Edenite | |
---|---|
General | |
Category | Amphibole mineral |
Formula (repeating unit) | NaCa2Mg5(Si7Al)O22(OH)2 |
IMA symbol | Ed [1] |
Strunz classification | 9.DE.15 |
Crystal system | Monoclinic |
Crystal class | Prismatic (2/m) (same H-M symbol) |
Space group | C2/m |
Unit cell | a = 9.83, b = 17.95 c = 5.3 [Å], β = 105.18°; Z = 2 |
Identification | |
Formula mass | 834.25 g/mol |
Color | White to gray, pale to dark green, also brown and pale pinkish-brown |
Crystal habit | Prismatic crystals, fibrous, as reaction rims on pyroxenes |
Twinning | Simple or multiple parallel to {010} |
Cleavage | Good on (110) |
Fracture | Conchoidal |
Tenacity | Brittle |
Mohs scale hardness | 5–6 |
Luster | Vitreous |
Streak | White |
Diaphaneity | Semitransparent |
Specific gravity | 3.05–3.37 |
Optical properties | Biaxial (+) |
Refractive index | nα = 1.606 – 1.649, nβ = 1.617 – 1.660, nγ = 1.631 – 1.672 |
Birefringence | δ = 0.025 |
Pleochroism | Distinct, greens, blue-greens, and yellow-browns |
2V angle | 50–82° |
References | [2] [3] [4] [5] |
Edenite or edenitic hornblende is a double chain silicate mineral of the amphibole group with the general chemical composition NaCa2Mg5(Si7Al)O22(OH)2. Edenite is named for the locality of Edenville, Orange County, New York, where it was first described. [4]
Edenite has been found primarily in metamorphic rocks, occurring in pods of other magnesium-rich minerals within a marble formation or with garnet-rich lherzolites from deep within the Earth's crust. [6] [7] Thus, finding edenite in the field can indicate high-temperature regional metamorphism of the surrounding rocks.
While edenite is not important for commercial or industrial applications, it is often studied because of its unique chemical substitution properties. Results from research performed on amphiboles have shown that edenite is particularly suited for fitting chloride anions into its chemical framework. [8] This makes edenite a good candidate for use in chlorine isotope fractionation in amphibole-bearing rocks. Many synthetic variations of edenite are also used in geochemical research to produce a boron analogue of fluoroedenite. [9]
Edenite is a member of the monoclinic crystal system and is in the crystal class 2/m (space group C2/m). [6] This means crystalline edenite is symmetrical around a two-fold rotation axis that is then reflected across a mirror plane perpendicular to the long axis of the mineral. [10]
Edenite is a biaxial positive mineral. When viewed in thin section with a petrographic microscope, it is white-gray with pale green pleochroism in plane-polarized light. Under crossed polars, its interference colors range from first order gray to first order blue. [3]
Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks.
Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO
4 tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.
Tremolite is a member of the amphibole group of silicate minerals with composition: Ca2(Mg5.0-4.5Fe2+0.0-0.5)Si8O22(OH)2. Tremolite forms by metamorphism of sediments rich in dolomite and quartz. Tremolite forms a series with actinolite and ferro-actinolite. Pure magnesium tremolite is creamy white, but the color grades to dark green with increasing iron content. It has a hardness on Mohs scale of 5 to 6. Nephrite, one of the two minerals known as the gemstone jade, is a green variety of tremolite.
Glaucophane is the name of a mineral and a mineral group belonging to the sodic amphibole supergroup of the double chain inosilicates, with the chemical formula ☐Na2(Mg3Al2)Si8O22(OH)2.
Cummingtonite is a metamorphic amphibole with the chemical composition (Mg,Fe2+
)
2(Mg,Fe2+
)
5Si
8O
22(OH)
2, magnesium iron silicate hydroxide.
Omphacite is a member of the clinopyroxene group of silicate minerals with formula: (Ca, Na)(Mg, Fe2+, Al)Si2O6. It is a variably deep to pale green or nearly colorless variety of clinopyroxene. It normally appears in eclogite, which is the high-pressure metamorphic rock of basalt. Omphacite is the solid solution of Fe-bearing diopside and jadeite. It crystallizes in the monoclinic system with prismatic, typically twinned forms, though usually anhedral. Its space group can be P2/n or C2/c depending on the thermal history. It exhibits the typical near 90° pyroxene cleavage. It is brittle with specific gravity of 3.29 to 3.39 and a Mohs hardness of 5 to 6.
Frank Christopher Hawthorne is a Canadian mineralogist, crystallographer and spectroscopist. He works at the University of Manitoba, Winnipeg, Manitoba, Canada, and is currently Distinguished Professor Emeritus. By combining Graph Theory, Bond-Valence Theory and the moments approach to the electronic energy density of solids he has developed Bond Topology as a rigorous approach to understanding the atomic arrangements, chemical compositions and paragenesis of complex oxide and oxysalt minerals.
In inorganic chemistry, mineral hydration is a reaction which adds water to the crystal structure of a mineral, usually creating a new mineral, commonly called a hydrate.
Geothermobarometry is the methodology for estimating the pressure and temperature history of rocks. Geothermobarometry is a combination of geobarometry, where the pressure attained by a mineral assemblage is estimated, and geothermometry where the temperature attained by a mineral assemblage is estimated.
Mackinawite is an iron nickel sulfide mineral with the chemical formula (Fe,Ni)
1+xS. The mineral crystallizes in the tetragonal crystal system and has been described as a distorted, close packed, cubic array of S atoms with some of the gaps filled with Fe. Mackinawite occurs as opaque bronze to grey-white tabular crystals and anhedral masses. It has a Mohs hardness of 2.5 and a specific gravity of 4.17. It was first described in 1962 for an occurrence in the Mackinaw mine, Snohomish County, Washington for which it was named.
Majorite is a type of garnet mineral found in the mantle of the Earth. Its chemical formula is Mg3(MgSi)(SiO4)3. It is distinguished from other garnets in having Si in octahedral as well as tetrahedral coordination. Majorite was first described in 1970 from the Coorara Meteorite of Western Australia and has been reported from various other meteorites in which majorite is thought to result from an extraterrestrial high pressure shock event. Mantle derived xenoliths containing majorite have been reported from potassic ultramafic magmas on Malaita Island on the Ontong Java Plateau Southwest Pacific.
The endmember hornblende tschermakite (☐Ca2(Mg3Al2)(Si6Al2)O22(OH)2) is a calcium rich monoclinic amphibole mineral. It is frequently synthesized along with its ternary solid solution series members tremolite and cummingtonite so that the thermodynamic properties of its assemblage can be applied to solving other solid solution series from a variety of amphibole minerals.
Betafite is a mineral group in the pyrochlore supergroup, with the chemical formula (Ca,U)2(Ti,Nb,Ta)2O6(OH). Betafite typically occurs as a primary mineral in granite pegmatites, rarely in carbonatites. Originally defined by the B-site atom Ti, the development of new nomenclature for mineral names led to modernization of the system for nomenclature of pyrochlore and betafite in order to further rationalize the naming process of this grouping of minerals. Only two of the mineral species that were formerly recognized as betafite are presently retained. They are oxyuranobetafite and oxycalciobetafite. The term betafite is now a synonym or varietal group name under the pyrochlore super group.
Gedrite is a crystal belonging to the orthorhombic ferromagnesian subgroup of the amphibole supergroup of the double chain inosilicate minerals with the ideal chemical formula Mg2(Mg3Al2)(Si6Al2)O22(OH)2.
The Zakłodzie meteorite is a stony-iron meteorite found in Poland in 1998. Its mass is 8.68 kilograms (19.1 lb). It is composed predominantly from enstatite and meteoric iron. Currently classified as an ungrouped enstatite achondrite its classification is still an ongoing scientific debate.
Gugiaite is a melilite mineral, named for the Chinese village of Gugia where it was first discovered. Its chemical formula is Ca2BeSi2O7. It occurs mostly in skarns with melanite adjacent to an alkali syenite and has no economic value. Its crystals are small tetragonal tablets with vitreous luster and perfect cleavage. It is colorless and transparent with a density of three. The mineral belongs to space group P421m and is strongly piezoelectric.
Ferrogedrite is an amphibole mineral with the complex chemical formula of ☐Fe2+2(Fe2+3Al2)(Si6Al2)O22(OH)2. It is sodium and calcium poor, making it part of the magnesium-iron-manganese-lithium amphibole subgroup. Defined as less than 1.00 apfu (atoms per formula unit) of Na + Ca and consisting of greater than 1.00 apfu of (Mg, Fe2+, Mn2+, Li) separating it from the calcic-sodic amphiboles. It is related to anthophyllite amphibole and gedrite through coupled substitution of (Al, Fe3+) for (Mg, Fe2+, Mn) and Al for Si. and determined by the content of silicon in the standard cell.
Rockbridgeite is an anhydrous phosphate mineral in the "Rockbridgeite" supergroup with the chemical formula Fe2+Fe3+4(PO4)3(OH)5. It was discovered at the since-shut-down Midvale Mine in Rockbridge County, Virginia, United States. The researcher who first identified it, Clifford Frondel, named it in 1949 for its region of discovery, Rockbridge County.