Glauberite

Last updated
Glauberite
Glauberite-172284.jpg
Glauberite crystal group from the Bertram Siding Sulfate deposit, Imperial County, California
General
Category Sulfate minerals, anhydrous sulfate subgroup
Formula
(repeating unit)
Na2Ca(SO4)2
IMA symbol Glb [1]
Strunz classification 7.AD.25
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group C2/c
Unit cell a = 10.129, b = 8.306
c = 8.533 [Å]; β = 112.19°; Z = 4
Identification
ColorGray or pale yellow, colorless
Crystal habit Tabular prismatic crystals
Cleavage Perfect on {001}, imperfect on {110}
Fracture Conchoidal
Tenacity Brittle
Mohs scale hardness2.5–3
Luster Vitreous to waxy, pearly on cleavages
Streak White
Diaphaneity Transparent to translucent
Specific gravity 2.75–2.85
Optical propertiesBiaxial (−)
Refractive index nα = 1.507 – 1.515 nβ = 1.527 – 1.535 nγ = 1.529 – 1.536
Birefringence δ = 0.022
2V angle 24° to 34°
Dispersion strong r > v
Solubility HCl and H2O (water) soluble
Alters toreadily alters to gypsum
Other characteristicsoften a pseudomorph
References [2] [3] [4]

Glauberite is a monoclinic sodium calcium sulfate mineral with the formula Na 2 Ca(S O 4)2.

It was first described in 1808 for material from the El Castellar Mine, Villarrubia de Santiago, Toledo, Castile-La Mancha, Spain. It was named for the extracted Glauber's salts after the German alchemist Johann Rudolf Glauber (1604–1668). [2]

Glauberite often forms in continental and marine evaporite deposits, but may also form from hydrothermal deposits, as mineral sublimates deposited near fumaroles, in amygdules in basalt, and in nitrate deposits in arid climates. It occurs associated with halite, polyhalite, anhydrite, gypsum, thenardite, mirabilite, sassolite and blodite. [4]

Because of its solubility, glauberite is often dissolved away from the crystal matrix leaving a distinctly shaped hollow cast. Its mineral composition is readily altered into other minerals as pseudomorphs. Gypsum pseudomorphs are common due to increased humidity.

Glauberite, its cast impressions, and its pseudomorphed crystals are often easily recognizable due to its common crystal twinning, and crystal habit displayed by uniquely shaped flattened, often seeming rhombohedral, large individual 'floater crystals'.

The mineral is commercially mined for its sulfate contents. [5]

Related Research Articles

<span class="mw-page-title-main">Gypsum</span> Soft calcium sulfate mineral

Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO4·2H2O. It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk chalk. Gypsum also crystallizes as translucent crystals of selenite. It forms as an evaporite mineral and as a hydration product of anhydrite. The Mohs scale of mineral hardness defines gypsum as hardness value 2 based on scratch hardness comparison.

<span class="mw-page-title-main">Pyrite</span> Iron (II) disulfide mineral

The mineral pyrite ( PY-ryte), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula FeS2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.

<span class="mw-page-title-main">Celestine (mineral)</span> Sulfate mineral

Celestine (the IMA-accepted name) or celestite is a mineral consisting of strontium sulfate (SrSO4). The mineral is named for its occasional delicate blue color. Celestine and the carbonate mineral strontianite are the principal sources of the element strontium, commonly used in fireworks and in various metal alloys.

<span class="mw-page-title-main">Goethite</span> Iron(III) oxide-hydroxide named in honor to the poet Goethe

Goethite is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the α-polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient times for its use as a pigment. Evidence has been found of its use in paint pigment samples taken from the caves of Lascaux in France. It was first described in 1806 based on samples found in the Hollertszug Mine in Herdorf, Germany. The mineral was named after the German polymath and poet Johann Wolfgang von Goethe (1749–1832).

<span class="mw-page-title-main">Evaporite</span> Water-soluble mineral deposit formed by evaporation from an aqueous solution

An evaporite is a water-soluble sedimentary mineral deposit that results from concentration and crystallization by evaporation from an aqueous solution. There are two types of evaporite deposits: marine, which can also be described as ocean deposits, and non-marine, which are found in standing bodies of water such as lakes. Evaporites are considered sedimentary rocks and are formed by chemical sediments.

<span class="mw-page-title-main">Halite</span> Mineral form of sodium chloride

Halite, commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride (NaCl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, pink, red, orange, yellow or gray depending on inclusion of other materials, impurities, and structural or isotopic abnormalities in the crystals. It commonly occurs with other evaporite deposit minerals such as several of the sulfates, halides, and borates. The name halite is derived from the Ancient Greek word for "salt", ἅλς (háls).

<span class="mw-page-title-main">Selenite (mineral)</span> Mineral variety of gypsum

Selenite, satin spar, desert rose, and gypsum flower are crystal habit varieties of the mineral gypsum.

<span class="mw-page-title-main">Chalcocite</span> Sulfide mineral

Chalcocite, copper(I) sulfide (Cu2S), is an important copper ore mineral. It is opaque and dark gray to black, with a metallic luster. It has a hardness of 2.5–3 on the Mohs scale. It is a sulfide with a monoclinic crystal system.

<span class="mw-page-title-main">Anhydrite</span> Mineral, anhydrous calcium sulfate

Anhydrite, or anhydrous calcium sulfate, is a mineral with the chemical formula CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the orthorhombic barium (baryte) and strontium (celestine) sulfates, as might be expected from the chemical formulas. Distinctly developed crystals are somewhat rare, the mineral usually presenting the form of cleavage masses. The Mohs hardness is 3.5, and the specific gravity is 2.9. The color is white, sometimes greyish, bluish, or purple. On the best developed of the three cleavages, the lustre is pearly; on other surfaces it is glassy. When exposed to water, anhydrite readily transforms to the more commonly occurring gypsum, (CaSO4·2H2O) by the absorption of water. This transformation is reversible, with gypsum or calcium sulfate hemihydrate forming anhydrite by heating to around 200 °C (400 °F) under normal atmospheric conditions. Anhydrite is commonly associated with calcite, halite, and sulfides such as galena, chalcopyrite, molybdenite, and pyrite in vein deposits.

<span class="mw-page-title-main">Thénardite</span> Anhydrous sodium sulfate mineral

Thénardite is an anhydrous sodium sulfate mineral, Na2SO4 which occurs in arid evaporite environments, specifically lakes and playas. It also occurs in dry caves and old mine workings as an efflorescence and as a crusty sublimate deposit around fumaroles. It occurs in volcanic caves on Mount Etna, Italy. It was first described in 1825 for an occurrence in the Espartinas Saltworks, Ciempozuelos, Madrid, Spain and was named for the French chemist, Louis Jacques Thénard (1777–1826).

<span class="mw-page-title-main">Mirabilite</span> Decahydrated sodium sulfate mineral

Mirabilite, also known as Glauber's salt, is a hydrous sodium sulfate mineral with the chemical formula Na2SO4·10H2O. It is a vitreous, colorless to white monoclinic mineral that forms as an evaporite from sodium sulfate-bearing brines. It is found around saline springs and along saline playa lakes. Associated minerals include gypsum, halite, thenardite, trona, glauberite, and epsomite.

<span class="mw-page-title-main">Brochantite</span> Copper sulfate mineral

Brochantite is a sulfate mineral, one of a number of cupric sulfates. Its chemical formula is Cu4SO4(OH)6. Formed in arid climates or in rapidly oxidizing copper sulfide deposits, it was named by Armand Lévy for his fellow Frenchman, geologist and mineralogist A. J. M. Brochant de Villiers.

<span class="mw-page-title-main">Leadhillite</span> Lead sulfate carbonate hydroxide mineral

Leadhillite is a lead sulfate carbonate hydroxide mineral, often associated with anglesite. It has the formula Pb4SO4(CO3)2(OH)2. Leadhillite crystallises in the monoclinic system, but develops pseudo-hexagonal forms due to crystal twinning. It forms transparent to translucent variably coloured crystals with an adamantine lustre. It is quite soft with a Mohs hardness of 2.5 and a relatively high specific gravity of 6.26 to 6.55.

<span class="mw-page-title-main">Howlite</span>

Howlite, a calcium borosilicate hydroxide (Ca2B5SiO9(OH)5), is a borate mineral found in evaporite deposits.

Mosesite is a very rare mineral found in few locations. It is a mercury mineral found as an accessory in deposits of mercury, often in conjunction with limestone. It is known to be found in the U.S. states of Texas and Nevada, and the Mexican states of Guerrero and Querétaro. It was named after Professor Alfred J. Moses (1859–1920) for his contributions to the field of mineralogy in discovering several minerals found alongside mosesite. The mineral itself is various shades of yellow and a high occurrence of spinel twinning. It becomes isotropic when heated to 186 °C (367 °F).

<span class="mw-page-title-main">Duftite</span> Arsenate mineral

Duftite is a relatively common arsenate mineral with the formula CuPb(AsO4)(OH), related to conichalcite. It is green and often forms botryoidal aggregates. It is a member of the adelite-descloizite Group, Conichalcite-Duftite Series. Duftite and conichalcite specimens from Tsumeb are commonly zoned in color and composition. Microprobe analyses and X-ray powder-diffraction studies indicate extensive substitution of Zn for Cu, and Ca for Pb in the duftite structure. This indicates a solid solution among conichalcite, CaCu(AsO4 )(OH), austinite, CaZn(AsO4)(OH) and duftite PbCu(AsO4)(OH), all of them belonging to the adelite group of arsenates. It was named after Mining Councilor G Duft, Director of the Otavi Mine and Railroad Company, Tsumeb, Namibia. The type locality is the Tsumeb Mine, Tsumeb, Otjikoto Region, Namibia.

<span class="mw-page-title-main">Campigliaite</span>

Campigliaite is a copper and manganese sulfate mineral with a chemical formula of Cu4Mn(SO4)2(OH)6·4H2O. It has a chemical formula and also a crystal structure similar to niedermayrite, with Cd(II) cation replacing by Mn(II). The formation of campigliaite is related to the oxidation of sulfide minerals to form sulfate solutions with ilvaite associated with the presence of manganese. Campigliaite is a rare secondary mineral formed when metallic sulfide skarn deposits are oxidized. While there are several related associations, there is no abundant source for this mineral due to its rare process of formation. Based on its crystallographic data and chemical formula, campigliaite is placed in the devillite group and considered the manganese analogue of devillite. Campigliaite belongs to the copper oxysalt minerals as well followed by the subgroup M=M-T sheets. The infinite sheet structures that campigliaite has are characterized by strongly bonded polyhedral sheets, which are linked in the third dimension by weaker hydrogen bonds.

<span class="mw-page-title-main">Leightonite</span>

Leightonite is a rare sulfate mineral with formula of K2Ca2Cu(SO4)4•2H2O.

<span class="mw-page-title-main">Syngenite</span>

Syngenite is an uncommon potassium calcium sulfate mineral with formula K2Ca(SO4)2·H2O. It forms as prismatic monoclinic crystals and as encrustations.

<span class="mw-page-title-main">Rampghill mine</span>

Rampgill mine is a disused lead mine at Nenthead, Alston Moor, Cumbria, England UK Grid Reference: NY78184351

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 Glauberite on Mindat
  3. Glauberite data on Webmineral
  4. 1 2 Glauberite in the Handbook of Mineralogy
  5. Chen, Shuzhao; Zhang, Donghua; Shang, Tao; Meng, Tao (August 2018). "Experimental Study of the Microstructural Evolution of Glauberite and Its Weakening Mechanism under the Effect of Thermal-Hydrological-Chemical Coupling". Processes. 6 (8): 99. doi: 10.3390/pr6080099 .