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Donald DePaolo | |
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![]() Donald J. DePaolo on a University of California Berkeley field trip, 2009 | |
Born | Donald James DePaolo 1951 (age 73–74) |
Nationality | American |
Alma mater | Binghamton University California Institute of Technology |
Scientific career | |
Fields | Earth science |
Institutions | University of California, Berkeley |
Doctoral advisor | Gerald Wasserburg |
Doctoral students | Daniel P. Schrag |
Donald James DePaolo (born 1951) is an American professor of geochemistry in the department of earth and planetary science at the University of California, Berkeley and associate laboratory director for energy and environmental sciences at the Lawrence Berkeley National Laboratory.
DePaolo was born in 1951 and grew up in upstate New York.[ citation needed ]
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DePaolo received his B.S. degree with honors in geology from Binghamton University in 1973 and earned his Ph.D. in geology with a minor in chemistry under Gerald Wasserburg at the California Institute of Technology in 1978. That same year, he began an assistant professorship at the University of California, Los Angeles Department of Geology and Geochemistry and subsequently earned his associate (1981–1983) and full professorship (1983–1988).
In 1988, he began his term as professor of geochemistry at the University of California, Berkeley in the department of earth and planetary science, with a joint appointment as a faculty scientist in the earth sciences division at the Lawrence Berkeley National Laboratory. Upon his arrival at LBNL, DePaolo established the Center for Isotope Geochemistry, a joint research facility between LBNL and UC Berkeley.
In 1998, he was made the Class of 1951 Professor of Geochemistry, and served as chair of the department from 1990 to 1993. From 1998 to 2006 DePaolo served as geochemistry department head at LBNL; in 2007 he became earth sciences division director and from 2010 to 2011 he served as acting associate laboratory director for energy and environmental sciences before accepting the position permanently on April 1, 2011. In 2009, DePaolo became the director of the Center for Nanoscale Control of Geologic CO2 (EFRC).
DePaolo has coauthored over 300 peer-reviewed articles and reviews. His research interests focus on using naturally occurring isotope variations to explore questions such as:
In his early career, DePaolo pioneered the use of samarium and neodymium isotope ratios to constrain the age and chemical evolution of rocks. DePaolo and his then advisor Gerald Wasserburg made the first Nd isotope measurements on terrestrial igneous rocks. An important byproduct of this work was the development of epsilon notation (ε), with which initial 143Nd/144Nd values could be distinguished from the chondritic uniform reservoir (CHUR) in parts per ten thousand. Key principles of the Nd isotope system were laid out in his 1988 book, Neodymium Isotope Geochemistry: An Introduction.
DePaolo's work has since led to significant advances in using various isotope systems to constrain rates of metamorphic processes [6], quantify continental weathering and elemental seawater budgets through geologic time and model fluid-rock interactions. As principal investigator of the Hawaii Scientific Drilling Project (HSDP), DePaolo and coworkers sampled the flank of Mauna Kea volcano to a depth of several kilometers. Major findings included a determination of the geochemical structure of the Hawaiian mantle plume. His recent research provides a framework for understanding the partitioning of stable isotopes during mineral growth, [20] [21] [22] with a focus on isotopes of calcium. [23] [24]
A micrometeorite is a micrometeoroid that has survived entry through the Earth's atmosphere. Usually found on Earth's surface, micrometeorites differ from meteorites in that they are smaller in size, more abundant, and different in composition. The IAU officially defines meteoroids as 30 micrometers to 1 meter; micrometeorites are the small end of the range (~submillimeter). They are a subset of cosmic dust, which also includes the smaller interplanetary dust particles (IDPs).
Meteoritics is the science that deals with meteors, meteorites, and meteoroids. It is closely connected to cosmochemistry, mineralogy and geochemistry. A specialist who studies meteoritics is known as a meteoriticist.
Calcium (20Ca) has 26 known isotopes, ranging from 35Ca to 60Ca. There are five stable isotopes, plus one isotope (48Ca) with such a long half-life that it is for all practical purposes stable. The most abundant isotope, 40Ca, as well as the rare 46Ca, are theoretically unstable on energetic grounds, but their decay has not been observed. Calcium also has a cosmogenic isotope, 41Ca, with half-life 99,400 years. Unlike cosmogenic isotopes that are produced in the air, 41Ca is produced by neutron activation of 40Ca. Most of its production is in the upper metre of the soil column, where the cosmogenic neutron flux is still strong enough. 41Ca has received much attention in stellar studies because it decays to 41K, a critical indicator of solar system anomalies. The most stable artificial isotopes are 45Ca with half-life 163 days and 47Ca with half-life 4.5 days. All other calcium isotopes have half-lives of minutes or less.
A paleothermometer is a methodology that provides an estimate of the ambient temperature at the time of formation of a natural material. Most paleothermometers are based on empirically-calibrated proxy relationships, such as the tree ring or TEX86 methods. Isotope methods, such as the δ18O method or the clumped-isotope method, are able to provide, at least in theory, direct measurements of temperature.
The Lunar Magma Ocean (LMO) is the layer of molten rock that is theorized to have been present on the surface of the Moon. The LMO was likely present on the Moon from the time of the Moon's formation to tens or hundreds of millions of years after that time. The LMO was a thermodynamic consequence of the Moon's relatively rapid formation in the aftermath of a giant impact between the proto-Earth and another planetary body. As the Moon accreted from the debris from the giant impact, gravitational potential energy was converted to thermal energy. Due to the rapid accretion of the Moon, thermal energy was trapped since it did not have sufficient time to thermally radiate away energy through the lunar surface. The subsequent thermochemical evolution of the LMO explains the Moon's largely anorthositic crust, europium anomaly, and KREEP material.
Clumped isotopes are heavy isotopes that are bonded to other heavy isotopes. The relative abundance of clumped isotopes (and multiply-substituted isotopologues) in molecules such as methane, nitrous oxide, and carbonate is an area of active investigation. The carbonate clumped-isotope thermometer, or "13C–18O order/disorder carbonate thermometer", is a new approach for paleoclimate reconstruction, based on the temperature dependence of the clumping of 13C and 18O into bonds within the carbonate mineral lattice. This approach has the advantage that the 18O ratio in water is not necessary (different from the δ18O approach), but for precise paleotemperature estimation, it also needs very large and uncontaminated samples, long analytical runs, and extensive replication. Commonly used sample sources for paleoclimatological work include corals, otoliths, gastropods, tufa, bivalves, and foraminifera. Results are usually expressed as Δ47 (said as "cap 47"), which is the deviation of the ratio of isotopologues of CO2 with a molecular weight of 47 to those with a weight of 44 from the ratio expected if they were randomly distributed.
Robert Norman Clayton was a Canadian-American chemist and academic. He was the Enrico Fermi Distinguished Service Professor Emeritus of Chemistry at the University of Chicago. Clayton studied cosmochemistry and held a joint appointment in the university's geophysical sciences department. He was a member of the National Academy of Sciences and was named a fellow of several academic societies, including the Royal Society.
Dimitri Alexander Sverjensky is a professor in Earth and Planetary Sciences at Johns Hopkins University where his research is focused on geochemistry.
Anat Shahar is a staff scientist at the Earth and Planets Laboratory, Carnegie Institution of Washington and adjunct professor at the University of Maryland. Her work uses high-pressure, high-temperature experiments and stable isotope geochemistry to understand the formation of planets in the Solar System.
Carbonate-associated sulfates (CAS) are sulfate species found in association with carbonate minerals, either as inclusions, adsorbed phases, or in distorted sites within the carbonate mineral lattice. It is derived primarily from dissolved sulfate in the solution from which the carbonate precipitates. In the ocean, the source of this sulfate is a combination of riverine and atmospheric inputs, as well as the products of marine hydrothermal reactions and biomass remineralisation. CAS is a common component of most carbonate rocks, having concentrations in the parts per thousand within biogenic carbonates and parts per million within abiogenic carbonates. Through its abundance and sulfur isotope composition, it provides a valuable record of the global sulfur cycle across time and space.
Toshiko K. Mayeda was a Japanese American chemist who worked at the Enrico Fermi Institute in the University of Chicago. She worked on climate science and meteorites from 1958 to 2004.
Roberta L. Rudnick is an American earth scientist and professor of geology at the University of California, Santa Barbara. She was elected a member of the National Academy of Sciences in 2010 and was awarded the Dana Medal by the Mineralogical Society of America. Rudnick is a world expert in the continental crust and lithosphere.
Hafnium–tungsten dating is a geochronological radiometric dating method utilizing the radioactive decay system of hafnium-182 to tungsten-182. The half-life of the system is 8.9±0.1 million years. Today hafnium-182 is an extinct radionuclide, but the hafnium–tungsten radioactive system is useful in studies of the early Solar system since hafnium is lithophilic while tungsten is moderately siderophilic, which allows the system to be used to date the differentiation of a planet's core. It is also useful in determining the formation times of the parent bodies of iron meteorites.
Gas-rich meteorites are meteorites with high levels of primordial gases, such as helium, neon, argon, krypton, xenon and sometimes other elements. Though these gases are present "in virtually all meteorites," the Fayetteville meteorite has ~2,000,000 x10−8 ccSTP/g helium, or ~2% helium by volume equivalent. In comparison, background level is a few ppm.
Sulfur isotope biogeochemistry is the study of the distribution of sulfur isotopes in biological and geological materials. In addition to its common isotope, 32S, sulfur has three rare stable isotopes: 34S, 36S, and 33S. The distribution of these isotopes in the environment is controlled by many biochemical and physical processes, including biological metabolisms, mineral formation processes, and atmospheric chemistry. Measuring the abundance of sulfur stable isotopes in natural materials, like bacterial cultures, minerals, or seawater, can reveal information about these processes both in the modern environment and over Earth history.
Ghislaine Crozaz is a cosmochemist known for her research on the early history of the solar system through tracking trace elements in meteorites.
Ariel Anbar is an isotope geochemist and President's Professor at Arizona State University. He has published over 180 refereed papers on topics ranging from the origins of Earth's atmosphere to detecting life on other worlds to diagnosing human disease.
Catherine Chauvel is a geochemist at the Institut de Physique du Globe de Paris known for her research on the impact of volcanic activity on the chemistry of the mantle, continental crust, and island arc geochemistry.
Diamond inclusions are the non-diamond materials that get encapsulated inside diamond during its formation process in the mantle. The trapped materials can be other minerals or fluids like water. Since diamonds have high strength and low reactivity with either the inclusion or the volcanic host rocks which carry the diamond to the Earth's surface, the diamond serves as a container that preserves the included material intact under the changing conditions from the mantle to the surface. Although diamonds can only place a lower bound on the pressure of their formation, many inclusions provide additional constraints on the pressure, temperature and even age of formation.
Silicon isotope biogeochemistry is the study of environmental processes using the relative abundance of Si isotopes. As the relative abundance of Si stable isotopes varies among different natural materials, the differences in abundance can be used to trace the source of Si, and to study biological, geological, and chemical processes. The study of stable isotope biogeochemistry of Si aims to quantify the different Si fluxes in the global biogeochemical silicon cycle, to understand the role of biogenic silica within the global Si cycle, and to investigate the applications and limitations of the sedimentary Si record as an environmental and palaeoceanographic proxy.
2019 Donald J. DePaolo