Protein skimmer

Last updated

Protein skimmer Skimmer.jpg
Protein skimmer

A protein skimmer or foam fractionator is a device used to remove organic compounds such as food and waste particles from water. It is most commonly used in commercial applications like municipal water treatment facilities, public aquariums, and aquaculture facilities. Smaller protein skimmers are also used for filtration of home saltwater aquariums and even freshwater aquariums and ponds.

Contents

Function

Protein skimming removes certain organic compounds, including proteins and amino acids found in food particles and fish waste, by using the polarity of the protein itself. Due to their intrinsic charge, water-borne proteins are either repelled or attracted by the air/water interface and these molecules can be described as hydrophobic (such as fats or oils) or hydrophilic (such as salt, sugar, ammonia, most amino acids, and most inorganic compounds). However, some larger organic molecules can have both hydrophobic and hydrophilic portions. These molecules are called amphipathic or amphiphilic. Commercial protein skimmers work by generating a large air/water interface, specifically by injecting large numbers of bubbles into the water column. In general, the smaller the bubbles the more effective the protein skimming is because the surface area of small bubbles occupying the same volume is much greater than the same volume of larger bubbles. [1] Large numbers of small bubbles present an enormous air/water interface for hydrophobic organic molecules and amphipathic organic molecules to collect on the bubble surface (the air/water interface). Water movement hastens diffusion of organic molecules, which effectively brings more organic molecules to the air/water interface and lets the organic molecules accumulate on the surface of the air bubbles. This process continues until the interface is saturated, unless the bubble is removed from the water or it bursts, in which case the accumulated molecules release back into the water column. However, it is important to note that further exposure of a saturated air bubble to organic molecules may continue to result in changes as compounds that bind more strongly may replace those molecules with a weaker binding that have already accumulated on the interface. Although some aquarists believe that increasing the contact time (or dwell time as it is sometimes called) is always good, it is incorrect to claim that it is always better to increase the contact time between bubbles and the aquarium water. [2] As the bubbles increase near the top of the protein skimmer water column, they become denser and the water begins to drain and create the foam that will carry the organic molecules to the skimmate collection cup or to a separate skimmate waste collector and the organic molecules, and any inorganic molecules that may have become bound to the organic molecules, will be exported from the water system.

In addition to the proteins removed by skimming, there are a number of other organic and inorganic molecules that are typically removed. These include a variety of fats, fatty acids, carbohydrates, metals such as copper, and trace elements such as iodine. Particulates, phytoplankton, bacteria, and detritus are also removed; this is desired by some aquarists, and is often enhanced by placement of the skimmer before other forms of filtration, lessening the burden on the filtration system as a whole. There is at least one published study that provides a detailed list of the export products removed by the skimmer. [3] Aquarists who keep filter-feeding invertebrates, however, sometimes prefer to keep these particulates in the water to serve as natural food. [4] [5]

Protein skimmers are used to harvest algae and phytoplankton gently enough to maintain viability for culturing or commercial sale as live cultures.

Alternative forms of water filtration have recently come into use, including the algae scrubber, which leaves food particles in the water for corals and small fish to consume, but removes the noxious compounds including ammonia, nitrite, nitrate, and phosphate that protein skimmers do not remove.

Design

All skimmers have key features in common: water flows through a chamber and is brought into contact with a column of fine bubbles. The bubbles collect proteins and other substances and carry them to the top of the device where the foam, but not the water, collects in a cup. Here the foam condenses to a liquid, which can be easily removed from the system. The material that collects in the cup can range from pale greenish-yellow, watery liquid to a thick black tar.

Skimmate collection in MRC skimmer MRC Collection Cup.jpg
Skimmate collection in MRC skimmer
Alpha 170, designed by Klaus Jensen ConeSkimmer.JPEG
Alpha 170, designed by Klaus Jensen

Consider this summary of optimal protein skimmer design by Randy Holmes-Farley: [6]

For a skimmer to function maximally, the following things must take place:
1. A large amount of air/water interface must be generated.
2. Organic molecules must be allowed to collect at the air/water interface.
3. The bubbles forming this air/water interface must come together to form a foam.
4. The water in the foam must partially drain without the bubbles popping prematurely.
5. The drained foam must be separated from the bulk water and discarded.

Also under considerable recent attention has been the general shape of a skimmer as well. In particular, much attention has been given to the introduction of cone shaped skimmer units. Originally designed by Klaus Jensen in 2004, the concept was founded on the principle that a conical body allows the foam to accumulate more steadily through a gently sloping transition. It was claimed that this reduces the overall turbulence, resulting in more efficient skimming. However, this design reduces the overall volume inside the skimmer, reducing dwell time. Cylindrical-shaped protein skimmers are the most popular design and allow for the largest volume of air and water. [7]

Overall, protein skimmers can be classed in two ways depending on whether they operate by co-current flow or counter-current flow . In a co-current flow system, air is introduced at the bottom of the chamber and is in contact with the water as it rises upwards towards the collection chamber. In a counter-current system, air is forced into the system under pressure and moves against the flow of the water for a while before it rises up towards the collection cup. Because the air bubbles may be in contact with the water for a longer period in a counter-current flow system, protein skimmers of this type are considered by some to be more effective at removing organic wastes. [8]

Co-current flow systems

Air stone

The original method of protein skimming, running pressurized air through a diffuser to produce large quantities of micro bubbles, remains a viable, effective, and economic choice, although newer technologies may require lower maintenance. The air stone is most often an oblong, partially hollowed block of wood, most often of the genus Tilia. The most popular wooden air-stones for skimmers are made from limewood (Tilia europaea or European limewood) although basswood (Tilia americana or American Linden), works as well, may be cheaper and is often more readily available. The wooden blocks are drilled, tapped, fitted with an air fitting, and connected by air tubing to one or more air pumps delivering at least 1 cfm. The wooden air stone is placed at the bottom of a tall column of water. The tank water is pumped into the column, allowed to pass by the rising bubbles, and back into the tank. To get enough contact time with the bubble, these units can be many feet in height.

Air stone protein skimmers may be constructed as a DIY project from pvc pipes and fittings at low cost and with varying degrees of complexity .

Air stone protein skimmers require powerful air pumps which are often power hungry, loud, and hot, leading to an increase in the aquarium water temperatures. While this method has been around for many years, due to more efficient technologies emerging, many regard it as inefficient current uses in larger systems or systems with large bio-loads.

Venturi

The premise behind these skimmers is that a high pressure pump combined with a venturi, can be used to introduce the bubbles into the water stream. The tank water is pumped through the venturi, in which fine bubbles are introduced via pressure differential, then enters the skimmer body. This method was popular due to its compact size and high efficiency for the time but venturi designs are now outdated and surpassed by more efficient needle-wheel designs.

Counter-current flow systems

Aspirating: pin-wheel/adrian-wheel, needle-wheel, mesh-wheel

This basic concept is more correctly known as an aspirating skimmer, since some skimmer designs using an aspirator do not use a "Pin-Wheel"/"Adrian-Wheel" or "Needle-Wheel". "Pin-Wheel"/"Adrian-Wheel" describes the look of an impeller that consists of a disk with pins mounted perpendicular (90°) to the disc and parallel to the rotor. "Needle-Wheel" describes the look of an impeller that consists of a series of pins projecting out perpendicular to the rotor from a central axis. "Mesh-Wheel" describes the look of an impeller that consists of a mesh material attached to a plate or central axis on the rotor. The purpose of these modified impellers is to chop or shred the air that is introduced via an air aspirator apparatus or external air pump into very fine bubbles. The Mesh-Wheel design provides excellent results in the short term because of its ability to create fine bubbles with its thin cutting surfaces, but its propensity for clogging makes it an unreliable design.

The air aspirator differs from the venturi by the positioning of the water pump. With a venturi, the water is pushed through the unit, creating a vacuum to draw in air. With an air aspirator, the water is pulled through the unit, creating a vacuum to draw in air. These terms, however, are often incorrectly interchanged.

This style of protein skimmer has become very popular with public aquariums and is believed to be the most popular type of skimmer used with residential reef aquariums today. It has been particularly successful in smaller aquariums due to its usually compact size, ease of set up and use, and quiet operation. Since the pump is pushing a mixture of air and water, the power required to turn the rotor can be decreased and may result in a lower power requirement for that pump vs. the same pump with a different impeller when it is only pumping water.

Downdraft

The Downdraft skimmer is both a proprietary skimmer design and a style of protein skimmer that injects water under high pressure into tubes that have a foam or bubble generating mechanism and carry the air/water mixture down into the skimmer and into a separate chamber. The proprietary design is protected in the United States with patents and commercial skimmer products in the US are limited to that single company. Their design uses one or more tubes with plastic media such as bio balls inside to mix water under high pressure and air in the body of the skimmer resulting in foam that collects protein waste in a collection cup. This was one of the earlier high performance protein skimmer designs and large models were produced that saw success in large and public aquariums.

Beckett skimmer

The Beckett skimmer has some similarities to the downdraft skimmer but introduced a foam nozzle to produce the flow of air bubbles. The name Beckett comes from the patented foam nozzle developed and sold by the Beckett Corporation (United States), although similar foam nozzle designs are sold by other companies outside the United States (e.g. Sicce (Italy)). Instead of using the plastic media that is found in downdraft skimmer designs, the Beckett skimmer uses design concepts from previous generations of skimmers, specifically the downdraft skimmer and the venturi skimmer (the Beckett 1408 Foam Nozzle is a modified 4 port venturi) to produce a hybrid that is capable of using powerful pressure rated water pumps and quickly processing large amounts of aquarium water in a short period of time. Commercial Beckett skimmers come in single Beckett, dual Beckett, and quad Beckett designs. Well engineered Beckett skimmers are quiet and reliable. Due to the advances in pump technologies and introduction of DC pumps, the concerns of powerful pumps taking up additional space, introducing additional noise, and using more electricity have all been alleviated. Unlike the Downdraft and Spray Induction skimmers, Beckett skimmer designs are produced by a number of companies in the United States and elsewhere and are not known to be restricted by patents.

Spray induction

This method is related to the downdraft, but uses a pump to power a spray nozzle, fixed a few inches above the water level. The spray action entraps and shreds the air in the base of the unit, similar to holding your thumb over a garden hose, which then rises to the collection chamber. In the United States, one company has patented the spray induction technology and the commercial product offerings are limited to that single company.

Recirculating skimmer designs

A recent trend is to change the method by which the skimmer is fed 'dirty' water from the aquarium as a means to recirculate water within the skimmer multiple times before it is returned to the sump or the aquarium. Aspirating pump skimmers are the most popular type of skimmer to use recirculating designs although other types of skimmers, such as Beckett skimmers, are also available in recirculating versions. While there is a popular belief among some aquarist that this recirculation increases the dwell or contact time of the generated air bubbles within the skimmer there is no authoritative evidence that this is true. Each time water is recirculated within the skimmer any air bubbles in that water sample are destroyed and new bubbles are generated by the recirculating pump venturi apparatus so the air-water contact time begins again for these newly created bubbles. In non-recirculating skimmer designs, a skimmer has one inlet supplied by a pump that pulls water in from the aquarium and injects it with air into the skimmer and releasing the foam or air/water mix into the reaction chamber. With a recirculating design, the one inlet is usually driven by a separate feed pump, or in some cases may be gravity fed, to receive the dirty water to process, while the pump providing the foam or air/water mix into the reaction chamber is set up separately in a closed loop on the side of the skimmer. The recirculating pump pulls water out of the skimmer and injects air to generate the foam or air/water mix before returning it to the skimmer reaction chamber—thus 'recirculating' it. The feed pump in a recirculating design typically injects a smaller amount of dirty water than co/counter-current designs. The separate feed pump allows easy control of the rate of water exchange through the skimmer and for many aquarists this is one of the important attractions of recirculating skimmer designs. Because the pump configuration of these skimmers is similar to that of aspirating pump skimmers, the power consumption advantages are also similar.

Related Research Articles

<span class="mw-page-title-main">Angel food cake</span> Type of sponge cake

Angel food cake, or angel cake, is a type of sponge cake made with egg whites, flour, and sugar. A whipping agent, such as cream of tartar, is commonly added. It differs from other cakes because it uses no butter. Its aerated texture comes from whipped egg white. Angel food cake originated in the United States and first became popular in the late 19th century. It gained its unique reputation along with its name due to its light and fluffy texture.

<span class="mw-page-title-main">Reef aquarium</span> Marine aquarium that displays live corals and other marine invertebrates as well as fish

A reef aquarium or reef tank is a marine aquarium that prominently displays live corals and other marine invertebrates as well as fish that play a role in maintaining the tropical coral reef environment. A reef aquarium requires appropriately intense lighting, turbulent water movement, and more stable water chemistry than fish-only marine aquaria, and careful consideration is given to which reef animals are appropriate and compatible with each other.

<span class="mw-page-title-main">Marine aquarium</span> Salt water aquarium

A marine aquarium is an aquarium that keeps marine plants and animals in a contained environment. Marine aquaria are further subdivided by hobbyists into fish only (FO), fish only with live rock (FOWLR), and reef aquaria. Fish only tanks often showcase large or aggressive marine fish species and generally rely on mechanical and chemical filtration. FOWLR and reef tanks use live rock, a material composed of coral skeletons harboring beneficial nitrogen waste metabolizing bacteria, as a means of more natural biological filtration.

<span class="mw-page-title-main">Airstone</span>

An airstone, also called an aquarium bubbler, is a piece of aquarium furniture, traditionally a piece of limewood or porous stone, whose purpose is to gradually diffuse air into the tank, eliminating the noise and large bubbles of conventional air filtration systems, and providing other benefits to the health of the fish. "Airstone" is also a brand name stone or brick veneer used by homebuilders. Airstones are sold in a very wide variety of shapes, sizes, and levels of coarseness – from extremely rough, producing larger bubbles and letting in more oxygen – to very fine, producing minuscule bubbles. Airstones are increasingly being made from bonded glass beads and synthetic products like fiberglass.

The Berlin Method of biological filtration is a method for maintaining a clean and stable environment within a saltwater aquarium, typically a coral reef system. This method relies on the use of ample live rock. The theory is that aerobic bacteria covering the surface of the porous live rock and sand convert harmful ammonia into nitrites, then nitrates, which are much less harmful to the tank's inhabitants. Through the process of diffusion, the nitrates move deep within the rock where they are converted by anaerobic bacteria to free nitrogen gas. Left over nitrates are removed through regular partial water changes, or with algal filtration such as an algae scrubber. As an added measure, a protein skimmer is used to remove some of the dissolved organic compounds before they break down into ammonia, although skimmers do not remove ammonia from fish urea.

<span class="mw-page-title-main">Fishkeeping</span> Practice of containing fish

Fishkeeping is a popular hobby, practiced by aquarists, concerned with keeping fish in a home aquarium or garden pond. There is also a piscicultural fishkeeping industry, serving as a branch of agriculture.

<span class="mw-page-title-main">Koi pond</span> Ponds used for holding koi

Koi ponds are ponds used for holding koi carp, usually as part of a garden. Koi ponds can be designed specifically to promote health and growth of the Nishikigoi or Japanese Ornamental Carp. Koi ponds or lakes are a traditional feature of Japanese gardens, but many hobbyists use special ponds in small locations, with no attempt to suggest a natural landscape feature.

<span class="mw-page-title-main">Microfoam</span> Finely textured milk used in coffee drinks

Microfoam is finely textured milk used for making espresso-based coffee drinks, particularly those with latte art. It is typically made with the steam wand of an espresso machine, which pumps steam into a pitcher of milk.

Skimmer may refer to:

<span class="mw-page-title-main">Calcium reactor</span>

In marine and reef aquariums, a calcium reactor creates a balance of alkalinity. An acidic solution is produced by injecting carbon dioxide into a chamber with salt water and calcium rich media. The carbon dioxide lowers the pH by producing a solution high in carbonic acid, and dissolves calcium. The effluent is returned to the reef aquarium where the calcium is consumed by organisms, primarily corals when building skeletons. A calcium reactor is an efficient method to supply calcium to a reef aquarium. Reactors may be used in elaborate freshwater and brackish aquariums where freshwater clams and other invertebrates need a constant supply of calcium.

An oil skimmer is a device that is designed to remove oil floating on a liquid surface from oil spills. The effectiveness of a skimmer is highly dependent on the roughness of the surrounding water that it is working on: the more choppy the surrounding wake and water, the more water the oil skimmer will take in along with the oil, rather than take in oil alone. Skimmers can be self-propelled, used from shore, or operated from vessels, with the best choice being dependent on the specifics for the job at hand. Skimmers can be pressed into use for a number of applications other than oil spills, with the correct type to use again being dependent on the nature of the intended application. Examples of possible uses include making skimmers one component of oily water treatment systems, removing oil from machine tool coolant and aqueous parts washers, and collecting fats, oils, and greases as part of wastewater treatment efforts for food manufacturing industries.

<span class="mw-page-title-main">Aquarium filter</span>

Aquarium filters are critical components of both freshwater and marine aquaria. Aquarium filters remove physical and soluble chemical waste products from aquaria, simplifying maintenance. Furthermore, aquarium filters are necessary to support life as aquaria are relatively small, closed volumes of water compared to the natural environment of most fish.

Foam fractionation is a chemical process in which hydrophobic molecules are preferentially separated from a liquid solution using rising columns of foam. It is commonly used, albeit on a small scale, for the removal of organic waste from aquariums; these units are known as "protein skimmers". However it has much broader application in the chemical process industry and can be used for the removal of surface active contaminants from waste water streams in addition to the enrichment of bio-products.

Induced gas flotation (IGF) is a water treatment process that clarifies wastewaters by the removal of suspended matter such as oil or solids. The removal is achieved by injecting gas bubbles into the water or wastewater in a flotation tank or basin. The small bubbles adhere to the suspended matter causing the suspended matter to float to the surface of the water where it may then be removed by a skimming device.

Groundwater remediation is the process that is used to treat polluted groundwater by removing the pollutants or converting them into harmless products. Groundwater is water present below the ground surface that saturates the pore space in the subsurface. Globally, between 25 per cent and 40 per cent of the world's drinking water is drawn from boreholes and dug wells. Groundwater is also used by farmers to irrigate crops and by industries to produce everyday goods. Most groundwater is clean, but groundwater can become polluted, or contaminated as a result of human activities or as a result of natural conditions.

<span class="mw-page-title-main">Aquarium</span> Transparent tank of water for fish and water-dwelling species

An aquarium is a vivarium of any size having at least one transparent side in which aquatic plants or animals are kept and displayed. Fishkeepers use aquaria to keep fish, invertebrates, amphibians, aquatic reptiles, such as turtles, and aquatic plants. The term aquarium, coined by English naturalist Philip Henry Gosse, combines the Latin root aqua, meaning 'water', with the suffix -arium, meaning 'a place for relating to'.

Dissolved gas flotation (DGF) systems are used for a variety of applications throughout the world. The process floats solids, oils and other contaminants to the surface of liquids. Once on the surface these contaminants are skimmed off and removed from the liquids. Oil and gas production facilities have used flotation systems to remove oil and solids from their produced and processed water (wastewater) for many years. The relative density of candle wax is 0.93, hence objects made of wax float on water.

<span class="mw-page-title-main">Sump (aquarium)</span>

In fishkeeping, a sump is an accessory aquarium tank in which mechanical equipment is kept. A remote sump allows for a clutter-free display tank.

Continuous foam separation is a chemical process closely related to foam fractionation in which foam is used to separate components of a solution when they differ in surface activity. In any solution, surface active components tend to adsorb to gas-liquid interfaces while surface inactive components stay within the bulk solution. When a solution is foamed, the most surface active components collect in the foam and the foam can be easily extracted. This process is commonly used in large-scale projects such as water waste treatment due to a continuous gas flow in the solution.

<span class="mw-page-title-main">Skimmer (spa)</span>

A skimmer or surface separator is an essential accessory for the maintenance and cleaning of the water in a swimming pool. It is used to remove all the surface dirt floating on the water surface, such as leaves, tanning oil and human secretions. These impurities remain suspended on the surface, affect the appearance of the water and are not always removed by the conventional vacuuming process. The skimmer is installed directly in the surface water suction system and also has the function of controlling the water level to prevent accidental overflows. In the United States and Portugal, the use of skimmers in the construction of swimming pools is mandatory, regulated and standardized by competent bodies.

References

  1. P. R. Escobal: Aquatic Systems Engineering: Devices and How They Function, Dimension Engineering Press, 2000, ISBN   1-888381-10-8
  2. Holmes-Farley, Randy, What is Skimming?, Reefkeeping, August 2006, http://www.reefkeeping.com/issues/2006-08/rhf/index.php
  3. Shimak, Ronald L, Ph. D., "Down the Drain, Exports From Reef Aquaria, Reefkeeping, Dec. 2002, http://www.reefkeeping.com/issues/2002-12/rs/feature/index.php
  4. "The Food of Reefs, Part 6: Particulate Organic Matter". Reefkeeping Magazine. 2003. Retrieved 9 April 2015.
  5. "Coral Reef Ecosystem Dynamics". The Starving Ocean. Debbie MacKenzie. 2011. Retrieved 9 April 2015.
  6. Holmes-Farley, Randy, What is Skimming?, Reefkeeping, August 2006, http://www.reefkeeping.com/issues/2006-08/rhf/index.php
  7. The Best Protein Skimmer For Your Fish Tank, Fishcareguide, August 2017, https://fishcareguide.com/the-best-protein-skimmer-for-your-fish-tank/
  8. Escobal 2000

Further reading