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Carbon is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon makes up only about 0.025 percent of Earth's crust. Three isotopes occur naturally, 12C and 13C being stable, while 14C is a radionuclide, decaying with a half-life of about 5,730 years. Carbon is one of the few elements known since antiquity.
Graphite, archaically referred to as plumbago, is a crystalline form of the element carbon with its atoms arranged in a hexagonal structure. It occurs naturally in this form and is the most stable form of carbon under standard conditions. Under high pressures and temperatures it converts to diamond. Graphite is used in pencils and lubricants. It is a good conductor of heat and electricity. Its high conductivity makes it useful in electronic products such as electrodes, batteries, and solar panels.
Kamacite is an alloy of iron and nickel, which is found on Earth only in meteorites. The proportion iron:nickel is between 90:10 and 95:5; small quantities of other elements, such as cobalt or carbon may also be present. The mineral has a metallic luster, is gray and has no clear cleavage although its crystal structure is isometric-hexoctahedral. Its density is about 8 g/cm3 and its hardness is 4 on the Mohs scale. It is also sometimes called balkeneisen.
Beta carbon nitride (β-C3N4) is a superhard material predicted to be harder than diamond.
Cementite (or iron carbide) is a compound of iron and carbon, more precisely an intermediate transition metal carbide with the formula Fe3C. By weight, it is 6.67% carbon and 93.3% iron. It has an orthorhombic crystal structure. It is a hard, brittle material, normally classified as a ceramic in its pure form, and is a frequently found and important constituent in ferrous metallurgy. While cementite is present in most steels and cast irons, it is produced as a raw material in the iron carbide process, which belongs to the family of alternative ironmaking technologies. The name cementite originated from the research of Floris Osmond and J. Werth, where the structure of solidified steel consists of a kind of cellular tissue in theory, with ferrite as the nucleus and Fe3C the envelope of the cells. The carbide therefore cemented the iron.
Presolar grains are interstellar solid matter in the form of tiny solid grains that originated at a time before the Sun was formed. Presolar stardust grains formed within outflowing and cooling gases from earlier presolar stars.
Carbon is capable of forming many allotropes due to its valency. Well-known forms of carbon include diamond and graphite. In recent decades, many more allotropes have been discovered and researched including ball shapes such as buckminsterfullerene and sheets such as graphene. Larger scale structures of carbon include nanotubes, nanobuds and nanoribbons. Other unusual forms of carbon exist at very high temperatures or extreme pressures. Around 500 hypothetical 3‑periodic allotropes of carbon are known at the present time, according to the Samara Carbon Allotrope Database (SACADA).
Widmanstätten patterns, also known as Thomson structures, are figures of long nickel–iron crystals, found in the octahedrite iron meteorites and some pallasites. They consist of a fine interleaving of kamacite and taenite bands or ribbons called lamellae. Commonly, in gaps between the lamellae, a fine-grained mixture of kamacite and taenite called plessite can be found. Widmanstätten patterns describe features in modern steels, titanium and zirconium alloys.
The Canyon Diablo meteorites include the many fragments of the asteroid that created Meteor Crater, Arizona, United States. Meteorites have been found around the crater rim, and are named for nearby Canyon Diablo, which lies about three to four miles west of the crater.
Carbonado, commonly known as black diamond, is one of the toughest forms of natural diamond. It is an impure, high-density, micro-porous form of polycrystalline diamond consisting of diamond, graphite, and amorphous carbon, with minor crystalline precipitates filling pores and occasional reduced metal inclusions. It is found primarily in alluvial deposits where it is most prominent in mid-elevation equatorial regions such as Central African Republic and in Brazil, where the vast majority of carbonado diamondites have been found. Its natural colour is black or dark grey, and it is more porous than other diamonds.
Meteoric iron, sometimes meteoritic iron, is a native metal and early-universe protoplanetary-disk remnant found in meteorites and made from the elements iron and nickel mainly in the form of the mineral phases kamacite and taenite. Meteoric iron makes up the bulk of iron meteorites but is also found in other meteorites. Apart from minor amounts of telluric iron, meteoric iron is the only naturally occurring native metal of the element iron on the Earth's surface.
Iron meteorites, also known as siderites, or ferrous meteorites, are a type of meteorites that consist overwhelmingly of an iron–nickel alloy known as meteoric iron that usually consists of two mineral phases: kamacite and taenite. Iron meteorites originate from cores of planetesimals.
Silicate perovskite is either (Mg,Fe)SiO3 (the magnesium end-member is called bridgmanite) or CaSiO3 (calcium silicate) when arranged in a perovskite structure. Silicate perovskites are not stable at Earth's surface, and mainly exist in the lower part of Earth's mantle, between about 670 and 2,700 km (420 and 1,680 mi) depth. They are thought to form the main mineral phases, together with ferropericlase.
The Dronino meteorite is a 40-kilogram (88 lb) iron meteorite that was found in the Ryazan Oblast of Russia in July 2000. It is classified as an ataxite.
IAB meteorites are a group of iron meteorites according to their overall composition and a group of primitive achondrites because of silicate inclusions that show a strong affinity to winonaites and chondrites.
IIG meteorites are a group of iron meteorites. The group currently has six members. They are hexahedrites with large amounts of schreibersite. The meteoric iron is composed of kamacite.
Stony-iron meteorites or siderolites are meteorites that consist of nearly equal parts of meteoric iron and silicates. This distinguishes them from the stony meteorites, that are mostly silicates, and the iron meteorites, that are mostly meteoric iron.
This is a glossary of terms used in meteoritics, the science of meteorites.
Although diamonds on Earth are rare, extraterrestrial diamonds are very common. Diamonds so tiny that they contain only about 2000 carbon atoms are abundant in meteorites and some of them formed in stars before the Solar System existed. High pressure experiments suggest large amounts of diamonds are formed from methane on the ice giant planets Uranus and Neptune, while some planets in other planetary systems may be almost pure diamond. Diamonds are also found in stars and may have been the first mineral ever to have formed.
The geochemistry of carbon is the study of the transformations involving the element carbon within the systems of the Earth. To a large extent this study is organic geochemistry, but it also includes the very important carbon dioxide. Carbon is transformed by life, and moves between the major phases of the Earth, including the water bodies, atmosphere, and the rocky parts. Carbon is important in the formation of organic mineral deposits, such as coal, petroleum or natural gas. Most carbon is cycled through the atmosphere into living organisms and then respirated back into the atmosphere. However an important part of the carbon cycle involves the trapping of living matter into sediments. The carbon then becomes part of a sedimentary rock when lithification happens. Human technology or natural processes such as weathering, or underground life or water can return the carbon from sedimentary rocks to the atmosphere. From that point it can be transformed in the rock cycle into metamorphic rocks, or melted into igneous rocks. Carbon can return to the surface of the Earth by volcanoes or via uplift in tectonic processes. Carbon is returned to the atmosphere via volcanic gases. Carbon undergoes transformation in the mantle under pressure to diamond and other minerals, and also exists in the Earth's outer core in solution with iron, and may also be present in the inner core.
References
- 1 2 Cliftonite. Mindat.org.
- 1 2 Brett, R; Higgins, GT (1967). "Cliftonite in meteorites: A proposed origin" (PDF). Science. 156 (3776): 819–20. doi:10.1126/science.156.3776.819. PMID 17780301.
- 1 2 Brett, Robin; Higgins, G.T. (1969). "Cliftonite: A proposed origin, and its bearing on the origin of diamonds in meteorites". Geochimica et Cosmochimica Acta. 33 (12): 1473. doi:10.1016/0016-7037(69)90151-3.