The cementation process is an obsolete technology for making steel by carburization of iron. Unlike modern steelmaking, it increased the amount of carbon in the iron. It was apparently developed before the 17th century. Derwentcote Steel Furnace, built in 1720, is the earliest surviving example of a cementation furnace. Another example in the UK is the cementation furnace in Doncaster Street, Sheffield.
The process was described in a treatise published in Prague in 1574. It was invented by Johann Nussbaum of Magdeburg, who began operations at Nuremberg (with partners) in 1601. The process was patented in England by William Ellyot and Mathias Meysey in 1614. [1] At that date, the "invention" could consist merely of the introduction of a new industry or product, or even a mere monopoly. They evidently soon transferred the patent to Sir Basil Brooke, but he was forced to surrender it in 1619. A clause in the patent prohibiting the import of steel was found to be undesirable because he could not supply as much good steel as was needed. [2] Brooke's furnaces were probably in his manor of Madeley at Coalbrookdale (which certainly existed before the English Civil War) where two cementation furnaces have been excavated. [3] He probably used bar iron from the Forest of Dean, where he was a partner in farming the King's ironworks in two periods.
By 1631, it was recognised that Swedish iron was the best raw material and then or later particularly certain marks (brands) such as double bullet (so called from the mark OO) from Österby and hoop L from Leufsta (now Lövsta), whose mark consisted of an L in a circle, both belonging to Louis De Geer and his descendants. These were among the first ironworks in Sweden to use the Walloon process of fining iron, producing what was known in England as oregrounds iron. It was so called from the Swedish port of Öregrund, north of Stockholm, in whose hinterland most of the ironworks lay. The ore used came ultimately from the Dannemora mine. [2] [4]
The process begins with wrought iron and charcoal. It uses one or more long stone pots inside a furnace. Typically, in Sheffield, each pot was 14 feet by 4 feet and 3.5 feet deep. Iron bars and charcoal are packed in alternating layers, with a top layer of charcoal and then refractory matter to make the pot or "coffin" airtight. Some manufacturers used a mixture of powdered charcoal, soot and mineral salts, called cement powder. In larger works, up to 16 tons of iron were treated in each cycle, though it can be done on a small scale, such as in a small furnace or blacksmith's forge.
Depending on the thickness of the iron bars, the pots were then heated from below for a week or more. Bars were regularly examined and when the correct condition was reached the heat was withdrawn and the pots were left until cool—usually around fourteen days. The iron had gained a little over 1% in mass from the carbon in the charcoal, and had become heterogeneous bars of blister steel.
The bars were then shortened, bound, heated and forge welded together to become shear steel. It would be cut and re welded multiple times, with each new weld producing a more homogeneous, higher quality steel. This would be done at most 3-4 times, as more is unnecessary and could potentially cause carbon loss from the steel.
Alternatively they could be broken up and melted in a crucible using a crucible furnace with a flux to become crucible steel (at the time also called cast steel), a process devised by Benjamin Huntsman in Sheffield in the 1740s.
In the early modern period, brass, an alloy of copper and zinc, was usually produced by a cementation process in which metallic copper was heated with calamine, a zinc ore, to make calamine brass.
Steel is an alloy of iron and carbon with improved strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels, which are resistant to corrosion and oxidation, typically need an additional 11% chromium. Because of its high tensile strength and low cost, steel is used in buildings, infrastructure, tools, ships, trains, cars, bicycles, machines, electrical appliances, furniture, and weapons.
The Bessemer process was the first inexpensive industrial process for the mass production of steel from molten pig iron before the development of the open hearth furnace. The key principle is removal of impurities from the iron by oxidation with air being blown through the molten iron. The oxidation also raises the temperature of the iron mass and keeps it molten.
Major innovations in materials technology
Wrought iron is an iron alloy with a very low carbon content in contrast to that of cast iron. It is a semi-fused mass of iron with fibrous slag inclusions, which give it a wood-like "grain" that is visible when it is etched, rusted, or bent to failure. Wrought iron is tough, malleable, ductile, corrosion resistant, and easily forge welded, but is more difficult to weld electrically.
Steelmaking is the process of producing steel from iron ore and/or scrap. In steelmaking, impurities such as nitrogen, silicon, phosphorus, sulfur and excess carbon are removed from the sourced iron, and alloying elements such as manganese, nickel, chromium, carbon and vanadium are added to produce different grades of steel.
A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally pig iron, but also others such as lead or copper. Blast refers to the combustion air being supplied above atmospheric pressure.
Crucible steel is steel made by melting pig iron, iron, and sometimes steel, often along with sand, glass, ashes, and other fluxes, in a crucible. In ancient times steel and iron were impossible to melt using charcoal or coal fires, which could not produce temperatures high enough. However, pig iron, having a higher carbon content and thus a lower melting point, could be melted, and by soaking wrought iron or steel in the liquid pig-iron for a long time, the carbon content of the pig iron could be reduced as it slowly diffused into the iron, turning both into steel. Crucible steel of this type was produced in South and Central Asia during the medieval era. This generally produced a very hard steel, but also a composite steel that was inhomogeneous, consisting of a very high-carbon steel and a lower-carbon steel. This often resulted in an intricate pattern when the steel was forged, filed or polished, with possibly the most well-known examples coming from the wootz steel used in Damascus swords. The steel was often much higher in carbon content and in quality in comparison with other methods of steel production of the time because of the use of fluxes. The steel was usually worked very little and at relatively low temperatures to avoid any decarburization, hot short crumbling, or excess diffusion of carbon; just enough hammering to form the shape of a sword. With a carbon content close to that of cast iron, it usually required no heat treatment after shaping other than air cooling to achieve the correct hardness, relying on composition alone. The higher-carbon steel provided a very hard edge, but the lower-carbon steel helped to increase the toughness, helping to decrease the chance of chipping, cracking, or breaking.
William Kelly, born in Pittsburgh, Pennsylvania, was an American inventor. He is credited with being one of the inventors of modern steel production, through the process of injecting air into molten iron, which he experimented with in the early 1850s. A similar process was discovered independently by Henry Bessemer and patented in 1855. Due to a financial panic in 1857, a company that had already licensed the Bessemer process was able to purchase Kelly's patents, and licensed both under a single scheme using the Bessemer name. Kelly's role in the invention of the process is much less known.
Coalbrookdale is a village in the Ironbridge Gorge in Shropshire, England, containing a settlement of great significance in the history of iron ore smelting. It lies within the civil parish called the Gorge.
An open-hearth furnace or open hearth furnace is any of several kinds of industrial furnace in which excess carbon and other impurities are burnt out of pig iron to produce steel. Because steel is difficult to manufacture owing to its high melting point, normal fuels and furnaces were insufficient for mass production of steel, and the open-hearth type of furnace was one of several technologies developed in the nineteenth century to overcome this difficulty. Compared with the Bessemer process, which it displaced, its main advantages were that it did not expose the steel to excessive nitrogen, was easier to control, and permitted the melting and refining of large amounts of scrap iron and steel.
An ironworks or iron works is an industrial plant where iron is smelted and where heavy iron and steel products are made. The term is both singular and plural, i.e. the singular of ironworks is ironworks.
Puddling is the process of converting pig iron to bar (wrought) iron in a coal fired reverberatory furnace. It was developed in England during the 1780s. The molten pig iron was stirred in a reverberatory furnace, in an oxidizing environment to burn the carbon, resulting in wrought iron. It was one of the most important processes for making the first appreciable volumes of valuable and useful bar iron without the use of charcoal. Eventually, the furnace would be used to make small quantities of specialty steels.
A finery forge is a forge used to produce wrought iron from pig iron by decarburization in a process called "fining" which involved liquifying cast iron in a fining hearth and removing carbon from the molten cast iron through oxidation. Finery forges were used as early as the 3rd century BC in China. The finery forge process was replaced by the puddling process and the roller mill, both developed by Henry Cort in 1783–4, but not becoming widespread until after 1800.
A Walloon forge is a type of finery forge that decarbonizes pig iron into wrought iron.
Ferrous metallurgy is the metallurgy of iron and its alloys. The earliest surviving prehistoric iron artifacts, from the 4th millennium BC in Egypt, were made from meteoritic iron-nickel. It is not known when or where the smelting of iron from ores began, but by the end of the 2nd millennium BC iron was being produced from iron ores in the region from Greece to India, and sub-Saharan Africa. The use of wrought iron was known by the 1st millennium BC, and its spread defined the Iron Age. During the medieval period, smiths in Europe found a way of producing wrought iron from cast iron using finery forges. All these processes required charcoal as fuel.
Cornwall Iron Furnace is a designated National Historic Landmark that is administered by the Pennsylvania Historical and Museum Commission in Cornwall, Lebanon County, Pennsylvania in the United States. The furnace was a leading Pennsylvania iron producer from 1742 until it was shut down in 1883. The furnaces, support buildings and surrounding community have been preserved as a historical site and museum, providing a glimpse into Lebanon County's industrial past. The site is the only intact charcoal-burning iron blast furnace in its original plantation in the western hemisphere. Established by Peter Grubb in 1742, Cornwall Furnace was operated during the Revolution by his sons Curtis and Peter Jr. who were major arms providers to George Washington. Robert Coleman acquired Cornwall Furnace after the Revolution and became Pennsylvania's first millionaire. Ownership of the furnace and its surroundings was transferred to the Commonwealth of Pennsylvania in 1932.
Oregrounds iron was a grade of iron that was regarded as the best grade available in 18th century England. The term was derived from the small Swedish city of Öregrund, the port from which the bar iron was shipped. It was produced using the Walloon process.
Darkhill Ironworks, and the neighbouring Titanic Steelworks, are internationally important industrial remains associated with the development of the iron and steel industries. Both are scheduled monuments. They are located on the edge of a small hamlet called Gorsty Knoll, just to the west of Parkend, in the Forest of Dean, Gloucestershire. Historically, Darkhill was sometimes written Dark Hill.
Josiah Marshall Heath was an English metallurgist, businessman and ornithologist, who invented the use of manganese to deoxidise steel. In India he learned the local steelmaking processes, including wootz, but having failed to found a profitable steel mill there he returned to England and settled in Sheffield. His patent kick-started Sheffield's steel industry, but the poor wording of his patent caused competitors not to pay him royalties, and he died in poverty.
The Darnall Works is a former steelworks in the Darnall area of Sheffield in England. The only remaining large complex of crucible furnaces, the works opened in the 1835 and were frequently extended and adapted until the late 20th century. Some of the structures at the works are listed buildings, at Grade II* and Grade II, and part of the site is a Scheduled Ancient Monument.
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