Arumugam Manthiram

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Arumugam Manthiram
Born (1951-03-15) March 15, 1951 (age 73)
Amarapuram, Tamil Nadu, India [1]
Education Madurai University (BS, MS)
Indian Institute of Technology, Madras (PhD)
Known for Lithium ion battery
Awards Fellow, American Association for the Advancement of Science (2014) [2]
Fellow, Electrochemical Society (2011) [3]
Henry B. Linford Award for Distinguished Teaching, Electrochemical Society (2020)
Fellow, Materials Research Society (2016) [4]
Distinguished Alumnus Award, Indian Institute of Technology Madras (2015)
Fellow, Royal Society of Chemistry (2015)
Scientific career
Fields Materials Science
Institutions Madurai Kamaraj University
University of Oxford
University of Texas at Austin
Doctoral advisor J. Gopalakrishnan [5]

Arumugam Manthiram (MUN-thee-rum; [6] born March 15, 1951) is an Indian-American materials scientist and engineer, best known for his identification of the polyanion class of lithium-ion battery cathodes, understanding of how chemical instability limits the capacity of layered oxide cathodes, and technological advances in lithium sulfur batteries. He is a Cockrell Family Regents Chair in engineering, Director of the Texas Materials Institute, the Director of the Materials Science and Engineering Program at the University of Texas at Austin, and a former lecturer of Madurai Kamaraj University. Manthiram delivered the 2019 Nobel Lecture in Chemistry on behalf of Chemistry Laureate John B. Goodenough. [7] [3]

Contents

Early life and education

Manthiram was born in Amarapuram, Tamil Nadu, a small village in southern India. [1] He completed his B.S. and M.S. degrees in chemistry at Madurai University. He then received his Ph.D. in chemistry from the Indian Institute of Technology, Madras.

Career

After working as a lecturer at Madurai Kamaraj University for four years, he joined John B. Goodenough's lab as a Research Associate, first at Oxford University and then at the University of Texas at Austin. Manthiram joined the faculty of the University of Texas at Austin in 1991.

Research

Manthiram identified the polyanion class of cathode materials for lithium ion batteries, which are widely used in commercial applications. [8] [9] This is a class which includes lithium iron phosphate. He demonstrated that positive electrodes containing polyanions, e.g., sulfates, produce higher voltages than oxides due to the inductive effect of the polyanion. These polyanion cathodes are also used in sodium ion batteries. [10]

Manthiram discovered that the capacity limitations of layered oxide cathodes is a result of chemical instability that can be understood based on the relative positions of the metal 3d band relative to the top of the oxygen 2p band. [11] [12] [13] This discovery represents the theoretical underpinnings of the anion-redox energy storage mechanism and has had significant implications for the practically accessible compositional space of lithium-ion batteries, as well as their stability from a safety perspective.

He has identified the critical parameters needed for transitioning lithium sulfur batteries towards commercial use. [14] [15] Specifically, lithium sulfur batteries need to achieve a sulfur loading of >5 mg cm−2, a carbon content of <5%, electrolyte-to-sulfur ratio of <5 μL mg−1, electrolyte-to-capacity ratio of <5 μL (mA h)−1, and negative-to-positive capacity ratio of <5 in pouch-type cells. [14] Key technological advances for lithium sulfur batteries developed by Manthiram include the use of microporous carbon interlayers [16] and the use of doped graphene sponge electrodes. [17]

Related Research Articles

<span class="mw-page-title-main">Electrode</span> Electrical conductor used to make contact with nonmetallic parts of a circuit

An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit. Electrodes are essential parts of batteries that can consist of a variety of materials depending on the type of battery.

<span class="mw-page-title-main">Lithium-ion battery</span> Rechargeable battery type

A lithium-ion or Li-ion battery is a type of rechargeable battery that uses the reversible intercalation of Li+ ions into electronically conducting solids to store energy. In comparison with other commercial rechargeable batteries, Li-ion batteries are characterized by higher specific energy, higher energy density, higher energy efficiency, a longer cycle life, and a longer calendar life. Also noteworthy is a dramatic improvement in lithium-ion battery properties after their market introduction in 1991: during the next 30 years, their volumetric energy density increased threefold while their cost dropped tenfold.

<span class="mw-page-title-main">John B. Goodenough</span> American materials scientist (1922–2023)

John Bannister Goodenough was an American materials scientist, a solid-state physicist, and a Nobel laureate in chemistry. From 1986 he was a professor of Materials Science, Electrical Engineering and Mechanical Engineering, at the University of Texas at Austin. He is credited with identifying the Goodenough–Kanamori rules of the sign of the magnetic superexchange in materials, with developing materials for computer random-access memory and with inventing cathode materials for lithium-ion batteries.

<span class="mw-page-title-main">Intercalation (chemistry)</span> Reversible insertion of an ion into a material with layered structure

In chemistry, intercalation is the reversible inclusion or insertion of a molecule into layered materials with layered structures. Examples are found in graphite and transition metal dichalcogenides.

<span class="mw-page-title-main">M. Stanley Whittingham</span> British-American chemist

Sir Michael Stanley Whittingham is a British-American chemist. He is a professor of chemistry and director of both the Institute for Materials Research and the Materials Science and Engineering program at Binghamton University, State University of New York. He also serves as director of the Northeastern Center for Chemical Energy Storage (NECCES) of the U.S. Department of Energy at Binghamton. He was awarded the Nobel Prize in Chemistry in 2019 alongside Akira Yoshino and John B. Goodenough.

<span class="mw-page-title-main">Lithium iron phosphate battery</span> Type of rechargeable battery

The lithium iron phosphate battery or LFP battery is a type of lithium-ion battery using lithium iron phosphate as the cathode material, and a graphitic carbon electrode with a metallic backing as the anode. Because of their low cost, high safety, low toxicity, long cycle life and other factors, LFP batteries are finding a number of roles in vehicle use, utility-scale stationary applications, and backup power. LFP batteries are cobalt-free. As of September 2022, LFP type battery market share for EVs reached 31%, and of that, 68% were from EV makers Tesla and BYD alone. Chinese manufacturers currently hold a near monopoly of LFP battery type production. With patents having started to expire in 2022 and the increased demand for cheaper EV batteries, LFP type production is expected to rise further and surpass lithium nickel manganese cobalt oxides (NMC) type batteries in 2028.

<span class="mw-page-title-main">History of the battery</span> History of electricity source

Batteries provided the primary source of electricity before the development of electric generators and electrical grids around the end of the 19th century. Successive improvements in battery technology facilitated major electrical advances, from early scientific studies to the rise of telegraphs and telephones, eventually leading to portable computers, mobile phones, electric cars, and many other electrical devices.

<span class="mw-page-title-main">Lithium iron phosphate</span> Chemical compound

Lithium iron phosphate or lithium ferro-phosphate (LFP) is an inorganic compound with the formula LiFePO
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<span class="mw-page-title-main">Lithium–sulfur battery</span> Type of rechargeable battery

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<span class="mw-page-title-main">Sodium-ion battery</span> Type of rechargeable battery

Sodium-ion batteries (NIBs, SIBs, or Na-ion batteries) are several types of rechargeable batteries, which use sodium ions (Na+) as their charge carriers. In some cases, its working principle and cell construction are similar to those of lithium-ion battery (LIB) types, but it replaces lithium with sodium as the intercalating ion. Sodium belongs to the same group in the periodic table as lithium and thus has similar chemical properties. However, in some cases, such as aqueous batteries, SIBs can be quite different from LIBs.

<span class="mw-page-title-main">Akira Yoshino</span> Japanese chemist (born 1948)

Akira Yoshino is a Japanese chemist. He is a fellow of Asahi Kasei Corporation and a professor at Meijo University in Nagoya. He created the first safe, production-viable lithium-ion battery, which became used widely in cellular phones and notebook computers. Yoshino was awarded the Nobel Prize in Chemistry in 2019 alongside M. Stanley Whittingham and John B. Goodenough.

Research in lithium-ion batteries has produced many proposed refinements of lithium-ion batteries. Areas of research interest have focused on improving energy density, safety, rate capability, cycle durability, flexibility, and reducing cost.

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A magnesium sulfur battery is a rechargeable battery that uses magnesium ion as its charge carrier, magnesium metal as anode and sulfur as cathode. To increase the electronic conductivity of cathode, sulfur is usually mixed with carbon to form a cathode composite. Magnesium sulfur battery is an emerging energy storage technology and now is still in the stage of research. It is of great interest since in theory the Mg/S chemistry can provide 1722 Wh/kg energy density with a voltage at ~1.7 V.

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<span class="mw-page-title-main">Lithium nickel manganese cobalt oxides</span> Lithium-ion battery cathode material

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References

  1. 1 2 "Professor Arumugam Manthiram Delivered the Nobel Prize Lecture". Dinamalar . Archived from the original on May 24, 2022.
  2. ↑ "Arumugam Manthiram Elected as a Fellow of AAAS". Texas Materials Institute .
  3. 1 2 "Manthiram Presents Goodenough's Nobel Lecture". Electrochemical Society . 13 December 2019.
  4. ↑ "Three Indian American Professors Named 2016 Materials Research Society Fellows". India West .
  5. ↑ "Arumugam Manthiram". Chemistry Tree .
  6. ↑ Arumugam Manthiram, Challenges and Opportunities of Electrical Energy Storage Technologies) on YouTube
  7. ↑ "John B. Goodenough Nobel Lecture". Nobel Prize .
  8. ↑ Manthiram, A.; Goodenough, J. B. (1989). "Lithium insertion into Fe2(SO4)3 frameworks". Journal of Power Sources. 26 (3–4): 403–408. Bibcode:1989JPS....26..403M. doi:10.1016/0378-7753(89)80153-3.
  9. ↑ Manthiram, A.; Goodenough, J. B. (1987). "Lithium insertion into Fe2(MO4)3 frameworks: Comparison of M = W with M = Mo". Journal of Solid State Chemistry. 71 (2): 349–360. Bibcode:1987JSSCh..71..349M. doi: 10.1016/0022-4596(87)90242-8 .
  10. ↑ Masquelier, Christian; Croguennec, Laurence (2013). "Polyanionic (Phosphates, Silicates, Sulfates) Frameworks as Electrode Materials for Rechargeable Li (or Na) Batteries". Chemical Reviews. 113 (8): 6552–6591. doi:10.1021/cr3001862. PMID   23742145.
  11. ↑ Chebiam, R. V.; Kannan, A. M.; Prado, F.; Manthiram, A. (2001). "Comparison of the chemical stability of the high energy density cathodes of lithium-ion batteries". Electrochemistry Communications. 3 (11): 624–627. doi:10.1016/S1388-2481(01)00232-6.
  12. ↑ Chebiam, R. V.; Prado, F.; Manthiram, A. (2001). "Soft Chemistry Synthesis and Characterization of Layered Li1−xNi1−yCoyO2−δ (0 ≤ x ≤ 1 and 0 ≤ y ≤ 1)". Chemistry of Materials. 13: 2951–2957. doi:10.1021/cm0102537.
  13. ↑ Manthiram, Arumugam (2020). "A reflection on lithium-ion battery cathode chemistry". Nature Communications. 11 (1): 1550. Bibcode:2020NatCo..11.1550M. doi: 10.1038/s41467-020-15355-0 . PMC   7096394 . PMID   32214093.
  14. 1 2 Bhargav, Amruth; Jiarui, He (2020). "Lithium-Sulfur Batteries: Attaining the Critical Metrics". Joule. 4 (2): 285–291. doi: 10.1016/j.joule.2020.01.001 .
  15. ↑ Manthiram, Arumugam; Fu, Yongzhu; Chung, Sheng-Heng; Zu, Chenxi; Su, Yu-Sheng (2014). "Rechargeable Lithium–Sulfur Batteries". Chemical Reviews. 114 (23): 11751–11787. doi:10.1021/cr500062v. PMID   25026475.
  16. ↑ Su, Yu-Sheng; Manthiram, Arumugam (2012). "Lithium–sulphur batteries with a microporous carbon paper as a bifunctional interlayer". Nature Communications. 3: 1166. Bibcode:2012NatCo...3.1166S. doi: 10.1038/ncomms2163 . PMID   23132016.
  17. ↑ Zhou, Guangmin; Paek, Eunsu; Hwang, Gyeong; Manthiram, Arumugam (2015). "Long-life Li/polysulphide batteries with high sulphur loading enabled by lightweight three-dimensional nitrogen/sulphur codoped graphene sponge". Nature Communications. 6: 7760. Bibcode:2015NatCo...6.7760Z. doi: 10.1038/ncomms8760 . PMC   4518288 . PMID   26182892.
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