In organometallic chemistry, extended metal atom chains (EMACs) are molecules that consist of a linear chain of directly bonded metal atoms, surrounded by organic ligands. These compounds represent the smallest molecular wires. Such species are researched for the bottom-up approach to nanoelectronics, although no applications are near term. [1]
An EMAC molecule contains a linear string of transition metals (typically Cr, Co, Ni, or Cu) that are bonded to each other and surrounded helically by organic ligands. The metal chains are usually end-capped by anions, usually halides. The organic ligands often pyridylamide, pyridone, naphthyridine, or their derivatives. Each metal atom is six-coordinate, bonded to two other metals along the axis of the molecule (except terminal metals, which are bonded to one metal and one capping anion) and to four nitrogen atoms perpendicular to the axis.
The organic ligands template the formation of the chains by bringing the metal ions together and aligning them into a linear string. The number of nitrogen atoms in the ligand determines the number of metal atoms that will be incorporated into the chain. Thus, the synthesis yields molecular wires of predetermined length. This feature, in combination with the fact that the molecules have well-defined ends, differentiates EMACs from other kinds of molecular wires: EMACs exist only as distinct molecular entities, they do not aggregate and they do not form periodic structures of repeating units.
Most known EMACs contain from three to nine metal atoms. The longest EMACs that have been constructed so far incorporate eleven Ni atoms and have a length of approximately 2 nanometers, although it is estimated that chains with up to 17 metal atoms (4-5 nanometers) could be accessed with currently available ligands. [3]
In contrast with EMACs, linear chain compounds are infinite in length. They are not terminated with capping ligands.
The first EMACs with three metal atoms were synthesized in the early 1990s independently by the groups of Shie-Ming Peng (NTU) and F. Albert Cotton (Texas A&M), who coined the term extended metal atom chains. The cobalt-containing molecule Co3(dpa)4Cl2 (dpa = 2,2'-dipyridylamide) was synthesized by both research groups, but each proposed a different structure: the group from Taiwan reported an unsymmetric structure with a long and a short Co-Co bond, whereas the Texas group identified a symmetric structure with equal Co-Co bond lengths. This disagreement sparked a controversy that lasted for years, until it was realized that both forms of the molecule actually exist simultaneously. While this debate led to the realization that the compound can be used as a molecular switch, it also created a new problem since none of the recognized types of isomerism could explain the existence of a molecule in two structural forms that differ only in the length of one or more bonds (and not in their stereochemistry or connectivity of the atoms). The problem was finally resolved through a quantum chemical study by Pantazis and McGrady, who showed that the two structural forms result from different electronic configurations. [4] The Pantazis-McGrady model is currently used to understand the different electronic states and interpret the magnetic properties of EMACs.
EMACs have no commercial applications, but they are of potential use as electrical conductors in nanocircuits. Moreover, conductance can be controlled and fine-tuned by oxidation or reduction of the metal chain, opening the way for the construction of molecular rheostats, switches, and transistors. These possibilities have been demonstrated:
In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and plus (+) and minus (−) signs. These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a chemical name, and it contains no words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulae can fully specify the structure of only the simplest of molecules and chemical substances, and are generally more limited in power than chemical names and structural formulae.
A coordination complex consists of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents. Many metal-containing compounds, especially those that include transition metals, are coordination complexes.
Inorganic chemistry deals with synthesis and behavior of inorganic and organometallic compounds. This field covers chemical compounds that are not carbon-based, which are the subjects of organic chemistry. The distinction between the two disciplines is far from absolute, as there is much overlap in the subdiscipline of organometallic chemistry. It has applications in every aspect of the chemical industry, including catalysis, materials science, pigments, surfactants, coatings, medications, fuels, and agriculture.
In coordination chemistry, a ligand is an ion or molecule that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's electron pairs often through Lewis Bases. The nature of metal–ligand bonding can range from covalent to ionic. Furthermore, the metal–ligand bond order can range from one to three. Ligands are viewed as Lewis bases, although rare cases are known to involve Lewis acidic "ligands".
In chemistry, catenation is the bonding of atoms of the same element into a series, called a chain. A chain or a ring shape may be open if its ends are not bonded to each other, or closed if they are bonded in a ring. The words to catenate and catenation reflect the Latin root catena, "chain".
The skeletal formula, or line-angle formula or shorthand formula, of an organic compound is a type of molecular structural formula that serves as a shorthand representation of a molecule's bonding and some details of its molecular geometry. A skeletal formula shows the skeletal structure or skeleton of a molecule, which is composed of the skeletal atoms that make up the molecule. It is represented in two dimensions, as on a piece of paper. It employs certain conventions to represent carbon and hydrogen atoms, which are the most common in organic chemistry.
Valence shell electron pair repulsion (VSEPR) theory, is a model used in chemistry to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms. It is also named the Gillespie-Nyholm theory after its two main developers, Ronald Gillespie and Ronald Nyholm.
Cyanate is an anion with the structural formula [O=C=N]−, usually written OCN−. It also refers to any salt containing it, such as ammonium cyanate.
In chemistry, a trigonal bipyramid formation is a molecular geometry with one atom at the center and 5 more atoms at the corners of a triangular bipyramid. This is one geometry for which the bond angles surrounding the central atom are not identical, because there is no geometrical arrangement with five terminal atoms in equivalent positions. Examples of this molecular geometry are phosphorus pentafluoride, and phosphorus pentachloride in the gas phase.
A quintuple bond in chemistry is an unusual type of chemical bond, first reported in 2005 for a dichromium compound. Single bonds, double bonds, and triple bonds are commonplace in chemistry. Quadruple bonds are rarer but are currently known only among the transition metals, especially for Cr, Mo, W, and Re, e.g. [Mo2Cl8]4− and [Re2Cl8]2−. In a quintuple bond, ten electrons participate in bonding between the two metal centers, allocated as σ2π4δ4.
In a tetrahedral molecular geometry, a central atom is located at the center with four substituents that are located at the corners of a tetrahedron. The bond angles are cos−1(−1⁄3) = 109.4712206...° ≈ 109.5° when all four substituents are the same, as in methane as well as its heavier analogues. Methane and other perfectly symmetrical tetrahedral molecules belong to point group Td, but most tetrahedral molecules have lower symmetry. Tetrahedral molecules can be chiral.
A coordination polymer is an inorganic or organometallic polymer structure containing metal cation centers linked by ligands. More formally a coordination polymer is a coordination compound with repeating coordination entities extending in 1, 2, or 3 dimensions.
In coordination chemistry, hapticity is the coordination of a ligand to a metal center via an uninterrupted and contiguous series of atoms. The hapticity of a ligand is described with the Greek letter η ('eta'). For example, η2 describes a ligand that coordinates through 2 contiguous atoms. In general the η-notation only applies when multiple atoms are coordinated. In addition, if the ligand coordinates through multiple atoms that are not contiguous then this is considered denticity, and the κ-notation is used once again. When naming complexes care should be taken not to confuse η with μ ('mu'), which relates to bridging ligands.
Metal nitrosyl complexes are complexes that contain nitric oxide, NO, bonded to a transition metal. Many kinds of nitrosyl complexes are known, which vary both in structure and coligand.
Molecular wires are molecular chains that conduct electric current. They are the proposed building blocks for molecular electronic devices. Their typical diameters are less than three nanometers, while their lengths may be macroscopic, extending to centimeters or more.
An electronic effect influences the structure, reactivity, or properties of molecule but is neither a traditional bond nor a steric effect. In organic chemistry, the term stereoelectronic effect is also used to emphasize the relation between the electronic structure and the geometry (stereochemistry) of a molecule.
Molecular scale electronics, also called single-molecule electronics, is a branch of nanotechnology that uses single molecules, or nanoscale collections of single molecules, as electronic components. Because single molecules constitute the smallest stable structures imaginable, this miniaturization is the ultimate goal for shrinking electrical circuits.
Emac, Emacs or similar may refer to:-
1,8-Naphthyridine is an organic compound with the formula C8H6N2. It is the most well-studied of the six isomeric naphthyridines, a subset of diazanaphthalenes with nitrogen in the separate rings. Enoxacin, nalidixic acid, and trovafloxacin are 1,8-naphthyridine derivatives with antibacterial properties related to the fluoroquinolones.
In chemistry and materials science, linear chain compounds are materials composed of one-dimensional arrays of metal-metal bonded molecules or ions. Such materials exhibit anisotropic electrical conductivity.