Filipstadite

Last updated
Filipstadite
General
Category Oxide mineral
Formula
(repeating unit)
(Mn,Mg)(Sb5+0.5Fe3+0.5)O4
IMA symbol Fps [1]
Strunz classification 4.BB.05 (10 ed)
4/B.05-70 (8 ed)
Dana classification7.2.13.1
Crystal system Isometric
Crystal class Hexoctahedral (m3m)
H–M Symbol (4/m 3 2/m)
Space group Fd3m
Unit cell a = 25.93 Å (approximated); Z = 216
Identification
ColorBlack
Crystal habit modified (pseudo)octahedra
Twinning Poor
Fracture Conchoidal
Tenacity Brittle
Mohs scale hardness6-6.5
Luster Metallic
Streak Brown
Density 4.9 (calculated)
Optical propertiesBiaxal
References [2] [3] [4]

Filipstadite is a very rare mineral [4] of the spinel group, with the formula (Mn,Mg)(Sb5+0.5Fe3+0.5)O4. [5] It is isometric, [3] although it was previously thought to be orthorhombic. When compared to a typical spinel, both the octahedral and tetrahedral sites are split due to cation ordering. [3] Filipstadite is chemically close to melanostibite. [6] The mineral comes from Långban, Sweden, a manganese skarn deposit famous for many rare minerals. [7]

Contents

Occurrence and association

In the metamorphic Fe-Mn ore bodies of the Långban-type filipstadite associates with native antimony, calcite, native copper, forsterite, hausmannite, hedyphane, ingersonite, jacobsite, phlogopite, and svabite. [2]

Notes on crystal structure

Cations and anions in filipstadite occupy 18 of the octahedral and 12 of the tetrahedral holes of the spinel-type oxygen lattice, that has cubic close-packing. Tetrahedral sites are split into 5, and octahedral into 6 substitutes, due to cation ordering, which also causes the unit cell edge to be tripled. Antimony, most of magnesium and trace aluminium are located on the octahedral (M) sites, trace magnesium, zinc and silicon are on the tetrahedral (T) sites. Manganese and iron are on both M and T sites. [3]

Related Research Articles

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<span class="mw-page-title-main">Kutnohorite</span> Mineral of calcium manganese carbonate

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<span class="mw-page-title-main">Richterite</span> Sodium amphibole mineral

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Arsenoclasite (originally arsenoklasite) is a red or dark orange brown mineral with formula Mn5(AsO4)2(OH)4. The name comes from the Greek words αρσενικόν (for arsenic) and κλάσις (for cleavage), as arsenoclasite contains arsenic and has perfect cleavage. The mineral was discovered in 1931 in Långban, Sweden.

The spinels are any of a class of minerals of general formulation AB
2
X
4
which crystallise in the cubic (isometric) crystal system, with the X anions arranged in a cubic close-packed lattice and the cations A and B occupying some or all of the octahedral and tetrahedral sites in the lattice. Although the charges of A and B in the prototypical spinel structure are +2 and +3, respectively, other combinations incorporating divalent, trivalent, or tetravalent cations, including magnesium, zinc, iron, manganese, aluminium, chromium, titanium, and silicon, are also possible. The anion is normally oxygen; when other chalcogenides constitute the anion sublattice the structure is referred to as a thiospinel.

Hiärneite is an oxide mineral named after the Swedish geologist Urban Hiärne (1641–1727). The mineral can be found in rocks that mainly consists of fine grained phlogopite. Hiärneite is the first known mineral that contains both of the chemical elements antimony and zirconium. The mineral was described in 1997 for its occurrence in a skarn environment in Långban iron–manganese deposit of the Filipstad district, Värmland, Sweden.

<span class="mw-page-title-main">Brokenhillite</span>

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<span class="mw-page-title-main">Raslakite</span>

Raslakite is a rare mineral of the eudialyte group with the chemical formula Na15Ca3Fe3(Na,Zr)3Zr3(Si,Nb)SiO(Si9O27)2(Si3O9)2(OH,H2O)3(Cl,OH). This formula is based on the original one, and is extended to show the presence of cyclic silicate groups. The additional silicon and oxygen shown in separation from the cyclic groups are in fact connected with two 9-fold rings. The mineral has lowered symmetry, similarly to some other eudialyte-group members: aqualite, labyrinthite, oneillite and voronkovite. The specific feature of raslakite is, among others, the presence of sodium and zirconium at the M2 site. Raslakite was named after Raslak Cirques located nearby the type locality.

Arakiite (IMA symbol: Ark) is a rare mineral with the formula (Zn,Mn2+)(Mn2+,Mg)12(Fe3+,Al)2(As3+O3)(As5+O4)2(OH)23. It is both arsenate and arsenite mineral, a combination that is rare in the world of minerals. Arakiite is stoichiometrically similar to hematolite. It is one of many rare minerals coming from the famous Långban manganese skarn deposit in Sweden. Other minerals bearing both arsenite and zinc include kraisslite and mcgovernite.

<span class="mw-page-title-main">Miguelromeroite</span> Pale pink mineral - synthetic compound

Miguelromeroite is a mineral named for Miguel Romero Sanchez by Anthony Robert Kampf. The mineral, first described in 2008 was named in 2009, the same year it got approved by the International Mineralogical Association.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 "Filipstadite - Handbook of Mineralogy" (PDF). Handbookofmineralogy.org. Retrieved 2016-03-12.
  3. 1 2 3 4 Bonazzi, P., Chelazzi, L., and Bindi, L., 2013. Superstructure, crystal chemistry, and cation distribution in filipstadite, a Sb5+-bearing, spinel-related mineral. American Mineralogist 98, 361-366
  4. 1 2 "Filipstadite: Filipstadite mineral information and data". Mindat.org. Retrieved 2016-03-05.
  5. Dunn, P.J., Peacor, D.R., Criddle, A.J., and Stanley, C.J., 1988. Filipstadite, a new Mn-Fe3+-Sb derivative of spinel, from Långban, Sweden. American Mineralogist 73, 413-419.
  6. "Melanostibite: Melanostibite mineral information and data". Mindat.org. Retrieved 2016-03-10.
  7. "Långban, Filipstad, Värmland, Sweden - Mindat.org". Mindat.org. Retrieved 2016-03-10.