisture present in a substance, usually a wet solid, is removed by means of creating a vacuum.

<span class="mw-page-title-main">Pasta processing</span> Process of making pasta

Pasta processing is the process in which wheat semolina or flour is mixed with water and the dough is extruded to a specific shape, dried and packaged.

<span class="mw-page-title-main">Instant tea</span> Concentrated dry tea beverage mix

Instant tea is a powdered mix in which water is added, in order to reconstitute it into a cup of tea. The earliest form of instant tea was developed in the United Kingdom in 1885. A patent was granted for a paste made of concentrated tea extract, sugar, and evaporated milk, which became tea when hot water was added. However, no notable developments were made until spray drying technology allowed for drying the tea concentrates at a temperature which did not damage the flavors of the product.

Food powder or powdery food is the most common format of dried solid food material that meets specific quality standards, such as moisture content, particle size, and particular morphology. Common powdery food products include milk powder, tea powder, cocoa powder, coffee powder, soybean flour, wheat flour, and chili powder. Powders are particulate discrete solid particles of size ranging from nanometres to millimetres that generally flow freely when shaken or tilted. The bulk powder properties are the combined effect of particle properties by the conversion of food products in solid state into powdery form for ease of use, processing and keeping quality. Various terms are used to indicate the particulate solids in bulk, such as powder, granules, flour and dust, though all these materials can be treated under powder category. These common terminologies are based on the size or the source of the materials.

<span class="mw-page-title-main">Dried mango</span> Preserved fruit food product

The mango fruit is commonly dried and eaten as a snack.

References

  1. "drying - definition of drying by the Free Online Dictionary, Thesaurus and Encyclopedia". Farlex. Retrieved 23 April 2011.
  2. Onwude, Daniel I.; Hashim, Norhashila; Janius, Rimfiel B.; Nawi, Nazmi Mat; Abdan, Khalina (2016-02-04). "Modeling the thin-layer drying of fruits and vegetables: A review" (PDF). Comprehensive Reviews in Food Science and Food Safety. 15 (3): 599–618. doi: 10.1111/1541-4337.12196 . PMID   33401820.
  3. Kord, Tyler (June 29, 2019). "Cooking (and Shrinking) the Modern Combat Ration". www.yahoo.com.
  4. Carroll, Gregory T.; Jongejan, Mahthild G. M.; Pijper, Dirk; Feringa, Ben L. (2010). "Spontaneous generation and patterning of chiral polymeric surface toroids". Chemical Science. 1 (4): 469. doi:10.1039/c0sc00159g. ISSN   2041-6520.
  5. Strande, L., Ronteltap, M., Brdjanovic, D. (eds.) (2014). Faecal Sludge Management (FSM) book - Systems Approach for Implementation and Operation Archived 2017-10-14 at the Wayback Machine . IWA Publishing, UK ( ISBN   9781780404738)