|Steels and other iron–carbon alloy phases|
|Other iron-based materials|
Wrought iron is an iron alloy with a very low carbon (less than 0.08%) content in contrast to cast iron (2.1% to 4%). It is a semi-fused mass of iron with fibrous slag inclusions (up to 2% by weight), which gives it a "grain" resembling wood that is visible when it is etched or bent to the point of failure. Wrought iron is tough, malleable, ductile, corrosion-resistant and easily welded.
Before the development of effective methods of steelmaking and the availability of large quantities of steel, wrought iron was the most common form of malleable iron. It was given the name wrought because it was hammered, rolled or otherwise worked while hot enough to expel molten slag. 145The modern functional equivalent of wrought iron is mild steel, also called low-carbon steel. Neither wrought iron nor mild steel contain enough carbon to be hardenable by heating and quenching. :
Wrought iron is highly refined, with a small amount of slag forged out into fibres. It consists of around 99.4% iron by mass.The presence of slag is beneficial for blacksmithing operations, and gives the material its unique fibrous structure. The silicate filaments of the slag also protect the iron from corrosion and diminish the effect of fatigue caused by shock and vibration.
Historically, a modest amount of wrought iron was refined into steel, which was used mainly to produce swords, cutlery, chisels, axes and other edged tools as well as springs and files. The demand for wrought iron reached its peak in the 1860s, being in high demand for ironclad warships and railway use. However, as properties such as brittleness of mild steel improved with better ferrous metallurgy and as steel became less costly to make thanks to the Bessemer process and the Siemens-Martin process, the use of wrought iron declined.
Many items, before they came to be made of mild steel, were produced from wrought iron, including rivets, nails, wire, chains, rails, railway couplings, water and steam pipes, nuts, bolts, horseshoes, handrails, wagon tires, straps for timber roof trusses, and ornamental ironwork, among many other things.
Wrought iron is no longer produced on a commercial scale. Many products described as wrought iron, such as guard rails, garden furnitureand gates, are actually made of mild steel. They retain that description because they are made to resemble objects which in the past were wrought (worked) by hand by a blacksmith (although many decorative iron objects, including fences and gates, were often cast rather than wrought).
The word "wrought" is an archaic past participle of the verb "to work," and so "wrought iron" literally means "worked iron". Wrought iron is a general term for the commodity, but is also used more specifically for finished iron goods, as manufactured by a blacksmith. It was used in that narrower sense in British Customs records, such manufactured iron was subject to a higher rate of duty than what might be called "unwrought" iron. Cast iron, unlike wrought iron, is brittle and cannot be worked either hot or cold. Cast iron can break if struck with a hammer.
In the 17th, 18th, and 19th centuries, wrought iron went by a wide variety of terms according to its form, origin, or quality.
While the bloomery process produced wrought iron directly from ore, cast iron or pig iron were the starting materials used in the finery forge and puddling furnace. Pig iron and cast iron have higher carbon content than wrought iron, but have a lower melting point than iron or steel. Cast and especially pig iron have excess slag which must be at least partially removed to produce quality wrought iron. At foundries it was common to blend scrap wrought iron with cast iron to improve the physical properties of castings.
For several years after the introduction of Bessemer and open hearth steel, there were different opinions as to what differentiated iron from steel; some believed it was the chemical composition and others that it was whether the iron heated sufficiently to melt and "fuse". Fusion eventually became generally accepted as relatively more important than composition below a given low carbon concentration. 32–39 Another difference is that steel can be hardened by heat treating.:
Historically, wrought iron was known as "commercially pure iron",however, it no longer qualifies because current standards for commercially pure iron require a carbon content of less than 0.008 wt%.
Bar iron is a generic term sometimes used to distinguish it from cast iron. It is the equivalent of an ingot of cast metal, in a convenient form for handling, storage, shipping and further working into a finished product.
The bars were the usual product of the finery forge, but not necessarily made by that process.
Wrought iron is a form of commercial iron containing less than 0.10% of carbon, less than 0.25% of impurities total of sulfur, phosphorus, silicon and manganese, and less than 2% slag by weight.
Wrought iron is redshort or hot short if it contains sulfur in excess quantity. It has sufficient tenacity when cold, but cracks when bent or finished at a red heat. 7 Hot short iron was considered unmarketable.:
Cold short iron, also known as coldshear, colshire, contains excessive phosphorus. It is very brittle when cold and cracks if bent. 7, 215 It may, however, be worked at high temperature. Historically, coldshort iron was considered sufficient for nails.:
Phosphorus is not necessarily detrimental to iron. Ancient Near Eastern smiths did not add lime to their furnaces. The absence of calcium oxide in the slag, and the deliberate use of wood with high phosphorus content during the smelting, induces a higher phosphorus content (typically <.3%) than in modern iron (<.02-.03%). 69 The included slag in wrought iron also imparts corrosion resistance.Analysis of the Iron Pillar of Delhi gives 0.11% in the iron. :
The presence of phosphorus (without carbon) produces a ductile iron suitable for wire drawing for piano wire.
Wrought iron has been used for many centuries, and is the "iron" that is referred to throughout Western history. The other form of iron, cast iron, was in use in China since ancient times but was not introduced into Western Europe until the 15th century; even then, due to its brittleness, it could be used for only a limited number of purposes. Throughout much of the Middle Ages iron was produced by the direct reduction of ore in manually operated bloomeries, although waterpower had begun to be employed by 1104.
The raw material produced by all indirect processes is pig iron. It has a high carbon content and as a consequence it is brittle and could not be used to make hardware. The osmond process was the first of the indirect processes, developed by 1203, but bloomery production continued in many places. The process depended on the development of the blast furnace, of which medieval examples have been discovered at Lapphyttan, Sweden and in Germany.
The bloomery and osmond processes were gradually replaced from the 15th century by finery processes, of which there were two versions, the German and Walloon. They were in turn replaced from the late 18th century by puddling, with certain variants such as the Swedish Lancashire process. Those, too, are now obsolete, and wrought iron is no longer manufactured commercially.
During the Han dynasty, new iron smelting processes led to the manufacture of new wrought iron implements for use in agriculture, such as the multi-tube seed drill and iron plough. – 220 AD) site at Tieshengguo. :186 Pigott speculates that the finery forge existed in the previous Warring States period (403–221 BC), due to the fact that there are wrought iron items from China dating to that period and there is no documented evidence of the bloomery ever being used in China. :186–187 The fining process involved liquifying cast iron in a fining hearth and removing carbon from the molten cast iron through oxidation. :186 Wagner writes that in addition to the Han Dynasty hearths believed to be fining hearths, there is also pictoral evidence of the fining hearth from a Shandong tomb mural dated 1st to 2nd century AD, as well as a hint of written evidence in the 4th century AD Daoist text Taiping Jing .In addition to accidental lumps of low-carbon wrought iron produced by excessive injected air in ancient Chinese cupola furnaces. The ancient Chinese created wrought iron by using the finery forge at least by the 2nd century BC, the earliest specimens of cast and pig iron fined into wrought iron and steel found at the early Han Dynasty (202 BC
Wrought iron was originally produced by a variety of smelting processes, all described today as "bloomeries". Different forms of bloomery were used at different places and times. The bloomery was charged with charcoal and iron ore and then lit. Air was blown in through a tuyere to heat the bloomery to a temperature somewhat below the melting point of iron. In the course of the smelt, slag would melt and run out, and carbon monoxide from the charcoal would reduce the ore to iron, which formed a spongy mass (called a "bloom") containing iron and also molten silicate minerals (slag) from the ore. The iron remained in the solid state. If the bloomery were allowed to become hot enough to melt the iron, carbon would dissolve into it and form pig or cast iron, but that was not the intention. However, the design of a bloomery made it difficult to reach the melting point of iron and also prevented the concentration of carbon monoxide from becoming high. 46–57:
After smelting was complete, the bloom was removed, and the process could then be started again. It was thus a batch process, rather than a continuous one such as a blast furnace. The bloom had to be forged mechanically to consolidate it and shape it into a bar, expelling slag in the process. 62–66:
During the Middle Ages, water-power was applied to the process, probably initially for powering bellows, and only later to hammers for forging the blooms. However, while it is certain that water-power was used, the details remain uncertain. 75–76 That was the culmination of the direct process of ironmaking. It survived in Spain and southern France as Catalan Forges to the mid 19th century, in Austria as the stuckofen to 1775, :100–101 and near Garstang in England until about 1770; it was still in use with hot blast in New York in the 1880s. In Japan the last of the old tatara bloomeries used in production of traditional tamahagane steel, mainly used in swordmaking, was extinguished only in 1925, though in the late 20th century the production resumed on a low scale to supply the steel to the artisan swordmakers.:
Osmond iron consisted of balls of wrought iron, produced by melting pig iron and catching the droplets on a staff, which was spun in front of a blast of air so as to expose as much of it as possible to the air and oxidise its carbon content.The resultant ball was often forged into bar iron in a hammer mill.
In the 15th century, the blast furnace spread into what is now Belgium where it was improved. From there, it spread via the Pays de Bray on the boundary of Normandy and then to the Weald in England. With it, the finery forge spread. Those remelted the pig iron and (in effect) burnt out the carbon, producing a bloom, which was then forged into a bar iron. If rod iron was required, a slitting mill was used.
The finery process existed in two slightly different forms. In Great Britain, France, and parts of Sweden, only the Walloon process was used. That employed two different hearths, a finery hearth for finishing the iron and a chafery hearth for reheating it in the course of drawing the bloom out into a bar. The finery always burnt charcoal, but the chafery could be fired with mineral coal, since its impurities would not harm the iron when it was in the solid state. On the other hand, the German process, used in Germany, Russia, and most of Sweden used a single hearth for all stages.
The introduction of coke for use in the blast furnace by Abraham Darby in 1709 (or perhaps others a little earlier) initially had little effect on wrought iron production. Only in the 1750s was coke pig iron used on any significant scale as the feedstock of finery forges. However, charcoal continued to be the fuel for the finery.
From the late 1750s, ironmasters began to develop processes for making bar iron without charcoal. There were a number of patented processes for that, which are referred to today as potting and stamping. The earliest were developed by John Wood of Wednesbury and his brother Charles Wood of Low Mill at Egremont, patented in 1763. 723–724 Another was developed for the Coalbrookdale Company by the Cranage brothers. Another important one was that of John Wright and Joseph Jesson of West Bromwich. :725–726:
A number of processes for making wrought iron without charcoal were devised as the Industrial Revolution began during the latter half of the 18th century. The most successful of those was puddling, using a puddling furnace (a variety of the reverberatory furnace), which was invented by Henry Cort in 1784.It was later improved by others including Joseph Hall, who was the first to add iron oxide to the charge. In that type of furnace, the metal does not come into contact with the fuel, and so is not contaminated by its impurities . The heat of the combustion products pass over the surface of the puddle and the roof of the furnace reverberates (reflects) the heat onto the metal puddle on the fire bridge of the furnace.
Unless the raw material used is white cast iron, the pig iron or other raw product of the puddling first had to be refined into refined iron, or finers metal. That would be done in a refinery where raw coal was used to remove silicon and convert carbon within the raw material, found in the form of graphite, to a combination with iron called cementite.
In the fully developed process (of Hall), this metal was placed into the hearth of the puddling furnace where it was melted. The hearth was lined with oxidizing agents such as haematite and iron oxide. 165 through working doors. :236–240 The air, the stirring, and the "boiling" action of the metal helped the oxidizing agents to oxidize the impurities and carbon out of the pig iron. As the impurities oxidize, they formed a molten slag or drifted off as gas while the retaining iron solidified into spongy wrought iron that floated to the top of the puddle and were fished out of the melt as puddle balls using puddle bars.The mixture was subjected to a strong current of air and stirred with long bars, called puddling bars or rabbles, :
There was still some slag left in the puddle balls, so while they were still hot they would be shingledto remove the remaining slag and cinder. That was achieved by forging the balls under a hammer, or by squeezing the bloom in a machine. The material obtained at the end of shingling is known as bloom. The blooms are not useful in that form, so they were rolled into a final product.
Sometimes European ironworks would skip the shingling process completely and roll the puddle balls. The only drawback to that is that the edges of the rough bars were not as well compressed. When the rough bar was reheated, the edges might separate and be lost into the furnace.
The bloom was passed through rollers and to produce bars. The bars of wrought iron were of poor quality, called muck bars 137 or puddle bars. To improve their quality, the bars were cut up, piled and tied together by wires, a process known as faggoting or piling. They were then reheated to a welding state, forge welded, and rolled again into bars. The process could be repeated several times to produce wrought iron of desired quality. Wrought iron that has been rolled multiple times is called merchant bar or merchant iron.:
The advantage of puddling was that it used coal, not charcoal as fuel. However, that was of little advantage in Sweden, which lacked coal. Gustaf Ekman observed charcoal fineries at Ulverston, which were quite different from any in Sweden. After his return to Sweden in the 1830s, he experimented and developed a process similar to puddling but used firewood and charcoal, which was widely adopted in the Bergslagen in the following decades. 282–285:
In 1925, James Aston of the United States developed a process for manufacturing wrought iron quickly and economically. It involved taking molten steel from a Bessemer converter and pouring it into cooler liquid slag. The temperature of the steel is about 1500 °C and the liquid slag is maintained at approximately 1200 °C. The molten steel contains a large amount of dissolved gases so when the liquid steel hit the cooler surfaces of the liquid slag the gases were liberated. The molten steel then froze to yield a spongy mass having a temperature of about 1370 °C. The spongy mass would then be finished by being shingled and rolled as described under puddling (above). Three to four tons could be converted per batch with the method.
Steel began to replace iron for railroad rails as soon as the Bessemer process for its manufacture was adopted (1865 on). Iron remained dominant for structural applications until the 1880s, because of problems with brittle steel, caused by introduced nitrogen, high carbon, excess phosphorus, or excessive temperature during or too-rapid rolling. 144–151 By 1890 steel had largely replaced iron for structural applications.:
Sheet iron (Armco 99.97% pure iron) had good properties for use in appliances, being well-suited for enamelling and welding, and being rust-resistant. 242:
In the 1960s, the price of steel production was dropping due to recycling, and even using the Aston process, wrought iron production was labor-intensive. It has been estimated that the production of wrought iron is approximately twice as expensive as that of low-carbon steel.In the United States, the last plant closed in 1969. The last in the world was the Atlas Forge of Thomas Walmsley and Sons in Bolton, Great Britain, which closed in 1973. Its 1860s-era equipment was moved to the Blists Hill site of Ironbridge Gorge Museum for preservation. Some wrought iron is still being produced for heritage restoration purposes, but only by recycling scrap.
The slag inclusions, or stringers, in wrought iron give it properties not found in other forms of ferrous metal. There are approximately 250,000 inclusions per square inch.A fresh fracture shows a clear bluish color with a high silky luster and fibrous appearance.
Wrought iron lacks the carbon content necessary for hardening through heat treatment, but in areas where steel was uncommon or unknown, tools were sometimes cold-worked (hence cold iron) in order to harden them.[ citation needed ] An advantage of its low carbon content is its excellent weldability. Furthermore, sheet wrought iron cannot bend as much as steel sheet metal (when cold worked). Wrought iron can be melted and cast, however the product is no longer wrought iron, since the slag stringers characteristic of wrought iron disappear on melting, so the product resembles impure cast Bessemer steel. There is no engineering advantage as compared to cast iron or steel, both of which are cheaper.
Due to the variations in iron ore origin and iron manufacture, wrought iron can be inferior or superior in corrosion resistance compared to other iron alloys.There are many mechanisms behind that corrosion resistance. Chilton and Evans found that nickel enrichment bands reduce corrosion. They also found that in puddled, forged and piled iron, the working-over of the metal spread out copper, nickel and tin impurities, which produces electrochemical conditions that slow down corrosion. The slag inclusions have been shown to disperse corrosion to an even film, enabling the iron to resist pitting. Another study has shown that slag inclusions are pathways to corrosion. Other studies show that sulfur impurities in the wrought iron decrease corrosion resistance, but phosphorus increase corrosion resistance. Environments with a high concentration of chloride ions also decreases wrought iron's corrosion resistance.
Wrought iron may be welded in the same manner as mild steel, but the presence of oxide or inclusions will give defective results.The material has a rough surface, so it can hold platings and coatings better. For instance, a galvanic zinc finish applied to wrought iron is approximately 25–40% thicker than the same finish on steel. In Table 1, the chemical composition of wrought iron is compared to that of pig iron and carbon steel. Although it appears that wrought iron and plain carbon steel have similar chemical compositions, that is deceiving. Most of the manganese, sulfur, phosphorus, and silicon are incorporated into the slag fibers present in the wrought iron, so, really, wrought iron is purer than plain carbon steel.
|Ultimate tensile strength [psi (MPa)]||34,000–54,000 (234–372)|
|Ultimate compression strength [psi (MPa)]||34,000–54,000 (234–372)|
|Ultimate shear strength [psi (MPa)]||28,000–45,000 (193–310)|
|Yield point [psi (MPa)]||23,000–32,000 (159–221)|
|Modulus of elasticity (in tension) [psi (MPa)]||28,000,000 (193,100)|
|Melting point [°F (°C)]||2,800 (1,540)|
Amongst its other properties, wrought iron becomes soft at red heat, and can be easily forged and forge welded.It can be used to form temporary magnets, but cannot be magnetized permanently, and is ductile, malleable and tough.
For most purposes, ductility is a more important measure of the quality of wrought iron than tensile strength. In tensile testing, the best irons are able to undergo considerable elongation before failure. Higher tensile wrought iron is brittle.
Because of the large number of boiler explosions on steamboats, the U.S. Congress passed legislation in 1830 which approved funds for correcting the problem. The treasury awarded a $1500 contract to the Franklin Institute to conduct a study. As part of the study, Walter R. Johnson and Benjamin Reeves conducted strength tests on various boiler iron using a tester they had built in 1832 based on the design of one by Lagerhjelm in Sweden. Unfortunately, because of the misunderstanding of tensile strength and ductility, their work did little to reduce failures.
The importance of ductility was recognized by some very early in the development of tube boilers, such as Thurston's comment:
If made of such good iron as the makers claimed to have put into them "which worked like lead," they would, as also claimed, when ruptured, open by tearing, and discharge their contents without producing the usual disastrous consequences of a boiler explosion.
Various 19th-century investigations of boiler explosions, especially those by insurance companies, found causes to be most commonly the result of operating boilers above the safe pressure range, either to get more power or due to defective boiler pressure relief valves and difficulties of obtaining reliable indication of pressure and water level. Poor fabrication was also a common problem.Also, the thickness of the iron in steam drums was low by modern standards.
By the late 19th century, when metallurgists were able to better understand what properties and processes made good iron, it was being displaced by steel. Also, the old cylindrical boilers with fire tubes were displaced by water tube boilers, which are inherently safer.
In 2010 Dr Gerry McDonnelldemonstrated in England by analysis that a wrought iron bloom, from a traditional smelt, could be worked into 99.7% pure iron with no evidence of carbon. It was found that the stringers common to other wrought irons were not present, thus making it very malleable for the smith to work hot and cold. A commercial source of pure iron is available and is used by smiths as an alternative to traditional wrought iron and other new generation ferrous metals.
Wrought iron furniture has a long history, dating back to Roman times. There are 13th-century wrought iron gates in Westminster Abbey in London, and wrought iron furniture appeared to reach its peak popularity in Britain in the 17th century, during the reign of William III and Mary II.[ citation needed ] However, cast iron and cheaper steel caused a gradual decline in wrought iron manufacture; the last wrought ironworks in Britain closed in 1974.
It is also used to make home decor items such as baker's racks, wine racks, pot racks, etageres, table bases, desks, gates, beds, candle holders, curtain rods, bars and bar stools.
The vast majority of wrought iron available today is from reclaimed materials. Old bridges and anchor chains dredged from harbors are major sources.[ citation needed ] The greater corrosion resistance of wrought iron is due to the siliceous impurities (naturally occurring in iron ore), namely ferric silicate.
Wrought iron has been used for decades as a generic term across the gate and fencing industry, even though mild steel is used for manufacturing these "wrought iron" gates.This is mainly because of the limited availability of true wrought iron. Steel can also be hot-dip galvanised to prevent corrosion, which cannot be done with wrought iron.
Steel is an alloy of iron and carbon, and sometimes other elements like chromium. Because of its high tensile strength and low cost, it is a major component used in buildings, infrastructure, tools, ships, trains, automobiles, machines, appliances, and weapons.
Smelting is a process of applying heat to ore in order to extract a base metal. It is a form of extractive metallurgy. It is used to extract many metals from their ores, including silver, iron, copper, and other base metals. Smelting uses heat and a chemical reducing agent to decompose the ore, driving off other elements as gases or slag and leaving the metal base behind. The reducing agent is commonly a source of carbon, such as coke—or, in earlier times, charcoal.
The Bessemer process was the first inexpensive industrial process for the mass production of steel from molten pig iron before the development of the open hearth furnace. The key principle is removal of impurities from the iron by oxidation with air being blown through the molten iron. The oxidation also raises the temperature of the iron mass and keeps it molten.
Pig iron is an intermediate product of the iron industry, also known as crude iron, which is obtained by smelting iron ore in a blast furnace. Pig iron has a very high carbon content, typically 3.8–4.7%, along with silica and other constituents of dross, which makes it very brittle and not useful directly as a material except for limited applications.
Steelmaking is the process of producing steel from iron ore and/or scrap. In steelmaking, impurities such as nitrogen, silicon, phosphorus, sulfur and excess carbon are removed from the sourced iron, and alloying elements such as manganese, nickel, chromium, carbon and vanadium are added to produce different grades of steel. Limiting dissolved gases such as nitrogen and oxygen and entrained impurities in the steel is also important to ensure the quality of the products cast from the liquid steel.
A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally pig iron, but also others such as lead or copper. Blast refers to the combustion air being "forced" or supplied above atmospheric pressure.
Crucible steel is steel made by melting pig iron, iron, and sometimes steel, often along with sand, glass, ashes, and other fluxes, in a crucible. In ancient times steel and iron were impossible to melt using charcoal or coal fires, which could not produce temperatures high enough. However, pig iron, having a higher carbon content thus a lower melting point, could be melted, and by soaking wrought iron or steel in the liquid pig-iron for a long time, the carbon content of the pig iron could be reduced as it slowly diffused into the iron. Crucible steel of this type was produced in South and Central Asia during the medieval era. This generally produced a very hard steel, but also a composite steel that was inhomogeneous, consisting of a very high-carbon steel and a lower-carbon steel. This often resulted in an intricate pattern when the steel was forged, filed or polished, with possibly the most well-known examples coming from the wootz steel used in Damascus swords. The steel was often much higher in carbon content and in quality in comparison with other methods of steel production of the time because of the use of fluxes.
William Kelly, born in Pittsburgh, Pennsylvania, was an American inventor. He is credited with being one of the inventors of modern steel production, through the process of injecting air into molten iron, which he experimented with in the early 1850s. A similar process was discovered independently by Henry Bessemer and patented in 1855. Due to a financial panic in 1857, a company that had already licensed the Bessemer process was able to purchase Kelly's patents, and licensed both under a single scheme using the Bessemer name. Kelly's role in the invention of the process is much less known.
The Wealden iron industry was located in the Weald of south-eastern England. It was formerly an important industry, producing a large proportion of the bar iron made in England in the 16th century and most British cannon until about 1770. Ironmaking in the Weald used ironstone from various clay beds, and was fuelled by charcoal made from trees in the heavily wooded landscape. The industry in the Weald declined when ironmaking began to be fuelled by coke made from coal, which does not occur accessibly in the area.
Open hearth furnaces are one of a number of kinds of furnace where excess carbon and other impurities are burnt out of pig iron to produce steel. Since steel is difficult to manufacture due to its high melting point, normal fuels and furnaces were insufficient and the open hearth furnace was developed to overcome this difficulty. Compared to Bessemer steel, which it displaced, its main advantages were that it did not expose the steel to excessive nitrogen, was easier to control, and it permitted the melting and refining of large amounts of scrap iron and steel.
A bloomery is a type of furnace once used widely for smelting iron from its oxides. The bloomery was the earliest form of smelter capable of smelting iron. Bloomeries produce a porous mass of iron and slag called a bloom. The mix of slag and iron in the bloom, termed sponge iron, is usually consolidated and further forged into wrought iron. Blast furnaces, which produce pig iron, have largely superseded bloomeries.
A reverberatory furnace is a metallurgical or process furnace that isolates the material being processed from contact with the fuel, but not from contact with combustion gases. The term reverberation is used here in a generic sense of rebounding or reflecting, not in the acoustic sense of echoing.
An ironworks or iron works is a building or site where iron is smelted and where heavy iron and steel products are made. The term is both singular and plural, i.e. the singular of ironworks is ironworks.
Puddling is a step in the manufacture of high-grade iron in a crucible or furnace. Known by the 1st century AD in the Han Dynasty of ancient China, it was advanced in Great Britain during the Industrial Revolution. There molten pig iron in a reverberatory furnace was stirred with consumable rods resulting in a less brittle, more purified steel. It was one of the most important processes of making the first appreciable volumes of valuable and useful bar iron. Eventually, the furnace would be used to make small quantities of specialty steels.
A finery forge is a forge used to produce wrought iron from pig iron by decarburization. The process involved liquifying cast iron in a fining hearth and removing carbon from the molten cast iron through oxidation. Finery forges were used as early as 3rd century BC, based on archaeological evidence found at a site in Tieshengguo, China. The finery forge process was replaced by the puddling process and the roller mill, both developed by Henry Cort in 1783-4, but not becoming widespread until after 1800.
Ferrous metallurgy is the metallurgy of iron and its alloys. It began far back in prehistory. The earliest surviving iron artifacts, from the 4th millennium BC in Egypt, were made from meteoritic iron-nickel. It is not known when or where the smelting of iron from ores began, but by the end of the 2nd millennium BC iron was being produced from iron ores from at least Greece to India, and more controversially Sub-Saharan Africa. The use of wrought iron was known by the 1st millennium BC, and its spread marked the Iron Age. During the medieval period, means were found in Europe of producing wrought iron from cast iron using finery forges. For all these processes, charcoal was required as fuel.
In metallurgy, refining consists of purifying an impure metal. It is to be distinguished from other processes such as smelting and calcining in that those two involve a chemical change to the raw material, whereas in refining, the final material is usually identical chemically to the original one, only it is purer. The processes used are of many types, including pyrometallurgical and hydrometallurgical techniques.
Cornwall Iron Furnace is a designated National Historic Landmark that is administered by the Pennsylvania Historical and Museum Commission in Cornwall, Lebanon County, Pennsylvania in the United States. The furnace was a leading Pennsylvania iron producer from 1742 until it was shut down in 1883. The furnaces, support buildings and surrounding community have been preserved as a historical site and museum, providing a glimpse into Lebanon County's industrial past. The site is the only intact charcoal-burning iron blast furnace in its original plantation in the western hemisphere. Established by Peter Grubb in 1742, Cornwall Furnace was operated during the Revolution by his sons Curtis and Peter Jr. who were major arms providers to George Washington. Robert Coleman acquired Cornwall Furnace after the Revolution and became Pennsylvania's first millionaire. Ownership of the furnace and its surroundings was transferred to the Commonwealth of Pennsylvania in 1932.
Ancient iron production refers to iron working in times from prehistory to the early Middle Ages where knowledge of production processes is derived from archaeological investigation. Slag, the byproduct of iron-working processes such as smelting or smithing, is left at the iron-working site rather than being moved away with the product. It also weathers well and hence it is readily available for study. The size, shape, chemical composition and microstructure of slag are determined by features of the iron-working processes used at the time of its formation.
The Lancashire hearth was used to fine pig iron, removing carbon to produce wrought iron.