Dionisios Vlachos

Last updated
Allan & Myra Ferguson Chair
Dionisios G. Vlachos
Born1964 (age 6162)
Alma mater University of Minnesota
National Technical University of Athens
Known for Catalysis, Reaction Engineering, Microreactors, Biomass
AwardsAIChE Wilhelm Award (2011), AAAS Fellow (2009)
Scientific career
Fields Chemical Engineer
Institutions University of Delaware
Doctoral advisor Lanny D. Schmidt
Rutherford Aris
External videos
Nuvola apps kaboodle.svg “Dion Vlachos as The Allan & Myra Ferguson Professor of Chemical and Biomolecular Engineering” “Catalysis Center for Energy Innovation”

Dionisios G. Vlachos is an American chemical engineer, the Allan & Myra Ferguson Endowed Chair Professor of Chemical Engineering at the University of Delaware and director of the Catalysis Center for Energy Innovation, a U.S. Department of Energy - Energy Frontiers Research Center. Throughout his career at University of Delaware and the University of Minnesota, he has advanced the study of catalysts and reaction engineering including catalytic applications in biomass utilization, alkane conversion and zeolites. He is a fellow of the American Association for the Advancement of Science (AAAS, 2009) and recipient of the Wilhelm Award of the American Institute of Chemical Engineers (2011). [1]

Contents

Early life and education

Dionisios was born in Greece and grew up on the island of Cephalonia, Greece in the Ionian Sea. In 1987, he earned a diploma in chemical engineering from the National Technical University of Athens. He completed a master's degree in 1990 with thesis, "Step Dynamics for Modeling of Crystal Surfaces". He completed his Ph.D. in chemical engineering at the University of Minnesota in 1992 with advisors Lanny D. Schmidt and Rutherford Aris on the topic of dynamic crystal surfaces as it pertains to catalysis. His thesis was published in 1992 with the title, "Structure and Dynamics of Adsorbed Phases and Crystal Surfaces". [2] During his time in graduate school, Dionisios prepared thirteen journal publications with his advisor including:

Professor of chemical engineering

Dr. Vlachos joined the University of Massachusetts Amherst Department of Chemical Engineering in Amherst, MA in 1993 as an assistant professor. He was promoted to associate professor in 1998, after which he took a position as associate professor of chemical engineering at the University of Delaware in 2000. In 2003, he was promoted to the rank of professor of chemical engineering. In 2009, he became the Elizabeth Inez Kelley Professor of Chemical Engineering, a position which he held until 2016. In 2015, he became a professor (joint) of physics and astronomy at the University of Delaware.

Leadership roles

Vlachos has served in leadership roles with national and international oversight of chemical engineering research. In 2008, he became the director of the University of Delaware Center for Catalytic Science and Technology (CCST), which he held until 2011. [6] In 2009, he led the formation of the Catalysis Center for Energy Innovation (CCEI), a national Department of Energy research center with over 70 people from around the United States. [7] In 2016, he was appointed the director of the Delaware Energy Institute (UDEI). [8] He is also the fundamentals division leader within the Dept. of Energy RAPID Manufacturing Institute starting in 2017. [9]

Research

Vlachos' research has focused on four areas of chemical engineering and materials science:

Surface chemistry and catalysis

His contributions to catalysis and surface chemistry have addressed the challenges associated with combining experiment, calculation and modeling for complex catalysis. For example, he has published numerous papers on the reforming of hydrocarbons, including microkinetic descriptions of hundreds of reactions on supported metals. [10] Other research has addressed liquid phase dehydration and/or hydrodeoxygenation of biomass-derived molecules such as furfural, dimethylfuran, or benzoic acid. [11] He has expanded on general approaches to catalytic design by using descriptors in parallel with efforts to develop reaction models with the accuracy of first principles approaches. [12]

Nanoparticles and synthesis

His interest in nanoparticles includes his master's thesis entitled, "Step Dynamics for Modeling of Crystal Surfaces." A focus on crystal structures and growth behavior continued with a focus on the nucleation, growth and design of nanoporous materials including zeolites and MOFs. [13] His research on nanoparticle synthesis was frequently combined in the impact on applications including catalysis, adsorption, and separation via membranes. [14]

Modeling and simulation

Vlachos' approach to modeling is identified by its breadth of scale from molecular, to particle, and macroscale for applications across reaction chemistry, separations, and biology. [15] His interests also include advanced approaches to couple molecular dynamics with quantum mechanical simulations as well as accelerate stochastic simulations. [16]

Energy, fuels and reactors

Vlachos' research in engineering and science applications in to fuel and energy address broad areas including microreactor design, catalyst design, chemical reaction network development for fuel chemistry, and optimization of energy systems. [17] For example, his research on hydrocarbon microflame stability provides insight into the design principles of microburners. [18] He has also developed molecular-level descriptions of the pyrolysis of cellulose and biomass with applications in renewable biofuels. [19]

Broader impact

His research has had broader impact on the educational and industrial sectors by translation of his interests beyond the university.

His research in collaboration with his colleagues has directly led to the following technologies:

Teaching and advising

Vlachos has supervised and mentored over 50 graduate Ph.D. students and 40 post-doctoral scholars. [24] His advising has produced numerous industrial leaders and faculty in the academia, with several former students at leading institutions of research and education including Jeff Rimer (Univ. of Houston), Mark Snyder (Lehigh University), Ayman Karim (Virginia Tech), George Tsilomelekis (Rutgers University), and Giannis Mpourmpakis (Univ. of Pittsburgh). [25] [26] [27]

Journal publications

Dionisios Vlachos has authored more than 350 journal articles describing significant advances in catalysis, microreactors, and energy applications which include:

Awards and honors

Vlachos' contributions to research, education and service have received numerous awards, many of which demonstrate his interests in catalysis, mathematics and the problems associated with energy and sustainability. In 2016, he was appointed director of the University of Delaware Energy Institute. His appointment was highlighted as:

"Dion Vlachos has an international reputation as a leader in renewable energy research and catalysis,"

Provost Domenico Grasso, Univ. of Delaware 2016 [33]

Other awards and honors include: [34]

References

  1. "AAAS Fellows - 2009". AAAS. Retrieved April 7, 2017.
  2. "Thesis - Raymond J. Gorte". ProQuest   303136437.{{cite journal}}: Cite journal requires |journal= (help)
  3. Vlachos, D. G; Schmidt, L. D; Aris, R (1990). "The Effect of Phase Transitions, Surface Diffusion, and Defects on Surface Reactions: Fluctuations and Oscillations". The Journal of Chemical Physics. 93 (11): 8306. doi: 10.1063/1.459313 .
  4. Vlachos, D. G; Schmidt, L. D; Aris, R (1992). "Structures of small metal clusters. II. Phase transitions and isomerization". The Journal of Chemical Physics. 96 (9): 6891. Bibcode:1992JChPh..96.6891V. doi:10.1063/1.462583.
  5. Vlachos, D.G.; Schüth, F.; Aris, R.; Schmidt, L.D. (1992). "Spatial and Temporal Patterns in Catalytic Oscillations". Physica A: Statistical Mechanics and Its Applications. 188 (1–3): 302–321. Bibcode:1992PhyA..188..302V. doi:10.1016/0378-4371(92)90275-U.
  6. "Delaware Center for Catalytic Science & Technology" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)[ dead link ]
  7. "Membership - Catalysis Center for Energy Innovation" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  8. "Leadership - Delaware Energy Institute" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)[ dead link ]
  9. "RAPID - Intensified Process Fundamentals". 2017-10-03. Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  10. Mhadeshwar, A. B; Vlachos, D. G (2005). "Hierarchical multiscale mechanism development for methane partial oxidation and reforming, and for thermal decomposition of oxygenates on Rh". The Journal of Physical Chemistry B. 109 (35): 16819–35. Bibcode:2005JPCB..10916819M. doi:10.1021/jp052479t. PMID   16853141.
  11. Luo, Jing; Arroyo-Ramírez, Lisandra; Gorte, Raymond J; Tzoulaki, Despina; Vlachos, Dionisios G (2015). "Hydrodeoxygenation of HMF Over Pt/C in a Continuous Flow Reactor". AIChE Journal. 61 (2): 590. Bibcode:2015AIChE..61..590L. doi:10.1002/aic.14660. OSTI   1400877.
  12. Sutton, Jonathan E.; Vlachos, Dionisios G. (2015). "Building large microkinetic models with first-principles' accuracy at reduced computational cost". Chemical Engineering Science. 121: 190–199. Bibcode:2015ChEnS.121..190S. doi: 10.1016/j.ces.2014.09.011 .
  13. Nikolakis, Vladimiros; Kokkoli, Efrosini; Tirrell, Matthew; Tsapatsis, Michael; Vlachos, Dionisios G (2000). "Zeolite growth by addition of subcolloidal particles: Modeling and experimental validation". Chemistry of Materials. 12 (3): 845. doi:10.1021/cm990653i.
  14. Salama, G.; Morad, M.; Diaz, I.; Nery, J. G.; Sujaoti, K.; Amat, M. A.; Kokkoli, E.; Terasaki, O.; Thompson, R. W.; Tsapatsis, M.; Vlachos, D. G. (2003). "Microstructural optimization of a zeolite membrane for organic vapor separation". Science. 191 (4226): 485–487. Bibcode:2003Sci...300..456L. doi: 10.1126/science.1082169 . PMID   12624179. S2CID   25364470.
  15. "Vlachos Research Group - Research Areas" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  16. "Vlachos Research" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  17. Norton, D.G.; Vlachos, D.G. (2003). "Combustion characteristics and flame stability at the microscale: a CFD study of premixed methane/air mixtures". Chemical Engineering Science. 58 (21): 4871–4882. Bibcode:2003ChEnS..58.4871N. doi:10.1016/j.ces.2002.12.005.
  18. Norton, D.G.; Vlachos, D.G. (2004). "A CFD study of propane/air microflame stability". Combustion and Flame. 138 (1–2): 97–107. Bibcode:2004CoFl..138...97N. doi:10.1016/j.combustflame.2004.04.004.
  19. Mettler, Matthew S.; Mushrif, Samir H.; Paulsen, Alex D.; Javadekar, Ashay D.; Vlachos, Dionisios G.; Dauenhauer, Paul J. (2012). "Revealing pyrolysis chemistry for biofuels production: Conversion of cellulose to furans and small oxygenates". Energy Environ. Sci. 5 (1): 5414–5424. Bibcode:2012EnEnS...5.5414M. doi:10.1039/C1EE02743C. Archived from the original on 22 April 2018. Retrieved 2 March 2018.
  20. "New Material Could be the Catalyst to an Eco-Friendly Fuel Cell". 2017-10-09. Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  21. "University of Delaware researchers look to make tires made from plants and wood" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  22. "'Perfect' Soap Molecule" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  23. "Plants into Plastics" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  24. "Vlachos Alumni" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)[ dead link ]
  25. "Giannis Bourmpakis - Univ. of Pittsburgh". Archived from the original on 16 March 2018. Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  26. "Mark Snyder - Lehigh University" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  27. "Jeff Rimer - University of Houston". 2016-05-25. Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  28. Nikolakis, Vladimiros; Kokkoli, Efrosini; Tirrell, Matthew; Tsapatsis, Michael; Vlachos, Dionisios G (2000). "Zeolite growth by addition of subcolloidal particles: Modeling and experimental validation". Chemistry of Materials. 12 (3): 845. doi:10.1021/cm990653i.
  29. Salama, G.; Morad, M.; Diaz, I.; Nery, J. G.; Sujaoti, K.; Amat, M. A.; Kokkoli, E.; Terasaki, O.; Thompson, R. W.; Tsapatsis, M.; Vlachos, D. G. (2003). "Microstructural optimization of a zeolite membrane for organic vapor separation". Science. 191 (4226): 485–487. Bibcode:2003Sci...300..456L. doi: 10.1126/science.1082169 . PMID   12624179. S2CID   25364470.
  30. Chen, Ying; Vlachos, Dionisios G (2010). "Hydrogenation of ethylene and dehydrogenation and hydrogenolysis of ethane on Pt (111) and Pt (211): a density functional theory study". The Journal of Physical Chemistry C. 114 (11): 4973. doi:10.1021/jp909163z.
  31. Vorotnikov, Vassili; Mpourmpakis, Giannis; Vlachos, Dionisios G (2012). "DFT study of furfural conversion to furan, furfuryl alcohol, and 2-methylfuran on Pd (111)". ACS Catalysis. 2 (12): 2496. doi:10.1021/cs300395a.
  32. Choudhary, Vinit; Mushrif, Samir H; Ho, Christopher; Anderko, Andrzej; Nikolakis, Vladimiros; Marinkovic, Nebojsa S; Frenkel, Anatoly I; Sandler, Stanley I; Vlachos, Dionisios G (2013). "Insights into the interplay of Lewis and Brønsted acid catalysts in glucose and fructose conversion to 5-(hydroxymethyl) furfural and levulinic acid in aqueous media". Journal of the American Chemical Society. 135 (10): 3997–4006. Bibcode:2013JAChS.135.3997C. doi:10.1021/ja3122763. PMID   23432136.
  33. "Vlachos appointed Ferguson Professor and UD Energy Institute Director" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  34. "Dionisios Vlachos" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  35. "Philadelphia Catalysis Club Award" . Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  36. "Previous iCI Distinguished Lecturers". Archived from the original on 24 March 2018. Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  37. "AIChE Wilhelm Award". 2012-03-28. Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)
  38. "AAAS Fellow - Dionisios Vlachos". Archived from the original on 22 April 2018. Retrieved 2 March 2018.{{cite journal}}: Cite journal requires |journal= (help)