Biopolymers are natural polymers produced by the cells of living organisms. Like other polymers, biopolymers consist of monomeric units that are covalently bonded in chains to form larger molecules. There are three main classes of biopolymers, classified according to the monomers used and the structure of the biopolymer formed: polynucleotides, polypeptides, and polysaccharides. The Polynucleotides, RNA and DNA, are long polymers of nucleotides. Polypeptides include proteins and shorter polymers of amino acids; some major examples include collagen, actin, and fibrin. Polysaccharides are linear or branched chains of sugar carbohydrates; examples include starch, cellulose, and alginate. Other examples of biopolymers include natural rubbers, suberin and lignin, cutin and cutan, melanin, and polyhydroxyalkanoates (PHAs).
Cellulose is an organic compound with the formula (C
6H
10O
5)
n, a polysaccharide consisting of a linear chain of several hundred to many thousands of β(1→4) linked D-glucose units. Cellulose is an important structural component of the primary cell wall of green plants, many forms of algae and the oomycetes. Some species of bacteria secrete it to form biofilms. Cellulose is the most abundant organic polymer on Earth. The cellulose content of cotton fiber is 90%, that of wood is 40–50%, and that of dried hemp is approximately 57%.
Fiber or fibre is a natural or artificial substance that is significantly longer than it is wide. Fibers are often used in the manufacture of other materials. The strongest engineering materials often incorporate fibers, for example carbon fiber and ultra-high-molecular-weight polyethylene.
Rayon, also called viscose and commercialised in some countries as sabra silk or cactus silk, is a semi-synthetic fiber, made from natural sources of regenerated cellulose, such as wood and related agricultural products. It has the same molecular structure as cellulose. Many types and grades of viscose fibers and films exist. Some imitate the feel and texture of natural fibers such as silk, wool, cotton, and linen. The types that resemble silk are often called artificial silk. It is used to make textiles for clothing and other purposes.
Carbon disulfide is an inorganic compound with the chemical formula CS2 and structure S=C=S. It is a colorless, flammable, neurotoxic liquid that is used as a building block in organic synthesis. Pure carbon disulfide has a pleasant, ether- or chloroform-like odor, but commercial samples are usually yellowish and are typically contaminated with foul-smelling impurities.
Synthetic fibers or synthetic fibres are fibers made by humans through chemical synthesis, as opposed to natural fibers that are directly derived from living organisms, such as plants or fur from animals. They are the result of extensive research by scientists to replicate naturally occurring animal and plant fibers. In general, synthetic fibers are created by extruding fiber-forming materials through spinnerets, forming a fiber. These are called synthetic or artificial fibers. The word polymer comes from a Greek prefix "poly" which means "many" and suffix "mer" which means "single units"..
In biochemistry, cellulose acetate refers to any acetate ester of cellulose, usually cellulose diacetate. It was first prepared in 1865. A bioplastic, cellulose acetate is used as a film base in photography, as a component in some coatings, and as a frame material for eyeglasses; it is also used as a synthetic fiber in the manufacture of cigarette filters and playing cards. In photographic film, cellulose acetate film replaced nitrate film in the 1950s, being far less flammable and cheaper to produce.
Lyocell is a semi-synthetic fiber used to make textiles for clothing and other purposes. It is a form of regenerated cellulose made by dissolving pulp and dry jet-wet spinning. Unlike rayon made by some of the more common viscose processes, Lyocell production does not use carbon disulfide, which is toxic to workers and the environment. Lyocell was originally trademarked as Tencel in 1982.
Polymer chemistry is a sub-discipline of chemistry that focuses on the structures of chemicals, chemical synthesis, and chemical and physical properties of polymers and macromolecules. The principles and methods used within polymer chemistry are also applicable through a wide range of other chemistry sub-disciplines like organic chemistry, analytical chemistry, and physical chemistry. Many materials have polymeric structures, from fully inorganic metals and ceramics to DNA and other biological molecules. However, polymer chemistry is typically related to synthetic and organic compositions. Synthetic polymers are ubiquitous in commercial materials and products in everyday use, such as plastics, and rubbers, and are major components of composite materials. Polymer chemistry can also be included in the broader fields of polymer science or even nanotechnology, both of which can be described as encompassing polymer physics and polymer engineering.
A xanthate is a salt or ester of a xanthic acid. The formula of the salt of xanthic acid is [R−O−CS2]−M+. Xanthate also refers to the anion [R−O−CS2]−. The formula of a xanthic acid is R−O−C(=S)−S−H, such as ethyl xanthic acid, while the formula of an ester of a xanthic acid is R−O−C(=S)−S−R', where R and R' are organyl groups. The salts of xanthates are also called O-organyl dithioates. The esters of xanthic acid are also called O,S-diorganyl esters of dithiocarbonic acid. The name xanthate is derived from Ancient Greek ξανθός (xanthos) meaning 'yellowish' or 'golden', and indeed most xanthate salts are yellow. They were discovered and named in 1823 by Danish chemist William Christopher Zeise. These organosulfur compounds are important in two areas: the production of cellophane and related polymers from cellulose and for extraction of certain sulphide bearing ores. They are also versatile intermediates in organic synthesis.
Bioplastics are plastic materials produced from renewable biomass sources, such as vegetable fats and oils, corn starch, straw, woodchips, sawdust, recycled food waste, etc. Some bioplastics are obtained by processing directly from natural biopolymers including polysaccharides and proteins, while others are chemically synthesised from sugar derivatives and lipids from either plants or animals, or biologically generated by fermentation of sugars or lipids. In contrast, common plastics, such as fossil-fuel plastics are derived from petroleum or natural gas.
British Cellophane Ltd (BCL) was a joint venture company formed in 1935 between La Cellophane SA and Courtaulds, when they began building a major factory for producing Cellophane in Bridgwater, Somerset, England.
Courtaulds was a United Kingdom-based manufacturer of fabric, clothing, artificial fibres, and chemicals. It was established in 1794 and became the world's leading man-made fibre production company before being broken up in 1990 into Courtaulds plc and Courtaulds Textiles Ltd.
Viskase is a global corporation based out of Lombard, Illinois, United States that supplies plastic, cellulose, and fibrous film and packaging to the food service industry, including casings for processed meats such as hot dogs and sausages. Viskase has manufacturing facilities in the United States, Mexico, Brazil and France, as well as sales offices located around the world.
Bamboo textile is any cloth, yarn or clothing made from bamboo fibres. While historically used only for structural elements, such as bustles and the ribs of corsets, in recent years different technologies have been developed that allow bamboo fibre to be used for a wide range of textile and fashion applications.
Dissolving pulp, also called dissolving cellulose, is bleached wood pulp or cotton linters that has a high cellulose content. It has special properties including a high level of brightness and uniform molecular-weight distribution. This pulp is manufactured for uses that require a high chemical purity, and particularly low hemicellulose content, since the chemically similar hemicellulose can interfere with subsequent processes. Dissolving pulp is so named because it is not made into paper, but dissolved either in a solvent or by derivatization into a homogeneous solution, which makes it completely chemically accessible and removes any remaining fibrous structure. Once dissolved, it can be spun into textile fibers, or chemically reacted to produce derivatized celluloses, such cellulose triacetate, a plastic-like material formed into fibers or films, or cellulose ethers such as methyl cellulose, used as a thickener.
Cellulose fibers are fibers made with ethers or esters of cellulose, which can be obtained from the bark, wood or leaves of plants, or from other plant-based material. In addition to cellulose, the fibers may also contain hemicellulose and lignin, with different percentages of these components altering the mechanical properties of the fibers.
Biodegradable bags are bags that are capable of being decomposed by bacteria or other living organisms.
The U.S. Flammable Fabrics Act is an act that was passed in 1953 to regulate the manufacture of highly flammable clothing. It was enacted after years of rayon viscose fabrics being proven to be the primary cause of quick starting, high temperature fires as well as having the secondary effect of causing illnesses in factory workers. Viscose is the key word when describing the chemical dangers of rayon fabrics, because a chemical named carbon disulfide is used to convert cellulose into a viscose fabric capable of being threaded together for clothing. This is an important distinction to make for the sake of clarity as cellulose fabrics are still commonly advertised as "green" in the sense that the fabric is derived from the cellulose in plants, but the introduction of carbon disulfide in the manufacturing process creates a reaction that is remarkably toxic to the workers who are developing and working with the fabric. There was also a series of tragic deaths in the 1940s caused by the highly flammable nature of the fabric involving children who were wearing long rayon pile cowboy chaps or brushed rayon sweaters. The Federal Trade Commission was initially placed as the enforcement authority but this responsibility was later transferred over to the Consumer Product Safety Commission in 1967 when the act was amended to include interior furnishings, paper, plastic, foam, and other materials used in wearing apparel and interior furnishings. A provision of the act makes willful violation a felony with maximum penalties of a $10,000 fine and 3 years in prison, which reflects how seriously the dangers of flammable fabrics were being taken. The Consumer Product Safety Commission was given the authority, under the U.S. Flammable Fabrics Act, to issue mandatory flammability standards. Flammability standards for clothing textiles, vinyl plastic film in clothing, carpets, rugs, children's sleepwear, mattresses, and mattress pads have all been established.
Red Scar Works was built in 1939 by Courtaulds and produced rayon. It was located in Ribbleton Preston off Longridge Road. The closure of the works was announced in November 1979 and the issue raised in the UK Parliament House of Commons by the constituency MP. At the time of closure approximately 2,600 people were employed there but there were approximately 4,000 at its peak. It was the largest rayon producing site in Britain. Two main products were manufactured with one being tyre cord by a process known as CSPT – Continuous Spinning Process Tenasco. Two main denier of this product were manufactured. The other product was a general textile called Bright. A range of deniers of this were produced in a range of colours. The trade name for the coloured product was Duracol. At the time of closure, one reason given by management for the closure was the rising popularity of steel belt radial tires thus reducing demand for tyre cord.
