Chlorophane

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Chlorophane
Fluorite, var. Chlorophane.jpg
General
Category Halide mineral
Formula
(repeating unit)
CaF2
Strunz classification 3.AB.25
Crystal system Isometric
Crystal class Hexoctahedral (m3m)
H–M symbol: (4/m 3 2/m)
(cF12)
Space group Fm3m (No. 225)
Unit cell a = 5.4626 Å; Z = 4
Identification
ColorWhite, reddish pink or red (fluorescence/ phosphorescence in emerald green)
Crystal habit Well-formed coarse sized crystals; also nodular, botryoidal, rarely columnar or fibrous; granular, massive
Twinning Common on {111}, interpenetrant, flattened
Cleavage Octahedral, perfect on {111}, parting on {011}
Fracture Subconchoidal to uneven
Tenacity Brittle
Mohs scale hardness4 (defining mineral)
Luster Vitreous
Streak White
Specific gravity 3.175–3.184; to 3.56 if high in rare-earth elements
Optical propertiesIsotropic; weak anomalous anisotropism
Refractive index 1.433–1.448
Fusibility 3
Solubility slightly water soluble and in hot hydrochloric acid

Chlorophane, also sometimes known as pyroemerald, cobra stone, and pyrosmaragd, is a rare variety of the mineral fluorite with the unusual combined properties of thermoluminescence, thermophosphoresence, triboluminescence, and fluorescence: it will emit light in the visible spectrum when exposed to ultraviolet light, when heated, and when rubbed; if heated, it will continue to emit light for a period of time after a heat source is withdrawn. The small amount of heat generated by being held in the hand has been reported as enough to induce luminescence, though this may be the result of experimental error. [1] Although chemically very similar to fluorite, chlorophane has several impurities including magnesium, aluminum, manganese, and traces of iron and sodium (none of which occur in fluorite). As of 2013 it was still not known which if any of these impurities imparts to chlorophane the luminescent properties that distinguish it from fluorite. [2] Some samples of chlorophane, particularly those exposed to high temperatures, will only luminesce once or will do so with only weakened intensity over time. [3] A very bright luminescence can be achieved at between 200 °C (392 °F) and 300 °C (572 °F), [4] and mineralogists once believed that it would glow indefinitely at temperatures of just 30 °C (86 °F), meaning that when exposed on the ground in warmer climates, the mineral would glow year-round. [5] This effect, which was reported many times without having been observed, was eventually attributed in part to a combination of both heat and light acting on the mineral.

The unusual properties of chlorophane have been attributed to samarium, terbium, dysprosium, gadolinium, ytterbium, and yttrium; none of these rare earth elements, however, has been consistently found in all chlorophane specimens. [2] [6]

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Europium is a chemical element; it has symbol Eu and atomic number 63. Europium is a silvery-white metal of the lanthanide series that reacts readily with air to form a dark oxide coating. It is the most chemically reactive, least dense, and softest of the lanthanide elements. It is soft enough to be cut with a knife. Europium was isolated in 1901 and named after the continent of Europe. Europium usually assumes the oxidation state +3, like other members of the lanthanide series, but compounds having oxidation state +2 are also common. All europium compounds with oxidation state +2 are slightly reducing. Europium has no significant biological role and is relatively non-toxic compared to other heavy metals. Most applications of europium exploit the phosphorescence of europium compounds. Europium is one of the rarest of the rare-earth elements on Earth.

<span class="mw-page-title-main">Fluorescence</span> Emission of light by a substance that has absorbed light

Fluorescence is one of two kinds of emission of light by a substance that has absorbed light or other electromagnetic radiation. When exposed to ultraviolet radiation, many substances will glow (fluoresce) with colored visible light. The color of the light emitted depends on the chemical composition of the substance. Fluorescent materials generally cease to glow nearly immediately when the radiation source stops. This distinguishes them from the other type of light emission, phosphorescence. Phosphorescent materials continue to emit light for some time after the radiation stops.

<span class="mw-page-title-main">Ruby</span> Variety of corundum, mineral, gemstone

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Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon.

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Strontianite (SrCO3) is an important raw material for the extraction of strontium. It is a rare carbonate mineral and one of only a few strontium minerals. It is a member of the aragonite group.

<span class="mw-page-title-main">Luminescence</span> Spontaneous emission of light by a substance

Luminescence is a spontaneous emission of radiation from an electronically or vibrationally excited species not in thermal equilibrium with its environment. A luminescent object emits cold light in contrast to incandescence, where an object only emits light after heating. Generally, the emission of light is due to the movement of electrons between different energy levels within an atom after excitation by external factors. However, the exact mechanism of light emission in vibrationally excited species is unknown.

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A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or visible light, and cathodoluminescent substances which glow when struck by an electron beam in a cathode-ray tube.

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A fluorescent lamp, or fluorescent tube, is a low-pressure mercury-vapor gas-discharge lamp that uses fluorescence to produce visible light. An electric current in the gas excites mercury vapor, to produce ultraviolet and make a phosphor coating in the lamp glow. Fluorescent lamps convert electrical energy into useful light much more efficiently than incandescent lamps, but are less efficient than most LED lamps. The typical luminous efficacy of fluorescent lamps is 50–100 lumens per watt, several times the efficacy of incandescent bulbs with comparable light output.

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Phosphorescence is a type of photoluminescence related to fluorescence. When exposed to light (radiation) of a shorter wavelength, a phosphorescent substance will glow, absorbing the light and reemitting it at a longer wavelength. Unlike fluorescence, a phosphorescent material does not immediately reemit the radiation it absorbs. Instead, a phosphorescent material absorbs some of the radiation energy and reemits it for a much longer time after the radiation source is removed.

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An F-center or color center or Farbe center is a type of crystallographic defect in which an anionic vacancy in a crystal lattice is occupied by one or more unpaired electrons. Electrons in such a vacancy in a crystal lattice tend to absorb light in the visible spectrum such that a material that is usually transparent becomes colored. The greater the number of F centers, the more intense the color of the compound. F centers are a type of color center.

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Zinc sulfide is an inorganic compound with the chemical formula of ZnS. This is the main form of zinc found in nature, where it mainly occurs as the mineral sphalerite. Although this mineral is usually black because of various impurities, the pure material is white, and it is widely used as a pigment. In its dense synthetic form, zinc sulfide can be transparent, and it is used as a window for visible optics and infrared optics.

<span class="mw-page-title-main">Scheelite</span> Calcium tungstate mineral

Scheelite is a calcium tungstate mineral with the chemical formula CaWO4. It is an important ore of tungsten (wolfram). Scheelite is originally named after Swedish chemist Carl Wilhelm Scheele (1742–1786). Well-formed crystals are sought by collectors and are occasionally fashioned into gemstones when suitably free of flaws. Scheelite has been synthesized using the Czochralski process; the material produced may be used to imitate diamond, as a scintillator, or as a solid-state lasing medium. It was also used in radium paint in the same fashion as was zinc sulphide, and Thomas Edison invented a fluoroscope with a calcium tungstate-coated screen, making the images six times brighter than those with barium platinocyanide; the latter chemical allowed Röntgen to discover X-rays in early November 1895. Note, the semi-precious stone marketed as 'blue scheelite' is actually a rock type consisting mostly of calcite and dolomite, with occasional traces of yellow-orange scheelite.

Neodymium(III) chloride or neodymium trichloride is a chemical compound of neodymium and chlorine with the formula NdCl3. This anhydrous compound is a mauve-colored solid that rapidly absorbs water on exposure to air to form a purple-colored hexahydrate, NdCl3·6H2O. Neodymium(III) chloride is produced from minerals monazite and bastnäsite using a complex multistage extraction process. The chloride has several important applications as an intermediate chemical for production of neodymium metal and neodymium-based lasers and optical fibers. Other applications include a catalyst in organic synthesis and in decomposition of waste water contamination, corrosion protection of aluminium and its alloys, and fluorescent labeling of organic molecules (DNA).

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Diamond is the allotrope of carbon in which the carbon atoms are arranged in the specific type of cubic lattice called diamond cubic. It is a crystal that is transparent to opaque and which is generally isotropic. Diamond is the hardest naturally occurring material known. Yet, due to important structural brittleness, bulk diamond's toughness is only fair to good. The precise tensile strength of bulk diamond is little known; however, compressive strength up to 60 GPa has been observed, and it could be as high as 90–100 GPa in the form of micro/nanometer-sized wires or needles, with a corresponding maximum tensile elastic strain in excess of 9%. The anisotropy of diamond hardness is carefully considered during diamond cutting. Diamond has a high refractive index (2.417) and moderate dispersion (0.044) properties that give cut diamonds their brilliance. Scientists classify diamonds into four main types according to the nature of crystallographic defects present. Trace impurities substitutionally replacing carbon atoms in a diamond's crystal structure, and in some cases structural defects, are responsible for the wide range of colors seen in diamond. Most diamonds are electrical insulators and extremely efficient thermal conductors. Unlike many other minerals, the specific gravity of diamond crystals (3.52) has rather small variation from diamond to diamond.

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Strontium aluminate is an aluminate compound with the chemical formula SrAl2O4. It is a pale yellow, monoclinic crystalline powder that is odourless and non-flammable. When activated with a suitable dopant, it acts as a photoluminescent phosphor with long persistence of phosphorescence.

<span class="mw-page-title-main">Lutetium tantalate</span>

Lutetium tantalate is a chemical compound of lutetium, tantalum and oxygen with the formula LuTaO4. With a density of 9.81 g/cm3, this mixed oxide compound is the densest known white stable material. (Although thorium dioxide ThO2 is also white and has a higher density of 10 g/cm3, it is radioactively unstable; while not radioactive enough to make it unstable as a material, even its low rate of decay is still too much for certain uses such as phosphors for detecting ionising radiation.) The white color and high density of LuTaO4 make it ideal for phosphor applications, though the high cost of lutetium is a hindrance.

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References

  1. Suzanne Bettonville (2013). Rock Roles: Facts, Properties, and Lore of Gemstones. Lulu.com. p. 36. ISBN   978-1-257-03762-9.
  2. 1 2 Jack DeMent (16 April 2013). Handbook of Fluorescent Gems and Minerals - An Exposition and Catalog of the Fluorescent and Phosphorescent Gems and Minerals, Including the Use of Ultraviolet Light in the Earth Sciences. Read Books Limited. p. 64. ISBN   978-1-4733-8276-3.
  3. Charles Palache; Harry Berman; Clifford Frondel (1951). The System of Mineralogy: Of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892. Halides, nitrates, borates, carbonates, sulfates, phosphates, arsenates, tungstates, molybdates, etc. Wiley. p. 29.
  4. The Engineer. Morgan-Grampian (Publishers). 1881. p. 28.
  5. Gustave Le Bon (1908). ... The Evolution of Forces. K. Paul, Trench, Trübner & Company, Limited. p. 249.
  6. The Chemical News and Journal of Physical Science. Griffin, Bohn and Company. 1906. p. 290.