Dionisios Vlachos

Last updated
Allan & Myra Ferguson Chair

Dionisios G. Vlachos
Born1964 (age 5859)
Nationality American
Alma mater University of Minnesota
National Technical University of Athens
Known for Catalysis, Reaction Engineering, Microreactors, Biomass
AwardsAIChE Wilhelm Award (2011), AAAS Fellow (2009)
Scientific career
Fields Chemical Engineer
Institutions University of Delaware
Doctoral advisor Lanny D. Schmidt
Rutherford Aris
External videos
Nuvola apps kaboodle.svg “Dion Vlachos as The Allan & Myra Ferguson Professor of Chemical and Biomolecular Engineering” “Catalysis Center for Energy Innovation”

Dionisios G. Vlachos is an American chemical engineer, the Allan & Myra Ferguson Endowed Chair Professor of Chemical Engineering at the University of Delaware and director of the Catalysis Center for Energy Innovation, a U.S. Department of Energy - Energy Frontiers Research Center. Throughout his career at University of Delaware and the University of Minnesota, he has advanced the study of catalysts and reaction engineering including catalytic applications in biomass utilization, alkane conversion and zeolites. He is a fellow of the American Association for the Advancement of Science (AAAS, 2009) and recipient of the Wilhelm Award of the American Institute of Chemical Engineers (2011). [1]

Contents

Early life and education

Dionisios was born in Greece and grew up on the island of Cephalonia, Greece in the Ionian Sea. In 1987, he earned a diploma in chemical engineering from the National Technical University of Athens. He completed a master's degree in 1990 with thesis, "Step Dynamics for Modeling of Crystal Surfaces". He completed his Ph.D. in chemical engineering at the University of Minnesota in 1992 with advisors Lanny D. Schmidt and Rutherford Aris on the topic of dynamic crystal surfaces as it pertains to catalysis. His thesis was published in 1992 with the title, "Structure and Dynamics of Adsorbed Phases and Crystal Surfaces". [2] During his time in graduate school, Dionisios prepared thirteen journal publications with his advisor including:

Professor of chemical engineering

Dr. Vlachos joined the University of Massachusetts Amherst Department of Chemical Engineering in Amherst, MA in 1993 as an assistant professor. He was promoted to associate professor in 1998, after which he took a position as associate professor of chemical engineering at the University of Delaware in 2000. In 2003, he was promoted to the rank of professor of chemical engineering. In 2009, he became the Elizabeth Inez Kelley Professor of Chemical Engineering, a position which he held until 2016. In 2015, he became a professor (joint) of physics and astronomy at the University of Delaware.

Leadership roles

Vlachos has served in leadership roles with national and international oversight of chemical engineering research. In 2008, he became the director of the University of Delaware Center for Catalytic Science and Technology (CCST), which he held until 2011. [6] In 2009, he led the formation of the Catalysis Center for Energy Innovation (CCEI), a national Department of Energy research center with over 70 people from around the United States. [7] In 2016, he was appointed the director of the Delaware Energy Institute (UDEI). [8] He is also the fundamentals division leader within the Dept. of Energy RAPID Manufacturing Institute starting in 2017. [9]

Research

Vlachos' research has focused on four areas of chemical engineering and materials science:

Surface chemistry and catalysis

His contributions to catalysis and surface chemistry have addressed the challenges associated with combining experiment, calculation and modeling for complex catalysis. For example, he has published numerous papers on the reforming of hydrocarbons, including microkinetic descriptions of hundreds of reactions on supported metals. [10] Other research has addressed liquid phase dehydration and/or hydrodeoxygenation of biomass-derived molecules such as furfural, dimethylfuran, or benzoic acid. [11] He has expanded on general approaches to catalytic design by using descriptors in parallel with efforts to develop reaction models with the accuracy of first principles approaches. [12]

Nanoparticles and synthesis

His interest in nanoparticles includes his master's thesis entitled, "Step Dynamics for Modeling of Crystal Surfaces." A focus on crystal structures and growth behavior continued with a focus on the nucleation, growth and design of nanoporous materials including zeolites and MOFs. [13] His research on nanoparticle synthesis was frequently combined in the impact on applications including catalysis, adsorption, and separation via membranes. [14]

Modeling and simulation

Vlachos' approach to modeling is identified by its breadth of scale from molecular, to particle, and macroscale for applications across reaction chemistry, separations, and biology. [15] His interests also include advanced approaches to couple molecular dynamics with quantum mechanical simulations as well as accelerate stochastic simulations. [16]

Energy, fuels and reactors

Vlachos' research in engineering and science applications in to fuel and energy address broad areas including microreactor design, catalyst design, chemical reaction network development for fuel chemistry, and optimization of energy systems. [17] For example, his research on hydrocarbon microflame stability provides insight into the design principles of microburners. [18] He has also developed molecular-level descriptions of the pyrolysis of cellulose and biomass with applications in renewable biofuels. [19]

Broader impact

His research has had broader impact on the educational and industrial sectors by translation of his interests beyond the university.

His research in collaboration with his colleagues has directly led to the following technologies:

Teaching and advising

Vlachos has supervised and mentored over 50 graduate Ph.D. students and 40 post-doctoral scholars. [24] His advising has produced numerous industrial leaders and faculty in the academia, with several former students at leading institutions of research and education including Jeff Rimer (Univ. of Houston), Mark Snyder (Lehigh University), Ayman Karim (Virginia Tech), George Tsilomelekis (Rutgers University), and Giannis Mpourmpakis (Univ. of Pittsburgh). [25] [26] [27]

Journal publications

Dionisios Vlachos has authored more than 350 journal articles describing significant advances in catalysis, microreactors, and energy applications which include:

Awards and honors

Vlachos' contributions to research, education and service have received numerous awards, many of which demonstrate his interests in catalysis, mathematics and the problems associated with energy and sustainability. In 2016, he was appointed director of the University of Delaware Energy Institute. His appointment was highlighted as:

"Dion Vlachos has an international reputation as a leader in renewable energy research and catalysis,"

Provost Domenico Grasso, Univ. of Delaware 2016 [33]

Other awards and honors include: [34]

Related Research Articles

<span class="mw-page-title-main">Catalysis</span> Process of increasing the rate of a chemical reaction

Catalysis is the increase in rate of a chemical reaction due to an added substance known as a catalyst. Catalysts are not consumed by the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recycles quickly, very small amounts of catalyst often suffice; mixing, surface area, and temperature are important factors in reaction rate. Catalysts generally react with one or more reactants to form intermediates that subsequently give the final reaction product, in the process of regenerating the catalyst.

<span class="mw-page-title-main">Acid catalysis</span> Chemical reaction

In acid catalysis and base catalysis, a chemical reaction is catalyzed by an acid or a base. By Brønsted–Lowry acid–base theory, the acid is the proton (hydrogen ion, H+) donor and the base is the proton acceptor. Typical reactions catalyzed by proton transfer are esterifications and aldol reactions. In these reactions, the conjugate acid of the carbonyl group is a better electrophile than the neutral carbonyl group itself. Depending on the chemical species that act as the acid or base, catalytic mechanisms can be classified as either specific catalysis and general catalysis. Many enzymes operate by general catalysis.

<span class="mw-page-title-main">John Meurig Thomas</span> Welsh chemist

Sir John Meurig Thomas, also known as JMT, was a Welsh scientist, educator, university administrator, and historian of science primarily known for his work on heterogeneous catalysis, solid-state chemistry, and surface and materials science.

<span class="mw-page-title-main">Eugene Houdry</span> French mechanical engineer (1892–1962)

Eugène Jules Houdry was a mechanical engineer who graduated from École Nationale Supérieure d'Arts et Métiers in 1911. Houdry served as a lieutenant in a tank company in the French Army during World War One, receiving the French Legion of Honour. He helped innovate catalytic cracking of petroleum feed stocks, for which he received the Perkin Medal among others.

In chemistry, phase-boundary catalysis (PBC) is a type of heterogeneous catalytic system which facilitates the chemical reaction of a particular chemical component in an immiscible phase to react on a catalytic active site located at a phase boundary. The chemical component is soluble in one phase but insoluble in the other. The catalyst for PBC has been designed in which the external part of the zeolite is hydrophobic, internally it is usually hydrophilic, notwithstanding to polar nature of some reactants. In this sense, the medium environment in this system is close to that of an enzyme. The major difference between this system and enzyme is lattice flexibility. The lattice of zeolite is rigid, whereas the enzyme is flexible.

Reactive flash volatilization (RFV) is a chemical process that rapidly converts nonvolatile solids and liquids to volatile compounds by thermal decomposition for integration with catalytic chemistries.

<span class="mw-page-title-main">Lanny D. Schmidt</span> American physical chemist (1938–2020)

Lanny D. Schmidt was an American chemist, inventor, author, and Regents Professor of Chemical Engineering and Materials Science at the University of Minnesota. He is well known for his extensive work in surface science, detailed chemistry (microkinetics), chemical reaction engineering, catalysis, and renewable energy. He is also well known for mentoring over a hundred graduate students and his work on millisecond reactors and reactive flash volatilization.

Kathleen C. Taylor is a chemist who won the Garvan–Olin Medal in 1989, and is notable for developing catalytic converters for cars.

Paul Ratnasamy is an Indian catalyst scientist, INSA Srinivasa Ramanujan Research Professor and a former director of National Chemical Laboratory of the Council of Scientific and Industrial Research (CSIR). He was honored by the Government of India, in 2001, with one of the highest Indian civilian awards of Padma Shri.

Maria Flytzani-Stephanopoulos was a Greek chemical engineer and, at the time of her death, had been the Robert and Marcy Haber Endowed Professor in Energy Sustainability and a distinguished professor at Tufts University. Flytzani-Stephanopoulos had also been the Raytheon Professor of Pollution Prevention at Tufts. She published more than 160 scientific articles with over 14,000 citations as of April 2018. She was a Fellow of AIChE, the American Association for the Advancement of Science and American Institute of Chemical Engineers. She lived in the Greater Boston Area with her husband, Professor Gregory Stephanopoulos of MIT.

Michael Tsapatsis is an American chemical engineer and materials scientist. Tsapatsis is the 36th Bloomberg Distinguished Professor at Johns Hopkins University in the Department of Chemical and Biomolecular Engineering. Prior to this position he was the Amundson Chair (2008–present), professor (2003-present), and McKnight Presidential Endowed Chair (2017–present) in the department of chemical engineering and Materials Science at the University of Minnesota. Prior to his appointment at the University of Minnesota, Tsapatsis was an associate professor at the University of Massachusetts Amherst.

Raymond John Gorte is an American chemical engineer, currently the Russel Pearce and Elizabeth Crimian Heuer Endowed Professor of Chemical and Biomolecular Engineering (CBE) and Materials Science & Engineering (MSE) at the University of Pennsylvania. Throughout his career at the University of Pennsylvania and the University of Minnesota, he has advanced the study of fuel cells and catalysts including heterogeneous metals and zeolite materials. He is a member of the U.S. National Academy of Engineering.

Herman Pines was a Russian Empire-born American chemist. Born in Łódź—then part of the Russian Empire—he left his hometown as a young man as Jewish quotas and other anti-Jewish practices prevented Jewish students from attending university. After earning a degree in chemical engineering at the École Supérieure de Chimie Industrielle de Lyon in France, he worked at Universal Oil Products from 1930 to 1952. Pines also worked at Northwestern University beginning in 1941, and served from 1953–1970 as the Ipatieff Research Professor of Chemistry and director of the Ipatieff High Pressure and Catalytic Laboratory.

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References

  1. "AAAS Fellows - 2009". AAAS. Retrieved April 7, 2017.
  2. "Thesis - Raymond J. Gorte". ProQuest   303136437.{{cite journal}}: Cite journal requires |journal= (help)
  3. Vlachos, D. G; Schmidt, L. D; Aris, R (1990). "The Effect of Phase Transitions, Surface Diffusion, and Defects on Surface Reactions: Fluctuations and Oscillations". The Journal of Chemical Physics. 93 (11): 8306. doi: 10.1063/1.459313 .
  4. Vlachos, D. G; Schmidt, L. D; Aris, R (1992). "Structures of small metal clusters. II. Phase transitions and isomerization". The Journal of Chemical Physics. 96 (9): 6891. Bibcode:1992JChPh..96.6891V. doi:10.1063/1.462583.
  5. Vlachos, D.G.; Schüth, F.; Aris, R.; Schmidt, L.D. (1992). "Spatial and Temporal Patterns in Catalytic Oscillations". Physica A: Statistical Mechanics and Its Applications. 188 (1–3): 302–321. Bibcode:1992PhyA..188..302V. doi:10.1016/0378-4371(92)90275-U.
  6. "Delaware Center for Catalytic Science & Technology" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  7. "Membership - Catalysis Center for Energy Innovation" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  8. "Leadership - Delaware Energy Institute" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  9. "RAPID - Intensified Process Fundamentals". 2017-10-03. Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  10. Mhadeshwar, A. B; Vlachos, D. G (2005). "Hierarchical multiscale mechanism development for methane partial oxidation and reforming, and for thermal decomposition of oxygenates on Rh". The Journal of Physical Chemistry B. 109 (35): 16819–35. doi:10.1021/jp052479t. PMID   16853141.
  11. Luo, Jing; Arroyo-Ramírez, Lisandra; Gorte, Raymond J; Tzoulaki, Despina; Vlachos, Dionisios G (2015). "Hydrodeoxygenation of HMF Over Pt/C in a Continuous Flow Reactor". AIChE Journal. 61 (2): 590. doi:10.1002/aic.14660.
  12. Sutton, Jonathan E.; Vlachos, Dionisios G. (2015). "Building large microkinetic models with first-principles' accuracy at reduced computational cost". Chemical Engineering Science. 121: 190–199. doi: 10.1016/j.ces.2014.09.011 .
  13. Nikolakis, Vladimiros; Kokkoli, Efrosini; Tirrell, Matthew; Tsapatsis, Michael; Vlachos, Dionisios G (2000). "Zeolite growth by addition of subcolloidal particles: Modeling and experimental validation". Chemistry of Materials. 12 (3): 845. doi:10.1021/cm990653i.
  14. Salama, G.; Morad, M.; Diaz, I.; Nery, J. G.; Sujaoti, K.; Amat, M. A.; Kokkoli, E.; Terasaki, O.; Thompson, R. W.; Tsapatsis, M.; Vlachos, D. G. (2003). "Microstructural optimization of a zeolite membrane for organic vapor separation". Science. 191 (4226): 485–487. Bibcode:2003Sci...300..456L. doi: 10.1126/science.1082169 . PMID   12624179. S2CID   25364470.
  15. "Vlachos Research Group - Research Areas" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  16. "Vlachos Research" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  17. Norton, D.G.; Vlachos, D.G. (2003). "Combustion characteristics and flame stability at the microscale: a CFD study of premixed methane/air mixtures". Chemical Engineering Science. 58 (21): 4871–4882. doi:10.1016/j.ces.2002.12.005.
  18. Norton, D.G.; Vlachos, D.G. (2004). "A CFD study of propane/air microflame stability". Combustion and Flame. 138 (1–2): 97–107. doi:10.1016/j.combustflame.2004.04.004.
  19. Mettler, Matthew S.; Mushrif, Samir H.; Paulsen, Alex D.; Javadekar, Ashay D.; Vlachos, Dionisios G.; Dauenhauer, Paul J. (2012). "Revealing pyrolysis chemistry for biofuels production: Conversion of cellulose to furans and small oxygenates". Energy Environ. Sci. 5: 5414–5424. doi:10.1039/C1EE02743C . Retrieved 2 March 2018.
  20. "New Material Could be the Catalyst to an Eco-Friendly Fuel Cell". 2017-10-09. Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  21. "University of Delaware researchers look to make tires made from plants and wood" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  22. "'Perfect' Soap Molecule" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  23. "Plants into Plastics" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  24. "Vlachos Alumni" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  25. "Giannis Bourmpakis - Univ. of Pittsburgh" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  26. "Mark Snyder - Lehigh University" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  27. "Jeff Rimer - University of Houston". 2016-05-25. Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  28. Nikolakis, Vladimiros; Kokkoli, Efrosini; Tirrell, Matthew; Tsapatsis, Michael; Vlachos, Dionisios G (2000). "Zeolite growth by addition of subcolloidal particles: Modeling and experimental validation". Chemistry of Materials. 12 (3): 845. doi:10.1021/cm990653i.
  29. Salama, G.; Morad, M.; Diaz, I.; Nery, J. G.; Sujaoti, K.; Amat, M. A.; Kokkoli, E.; Terasaki, O.; Thompson, R. W.; Tsapatsis, M.; Vlachos, D. G. (2003). "Microstructural optimization of a zeolite membrane for organic vapor separation". Science. 191 (4226): 485–487. Bibcode:2003Sci...300..456L. doi: 10.1126/science.1082169 . PMID   12624179. S2CID   25364470.
  30. Chen, Ying; Vlachos, Dionisios G (2010). "Hydrogenation of ethylene and dehydrogenation and hydrogenolysis of ethane on Pt (111) and Pt (211): a density functional theory study". The Journal of Physical Chemistry C. 114 (11): 4973. doi:10.1021/jp909163z.
  31. Vorotnikov, Vassili; Mpourmpakis, Giannis; Vlachos, Dionisios G (2012). "DFT study of furfural conversion to furan, furfuryl alcohol, and 2-methylfuran on Pd (111)". ACS Catalysis. 2 (12): 2496. doi:10.1021/cs300395a.
  32. Choudhary, Vinit; Mushrif, Samir H; Ho, Christopher; Anderko, Andrzej; Nikolakis, Vladimiros; Marinkovic, Nebojsa S; Frenkel, Anatoly I; Sandler, Stanley I; Vlachos, Dionisios G (2013). "Insights into the interplay of Lewis and Brønsted acid catalysts in glucose and fructose conversion to 5-(hydroxymethyl) furfural and levulinic acid in aqueous media". Journal of the American Chemical Society. 135 (10): 3997–4006. doi:10.1021/ja3122763. PMID   23432136.
  33. "Vlachos appointed Ferguson Professor and UD Energy Institute Director" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  34. "Dionisios Vlachos" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  35. "Philadelphia Catalysis Club Award" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  36. "Previous iCI Distinguished Lecturers" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  37. "AIChE Wilhelm Award". 2012-03-28. Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  38. "AAAS Fellow - Dionisios Vlachos" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)