Bernard Raveau

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Bernard Raveau, born in 1940, is a French researcher in materials science, professor emeritus at the University of Caen Normandy, member of the French Academy of sciences. [1]

Contents

Biography

He has directed CRISMAT, a joint laboratory of the National Engineering School of Caen (ENSICAEN) of the University of Caen and the CNRS.

He worked on cuprates, [2] with the aim of making them electrodes of capacitors resistant to oxidation due to sintering, without noble metals. Karl Alexander Müller and Johannes Georg Bednorz have shown that some of these compounds are superconductors, [3] beginning the aerea of high temperature superconductors. They were awarded the Nobel Prize in Physics in 1987, after having reused a "sandwich" of copper oxide sheets designed by Bernard Raveau and his laboratory in Caen. [4]

Scientific work

Bernard Raveau is a specialist in the crystallochemistry of transition metal oxides. He has devoted a large part of his research to solid-state chemistry and materials science.

Bernard Raveau discovered new tunnel structures and explained non-stop stoichiometry phenomena.

He then focused on the discovery of original structures with new physical or chemical properties, Bernard Raveau discovered new series of cuprates with a layered structure based on bismuth or thallium, or mercury associated with an alkaline earth cation, which are new superconducting materials at high critical temperature.

Bernard Raveau showed the colossal magnetoresistance (CMR) effect in insulating manganites, in small-sized A cation manganites doped with n, and discovered the CMR effect induced by doping manganese sites with different cations such as cobalt, nickel, chromium, strontium, ruthenium. This work could have developments in information storage processes. Finally, Bernard Raveau has identified cobaltites with a disjointed structure (misfits) whose remarkable thermoelectric properties are well studied for energy conversion at high temperatures.

Distinctions

He was awarded Chevalier de la Légion d'honneur in 2001. [5]

He was awarded the title of Fellow of the Royal Society of Chemistry on 25 March 2009 for his work in materials science.

Books

Related Research Articles

<span class="mw-page-title-main">Superconductivity</span> Electrical conductivity with exactly zero resistance

Superconductivity is a set of physical properties observed in certain materials where electrical resistance vanishes and magnetic fields are expelled from the material. Any material exhibiting these properties is a superconductor. Unlike an ordinary metallic conductor, whose resistance decreases gradually as its temperature is lowered, even down to near absolute zero, a superconductor has a characteristic critical temperature below which the resistance drops abruptly to zero. An electric current through a loop of superconducting wire can persist indefinitely with no power source.

Unconventional superconductors are materials that display superconductivity which does not conform to conventional BCS theory or its extensions.

<span class="mw-page-title-main">High-temperature superconductivity</span> Superconductive behavior at temperatures much higher than absolute zero

High-temperature superconductors are defined as materials with critical temperature above 77 K, the boiling point of liquid nitrogen. They are only "high-temperature" relative to previously known superconductors, which function at even colder temperatures, close to absolute zero. The "high temperatures" are still far below ambient, and therefore require cooling. The first break through of high-temperature superconductor was discovered in 1986 by IBM researchers Georg Bednorz and K. Alex Müller. Although the critical temperature is around 35.1 K, this new type of superconductor was readily modified by Ching-Wu Chu to make the first high-temperature superconductor with critical temperature 93 K. Bednorz and Müller were awarded the Nobel Prize in Physics in 1987 "for their important break-through in the discovery of superconductivity in ceramic materials". Most high-Tc materials are type-II superconductors.

<span class="mw-page-title-main">Yttrium barium copper oxide</span> Chemical compound

Yttrium barium copper oxide (YBCO) is a family of crystalline chemical compounds that display high-temperature superconductivity; it includes the first material ever discovered to become superconducting above the boiling point of liquid nitrogen [77 K ] at about 93 K.

Cuprates are a class of compounds that contain copper (Cu). They can be broadly categorized into two main types:

<span class="mw-page-title-main">History of superconductivity</span>

Superconductivity is the phenomenon of certain materials exhibiting zero electrical resistance and the expulsion of magnetic fields below a characteristic temperature. The history of superconductivity began with Dutch physicist Heike Kamerlingh Onnes's discovery of superconductivity in mercury in 1911. Since then, many other superconducting materials have been discovered and the theory of superconductivity has been developed. These subjects remain active areas of study in the field of condensed matter physics.

<span class="mw-page-title-main">Bismuth strontium calcium copper oxide</span> Family of high-temperature superconductors

Bismuth strontium calcium copper oxide (BSCCO, pronounced bisko), is a type of cuprate superconductor having the generalized chemical formula Bi2Sr2Can−1CunO2n+4+x, with n = 2 being the most commonly studied compound (though n = 1 and n = 3 have also received significant attention). Discovered as a general class in 1988, BSCCO was the first high-temperature superconductor which did not contain a rare-earth element.

<span class="mw-page-title-main">Georg Bednorz</span> German physicist

Johannes Georg Bednorz is a German physicist who, together with K. Alex Müller, discovered high-temperature superconductivity in ceramics, for which they shared the 1987 Nobel Prize in Physics.

<span class="mw-page-title-main">K. Alex Müller</span> Swiss physicist and Nobel laureate (1927–2023)

Karl Alexander Müller was a Swiss physicist and Nobel laureate. He received the Nobel Prize in Physics in 1987 with Georg Bednorz for their work in superconductivity in ceramic materials.

Cuprate superconductors are a family of high-temperature superconducting materials made of layers of copper oxides (CuO2) alternating with layers of other metal oxides, which act as charge reservoirs. At ambient pressure, cuprate superconductors are the highest temperature superconductors known. However, the mechanism by which superconductivity occurs is still not understood.

<span class="mw-page-title-main">Iron-based superconductor</span>

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In chemistry, oxypnictides are a class of materials composed of oxygen, a pnictogen and one or more other elements. Although this group of compounds has been recognized since 1995, interest in these compounds increased dramatically after the publication of the superconducting properties of LaOFeP and LaOFeAs which were discovered in 2006 and 2008. In these experiments the oxide was partly replaced by fluoride.

<span class="mw-page-title-main">Lanthanum barium copper oxide</span> High temperature superconductor

Lanthanum barium copper oxide, or LBCO, is an inorganic compound with the formula CuBa0.15La1.85O4. It is a black solid produced by heating an intimate mixture of barium oxide, copper(II) oxide, and lanthanum oxide in the presence of oxygen. The material was discovered in 1986 and was the first high temperature superconductor. Johannes Georg Bednorz and K. Alex Müller shared the 1987 Nobel Prize in physics for the discovery that this material exhibits superconductivity at the then unusually high temperature. This finding led to intense and fruitful efforts to generate other cuprate superconductors.

Superstripes is a generic name for a phase with spatial broken symmetry that favors the onset of superconducting or superfluid quantum order. This scenario emerged in the 1990s when non-homogeneous metallic heterostructures at the atomic limit with a broken spatial symmetry have been found to favor superconductivity. Before a broken spatial symmetry was expected to compete and suppress the superconducting order. The driving mechanism for the amplification of the superconductivity critical temperature in superstripes matter has been proposed to be the shape resonance in the energy gap parameters ∆n that is a type of Fano resonance for coexisting condensates.

<span class="mw-page-title-main">Laura Greene (physicist)</span> American physics professor

Laura H. Greene is the Marie Krafft Professor of Physics at Florida State University and chief scientist at the National High Magnetic Field Laboratory. She was previously a professor of physics at the University of Illinois at Urbana-Champaign. In September 2021, she was appointed to the President's Council of Advisors on Science and Technology (PCAST).

LSAT is the most common name for the inorganic compound lanthanum aluminate - strontium aluminium tantalate, which has the chemical formula (LaAlO3)0.3(Sr2TaAlO6)0.7 or its less common alternative: (La0.18Sr0.82)(Al0.59Ta0.41)O3. LSAT is a hard, optically transparent oxide of the elements lanthanum, aluminium, strontium and tantalum. LSAT has the perovskite crystal structure, and its most common use is as a single crystal substrate for the growth of epitaxial thin films.

Akhoury Purnendu Bhusan Sinha is an Indian solid state chemist and a former head of the Physical Chemistry Division of the National Chemical Laboratory, Pune. He is known for his theories on semiconductors and his studies on synthesis of manganites. He is an elected fellow of the Indian National Science Academy and the Indian Academy of Sciences. The Council of Scientific and Industrial Research, the apex agency of the Government of India for scientific research, awarded Sinha the Shanti Swarup Bhatnagar Prize for Science and Technology, one of the highest Indian science awards, in 1972, for his contributions to chemical sciences.

<span class="mw-page-title-main">Thomas Maurice Rice</span>

Thomas Maurice Rice, known professionally as Maurice Rice, is an Irish theoretical physicist specializing in condensed matter physics.

John F. Mitchell is an American chemist and researcher. He is the deputy director of the materials science division at the U.S. Department of Energy's (DOE) Argonne National Laboratory and leads Argonne's Emerging Materials Group.

<span class="mw-page-title-main">Lanthanum cuprate</span> Chemical compound

Lanthanum cuprate usually refers to the inorganic compound with the formula CuLa2O4. The name implies that the compound consists of a cuprate (CuOn]2n-) salt of lanthanum (La3+). In fact it is a highly covalent solid. It is prepared by high temperature reaction of lanthanum oxide and copper(II) oxide follow by annealing under oxygen.

References

  1. "Académie des sciences".
  2. L. ER Rakho, C. Michel, J. Provost et B. Raveau, « A series of oxygen-defect perovskites containing CuII and CuIII: The oxides La
    3−x
    Ln
    x
    Ba
    3
    [CuII
    5−2y
    CuIII
    1+2y
    ]O
    14+y
     », J. Solid State Chem., vol. 37, no 2, avril 1981, p. 151–156 (DOI 10.1016/0022-4596(81)90080-3)
  3. Johannes Georg Bednorz et Karl Alexander Müller, « Possible High Tc Superconductivity in the Ba-La-Cu-O System », Z. Phys. B Condens. Matter, vol. 64, no 2, 1986, p. 189–193 (DOI 10.1007/BF01303701)
  4. Azar Khalatbari,« Bernard Raveau, 57 ans, invente les matériaux du futur à l'université de Caen. Mais il reste surtout celui qui aurait pu partager le Nobel de physique en 1987. Ce chercheur n'a pas de prix. », Libération , 12 mai 1998, lire en ligne
  5. "C.V. de Bernard Raveau" (PDF). Académie des sciences. Archived from the original (PDF) on 27 October 2014. Retrieved 7 May 2011.