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Metals used for architectural purposes include lead, for water pipes, roofing, and windows; tin, formed into tinplate; zinc, copper and aluminium, in a range of applications including roofing and decoration; and iron, which has structural and other uses in the form of cast iron or wrought iron, or made into steel. Metal alloys used in building include bronze (mainly copper and tin); brass (copper and zinc); monel metal and nickel silver, mainly consisting of nickel and copper; and stainless steel, with important components of nickel and chromium.
The low melting point of lead permitted its use on a wide scale throughout human history. Lead was one of the first to be made into sheet metal for architectural purposes. [1] Water pipes were frequently constructed of lead, until its health hazards were publicised in the late 19th century.
Lead is not subject to rust and has been a popular roofing material for centuries, being used for roofing, flashing, gutters, downspouts, and conductor heads. Lead was best suited for low-pitched roofs, as steep roofs experienced creep. Lead roofs in regions with large temperature fluctuations, such as the mid-Atlantic states, experienced deterioration from constant expansion and contraction, called fatigue. Beginning in the 19th century, a roofing material called “terne” or “terneplate” was used, consisting of sheet iron or sheet steel coated with a lead-tin alloy. It is frequently confused with tinplate. [2]
Lead came was also frequently used for window panes in skylights and stained glass. It was also used for small pieces of sculpture and garden ornamentation. Lead was frequently added to paint, with red lead used as an anti-corrosive pigment for iron, and white lead used as paint for wooden houses. Lead-based paint was one of the most durable materials developed as a protective exterior coating. The use of lead paint has been restricted on most buildings, due to concerns of lead poisoning.
Tin is too soft to be used by itself for architectural purposes so it generally falls into two categories: the alloying of tin with other metals such as copper to form bronze, and the coating of tin on harder metals, such as tinplated iron or steel. Architectural bronzes usually contain about 90% copper and 10% tin, although the content may vary widely. The term “tin ceiling” is a misnomer and early manufacturers did not use the name. However, persons who worked with sheet metal were called tinsmiths, so the term could have sprung from this title. [3]
Tinplate was a type of architectural material consisting of sheet iron or steel coated with tin. “Tin roofs,” a type of tinplate, was originally used for armor but eventually as a roofing material. Tinplate was also used for decoration, such as ornamental windows, door lintels and stamped ceilings. Ornamental stamped metal made from tinplate was an affordable alternative to plasterwork. Although tinplate is still available today for ceilings, roofing and flashing, it is generally considered expensive since the initial cost is more than that for common modern roofing types such as asphalt shingles or built-up roofs. A well-maintained tinplate roof or ceiling typically lasts several times longer than modern materials, and is more economical when the longer lifespan is taken into account. [4]
Pure zinc was used for roofing in Belgium, France and Germany, where it replaced more expensive copper and lead in roofing. Starting in the 1820s, Belgian sheet zinc was imported in America, used by builders in New York City and elsewhere. Pure zinc is subject to creep at ordinary temperatures.
Zinc-coated metals were first patented in 1837, separately by M. Sorel in France and H. W. Crawford in England. The methods employed a “hot dipping” process to coat sheet iron with zinc. By 1839 “galvanized” sheet iron roofing was being used in New York City. The Merchant's Exchange in Manhattan was one of the first buildings to have both a galvanized roof and galvanized gutters. Some galvanized sheet roofing was pressed with designs, a popular technique in the Victorian era. [5]
Zinc was also cast for sculptures and decorative elements in Germany and Austria as early as 1832. Decorative architectural elements were frequently cast in zinc, since it molded readily, was inexpensive compared to stone, and could be painted to imitate more expensive metals. Stamped swags, rosettes, fleur-de-lis and acanthus leaves provided popular decorative ornamentation of both exteriors and interiors by the late 19th century. [6]
Zinc oxide paints were nontoxic and resistant to pollution. They became commercially successful and readily available in America in about 1850 and used widely starting around the 1870s. They had the added benefit of being good rust inhibitors on iron and steel.
During the early decades of the 20th century, the use of pure zinc roofing and ornament decreased in use in the US. It is now gaining popularity in its pure form (99.95%)for building materials. Typically, architectural grade zinc is 99.995 percent pure zinc with trace amounts of titanium, to reduce coefficient of thermal expansion and improve tensile strength and hardness, and copper to improve workability. [7] Exact alloy composition is subject to manufacturer and is a color determinant in zinc's final patina. Over time, zinc develops its distinctive patina, transforming from a shiny silver to a matte bluish-grey. Pre patinated finishes are available from certain manufacturers to expedite the natural patination process. Zinc is still used in alloys such as brass and nickel silver, and in the electroplating of steel as well. Today, galvanized steel and pure zinc material, usually Double Locked Standing Seam panels, are used for roofing a variety of buildings. Creep has been reduced by the introduction of titanium in most architectural zinc available in North America. Galvanized nails and sheet metal ducts are also common.
Architectural grade zinc is 90 to 95% recycled. Replacement costs are negligible with a long lifetime of 80 to 100 years for zinc roofing and 200 to 300 years for wall systems. [8] This long-life durability is a key component in durability. At the end of its service life, zinc building products can be recycled indefinitely without loss to chemical or physical properties. The use of architectural grade zinc can help building qualify for LEED certification due to its high recycled content and sustainability.
Copper is a very durable metal, withstanding corrosion when forming a bluish-green patina that variably consists of copper carbonates, sulfates, sulfides, and chlorides. Sheet copper used as roofing is lighter than wooden shingles and much lighter than slate, tile, or lead. Roofing copper can be folded readily into waterproof seams, or shaped over curved frameworks for cupolas and domes.
The initial cost of copper was traditionally high, but its length of service more than compensated for the price. Copper could also be shaped to the bends and angles around chimneys and at roof edges and dormers. All nails, screws, bolts, and cleats used with sheet copper must be made of copper or a copper alloy, otherwise galvanic action between the dissimilar metals would occur, causing deterioration. [9]
Copper was also used for decorative purposes, including architectural ornaments, siding, ceilings or sculptures. One famous example is the Statue of Liberty.
Copper alloys used in architecture include bronze, an alloy of copper and tin, and brass, an alloy of copper and zinc.
Although somewhat rare, nickel has been used for plating architectural details. Nickel is most frequently used for building components in the form of alloys: nickel silver, Monel metal, and stainless steel.
Nickel silver was originally called “German Silver,” until World War I. It has been called “white brass” but probably should be termed “nickel brass,” because it generally contains 75% copper, 20% nickel, and 5% zinc. Different percentages result in a range of colors, including silvery-white, yellow, slight blue, green or pink. Nickel silver hardware was popular in the US during the Art Deco and Depression Modern periods. Architects and designers preferred nickel silver because it could take and retain appropriate finishes, and it resisted corrosion. [10]
Monel metal is an alloy of approximately two-thirds nickel and one-third copper. It is similar to platinum in color. Monel pioneered many of the present uses of stainless steel. The first architectural use of Monel was for roofing the Pennsylvania Railroad Terminal in New York City in 1909. In 1936, the copper roof on the New York City Public Library at Fifth Avenue and 42nd Street was replaced with a Monel metal roof. Its advantages as a roofing material included its ability to be brazed, welded, or soldered in place to provide a watertight, continuous cover. Monel was popular during the Art Deco periods. During World War II large quantities of nickel and copper were diverted to the war effort, and the supply of Monel was greatly reduced. Following the war, stainless steel and aluminium replaced Monel because of lower production costs. [11]
Iron has become an important architectural building component. It has been used in four common forms: wrought iron, cast iron, sheet iron, and steel. [12]
Wrought iron was used for minor structural and decorative elements starting in the 18th century. Until the mid-19th century, the use of wrought iron in buildings was generally limited to small items such as tie rods, straps, nails, and hardware, or to decorative ironwork in balconies, railings fences and gates. Around 1850 its structural use became more widespread as iron mills began to roll rails, bulb-tees, and eventually I-beams. It was also used for decorative purposes, such as ornamental balconies or hardware. Since wrought iron is handmade, no two pieces are identical.
Cast iron was a major 19th century building material of the Industrial Revolution. Although brittle, it is remarkably strong in compression. It was frequently used for structural purposes, such as columns, building fronts, domes and light courts. Decorative uses have included stairs, elevators, lintels, grilles, verandas, balconies, railings, fences, streetlights, and tombs. The Bradbury Building is an example of extensive decorative cast iron. Today, cast iron is used for plumbing fixtures and piping in new construction, and its structural and decorative use is used occasionally through historic preservation practices.
Sheet iron can be subject to rapid corrosion, forming rust. Sheet iron was used throughout the 19th century, although it is not clear how widespread sheet iron roofs became. Pressed decorative sheet iron used for ceilings was frequently called a “tin ceiling,” which was actually sheets of iron dipped in molten tin to prevent them from rusting.
Steel was introduced to the construction industry at the end of the 19th century. The development of structural steel in the mid-19th century allowed construction of tall buildings. Builders and manufacturers turned to steel, which was stronger than cast iron in compression and wrought iron in tension. When the Bessemer process was developed in England in 1856, and the open-hearth process was invented, steel was produced in a quantity that allowed it to be economical. Bridges, railroad companies, and skyscrapers were among the first large-scale uses of structural steel. Although iron and steel are not combustible, they lose strength in a fire if they are not protected from the heat. Almost all structural steel must be “fireproofed” in some manner, utilizing a cladding of terra-cotta, tile, plaster-poured concrete, sprayed concrete, or sprayed insulation. Ferro concrete, also called reinforced concrete, was developed in the late 19th century when steel wire was added to concrete.
Decorative steels used in buildings include:
Much like copper, Aluminium is highly resistant to corrosion. It also has the added benefit of being a third lighter than steel with comparable strength. Aluminium can also be easily and repeatedly recycled. It has been estimated that of the estimated 900 million tonnes of aluminium produced since 1880, three quarters is still in productive use, 35% of which is in building construction. [13]
Aluminium was unavailable at reasonable cost or in sufficient quantities for general architectural use until after the beginning of the 20th century. Architectural use of aluminum increased in the 1920s, mainly for decorative detailing. It was used for roofing, flashing, gutters, downspouts, wall panels, and spandrels. Art Deco designs frequently used aluminum for ornamental features. The first extensive use of aluminum in construction was the Empire State Building, where the entire tower portion is aluminum, as well as many decorative features, such as the entrances, elevator doors, ornamental trim, and some 6,000 window spandrels. Today, aluminum is used frequently in construction except major structural members. [14]
Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals and sometimes non-metals, such as phosphorus, or metalloids such as arsenic or silicon. These additions produce a range of alloys that may be harder than copper alone, or have other useful properties, such as strength, ductility, or machinability.
Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys. Metallurgy encompasses both the science and the technology of metals; that is, the way in which science is applied to the production of metals, and the engineering of metal components used in products for both consumers and manufacturers. Metallurgy is distinct from the craft of metalworking. Metalworking relies on metallurgy in a similar manner to how medicine relies on medical science for technical advancement. A specialist practitioner of metallurgy is known as a metallurgist.
Hot-dip galvanization is a form of galvanization. It is the process of coating iron and steel with zinc, which alloys with the surface of the base metal when immersing the metal in a bath of molten zinc at a temperature of around 450 °C (842 °F). When exposed to the atmosphere, the pure zinc (Zn) reacts with oxygen (O2) to form zinc oxide (ZnO), which further reacts with carbon dioxide (CO2) to form zinc carbonate (ZnCO3), a usually dull grey, fairly strong material that protects the steel underneath from further corrosion in many circumstances. Galvanized steel is widely used in applications where corrosion resistance is needed without the cost of stainless steel, and is considered superior in terms of cost and life-cycle. It can be identified by the crystallization patterning on the surface (often called a "spangle").
Cookware and bakeware is food preparation equipment, such as cooking pots, pans, baking sheets etc. used in kitchens. Cookware is used on a stove or range cooktop, while bakeware is used in an oven. Some utensils are considered both cookware and bakeware.
Brazing is a metal-joining process in which two or more metal items are joined together by melting and flowing a filler metal into the joint, with the filler metal having a lower melting point than the adjoining metal.
Terne plate is a form of tinplate: a thin steel sheet coated with an alloy of lead and tin. The terne alloy was in the ratio of 10-20% tin and the remainder lead. The low tin content made it cheaper than other tinplates.
Corrugated galvanised iron or steel, colloquially corrugated iron, wriggly tin, pailing, corrugated sheet metal and occasionally abbreviated CGI is a building material composed of sheets of hot-dip galvanised mild steel, cold-rolled to produce a linear ridged pattern in them. Although it is still popularly called "iron" in the UK, the material used is actually steel, and only the surviving vintage sheets may actually be made up of 100% iron. The corrugations increase the bending strength of the sheet in the direction perpendicular to the corrugations, but not parallel to them, because the steel must be stretched to bend perpendicular to the corrugations. Normally each sheet is manufactured longer in its strong direction.
Monel is a group of alloys of nickel and copper, with small amounts of iron, manganese, carbon, and silicon. Monel is not a cupronickel alloy because it has less than 60% copper.
Tombac, or tombak, is a brass alloy with high copper content and 5–20% zinc content. Tin, lead or arsenic may be added for colouration. It is a cheap malleable alloy mainly used for medals, ornament, decoration and some munitions. In older use, the term may apply to brass alloy with a zinc content as high as 28–35%.
Plating is a surface covering in which a metal is deposited on a conductive surface. Plating has been done for hundreds of years; it is also critical for modern technology. Plating is used to decorate objects, for corrosion inhibition, to improve solderability, to harden, to improve wearability, to reduce friction, to improve paint adhesion, to alter conductivity, to improve IR reflectivity, for radiation shielding, and for other purposes. Jewelry typically uses plating to give a silver or gold finish.
Sheet metal is metal formed into thin, flat pieces, usually by an industrial process. Sheet metal is one of the fundamental forms used in metalworking, and it can be cut and bent into a variety of shapes.
The galvanic series determines the nobility of metals and semi-metals. When two metals are submerged in an electrolyte, while also electrically connected by some external conductor, the less noble (base) will experience galvanic corrosion. The rate of corrosion is determined by the electrolyte, the difference in nobility, and the relative areas of the anode and cathode exposed to the electrolyte. The difference can be measured as a difference in voltage potential: the less noble metal is the one with a lower electrode potential than the nobler one, and will function as the anode within the electrolyte device functioning as described above. Galvanic reaction is the principle upon which batteries are based.
Aluminium bronze is a type of bronze in which aluminium is the main alloying metal added to copper, in contrast to standard bronze or brass. A variety of aluminium bronzes of differing compositions have found industrial use, with most ranging from 5% to 11% aluminium by weight, the remaining mass being copper; other alloying agents such as iron, nickel, manganese, and silicon are also sometimes added to aluminium bronzes.
Flashing refers to thin pieces of impervious material installed to prevent the passage of water into a structure from a joint or as part of a weather resistant barrier system. In modern buildings, flashing is intended to decrease water penetration at objects such as chimneys, vent pipes, walls, windows and door openings to make buildings more durable and to reduce indoor mold problems. Metal flashing materials include lead, aluminium, copper, stainless steel, zinc alloy, and other materials.
A metal roof is a roofing system made from metal pieces or tiles characterized by its high resistance, impermeability and longevity. It is a component of the building envelope. Zinc, copper and steel alloys are commonly used.
A tin ceiling is an architectural element, consisting of a ceiling finished with plates of tin with designs pressed into them, that was very popular in Victorian buildings in North America in the late 19th and early 20th century. They were also popular in Australia where they were commonly known as pressed metal ceilings or Wunderlich ceilings. They were also used in South Africa.
Japanese Industrial Standards (JIS) are the standards used for industrial activities in Japan, coordinated by the Japanese Industrial Standards Committee (JISC) and published by the Japanese Standards Association (JSA). The JISC is composed of many nationwide committees and plays a vital role in standardizing activities across Japan.
Copper has earned a respected place in the related fields of architecture, building construction, and interior design. From cathedrals to castles and from homes to offices, copper is used for a variety of architectural elements, including roofs, flashings, gutters, downspouts, domes, spires, vaults, wall cladding, and building expansion joints.
Galvanic corrosion is an electrochemical process in which one metal corrodes preferentially when it is in electrical contact with another, in the presence of an electrolyte. A similar galvanic reaction is exploited in primary cells to generate a useful electrical voltage to power portable devices. This phenomenon is named after Italian physician Luigi Galvani (1737-1798).