Carbon dioxide is a chemical compound with the chemical formula CO2. It is made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature, and as the source of available carbon in the carbon cycle, atmospheric CO2 is the primary carbon source for life on Earth. In the air, carbon dioxide is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, and seawater. When carbon dioxide dissolves in water, it forms carbonate and mainly bicarbonate, which causes ocean acidification as atmospheric CO2 levels increase.
Steelmaking is the process of producing steel from iron ore and/or scrap. In steelmaking, impurities such as nitrogen, silicon, phosphorus, sulfur and excess carbon are removed from the sourced iron, and alloying elements such as manganese, nickel, chromium, carbon and vanadium are added to produce different grades of steel.
A fossil fuel power station is a thermal power station which burns a fossil fuel, such as coal, oil, or natural gas, to produce electricity. Fossil fuel power stations have machinery to convert the heat energy of combustion into mechanical energy, which then operates an electrical generator. The prime mover may be a steam turbine, a gas turbine or, in small plants, a reciprocating gas engine. All plants use the energy extracted from the expansion of a hot gas, either steam or combustion gases. Although different energy conversion methods exist, all thermal power station conversion methods have their efficiency limited by the Carnot efficiency and therefore produce waste heat.
Flue gas is the gas exiting to the atmosphere via a flue, which is a pipe or channel for conveying exhaust gases, as from a fireplace, oven, furnace, boiler or steam generator. It often refers to the exhaust gas of combustion at power plants. Technology is available to remove pollutants from flue gas at power plants.
Carbon capture and storage (CCS) is a process in which a relatively pure stream of carbon dioxide (CO2) from industrial sources is separated, treated and transported to a long-term storage location. For example, the burning of fossil fuels or biomass results in a stream of CO2 that could be captured and stored by CCS. Usually the CO2 is captured from large point sources, such as a chemical plant or a bioenergy plant, and then stored in a suitable geological formation. The aim is to reduce greenhouse gas emissions and thus mitigate climate change. For example, CCS retrofits for existing power plants can be one of the ways to limit emissions from the electricity sector and meet the Paris Agreement goals.
An integrated gasification combined cycle (IGCC) is a technology using a high pressure gasifier to turn coal and other carbon based fuels into pressurized gas—synthesis gas (syngas). It can then remove impurities from the syngas prior to the electricity generation cycle. Some of these pollutants, such as sulfur, can be turned into re-usable byproducts through the Claus process. This results in lower emissions of sulfur dioxide, particulates, mercury, and in some cases carbon dioxide. With additional process equipment, a water-gas shift reaction can increase gasification efficiency and reduce carbon monoxide emissions by converting it to carbon dioxide. The resulting carbon dioxide from the shift reaction can be separated, compressed, and stored through sequestration. Excess heat from the primary combustion and syngas fired generation is then passed to a steam cycle, similar to a combined cycle gas turbine. This process results in improved thermodynamic efficiency, compared to conventional pulverized coal combustion.
Douglas Patrick Harrison is a professor emeritus of chemical engineering from Louisiana State University's Gordon A. and Mary Cain Department of Chemical Engineering, where he taught undergraduate and graduate classes and served as a dissertation advisor to Ph.D. and M.S. students.
Oxy-fuel combustion is the process of burning a fuel using pure oxygen, or a mixture of oxygen and recirculated flue gas, instead of air. Since the nitrogen component of air is not heated, fuel consumption is reduced, and higher flame temperatures are possible. Historically, the primary use of oxy-fuel combustion has been in welding and cutting of metals, especially steel, since oxy-fuel allows for higher flame temperatures than can be achieved with an air-fuel flame. It has also received a lot of attention in recent decades as a potential carbon capture and storage technology.
The Virgin Earth Challenge was a competition offering a $25 million prize for whoever could demonstrate a commercially viable design which results in the permanent removal of greenhouse gases out of the Earth's atmosphere to contribute materially in global warming avoidance. The prize was conceived by Richard Branson, and was announced in London on 9 February 2007 by Branson and former US Vice President Al Gore.
A carbon dioxide scrubber is a piece of equipment that absorbs carbon dioxide (CO2). It is used to treat exhaust gases from industrial plants or from exhaled air in life support systems such as rebreathers or in spacecraft, submersible craft or airtight chambers. Carbon dioxide scrubbers are also used in controlled atmosphere (CA) storage. They have also been researched for carbon capture and storage as a means of combating climate change.
Carbon dioxide removal (CDR) is a process in which carbon dioxide is removed from the atmosphere by deliberate human activities and durably stored in geological, terrestrial, or ocean reservoirs, or in products. This process is also known as carbon removal, greenhouse gas removal or negative emissions. CDR is more and more often integrated into climate policy, as an element of climate change mitigation strategies. Achieving net zero emissions will require first and foremost deep and sustained cuts in emissions, and then—in addition—the use of CDR. In the future, CDR may be able to counterbalance emissions that are technically difficult to eliminate, such as some agricultural and industrial emissions.
David W. Keith is a professor in the Department of the Geophysical Sciences at the University of Chicago. He joined the University of Chicago in April 2023. Keith previously served as the Gordon McKay Professor of Applied Physics for Harvard University's Paulson School of Engineering and Applied Sciences (SEAS) and professor of public policy for the Harvard Kennedy School at Harvard University. Early contributions include development of the first atom interferometer and a Fourier-transform spectrometer used by NASA to measure atmospheric temperature and radiation transfer from space.
Carbon-neutral fuel is fuel which produces no net-greenhouse gas emissions or carbon footprint. In practice, this usually means fuels that are made using carbon dioxide (CO2) as a feedstock. Proposed carbon-neutral fuels can broadly be grouped into synthetic fuels, which are made by chemically hydrogenating carbon dioxide, and biofuels, which are produced using natural CO2-consuming processes like photosynthesis.
Christopher W. Jones is an American chemical engineer and researcher on catalysis and carbon dioxide capture. In 2022 he is the John Brock III School Chair and Professor of Chemical & Biomolecular Engineering and adjunct professor of chemistry and biochemistry at the Georgia Institute of Technology, in Atlanta, Georgia. Previously he served as associate vice president for research at Georgia Tech (2013-2019), including a stint as interim executive vice-president for research in 2018.
Carbon Engineering Ltd. is a Canadian-based clean energy company focusing on the commercialization of direct air capture (DAC) technology that captures carbon dioxide directly from the atmosphere.
T. Alan Hatton is the Ralph Landau Professor and the Director of the David H. Koch School of Chemical Engineering Practice at Massachusetts Institute of Technology. As part of the MIT Energy Initiative, he co-directs the Center for Carbon Capture, Utilization and Storage. His work focuses on the development of purification technologies of various kinds for use with air, water, and other substances.
Carbon capture and utilization (CCU) is the process of capturing carbon dioxide (CO2) from industrial processes and transporting it via pipelines to where one intends to use it in industrial processes.
Direct air capture (DAC) is the use of chemical or physical processes to extract carbon dioxide directly from the ambient air. If the extracted CO2 is then sequestered in safe long-term storage, the overall process will achieve carbon dioxide removal and be a "negative emissions technology" (NET).
Sorption enhanced water gas shift (SEWGS) is a technology that combines a pre-combustion carbon capture process with the water gas shift reaction (WGS) in order to produce a hydrogen rich stream from the syngas fed to the SEWGS reactor.
