Brent Fultz

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Brent Fultz
Brent Fultz.png
Brent Fultz presenting at the William Hume-Rothery Award Lecture
Nationality American
Alma mater University of California, Berkeley (Ph.D., 1982)
Massachusetts Institute of Technology (B.Sc., 1975)
Scientific career
Fields Materials Science
Applied physics
Statistical Mechanics
Institutions California Institute of Technology
Doctoral advisor John. W. Morris

Brent Fultz is an American physicist and materials scientist and one of the world's leading authorities on statistical mechanics, diffraction, and phase transitions in materials. Fultz is the Barbara and Stanley Rawn Jr. Professor of Applied Physics and Materials Science at the California Institute of Technology. [1] He is known for his research in materials physics and materials chemistry, and for establishing the importance of phonon entropy to the phase stability of materials. [2] Additionally, Fultz oversaw the construction of the wide angular-range chopper spectrometer (ARCS) instrument at the Spallation Neutron Source [3] and has made advances in phonon measuring techniques. [2]

Contents

He is the author of two graduate level textbooks, Transmission Electron Microscopy and Diffractometry of Materials (with James M. Howe, Springer, 2001; 4th ed., 2013) on diffractometry of materials, [4] [5] and Phase Transitions in Materials (Cambridge University Press, 2014) on phase transitions in materials. [6]

Early life and career

Brent Fultz completed his undergraduate studies in physics at MIT in 1975, before earning his doctorate in engineering science from the University of California, Berkeley in 1982 where he studied under the advisement of John William Morris. [7] His early career was marked by his designation as a Presidential Young Investigator and his receipt of the IBM Faculty Development Award and a Jacob Wallenberg Scholarship. Fultz then worked as a scientist at Lawrence Berkeley Laboratory before becoming a professor of materials science at the California Institute of Technology (Caltech) in 1985.

Fultz's academic contributions were acknowledged through multiple recognitions, such as the TMS EMPMD Distinguished Scientist Award in 2010 and the William Hume-Rothery Award from TMS in 2016. [8] His work in the field of neutron scattering also earned him a fellowship from the Neutron Scattering Society of America in 2016. His accomplishments further include membership in the Society of Sigma Xi in 2017, a fellowship from the American Physical Society in 2017, a fellowship from TMS in 2018, and recognition as an "Outstanding Referee" by the American Physical Society in 2019. [9] [10]

He has played an advisory role for the Advanced Photon Source and the Spallation Neutron Source. His expertise in material sciences also led to consulting roles with Everett Charles Technologies, the Defense Science Board, and for firms like Actium Materials, Contour Energy, and the Materials Project. He has written or co-authored close to 400 papers.

In collaboration with his colleague, Prof. J. Howe from the University of Virginia, Fultz produced an advanced textbook on the subject of material diffraction and microscopy, which has now seen four editions in English and one in Russian, with a Chinese translation in progress. [11] More recently, Fultz developed a graduate-level textbook on material phase transitions, which integrates ideas from both traditional material sciences and condensed-matter physics. [12]

Research

Brent Fultz at the TMS-AIME Awards Ceremony Brent Fultz.jpg
Brent Fultz at the TMS-AIME Awards Ceremony

Brent Fultz's research delves into understanding the behavior of atoms within solids, particularly how their vibrations, or phonons, influence the entropy and free energy of materials. He employs inelastic neutron scattering techniques to examine these atomic vibrations, which are a primary source of entropy in solids. [13] The thermodynamic significance of magnetic and electronic excitations within solids, which are also detected by this method, forms another aspect of his study. His recent work emphasizes the interactions between phonons and electronic excitations across a wide range of temperatures, and how the entropy changes with varying temperature and pressure conditions. [14]

Modern computational methods, specifically density functional theory, play a key role in Fultz's research on phonons and electrons in solids. His team uses ab initio molecular dynamics to computationally investigate phonons and electron excitations at high temperatures. [15] In addition, they use high-resolution inelastic x-ray scattering to examine how vibrational thermodynamics change under high pressures, as might be experienced in a diamond anvil cell. [16]

Fultz's work also addresses the pressing global energy problem. His team is researching materials capable of storing lithium (used in rechargeable batteries) and hydrogen. [17] [18] They aim to understand how hydrogen molecules interact with surfaces and how new materials can optimize hydrogen storage. Furthermore, they are exploring the potential of using nuclear resonant scattering to study atomic distortions in materials as an electron moves between adjacent ions under pressure. Fultz's work (which often leans more towards quantum mechanics than classical mechanics, and statistical mechanics over classical thermodynamics) focuses on the position of atoms, especially in disordered materials, and how atoms vibrate or transfer electrons during bonding.

Fultz's team broke new ground by investigating the entropy of materials, specifically how variances in crystal structure, chemical composition, or local atomic arrangements might impact the vibrational spectrum and, in turn, the entropy. [14] [19] Over time, this research led to a recognition that such details of vibrational entropy significantly influence the thermodynamic stability of materials. [20] Fultz's team also undertakes numerous experiments at national facilities providing high-intensity x-ray or neutron beams. [13] This has led to collaborations with scientists from these national neutron sources. A notable accomplishment in this area was Fultz's leadership in building a cutting-edge neutron scattering instrument, the wide angular-range chopper spectrometer (ARCS) instrument at the Spallation Neutron Source. Along with this came the opportunity for novel scientific computing projects, such as the Distributed Data Analysis for Neutron Scattering Experiments (DANSE) initiative.

Awards

Related Research Articles

In condensed matter physics and materials science, an amorphous solid is a solid that lacks the long-range order that is characteristic of a crystal. The terms "glass" and "glassy solid" are sometimes used synonymously with amorphous solid; however, these terms refer specifically to amorphous materials that undergo a glass transition. Examples of amorphous solids include glasses, metallic glasses, and certain types of plastics and polymers.

<span class="mw-page-title-main">Condensed matter physics</span> Branch of physics

Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid phases that arise from electromagnetic forces between atoms and electrons. More generally, the subject deals with condensed phases of matter: systems of many constituents with strong interactions among them. More exotic condensed phases include the superconducting phase exhibited by certain materials at extremely low cryogenic temperatures, the ferromagnetic and antiferromagnetic phases of spins on crystal lattices of atoms, the Bose–Einstein condensates found in ultracold atomic systems, and liquid crystals. Condensed matter physicists seek to understand the behavior of these phases by experiments to measure various material properties, and by applying the physical laws of quantum mechanics, electromagnetism, statistical mechanics, and other physics theories to develop mathematical models and predict the properties of extremely large groups of atoms.

<span class="mw-page-title-main">Crystallography</span> Scientific study of crystal structures

Crystallography is the experimental science of determining the arrangement of atoms in crystalline solids. Crystallography is a fundamental subject in the fields of materials science and solid-state physics. The word crystallography is derived from the Ancient Greek word κρύσταλλος, with its meaning extending to all solids with some degree of transparency, and γράφειν. In July 2012, the United Nations recognised the importance of the science of crystallography by proclaiming that 2014 would be the International Year of Crystallography.

<span class="mw-page-title-main">Melting</span> Material phase change

Melting, or fusion, is a physical process that results in the phase transition of a substance from a solid to a liquid. This occurs when the internal energy of the solid increases, typically by the application of heat or pressure, which increases the substance's temperature to the melting point. At the melting point, the ordering of ions or molecules in the solid breaks down to a less ordered state, and the solid melts to become a liquid.

<span class="mw-page-title-main">Spectroscopy</span> Study involving matter and electromagnetic radiation

Spectroscopy is the field of study that measures and interprets electromagnetic spectra. In narrower contexts, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum.

The Mössbauer effect, or recoilless nuclear resonance fluorescence, is a physical phenomenon discovered by Rudolf Mössbauer in 1958. It involves the resonant and recoil-free emission and absorption of gamma radiation by atomic nuclei bound in a solid. Its main application is in Mössbauer spectroscopy.

<span class="mw-page-title-main">Photoluminescence</span> Light emission from substances after they absorb photons

Photoluminescence is light emission from any form of matter after the absorption of photons. It is one of many forms of luminescence and is initiated by photoexcitation, hence the prefix photo-. Following excitation, various relaxation processes typically occur in which other photons are re-radiated. Time periods between absorption and emission may vary: ranging from short femtosecond-regime for emission involving free-carrier plasma in inorganic semiconductors up to milliseconds for phosphoresence processes in molecular systems; and under special circumstances delay of emission may even span to minutes or hours.

<span class="mw-page-title-main">Surface science</span> Study of physical and chemical phenomena that occur at the interface of two phases

Surface science is the study of physical and chemical phenomena that occur at the interface of two phases, including solid–liquid interfaces, solid–gas interfaces, solid–vacuum interfaces, and liquid–gas interfaces. It includes the fields of surface chemistry and surface physics. Some related practical applications are classed as surface engineering. The science encompasses concepts such as heterogeneous catalysis, semiconductor device fabrication, fuel cells, self-assembled monolayers, and adhesives. Surface science is closely related to interface and colloid science. Interfacial chemistry and physics are common subjects for both. The methods are different. In addition, interface and colloid science studies macroscopic phenomena that occur in heterogeneous systems due to peculiarities of interfaces.

<span class="mw-page-title-main">Electron energy loss spectroscopy</span> Form of microscopy using an electron beam

Electron energy loss spectroscopy (EELS) is a form of electron microscopy in which a material is exposed to a beam of electrons with a known, narrow range of kinetic energies. Some of the electrons will undergo inelastic scattering, which means that they lose energy and have their paths slightly and randomly deflected. The amount of energy loss can be measured via an electron spectrometer and interpreted in terms of what caused the energy loss. Inelastic interactions include phonon excitations, inter- and intra-band transitions, plasmon excitations, inner shell ionizations, and Cherenkov radiation. The inner-shell ionizations are particularly useful for detecting the elemental components of a material. For example, one might find that a larger-than-expected number of electrons comes through the material with 285 eV less energy than they had when they entered the material. This is approximately the amount of energy needed to remove an inner-shell electron from a carbon atom, which can be taken as evidence that there is a significant amount of carbon present in the sample. With some care, and looking at a wide range of energy losses, one can determine the types of atoms, and the numbers of atoms of each type, being struck by the beam. The scattering angle can also be measured, giving information about the dispersion relation of whatever material excitation caused the inelastic scattering.

<span class="mw-page-title-main">Neutron diffraction</span> Technique to investigate atomic structures using neutron scattering

Neutron diffraction or elastic neutron scattering is the application of neutron scattering to the determination of the atomic and/or magnetic structure of a material. A sample to be examined is placed in a beam of thermal or cold neutrons to obtain a diffraction pattern that provides information of the structure of the material. The technique is similar to X-ray diffraction but due to their different scattering properties, neutrons and X-rays provide complementary information: X-Rays are suited for superficial analysis, strong x-rays from synchrotron radiation are suited for shallow depths or thin specimens, while neutrons having high penetration depth are suited for bulk samples.

<span class="mw-page-title-main">Raman scattering</span> Inelastic scattering of photons by matter

In physics, Raman scattering or the Raman effect is the inelastic scattering of photons by matter, meaning that there is both an exchange of energy and a change in the light's direction. Typically this effect involves vibrational energy being gained by a molecule as incident photons from a visible laser are shifted to lower energy. This is called normal Stokes-Raman scattering.

In condensed matter physics, a quasiparticle is a concept used to describe a collective behavior of a group of particles that can be treated as if they were a single particle. Formally, quasiparticles and collective excitations are closely related phenomena that arise when a microscopically complicated system such as a solid behaves as if it contained different weakly interacting particles in vacuum.

<span class="mw-page-title-main">Powder diffraction</span>

Powder diffraction is a scientific technique using X-ray, neutron, or electron diffraction on powder or microcrystalline samples for structural characterization of materials. An instrument dedicated to performing such powder measurements is called a powder diffractometer.

The glass–liquid transition, or glass transition, is the gradual and reversible transition in amorphous materials from a hard and relatively brittle "glassy" state into a viscous or rubbery state as the temperature is increased. An amorphous solid that exhibits a glass transition is called a glass. The reverse transition, achieved by supercooling a viscous liquid into the glass state, is called vitrification.

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Ondrej L. Krivanek is a Czech/British physicist resident in the United States, and a leading developer of electron-optical instrumentation. He won the Kavli Prize for Nanoscience in 2020 for his substantial innovations in atomic resolution electron microscopy.

Heat transfer physics describes the kinetics of energy storage, transport, and energy transformation by principal energy carriers: phonons, electrons, fluid particles, and photons. Heat is energy stored in temperature-dependent motion of particles including electrons, atomic nuclei, individual atoms, and molecules. Heat is transferred to and from matter by the principal energy carriers. The state of energy stored within matter, or transported by the carriers, is described by a combination of classical and quantum statistical mechanics. The energy is different made (converted) among various carriers. The heat transfer processes are governed by the rates at which various related physical phenomena occur, such as the rate of particle collisions in classical mechanics. These various states and kinetics determine the heat transfer, i.e., the net rate of energy storage or transport. Governing these process from the atomic level to macroscale are the laws of thermodynamics, including conservation of energy.

<span class="mw-page-title-main">Helium cryogenics</span>

In the field of cryogenics, helium [He] is utilized for a variety of reasons. The combination of helium’s extremely low molecular weight and weak interatomic reactions yield interesting properties when helium is cooled below its critical temperature of 5.2 K to form a liquid. Even at absolute zero (0K), helium does not condense to form a solid under ambient pressure. In this state, the zero point vibrational energies of helium are comparable to very weak interatomic binding interactions, thus preventing lattice formation and giving helium its fluid characteristics. Within this liquid state, helium has two phases referred to as helium I and helium II. Helium I displays thermodynamic and hydrodynamic properties of classical fluids, along with quantum characteristics. However, below its lambda point of 2.17 K, helium transitions to He II and becomes a quantum superfluid with zero viscosity.

Stephen E. Nagler is a Canadian condensed matter and materials science physicist. Nagler is the Corporate Research Fellow of the Oak Ridge National Laboratory (ORNL) and the Director of the laboratory's Quantum Condensed Matter Division. He is an adjunct professor with the Department of Physics at the University of Tennessee.

Gen Shirane was a Japanese-American experimental solid-state physicist, known for his investigations using neutron scattering as a probe of solids. He lived most of his life in the USA.

<span class="mw-page-title-main">Giorgio Benedek</span> Italian physicist

Giorgio Benedek is an Italian physicist, academic and researcher. He is an Emeritus Professor of Physics of Matter at University of Milano-Bicocca and Director of the International School of Solid State Physics at Ettore Majorana Foundation and Centre for Scientific Culture.

References

  1. Brent Fultz faculty page
  2. 1 2 3 TMS Awards, accessed 2017-08-22
  3. 1 2 Robinson, Lynne (January 31, 2011), "The Scientific Journey of Brent Fultz", Tech News Headlines, JOM: The Member Journal of the Minerals, Metals & Materials Society
  4. Review of Transmission Electron Microscopy and Diffractometry of Materials by John Hutchison (2001), Journal of Microsopy 204 (3): 263–264, doi : 10.1046/j.1365-2818.2001.00962-2.x
  5. Review of Transmission Electron Microscopy and Diffractometry of Materials by Douglas L. Dorset (202), Journal of Applied Crystallography 35 (1): 145–146, doi : 10.1107/S0021889801020532
  6. Review of Phase Transition in Materials by A. M. Glazer (2015), Acta Crystallographica B 71 (1): 122–123, doi : 10.1107/S205252061500075X
  7. "Brent Fultz | Division of Engineering and Applied Science". www.eas.caltech.edu. Retrieved 2023-06-19.
  8. "CMU MSE Seminar: Brent Fultz (California Institute of Technology) | Physics & Astronomy | University of Pittsburgh". www.physicsandastronomy.pitt.edu. Retrieved 2023-06-19.
  9. "Member Directory". www.sigmaxi.org. Retrieved 2023-06-19.
  10. "Brent Fultz, California Institute of Technology • Expertise Finder Network". network.expertisefinder.com. Retrieved 2023-06-19.
  11. Fultz, Brent; Howe, James M. (2012-10-14). Transmission Electron Microscopy and Diffractometry of Materials. Springer Science & Business Media. ISBN   978-3-642-29760-1.
  12. Fultz, Brent (2020-05-14). Phase Transitions in Materials. Cambridge University Press. ISBN   978-1-108-48578-4.
  13. 1 2 "Fultz Group Home". www.its.caltech.edu. Retrieved 2023-06-19.
  14. 1 2 Fultz, Brent (2010-05-01). "Vibrational thermodynamics of materials" (PDF). Progress in Materials Science. 55 (4): 247–352. doi:10.1016/j.pmatsci.2009.05.002. ISSN   0079-6425.
  15. Keith, J Brandon; Wang, Hao; Fultz, Brent; Lewis, James P (2007-12-06). "Ab initiofree energy of vacancy formation and mass-action kinetics in vis-active TiO2". Journal of Physics: Condensed Matter. 20 (2): 022202. doi:10.1088/0953-8984/20/02/022202. ISSN   0953-8984. S2CID   8977228.
  16. Tracy, S. J.; Mauger, L.; Tan, H. J.; Muñoz, J. A.; Xiao, Yuming; Fultz, B. (2014-09-12). "Polaron-ion correlations in ${\mathrm{Li}}_{x}{\mathrm{FePO}}_{4}$ studied by x-ray nuclear resonant forward scattering at elevated pressure and temperature". Physical Review B. 90 (9): 094303. doi: 10.1103/PhysRevB.90.094303 .
  17. Graetz, J.; Ahn, C. C.; Yazami, R.; Fultz, B. (2003). "Highly Reversible Lithium Storage in Nanostructured Silicon". Electrochemical and Solid-State Letters. 6 (9): A194. doi:10.1149/1.1596917. ISSN   1099-0062.
  18. Stadie, Nicholas P.; Vajo, John J.; Cumberland, Robert W.; Wilson, Andrew A.; Ahn, Channing C.; Fultz, Brent (2012-06-19). "Zeolite-Templated Carbon Materials for High-Pressure Hydrogen Storage". Langmuir. 28 (26): 10057–10063. doi:10.1021/la302050m. ISSN   0743-7463. PMID   22686576. S2CID   13027542.
  19. Hamdeh, H. H.; Okamoto, J.; Fultz, B. (1990-10-01). "Temperature dependence of hyperfine magnetic fields in Fe-Co alloys" (PDF). Physical Review B. 42 (10): 6694–6696. doi:10.1103/PhysRevB.42.6694. PMID   9994758.
  20. Fultz, Brent (2010). "Vibrational thermodynamics of materials". Progress in Materials Science. 55 (4): 247–352. doi:10.1016/j.pmatsci.2009.05.002. ISSN   0079-6425.
  21. NSSA Fellows, accessed 2017-08-22
  22. Professor Fultz Elected APS Fellow, accessed 2018-04-23
  23. Professor Fultz Named TMS Fellow, accessed 2018-04-23
  24. "Physical Review Journals - Outstanding Referees". journals.aps.org. Retrieved 2023-06-19.