Edenite

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Edenite
Edenite-188165.jpg
Edenite crystal from Bancroft District, Ontario
General
Category Amphibole mineral
Formula
(repeating unit)
NaCa2Mg5(Si7Al)O22(OH)2
IMA symbol Ed [1]
Strunz classification 9.DE.15
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group C2/m
Unit cell a = 9.83, b = 17.95
c = 5.3 [Å], β = 105.18°; Z = 2
Identification
Formula mass 834.25 g/mol
ColorWhite to gray, pale to dark green, also brown and pale pinkish-brown
Crystal habit Prismatic crystals, fibrous, as reaction rims on pyroxenes
Twinning Simple or multiple parallel to {010}
Cleavage Good on (110)
Fracture Conchoidal
Tenacity Brittle
Mohs scale hardness5–6
Luster Vitreous
Streak White
Diaphaneity Semitransparent
Specific gravity 3.05–3.37
Optical propertiesBiaxial (+)
Refractive index nα = 1.606 – 1.649, nβ = 1.617 – 1.660, nγ = 1.631 – 1.672
Birefringence δ = 0.025
Pleochroism Distinct, greens, blue-greens, and yellow-browns
2V angle 50–82°
References [2] [3] [4] [5]

Edenite or edenitic hornblende is a double chain silicate mineral of the amphibole group with the general chemical composition NaCa2Mg5(Si7Al)O22(OH)2. Edenite is named for the locality of Edenville, Orange County, New York, where it was first described. [4]

Contents

Occurrence

Edenite has been found primarily in metamorphic rocks, occurring in pods of other magnesium-rich minerals within a marble formation or with garnet-rich lherzolites from deep within the Earth's crust. [6] [7] Thus, finding edenite in the field can indicate high-temperature regional metamorphism of the surrounding rocks.

Uses and importance

While edenite is not important for commercial or industrial applications, it is often studied because of its unique chemical substitution properties. Results from research performed on amphiboles have shown that edenite is particularly suited for fitting chloride anions into its chemical framework. [8] This makes edenite a good candidate for use in chlorine isotope fractionation in amphibole-bearing rocks. Many synthetic variations of edenite are also used in geochemical research to produce a boron analogue of fluoroedenite. [9]

Crystal habit

Edenite is a member of the monoclinic crystal system and is in the crystal class 2/m (space group C2/m). [6] This means crystalline edenite is symmetrical around a two-fold rotation axis that is then reflected across a mirror plane perpendicular to the long axis of the mineral. [10]

Optical properties

Edenite is a biaxial positive mineral. When viewed in thin section with a petrographic microscope, it is white-gray with pale green pleochroism in plane-polarized light. Under crossed polars, its interference colors range from first order gray to first order blue. [3]

Related Research Articles

<span class="mw-page-title-main">Hornblende</span> Complex inosilicate series of minerals

Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks.

<span class="mw-page-title-main">Amphibole</span> Group of inosilicate minerals

Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO
4
tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.

<span class="mw-page-title-main">Tremolite</span> Amphibole, double chain inosilicate mineral

Tremolite is a member of the amphibole group of silicate minerals with composition: Ca2(Mg5.0-4.5Fe2+0.0-0.5)Si8O22(OH)2. Tremolite forms by metamorphism of sediments rich in dolomite and quartz. Tremolite forms a series with actinolite and ferro-actinolite. Pure magnesium tremolite is creamy white, but the color grades to dark green with increasing iron content. It has a hardness on Mohs scale of 5 to 6. Nephrite, one of the two minerals known as the gemstone jade, is a green variety of tremolite.

<span class="mw-page-title-main">Glaucophane</span>

Glaucophane is the name of a mineral and a mineral group belonging to the sodic amphibole supergroup of the double chain inosilicates, with the chemical formula ☐Na2(Mg3Al2)Si8O22(OH)2.

<span class="mw-page-title-main">Cummingtonite</span> Silicate mineral

Cummingtonite is a metamorphic amphibole with the chemical composition (Mg,Fe2+
)
2
(Mg,Fe2+
)
5
Si
8
O
22
(OH)
2
, magnesium iron silicate hydroxide.

<span class="mw-page-title-main">Omphacite</span> Member of the clinopyroxene group of silicate minerals

Omphacite is a member of the clinopyroxene group of silicate minerals with formula: (Ca, Na)(Mg, Fe2+, Al)Si2O6. It is a variably deep to pale green or nearly colorless variety of clinopyroxene. It normally appears in eclogite, which is the high-pressure metamorphic rock of basalt. Omphacite is the solid solution of Fe-bearing diopside and jadeite. It crystallizes in the monoclinic system with prismatic, typically twinned forms, though usually anhedral. Its space group can be P2/n or C2/c depending on the thermal history. It exhibits the typical near 90° pyroxene cleavage. It is brittle with specific gravity of 3.29 to 3.39 and a Mohs hardness of 5 to 6.

<span class="mw-page-title-main">Frank Hawthorne</span> Canadian mineralogist and crystallographer

Frank Christopher Hawthorne is a Canadian mineralogist, crystallographer and spectroscopist. He works at the University of Manitoba, Winnipeg, Manitoba, Canada, and is currently Distinguished Professor Emeritus. By combining Graph Theory, Bond-Valence Theory and the moments approach to the electronic energy density of solids he has developed Bond Topology as a rigorous approach to understanding the atomic arrangements, chemical compositions and paragenesis of complex oxide and oxysalt minerals.

In inorganic chemistry, mineral hydration is a reaction which adds water to the crystal structure of a mineral, usually creating a new mineral, commonly called a hydrate.

<span class="mw-page-title-main">Geothermobarometry</span> History of rock pressure and temperature

Geothermobarometry is the methodology for estimating the pressure and temperature history of rocks. Geothermobarometry is a combination of geobarometry, where the pressure attained by a mineral assemblage is estimated, and geothermometry where the temperature attained by a mineral assemblage is estimated.

<span class="mw-page-title-main">Mackinawite</span> Iron nickel sulfide mineral

Mackinawite is an iron nickel sulfide mineral with the chemical formula (Fe,Ni)
1+x
S
. The mineral crystallizes in the tetragonal crystal system and has been described as a distorted, close packed, cubic array of S atoms with some of the gaps filled with Fe. Mackinawite occurs as opaque bronze to grey-white tabular crystals and anhedral masses. It has a Mohs hardness of 2.5 and a specific gravity of 4.17. It was first described in 1962 for an occurrence in the Mackinaw mine, Snohomish County, Washington for which it was named.

<span class="mw-page-title-main">Majorite</span> Garnet mineral

Majorite is a type of garnet mineral found in the mantle of the Earth. Its chemical formula is Mg3(MgSi)(SiO4)3. It is distinguished from other garnets in having Si in octahedral as well as tetrahedral coordination. Majorite was first described in 1970 from the Coorara Meteorite of Western Australia and has been reported from various other meteorites in which majorite is thought to result from an extraterrestrial high pressure shock event. Mantle derived xenoliths containing majorite have been reported from potassic ultramafic magmas on Malaita Island on the Ontong Java Plateau Southwest Pacific.

<span class="mw-page-title-main">Tschermakite</span> Amphibole, double chain inosilicate mineral

The endmember hornblende tschermakite (☐Ca2(Mg3Al2)(Si6Al2)O22(OH)2) is a calcium rich monoclinic amphibole mineral. It is frequently synthesized along with its ternary solid solution series members tremolite and cummingtonite so that the thermodynamic properties of its assemblage can be applied to solving other solid solution series from a variety of amphibole minerals.

<span class="mw-page-title-main">Betafite</span> Mineral group

Betafite is a mineral group in the pyrochlore supergroup, with the chemical formula (Ca,U)2(Ti,Nb,Ta)2O6(OH). Betafite typically occurs as a primary mineral in granite pegmatites, rarely in carbonatites. Originally defined by the B-site atom Ti, the development of new nomenclature for mineral names led to modernization of the system for nomenclature of pyrochlore and betafite in order to further rationalize the naming process of this grouping of minerals. Only two of the mineral species that were formerly recognized as betafite are presently retained. They are oxyuranobetafite and oxycalciobetafite. The term betafite is now a synonym or varietal group name under the pyrochlore super group.

<span class="mw-page-title-main">Gedrite</span>

Gedrite is a crystal belonging to the orthorhombic ferromagnesian subgroup of the amphibole supergroup of the double chain inosilicate minerals with the ideal chemical formula Mg2(Mg3Al2)(Si6Al2)O22(OH)2.

<span class="mw-page-title-main">Zaklodzie meteorite</span> Meteorite found in Poland

The Zakłodzie meteorite is a stony-iron meteorite found in Poland in 1998. Its mass is 8.68 kilograms (19.1 lb). It is composed predominantly from enstatite and meteoric iron. Currently classified as an ungrouped enstatite achondrite its classification is still an ongoing scientific debate.

<span class="mw-page-title-main">Gugiaite</span>

Gugiaite is a melilite mineral, named for the Chinese village of Gugia where it was first discovered. Its chemical formula is Ca2BeSi2O7. It occurs mostly in skarns with melanite adjacent to an alkali syenite and has no economic value. Its crystals are small tetragonal tablets with vitreous luster and perfect cleavage. It is colorless and transparent with a density of three. The mineral belongs to space group P421m and is strongly piezoelectric.

<span class="mw-page-title-main">Ferrogedrite</span> Amphibole, double chain inosilicate mineral

Ferrogedrite is an amphibole mineral with the complex chemical formula of ☐Fe2+2(Fe2+3Al2)(Si6Al2)O22(OH)2. It is sodium and calcium poor, making it part of the magnesium-iron-manganese-lithium amphibole subgroup. Defined as less than 1.00 apfu (atoms per formula unit) of Na + Ca and consisting of greater than 1.00 apfu of (Mg, Fe2+, Mn2+, Li) separating it from the calcic-sodic amphiboles. It is related to anthophyllite amphibole and gedrite through coupled substitution of (Al, Fe3+) for (Mg, Fe2+, Mn) and Al for Si. and determined by the content of silicon in the standard cell.

Rockbridgeite is an anhydrous phosphate mineral in the "Rockbridgeite" supergroup with the chemical formula Fe2+Fe3+4(PO4)3(OH)5. It was discovered at the since-shut-down Midvale Mine in Rockbridge County, Virginia, United States. The researcher who first identified it, Clifford Frondel, named it in 1949 for its region of discovery, Rockbridge County.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Edenite Handbook of Mineralogy
  3. 1 2 Edenite on Mindat.org
  4. 1 2 Edenite on Webmineral
  5. IMA Master List
  6. 1 2 Oberti, R.; Cámara, F.; Della Ventura, G.; Iezzi, G. & Benimoff, A.I. (2006). "Parvo-mangano-edenite, parvo-manganotremolite, and the solid solution between Ca and Mn2+ at the M4 site in amphiboles" (PDF). American Mineralogist. 91 (4): 526–532. Bibcode:2006AmMin..91..526O. doi:10.2138/am.2006.1905. S2CID   55824304.
  7. Yang, J. (2003). "Relict edenite in a garnet lherzolite from the Chinese Su-Lu UHP metamorphic terrane: Implications for metamorphic history" (PDF). American Mineralogist. 88 (1): 180–188. Bibcode:2003AmMin..88..180Y. doi:10.2138/am-2003-0121. S2CID   133200002. Archived from the original (PDF) on 2012-03-29.
  8. Oberti, R.; Hawthorne, F.C.; Cannillo, E. & Cámara, F. (2007). "Long-Range Order in Amphiboles". Reviews in Mineralogy and Geochemistry. 67 (1): 125–171. Bibcode:2007RvMG...67..125O. doi:10.2138/rmg.2007.67.4.
  9. Oberti, R.; Della Ventura, G. & Cámara, F. (2007). "New Amphibole Compositions: Natural and Synthetic". Reviews in Mineralogy and Geochemistry. 67 (1): 89–124. Bibcode:2007RvMG...67...89O. doi:10.2138/rmg.2007.67.3.
  10. Klein, C., and Dutrow, B. (2007) The 23rd Edition of the Manual of Mineral Science, John Wiley and Sons, Inc. Hoboken, New Jersey, U.S.