Decontamination foam

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Sailors and marines take cover from thousands of gallons of aqueous film forming foam solution during a countermeasure washdown. US Navy 110323-N-UO379-006 Sailors and Marines take cover from thousands of gallons of aqueous film forming foam solution during a countermeasure w.jpg
Sailors and marines take cover from thousands of gallons of aqueous film forming foam solution during a countermeasure washdown.

Decontamination foam (known commonly as decon foam) is a spray-on cleaning solution used on surfaces that have been contaminated with biological or chemical agents (e.g., chemical warfare agents, anthrax spores or toxic industrial materials). [1] Decon foam has been found to make numerous chemical and biological agents harmless. It is also intended for use in areas where large numbers of people have possibly been contaminated (e.g. at conventions, airports, concerts). [1] [2]

Contents

Composition

The composition of decontamination foams is essentially water and a surfactant, creating an aqueous film forming foam that various reactive chemicals are then added, diminishing the amount of contaminants adhering to a surface and forming less hazardous products. Common reactants are hydrogen peroxide and quaternary ammonium complexes. Decon foam often comes in multiple bottles, that, when mixed, combine to form the decontamination solution. The bottles should be kept separate until needed as the foam may begin to lose effectiveness after mixing. After these bottles are mixed together, the foam can be applied by spraying it on a contaminated area or by manual application.

Solvent-based decontaminants work well on permeable polymers and are made to avoid corrosion, but can possibly alter polymer or plastic surfaces permanently. On the other hand, aqueous-based decontaminants are better with polar surfaces like concrete, but have the potential to corrode surfaces. [3] For decontamination foam to be successful, it is important to stabilize the foam as this will increase its efficiency. Modifying the surface of silica nanoparticles to a certain level has been found to increase stability of the foam. [4]

Effectiveness

Decontamination foams can have varying levels of effectiveness depending on the decon foam, the type of contaminating agent, and the surface that is being decontaminated. Many decontaminants show effectiveness against chemical agents on nonporous and non-permeable surfaces, such as glass and stainless steel, since the contaminant remains on the exterior of the surface and is easily accessible to the decontaminant. However, more porous and permeable surfaces can absorb the contaminant, making it more difficult to decontaminate, and decontaminating agents can leave residual chemical contaminants on these surfaces. [3]

Examples of use

U.S. Navy Officer passing through a decontamination shower. Decontamination shower, Exercise Desert Sailor, Feb. 27, 2008.jpg
U.S. Navy Officer passing through a decontamination shower.

Benefits of decontamination foam over other decontaminants

The two main benefits of decontamination foam over liquid decontaminants (chlorine, decontamination solutions, etc.) are its effectiveness on non horizontal surfaces and its high air to liquid ratio. Other decontaminants are difficult to apply to walls and ceilings due to poor adhesion, however decon foam is much better at adhering to surfaces, which increases the amount of time for the decontamination reaction to take place. Additionally, the high air to liquid ratio allows the foam to be used without over-applying the decontaminant. This high ratio also allows a small amount of liquid to cover a relatively large area in the event of a major contamination.

Formulas

Related Research Articles

Contamination is the presence of a constituent, impurity, or some other undesirable element that renders something unsuitable, unfit or harmful for both physical body, natural environment, workplace, etc.

<span class="mw-page-title-main">Environmental remediation</span> Removal of pollution from soil, groundwater etc.

Environmental remediation is the cleanup of hazardous substances dealing with the removal, treatment and containment of pollution or contaminants from environmental media such as soil, groundwater, sediment. Remediation may be required by regulations before development of land revitalization projects. Developers who agree to voluntary cleanup may be offered incentives under state or municipal programs like New York State's Brownfield Cleanup Program. If remediation is done by removal the waste materials are simply transported off-site for disposal at another location. The waste material can also be contained by physical barriers like slurry walls. The use of slurry walls is well-established in the construction industry. The application of (low) pressure grouting, used to mitigate soil liquefaction risks in San Francisco and other earthquake zones, has achieved mixed results in field tests to create barriers, and site-specific results depend upon many variable conditions that can greatly impact outcomes.

<span class="mw-page-title-main">Radioactive contamination</span> Undesirable radioactive elements on surfaces or in gases, liquids, or solids

Radioactive contamination, also called radiological pollution, is the deposition of, or presence of radioactive substances on surfaces or within solids, liquids, or gases, where their presence is unintended or undesirable.

Human decontamination is the process of removing hazardous materials from the human body, including chemicals, radioactive substances, and infectious material.

Mass decontamination is the decontamination of large numbers of people, in the event of industrial, accidental, or intentional contamination by toxic, infective, caustic, polluted, or otherwise unhealthful or damaging substances.

<span class="mw-page-title-main">Firefighting foam</span> Foam used for fire suppression

Firefighting foam is a foam used for fire suppression. Its role is to cool the fire and to coat the fuel, preventing its contact with oxygen, thus achieving suppression of the combustion. Firefighting foam was invented by the Russian engineer and chemist Aleksandr Loran in 1902.

The RCA clean is a standard set of wafer cleaning steps which need to be performed before high-temperature processing steps of silicon wafers in semiconductor manufacturing.

<span class="mw-page-title-main">Iron nanoparticle</span>

Nanoscale iron particles are sub-micrometer particles of iron metal. They are highly reactive because of their large surface area. In the presence of oxygen and water, they rapidly oxidize to form free iron ions. They are widely used in medical and laboratory applications and have also been studied for remediation of industrial sites contaminated with chlorinated organic compounds.

<span class="mw-page-title-main">Food contaminant</span> Harmful substance in food

A food contaminant is a harmful chemical or microorganism present in food, which can cause illness to the consumer.

Stripping is a physical separation process where one or more components are removed from a liquid stream by a vapor stream. In industrial applications the liquid and vapor streams can have co-current or countercurrent flows. Stripping is usually carried out in either a packed or trayed column.

Groundwater remediation is the process that is used to treat polluted groundwater by removing the pollutants or converting them into harmless products. Groundwater is water present below the ground surface that saturates the pore space in the subsurface. Globally, between 25 per cent and 40 per cent of the world's drinking water is drawn from boreholes and dug wells. Groundwater is also used by farmers to irrigate crops and by industries to produce everyday goods. Most groundwater is clean, but groundwater can become polluted, or contaminated as a result of human activities or as a result of natural conditions.

In situ chemical oxidation (ISCO), a form of advanced oxidation process, is an environmental remediation technique used for soil and/or groundwater remediation to lower the concentrations of targeted environmental contaminants to acceptable levels. ISCO is accomplished by introducing strong chemical oxidizers into the contaminated medium to destroy chemical contaminants in place. It can be used to remediate a variety of organic compounds, including some that are resistant to natural degradation. The in situ in ISCO is just Latin for "in place", signifying that ISCO is a chemical oxidation reaction that occurs at the site of the contamination.

A permeable reactive barrier (PRB), also referred to as a permeable reactive treatment zone (PRTZ), is a developing technology that has been recognized as being a cost-effective technology for in situ groundwater remediation. PRBs are barriers which allow some—but not all—materials to pass through. One definition for PRBs is an in situ treatment zone that passively captures a plume of contaminants and removes or breaks down the contaminants, releasing uncontaminated water. The primary removal methods include: (1) sorption and precipitation, (2) chemical reaction, and (3) reactions involving biological mechanisms.

In situ chemical reduction (ISCR) is a type of environmental remediation technique used for soil and/or groundwater remediation to reduce the concentrations of targeted environmental contaminants to acceptable levels. It is the mirror process of In Situ Chemical Oxidation (ISCO). ISCR is usually applied in the environment by injecting chemically reductive additives in liquid form into the contaminated area or placing a solid medium of chemical reductants in the path of a contaminant plume. It can be used to remediate a variety of organic compounds, including some that are resistant to natural degradation.

<span class="mw-page-title-main">DeconGel</span>

DeconGel is a gel created by CBI Polymers INC used to clean up after chemical and nuclear disasters. The product has been tested by numerous agencies and organizations in Japan including first responders, nuclear power plant operators, and private companies.

Nanoremediation is the use of nanoparticles for environmental remediation. It is being explored to treat ground water, wastewater, soil, sediment, or other contaminated environmental materials. Nanoremediation is an emerging industry; by 2009, nanoremediation technologies had been documented in at least 44 cleanup sites around the world, predominantly in the United States. In Europe, nanoremediation is being investigated by the EC funded NanoRem Project. A report produced by the NanoRem consortium has identified around 70 nanoremediation projects worldwide at pilot or full scale. During nanoremediation, a nanoparticle agent must be brought into contact with the target contaminant under conditions that allow a detoxifying or immobilizing reaction. This process typically involves a pump-and-treat process or in situ application.

<span class="mw-page-title-main">Non-aqueous phase liquid</span> Liquid solution contaminants that do not dissolve in or easily mix with water

Non-aqueous phase liquids, or NAPLs, are organic liquid contaminants characterized by their relative immiscibility with water. Common examples of NAPLs are petroleum products, coal tars, chlorinated solvents, and pesticides. Strategies employed for their removal from the subsurface environment have expanded since the late-20th century.

Dry decontamination is a method of removing contaminants without the need to use water or other liquids. Decontamination is an essential duty of hazmat responders as it protects victims from harmful reactions to the contaminants.

<span class="mw-page-title-main">Hazmat diving</span> Underwater diving in a known hazardous materials environment

Hazmat diving is underwater diving in a known hazardous materials environment. The environment may be contaminated by hazardous materials, the diving medium may be inherently a hazardous material, or the environment in which the diving medium is situated may include hazardous materials with a significant risk of exposure to these materials to members of the diving team. Special precautions, equipment and procedures are associated with hazmat diving so that the risk can be reduced to an acceptable level.

Diving equipment may be exposed to contamination in use and when this happens it must be decontaminated. This is a particular issue for hazmat diving, but incidental contamination can occur in other environments. Personal diving equipment shared by more than one user requires disinfection before use. Shared use is common for expensive commercial diving equipment, and for rental recreational equipment, and some items such as demand valves, masks, helmets and snorkels which are worn over the face or held in the mouth are possible vectors for infection by a variety of pathogens. Diving suits are also likely to be contaminated, but less likely to transmit infection directly.

References

  1. 1 2 Wadood Khan, Abdul; Kotta, Sabna; Hussain Ansari, Shahid; Kumar Sharma, Rakesh; Kumar, Vinod; Rana, Sudha; Ali, Javed (2012). "Chemical, biological, radiological, and nuclear threats-Decontamination technologies and recent patents: A review". Journal of Renewable and Sustainable Energy. 4 (1): 012704. doi:10.1063/1.3688029.
  2. Goolsby, Tommy D. (1997). Alexander, John B.; Spencer, Debra D.; Schmit, Steve; Steele, Basil J. (eds.). "Aqueous foam as a less-than-lethal technology for prison applications". Security Systems and Nonlethal Technologies for Law Enforcement. 2934. SPIE: 86–95. Bibcode:1997SPIE.2934...86G. doi:10.1117/12.265401. S2CID   110396848.
  3. 1 2 Love, Adam H.; Bailey, Christopher G.; Hanna, M. Leslie; Hok, Saphon; Vu, Alex K.; Reutter, Dennis J.; Raber, Ellen (2011). "Efficacy of liquid and foam decontamination technologies for chemical warfare agents on indoor surfaces". Journal of Hazardous Materials. 196: 115–122. doi:10.1016/j.jhazmat.2011.09.005. ISSN   0304-3894. PMID   21944706.
  4. Sonn, Jong Suk; Lee, Ju Yeon; Jo, Seon Hui; Yoon, In-Ho; Jung, Chong-Hun; Lim, Jong Choo (2018). "Effect of surface modification of silica nanoparticles by silane coupling agent on decontamination foam stability". Annals of Nuclear Energy. 114: 11–18. doi:10.1016/j.anucene.2017.12.007. ISSN   0306-4549.
  5. Glanz, James (2001-10-26). "A NATION CHALLENGED: DECONTAMINATION; Foam That Kills Anthrax Is to Be Used in Mailrooms". The New York Times. ISSN   0362-4331 . Retrieved 2021-11-24.
  6. 1 2 3 4 5 6 Sandia National Laboratories (2012-02-16). "Anthrax Decontamination Foam Used for Meth Lab Cleanup". SciTechDaily. Retrieved 2021-11-24.
  7. "Sandia decontamination foam". www.sandia.gov. Retrieved 2021-11-24.
  8. "MDF-200/500® - Span-World LLC". deconsolutions.com. Retrieved 2021-11-26.