Calcium aluminates are a range of materials [2] obtained by heating calcium oxide and aluminium oxide together at high temperatures. They are encountered in the manufacture of refractories and cements.
The stable phases shown in the phase diagram (formed at atmospheric pressure under an atmosphere of normal humidity) are:
In addition, other phases include:
In contrast to Portland cements, calcium aluminates do not release calcium hydroxide (Ca(OH)2) portlandite or lime during their hydration.
A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel (aggregate) together. Cement mixed with fine aggregate produces mortar for masonry, or with sand and gravel, produces concrete. Concrete is the most widely used material in existence and is behind only water as the planet's most-consumed resource.
Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula Al2O3. It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly called alumina and may also be called aloxide, aloxite, or alundum in various forms and applications. It occurs naturally in its crystalline polymorphic phase α-Al2O3 as the mineral corundum, varieties of which form the precious gemstones ruby and sapphire. Al2O3 is used to produce aluminium metal, as an abrasive owing to its hardness, and as a refractory material owing to its high melting point.
Cement chemist notation (CCN) was developed to simplify the formulas cement chemists use on a daily basis. It is a shorthand way of writing the chemical formula of oxides of calcium, silicon, and various metals.
In chemistry, an aluminate is a compound containing an oxyanion of aluminium, such as sodium aluminate. In the naming of inorganic compounds, it is a suffix that indicates a polyatomic anion with a central aluminium atom.
Dicalcium phosphate is the calcium phosphate with the formula CaHPO4 and its dihydrate. The "di" prefix in the common name arises because the formation of the HPO42– anion involves the removal of two protons from phosphoric acid, H3PO4. It is also known as dibasic calcium phosphate or calcium monohydrogen phosphate. Dicalcium phosphate is used as a food additive, it is found in some toothpastes as a polishing agent and is a biomaterial.
Aluminum silicate (or aluminium silicate) is a name commonly applied to chemical compounds which are derived from aluminium oxide, Al2O3 and silicon dioxide, SiO2 which may be anhydrous or hydrated, naturally occurring as minerals or synthetic. Their chemical formulae are often expressed as xAl2O3·ySiO2·zH2O. It is known as E number E559.
Ettringite is a hydrous calcium aluminium sulfate mineral with formula: Ca6Al2(SO4)3(OH)12·26H2O. It is a colorless to yellow mineral crystallizing in the trigonal system. The prismatic crystals are typically colorless, turning white on partial dehydration. It is part of the ettringite-group which includes other sulfates such as thaumasite and bentorite.
Ye'elimite is the naturally occurring form of anhydrous calcium sulfoaluminate, Ca
4(AlO
2)
6SO
4. It gets its name from Har Ye'elim in Israel in the Hatrurim Basin west of the Dead Sea where it was first found in nature by Shulamit Gross, an Israeli mineralogist and geologist who studied the Hatrurim Formation.
Belite is an industrial mineral important in Portland cement manufacture. Its main constituent is dicalcium silicate, Ca2SiO4, sometimes formulated as 2 CaO · SiO2 (C2S in cement chemist notation).
Tricalcium aluminate Ca3Al2O6, often formulated as 3CaO·Al2O3 to highlight the proportions of the oxides from which it is made, is the most basic of the calcium aluminates. It does not occur in nature, but is an important mineral phase in Portland cement.
Dodecacalcium hepta-aluminate (12CaO·7Al2O3, Ca12Al14O33 or C12A7) is an inorganic solid that occurs rarely in nature as the mineral mayenite. It is an important phase in calcium aluminate cements and is an intermediate in the manufacture of Portland cement. Its composition and properties have been the subject of much debate, because of variations in composition that can arise during its high-temperature formation.
Calcium aluminate cements are cements consisting predominantly of hydraulic calcium aluminates. Alternative names are "aluminous cement", "high-alumina cement", and "Ciment fondu" in French. They are used in a number of small-scale, specialized applications.
Monocalcium aluminate (CaAl2O4) is one of the series of calcium aluminates. It does occur in nature, although only very rarely, as two polymorphs known as krotite and dmitryivanovite, both from meteorites. It is important in the composition of calcium aluminate cements.
Calcium aluminoferrite is a dark brown crystalline phase commonly found in cements. In the cement industry it is termed tetra-calcium aluminoferrite or ferrite. In cement chemist notation (CCN), it is abbreviated as C
4AF meaning 4CaO·Al
2O
3·Fe
2O
3 in the oxide notation. It also exists in nature as the rare mineral brownmillerite.
An AFm phase is an "alumina, ferric oxide, monosubstituted" phase, or aluminate ferrite monosubstituted, or Al2O3, Fe2O3 mono, in cement chemist notation (CCN). AFm phases are important hydration products in the hydration of Portland cements and hydraulic cements.
Friedel's salt is an anion exchanger mineral belonging to the family of the layered double hydroxides (LDHs). It has affinity for anions as chloride and iodide and is capable of retaining them to a certain extent in its crystallographical structure.
Chlormayenite (after Mayen, Germany), Ca12Al14O32[☐4Cl2], is a rare calcium aluminium oxide mineral of cubic symmetry.
Grossite is a calcium aluminium oxide mineral with formula CaAl4O7. It is a colorless to white vitreous mineral which crystallizes in the monoclinic crystal system.
Krotite is a natural mineral composed of calcium, aluminium and oxygen, with the molecular formula CaAl2O4. It is the low-pressure dimorph of CaAl2O4, of which the high-pressure dimorph is named dmitryivanovite.
AFt Phases refer to the calcium Aluminate Ferrite trisubstituted, or calcium aluminate trisubstituted, phases present in hydrated cement paste (HCP) in concrete.