Hardenability is the depth to which a steel is hardened after putting it through a heat treatment process. It should not be confused with hardness, which is a measure of a sample's resistance to indentation or scratching. [1] It is an important property for welding, since it is inversely proportional to weldability, that is, the ease of welding a material.
When a hot steel work-piece is quenched, the area in contact with the water immediately cools and its temperature equilibrates with the quenching medium. The inner depths of the material however, do not cool so rapidly, and in work-pieces that are large, the cooling rate may be slow enough to allow the austenite to transform fully into a structure other than martensite or bainite. This results in a work-piece that does not have the same crystal structure throughout its entire depth; with a softer core and harder "shell". [2] The softer core is some combination of ferrite and cementite, such as pearlite.
The hardenability of ferrous alloys, i.e. steels, is a function of the carbon content and other alloying elements and the grain size of the austenite. [1] The relative importance of the various alloying elements is calculated by finding the equivalent carbon content of the material.
The fluid used for quenching the material influences the cooling rate due to varying thermal conductivities and specific heats. Substances like brine and water cool the steel much more quickly than oil or air. If the fluid is agitated cooling occurs even more quickly. The geometry of the part also affects the cooling rate: of two samples of equal volume, the one with higher surface area will cool faster. [3]
The hardenability of a ferrous alloy is measured by a Jominy test: a round metal bar of standard size (indicated in the top image) is transformed to 100% austenite through heat treatment, and is then quenched on one end with room-temperature water. The cooling rate will be highest at the end being quenched, and will decrease as distance from the end increases. Subsequent to cooling a flat surface is ground on the test piece and the hardenability is then found by measuring the hardness along the bar. The farther away from the quenched end that the hardness extends, the higher the hardenability. This information is plotted on a hardenability graph. [4] [5] [6]
The Jominy end-quench test was invented by Walter E. Jominy (1893-1976) and A.L. Boegehold, [7] metallurgists in the Research Laboratories Division of General Motors Corp., in 1937. For his pioneering work in heat treating, Jominy was recognized by the American Society for Metals (ASM) with its Albert Sauveur Achievement Award in 1944. Jominy served as president of ASM in 1951.
Stainless steel, also known as inox, corrosion-resistant steel (CRES), or Rustless steel, is an alloy of iron that is resistant to rusting and corrosion. It contains at least 10.5% chromium and usually nickel, and may also contain other elements, such as carbon, to obtain the desired properties. Stainless steel's resistance to corrosion results from the chromium, which forms a passive film that can protect the material and self-heal in the presence of oxygen.
Differential heat treatment is a technique used during heat treating of steel to harden or soften certain areas of an object, creating a difference in hardness between these areas. There are many techniques for creating a difference in properties, but most can be defined as either differential hardening or differential tempering. These were common heat treatment techniques used historically in Europe and Asia, with possibly the most widely known example being from Japanese swordsmithing. Some modern varieties were developed in the twentieth century as metallurgical knowledge and technology rapidly increased.
Heat treating is a group of industrial, thermal and metalworking processes used to alter the physical, and sometimes chemical, properties of a material. The most common application is metallurgical. Heat treatments are also used in the manufacture of many other materials, such as glass. Heat treatment involves the use of heating or chilling, normally to extreme temperatures, to achieve the desired result such as hardening or softening of a material. Heat treatment techniques include annealing, case hardening, precipitation strengthening, tempering, carburizing, normalizing and quenching. Although the term heat treatment applies only to processes where the heating and cooling are done for the specific purpose of altering properties intentionally, heating and cooling often occur incidentally during other manufacturing processes such as hot forming or welding.
Austenite, also known as gamma-phase iron (γ-Fe), is a metallic, non-magnetic allotrope of iron or a solid solution of iron with an alloying element. In plain-carbon steel, austenite exists above the critical eutectoid temperature of 1000 K (727 °C); other alloys of steel have different eutectoid temperatures. The austenite allotrope is named after Sir William Chandler Roberts-Austen (1843–1902); it exists at room temperature in some stainless steels due to the presence of nickel stabilizing the austenite at lower temperatures.
Martensitic stainless steel is a type of stainless steel alloy that has a martensite crystal structure. It can be hardened and tempered through aging and heat treatment. The other main types of stainless steel are austenitic, ferritic, duplex, and precipitation hardened.
Carbon steel is a steel with carbon content from about 0.05 up to 2.1 percent by weight. The definition of carbon steel from the American Iron and Steel Institute (AISI) states:
In materials science, quenching is the rapid cooling of a workpiece in water, oil, polymer, air, or other fluids to obtain certain material properties. A type of heat treating, quenching prevents undesired low-temperature processes, such as phase transformations, from occurring. It does this by reducing the window of time during which these undesired reactions are both thermodynamically favorable, and kinetically accessible; for instance, quenching can reduce the crystal grain size of both metallic and plastic materials, increasing their hardness.
Carburizing, or carburising, is a heat treatment process in which iron or steel absorbs carbon while the metal is heated in the presence of a carbon-bearing material, such as charcoal or carbon monoxide. The intent is to make the metal harder and more wear resistant. Depending on the amount of time and temperature, the affected area can vary in carbon content. Longer carburizing times and higher temperatures typically increase the depth of carbon diffusion. When the iron or steel is cooled rapidly by quenching, the higher carbon content on the outer surface becomes hard due to the transformation from austenite to martensite, while the core remains soft and tough as a ferritic and/or pearlite microstructure.
Case-hardening or surface hardening is the process of hardening the surface of a metal object while allowing the metal deeper underneath to remain soft, thus forming a thin layer of harder metal at the surface. For iron or steel with low carbon content, which has poor to no hardenability of its own, the case-hardening process involves infusing additional carbon or nitrogen into the surface layer. Case-hardening is usually done after the part has been formed into its final shape, but can also be done to increase the hardening element content of bars to be used in a pattern welding or similar process. The term face hardening is also used to describe this technique, when discussing modern armour.
Tempering is a process of heat treating, which is used to increase the toughness of iron-based alloys. Tempering is usually performed after hardening, to reduce some of the excess hardness, and is done by heating the metal to some temperature below the critical point for a certain period of time, then allowing it to cool in still air. The exact temperature determines the amount of hardness removed, and depends on both the specific composition of the alloy and on the desired properties in the finished product. For instance, very hard tools are often tempered at low temperatures, while springs are tempered at much higher temperatures.
Hardening is a metallurgical metalworking process used to increase the hardness of a metal. The hardness of a metal is directly proportional to the uniaxial yield stress at the location of the imposed strain. A harder metal will have a higher resistance to plastic deformation than a less hard metal.
In metallurgy and materials science, annealing is a heat treatment that alters the physical and sometimes chemical properties of a material to increase its ductility and reduce its hardness, making it more workable. It involves heating a material above its recrystallization temperature, maintaining a suitable temperature for an appropriate amount of time and then cooling.
The SAE steel grades system is a standard alloy numbering system for steel grades maintained by SAE International.
Eglin steel (ES-1) is a high-strength, high-performance, low-alloy, low-cost steel, developed for a new generation of bunker buster type bombs, e.g. the Massive Ordnance Penetrator and the improved version of the GBU-28 bomb known as EGBU-28. It was developed in collaboration between the US Air Force and the Ellwood National Forge Company.
Austempering is heat treatment that is applied to ferrous metals, most notably steel and ductile iron. In steel it produces a bainite microstructure whereas in cast irons it produces a structure of acicular ferrite and high carbon, stabilized austenite known as ausferrite. It is primarily used to improve mechanical properties or reduce / eliminate distortion. Austempering is defined by both the process and the resultant microstructure. Typical austempering process parameters applied to an unsuitable material will not result in the formation of bainite or ausferrite and thus the final product will not be called austempered. Both microstructures may also be produced via other methods. For example, they may be produced as-cast or air cooled with the proper alloy content. These materials are also not referred to as austempered.
Microalloyed steel is a type of alloy steel that contains small amounts of alloying elements, including niobium, vanadium, titanium, molybdenum, zirconium, boron, and rare-earth metals. They are used to refine the grain microstructure or facilitate precipitation hardening.
Mangalloy, also called manganese steel or Hadfield steel, is an alloy steel containing an average of around 13% manganese. Mangalloy is known for its high impact strength and resistance to abrasion once in its work-hardened state.
HY-80 is a high-tensile, high yield strength, low alloy steel. It was developed for use in naval applications, specifically the development of pressure hulls for the US nuclear submarine program and is still currently used in many naval applications. It is valued for its strength to weight ratio.
USAF-96 is a high-strength, high-performance, low-alloy, low-cost steel, developed for new generation of bunker buster type bombs, e.g. the Massive Ordnance Penetrator and the improved version of the GBU-28 bomb known as EGBU-28. It was developed by the US Air Force at the Eglin Air Force Munitions Directorate. It uses only materials domestic to the USA. In particular it requires no tungsten.
Abrasion resistant steel is a high-carbon alloy steel that is produced to resist wear and stress. There are several grades of abrasion resistant steel, including AR200, AR235, AR400, AR450, AR500 and AR600.